TWI495683B - 滑動性樹脂組成物及其成形品 - Google Patents
滑動性樹脂組成物及其成形品 Download PDFInfo
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- TWI495683B TWI495683B TW097118992A TW97118992A TWI495683B TW I495683 B TWI495683 B TW I495683B TW 097118992 A TW097118992 A TW 097118992A TW 97118992 A TW97118992 A TW 97118992A TW I495683 B TWI495683 B TW I495683B
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- 239000011342 resin composition Substances 0.000 title claims description 57
- -1 acryloxypropyl groups Chemical group 0.000 claims description 67
- 229920005668 polycarbonate resin Polymers 0.000 claims description 67
- 239000004431 polycarbonate resin Substances 0.000 claims description 67
- 125000003118 aryl group Chemical group 0.000 claims description 53
- 125000004432 carbon atom Chemical group C* 0.000 claims description 34
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 30
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 22
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 21
- 239000003063 flame retardant Substances 0.000 claims description 21
- 229910052783 alkali metal Inorganic materials 0.000 claims description 19
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 19
- 150000003839 salts Chemical class 0.000 claims description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 16
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- 229910019142 PO4 Inorganic materials 0.000 claims description 14
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- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 14
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- 229910052731 fluorine Inorganic materials 0.000 claims description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 11
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- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
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- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 claims description 4
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- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical group OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 claims description 4
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- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims description 3
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 claims description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 3
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 claims description 3
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- RXNYJUSEXLAVNQ-UHFFFAOYSA-N 4,4'-Dihydroxybenzophenone Chemical compound C1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1 RXNYJUSEXLAVNQ-UHFFFAOYSA-N 0.000 claims description 2
- LNNIPFBETXOKIA-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-9h-fluoren-2-yl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC=C(C=2C(=CC=CC=2)C2)C2=C1C1=CC=C(O)C=C1 LNNIPFBETXOKIA-UHFFFAOYSA-N 0.000 claims description 2
- IMHDGJOMLMDPJN-UHFFFAOYSA-N dihydroxybiphenyl Natural products OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 claims description 2
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical compound C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 claims description 2
- QBDSZLJBMIMQRS-UHFFFAOYSA-N p-Cumylphenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=CC=C1 QBDSZLJBMIMQRS-UHFFFAOYSA-N 0.000 claims description 2
- NKTOLZVEWDHZMU-UHFFFAOYSA-N p-cumyl phenol Natural products CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 claims 1
- 238000000034 method Methods 0.000 description 62
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- 239000004810 polytetrafluoroethylene Substances 0.000 description 24
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- 239000004417 polycarbonate Substances 0.000 description 21
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- 239000011347 resin Substances 0.000 description 20
- 239000002253 acid Substances 0.000 description 19
- 238000012360 testing method Methods 0.000 description 17
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- 239000003381 stabilizer Substances 0.000 description 14
- 150000003254 radicals Chemical group 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 10
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 150000001340 alkali metals Chemical class 0.000 description 9
- 238000001746 injection moulding Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 150000002430 hydrocarbons Chemical group 0.000 description 8
- 239000000155 melt Substances 0.000 description 8
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
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- 229910052698 phosphorus Inorganic materials 0.000 description 7
- 239000011574 phosphorus Substances 0.000 description 7
- 229960001755 resorcinol Drugs 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 6
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- 238000005259 measurement Methods 0.000 description 4
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
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- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 3
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 3
- 238000012695 Interfacial polymerization Methods 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
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- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 2
- OPKQAOBTBQLNCB-UHFFFAOYSA-N 4-[10-(4-hydroxyphenyl)anthracen-9-yl]phenol Chemical compound C1=CC(O)=CC=C1C(C1=CC=CC=C11)=C(C=CC=C2)C2=C1C1=CC=C(O)C=C1 OPKQAOBTBQLNCB-UHFFFAOYSA-N 0.000 description 2
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- UIXBHAVMRUOANR-UHFFFAOYSA-N [2,3-bis(2,4-ditert-butylphenyl)phenyl]-phenylphosphinic acid Chemical class C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C=1C(=C(C=CC1)P(O)(=O)C1=CC=CC=C1)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C UIXBHAVMRUOANR-UHFFFAOYSA-N 0.000 description 2
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
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- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/068—Polysiloxanes
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- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
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Description
本發明係有關於一種含有聚碳酸酯樹脂且滑動特性優良之樹脂組成物及由其所形成的成形品。更詳言之,係有關於一種具有耐衝擊性、耐熱性、尺寸安定性等聚碳酸酯樹脂本來的性質,且滑動特性及表面外觀優良之樹脂組成物及使用其所形成的成形品。
因為芳香族聚碳酸酯樹脂具有許多優良的特性,被利用在廣泛的產業領域,藉由射出成形等加工成各式各樣的製品。因為芳香族聚碳酸酯樹脂之尺寸精確度、機械強度及耐熱性優良,在OA機械或電氣、電子機器領域被使用於齒輪等的滑動組件之情況增加。但是,單獨使用聚碳酸酯樹脂時滑動性係不充分。因此,為了改良聚碳酸酯樹脂的滑動性,有各種提案。
例如,有提案(特開平4-136065號公報),揭示在聚碳酸酯樹脂添加聚四氟乙烯、聚烯烴、聚醯胺、聚酯等的樹脂作為滑動性改良劑。在聚碳酸酯樹脂調配聚四氟乙烯樹脂作為滑動性改良劑時,會有成形加工性或衝擊強度降低之情況。又,在聚碳酸酯樹脂添加聚烯烴、聚醯胺、聚酯等時,不僅無法得到充分的滑動性,而且會損害機械強度、耐熱性、難燃性等聚碳酸酯樹脂本來具有的特性。
又,有提案(特開平10-182987號公報、特開平9-316282號公報),揭示在聚碳酸酯樹脂添加聚有機矽氧烷。但是,
無法達到兼具滑動性及耐衝擊性。
又,有提案(特開2000-264935號公報、國際公開第2004/092236小冊子),揭示在聚碳酸酯樹脂添加聚有機矽氧烷系接枝共聚物用以賦予難燃性。該等文獻所記載之聚有機矽氧烷,具有與聚碳酸酯樹脂相溶性不充分之缺點。
又,亦有提案(特開2000-302958號公報),揭示在聚碳酸酯樹脂添加矽油及聚有機矽氧烷。但是矽油會有相分離致使成形品表面容易產生光澤不均之缺點。
又,有提案(特開平5-209129號公報)揭示在聚碳酸酯樹脂添加聚矽氧烷-聚乙烯接枝共聚物用以賦予脫模性。但是,因為添加量太少,滑動性不充分。
因此,本發明之目的係提供一種樹脂組成物,其具有優良的滑動性且能夠維持耐衝擊性、耐熱性、尺寸安定性等聚碳酸酯樹脂的本來特性。又,本發明之目的係提供一種樹脂組成物,其具有優良的滑動性且不容易產生因滑動性改良劑所引起的光澤不均等表面外觀的不良。又,本發明之目的係提供一種樹脂組成物,其具有優良的滑動性且難燃性優良。又,本發明之目的係提供一種成形品,其係由該樹脂組成物所構成。
為了達成上述目的,本發明者等專心研討的結果,發現使芳香族聚碳酸酯樹脂特定量含有特定結構的丙烯酸改性聚有機矽氧烷作為滑動性改良劑(B成分)時,能夠賦予優良的滑動性。又,發現使芳香族聚碳酸酯樹脂特定量含有
滑動性改良劑(B成分)時,不容易與芳香族聚碳酸酯樹脂相分離,成形品表面不容易產生光澤不均。又,發現一旦在芳香族聚碳酸酯樹脂添加滑動性改良劑(B成分),且亦添加有機金屬鹽系阻燃劑(C成分)、有機磷化合物系阻燃劑(D成分)及含氟防滴落劑(E成分)等,能夠得到難燃性優良的樹脂組成物。本發明係基於該等見識。
亦即,本發明係一種樹脂組成物及由該樹脂組成物所構成的成形品,該樹脂組成物之特徵係相對於芳香族聚碳酸酯樹脂(A成分)100重量份,含有3.0~7.0重量份之丙烯酸改性聚有機矽氧烷(B成分),該丙烯酸改性聚有機矽氧烷(B成分)係使由70重量%~100重量%之(甲基)丙烯酸酯(B2-1成分)及0重量%~30重量%之能夠共聚合之其他的單體(B2-2成分)所構成的混合物(B2成分),與下述式(1)所示聚有機矽氧烷(B1成分),以B2成分/B1成分重量比表示時為5/95~95/5的比例接枝共聚合而構成之丙烯酸改性聚有機矽氧烷。
以下,詳細地說明本發明。
在本發明使用作為A成分之芳香族聚碳酸酯樹脂能夠藉由使二元酚與碳酸酯前驅物反應而得到。反應方法的例子可舉出界面聚合法、熔融酯交換法、碳酸酯預聚物的固相酯交換法及環狀碳酸酯化合物的開環聚合法等。
在此所使用的二元酚的代表例,可舉出例如氫醌、間苯二酚、4,4’-雙酚、1,1-雙(4-羥苯基)乙烷、2,2-雙(4-羥苯基)丙烷(俗稱雙酚A,以下有簡稱為BPA之情況)、2,2-雙(4-羥基-3-甲基苯基)丙烷、2,2-雙(4-羥苯基)丁烷、1,1-雙(4-羥苯基)-1-苯基乙烷、1,1-雙(4-羥苯基)環己烷、1,1-雙(4-羥苯基)-3,3,5-三甲基環己烷、2,2-雙(4-羥苯基)戊烷、4,4’-(對伸苯基二異亞丙基)二苯酚、4,4’-(間伸苯基二異亞丙基)二苯酚、1,1-雙(4-羥苯基)-4-異丙基環己烷、雙(4-羥苯基)氧化物、雙(4-羥苯基)硫醚、雙(4-羥苯基)亞碸、雙(4-羥苯基)碸、雙(4-羥苯基)酮、雙(4-羥苯基)酯、雙(4-羥基-3-甲基苯基)硫醚、9,9-雙(4-羥苯基)茀及9,9-雙(4-羥基-3-甲基苯基)茀等。較佳的二元酚為雙(4-羥苯基)鏈烷,其中從耐衝擊性而言,以雙酚A為特佳而被泛用。
在本發明,除了泛用的聚碳酸酯之雙酚A系的聚碳酸酯以外,亦可使用採用其他的二元酚類所製成的特殊聚碳酸酯作為A成分。
例如二元酚成分的一部分或全部係使用4,4'-(間伸苯基二異亞丙基)二苯酚(以下有時簡稱為"BPM")、1,1-雙(4-羥苯基)環己烷、1,1-雙(4-羥苯基)-3,3,5-三甲基環己烷(以下有時簡稱為"Bis-TMC")、9,9-雙(4-羥苯基)茀及9,9-雙(4-羥基-3-甲基苯基)茀(以下有時簡稱為"BCF")而成的聚碳酸酯(同元聚合物或共聚物),適合於對吸水所引起的尺寸變化或形態安定性的要求特別嚴格的用途。此等BPA以外的二元酚的使用量為構成該聚碳酸酯之二元酚成分總體的5莫耳%以上、以10莫耳%以上為特佳。
特別是要求高剛性且更良好的耐加水分解性之情況,構成樹脂組成物的A成分係以下的(1)~(3)的共聚合聚碳酸酯為特佳。
(1)構成該聚碳酸酯的二元酚成分100莫耳%中,BPM為20~80莫耳%(較佳是40~75莫耳%、更佳是45~65莫耳%),且BCF為20~80莫耳%(較佳是25~60莫耳%、更佳是35~55莫耳%)之共聚合聚碳酸酯。
(2)構成該聚碳酸酯的二元酚成分100莫耳%中,BPA為10~95莫耳%(較佳是50~90莫耳%、更佳是60~85莫耳%),且BCF為5~90莫耳%(較佳是10~50莫耳%、更佳是15~40莫耳%)之共聚合聚碳酸酯。
(3)構成該聚碳酸酯的二元酚成分100莫耳%中,BPM為20~80莫耳%(較佳是40~75莫耳%、更佳是45~65莫耳%),
且Bis-TMC為20~80莫耳%(較佳是25~60莫耳%、更佳是35~55莫耳%)之共聚合聚碳酸酯。
此等特殊的聚碳酸酯可單獨使用,亦可適當地混合2種以上而使用。又,亦可將此等與泛用的雙酚A型的聚碳酸酯混合而使用。
此等特殊的聚碳酸酯的製法及特性係例如詳細地記載在特開平6-172508號公報、特開平8-27370號公報、特開2001-55435號公報及特開2002-117580號公報等。
又,在上述的各種聚碳酸酯之中,調整共聚合組成使吸水率及Tg(玻璃轉移溫度)在下述的範圍內而成者,因為聚合物本身的耐加水分解性良好、且成形後的低翹曲性亦特別優良,所以特別適合於要求形態安定性的領域。
(i)吸水率為0.05~0.15%,以0.06~0.13%為佳,且Tg為120~180℃之聚碳酸酯,或是(ii)Tg為160~250℃,以170~230℃為佳,且吸水率為0.10~0-30%,以0.13~0.30%為佳,以為0.14~0.27%更佳之聚碳酸酯。
在此,聚碳酸酯的吸水率係使用直徑為45毫米、厚度為3.0毫米的圓板狀試片,並依據ISO62-1980,測定在23℃的水中浸漬24小時後的水分率所得到的值。又,Tg(玻璃轉移溫度)係依據JIS K7121,藉由測定微差掃描熱量計(DSC)所求得的值。
碳酸酯前驅物可使用碳醯鹵、碳酸二酯或鹵甲酸酯等,具體上可舉出光氣、碳酸二苯酯或二元酚的二鹵甲酸酯等。
將前述二元酚與碳酸酯前驅物藉由界面聚合法來製造芳香族聚碳酸酯樹脂時,亦可按照必要使用觸媒、末端停止劑、用以防止二元酚氧化的抗氧化劑等。又,芳香族聚碳酸酯樹脂包含:共聚合三官能以上的多官能性芳香族化合物而成之分枝聚碳酸酯樹脂;共聚合芳香族或脂肪族(含脂環族)的二官能性羧酸而成之聚酯型聚碳酸酯樹脂;共聚合二官能性醇(含脂環族)而成之共聚合聚碳酸酯樹脂;及同時共聚合如此的二官能性羧酸及二官能性醇而成之聚酯型碳酸酯。又,亦可以是混合2種以上所得到的芳香族聚碳酸酯樹脂而成的混合物。
因為分枝聚碳酸酯樹脂能夠進一步相乘地改良防滴落性能,以使用為佳。此種分枝聚碳酸酯樹脂所使用的三官能以上的多官能性芳香族化合物可舉出根皮三酚、根皮葡酚、或4,6-二甲基-2,4,6-參(4-羥基二苯基)庚烯-2、2,4,6-三甲基-2,4,6-參(4-羥苯基)庚烷、1,3,5-參(4-羥苯基)苯、1,1,1-參(4-羥苯基)乙烷、1,1,1-參(3,5-二甲基-4-羥苯基)乙烷、2,6-雙(2-羥基-5-甲苄基)-4-甲基苯酚、4-{4-[1,1-雙(4-羥苯基)乙基]苯}-α,α-二甲苄基苯酚等的參酚、肆(4-羥苯基)甲烷、雙(2,4-二羥苯基)酮、1,4-雙(4,4-二羥基三苯基甲基)苯、或偏苯三甲酸、焦蜜石酸、二苯基酮四羧酸及此等的酸氯等,其中,以1,1,1-參(4-羥苯基)乙烷、1,1,1-參(3,5-二甲基-4-羥苯基)乙烷為佳,以1,1,1-參(4-羥苯基)乙烷為特佳。
在芳香族聚碳酸酯樹脂總量中,分枝聚碳酸酯樹脂中之多官能性化合物的比率為0.001~1莫耳%,以0.005~0.9
莫耳%為較佳,以0.01~0.8莫耳%為更佳,以0.05~0.4莫耳%為特佳。又,特別是熔融酯交換法時,副反應會有產生分枝結構的情況,在芳香族聚碳酸酯樹脂總量中,如此的分枝結構量以在前述的範圍為佳。又,此種分枝結構量,能夠藉由1
H-NMR測定來算出。
脂肪族的二官能性的羧酸以α,ω-二羧酸為佳。脂肪族的二官能性的羧酸適合舉出例如泌脂酸(癸二酸)、十二烷二酸、十四烷二酸、十八烷二酸、二十碳烷二酸等的直鏈飽和脂肪族二羧酸、及環己烷二羧酸等的脂環族二羧酸為佳。二官能性醇係以脂環族二醇為更佳,可例示例如環己烷二甲醇、環己烷二醇及三環癸烷二甲醇等。
而且,亦能夠使用共聚合聚有機矽氧烷單元而成之聚碳酸酯-聚有機矽氧烷共聚物。
聚碳酸酯樹脂的製法之界面聚合法、熔融酯交換法、碳酸酯預聚物的固相酯交換法及環狀碳酸酯化合物的開環聚合法等反應形式係在各種文獻及專利公報等已被熟悉的方法。前述以外的反應形式之詳細係在出版著作及專利公報等已被熟悉。
在製造本發明的樹脂組成物時,芳香族聚碳酸酯樹脂的黏度平均分子量(M)沒有特別限定,以1×104
~5×104
為佳,以1.4×104
~3×104
為較佳,以1.4×104
~2.4×104
為更佳。
黏度平均分子量小於1×104
的芳香族聚碳酸酯樹脂,在實用上會有無法得到期待的耐衝擊性等情況,又,因為無法得到充分的防滴落性能,難燃性亦容易變差。另一方面,由黏度平均分子量大於5×104
的芳香族聚碳酸酯樹脂所得
到的樹脂組成物,因為射出成形時的流動性差,所以泛用性較差。又,因為成形加工溫度變高,會有無充分活用本發明的特徵之情況。
又,芳香族聚碳酸酯樹脂亦可以是混合其黏度平均分子量在前述範圍以外的芳香族聚碳酸酯樹脂而成者。特別是具有黏度大於前述範圍(5×104
)的黏度平均分子量之芳香族聚碳酸酯樹脂,能夠藉由提高樹脂的熵彈性,來進而相乘地改良防滴落性能。此種改良效果係比前述分枝聚碳酸酯更為良好。更佳的態樣亦能夠使用A成分係由黏度平均分子量為7×104
~3×105
的芳香族聚碳酸酯樹脂(A-3-1成分)及黏度平均分子量為1×104
~3×104
的芳香族聚碳酸酯樹脂(A-3-2成分)所構成,且其黏度平均分子量為1.6×104
~3.5×104
之芳香族聚碳酸酯樹脂(A3成分)(以下,亦有稱為“含高分子量成分之芳香族聚碳酸酯樹脂”之情況)。
在此種含高分子量成分之芳香族聚碳酸酯樹脂(A3成分),A-3-1成分的分子量以7×104
~2×105
為佳,以8×104
~2×105
為較佳,以1×105
~2×105
為更佳,以1×105
~1.6×105
為特佳。又,A-3-2成分的分子量為1×104
~2.5×104
為佳,以1.1×104
~2.4×104
為較佳,以1.2×104
~2.4×104
為更佳,以1.2×104
~2.3×104
為特佳。
含高分子量成分之芳香族聚碳酸酯樹脂(A3成分)藉由以各種比率混合前述A-3-1成分及A-3-2成分,能夠調整來滿足規定分子量範圍。較佳是在100重量%A3成分中,A-3-1成分為2~40重量%,較佳是A-3-1成分為3~30重量%、更佳是A-3-1成分為4~20重量%、特佳是A-3-1成分為5~20
重量%。
又,A-3成分的調製方法可舉出以下的方法等,(1)將A-3-1成分及A-3-2成分各自獨立地聚合並將其等混合之方法;(2)以特開平5-306336號公報所示方法為代表,係使用在同一系統內製造GPC法的分子量分布圖顯示具有複數個聚合物尖峰之芳香族聚碳酸酯樹脂之方法,並以滿足本發明的A-1成分條件的方式來製造此種芳香族聚碳酸酯樹脂之方法;及(3)將藉由此種製造方法((2)的製造方法)所得到的芳香族聚碳酸酯樹脂與另外製造的A-3-1成分及/或A-3-2成分混合之方法等。
在本發明所稱黏度平均分子量係首先使用奧士瓦黏度計,從於20℃將0.7克芳香族聚碳酸酯樹脂溶解在100毫升二氯甲烷而成之溶液,藉由下式算出比黏度(ηsp
),比黏度(ηsp
)=(t-t0
)/t0
[t0
係二氯甲烷的落下秒數,t係試料溶液的落下秒數]
藉由以下的數學式,從所求得的比黏度(ηsp
)算出黏度平均分子量M。
ηsp
/c=[η]+0.45×[η]2
c(其中[η]為固有黏度)[η]=1.23×10-4
M0.83
c=0.7
又,前述黏度平均分子量的算法亦能夠應用於本發明的樹脂組成物或由該樹脂組成物所成形的成形品之黏度平均分子量的測定。亦即,在本發明,該等黏度平均分子量係從將0.7克成形品溶解於100毫升二氯甲烷而成的溶液,求取在20℃之比黏度(ηsp
),並將該比黏度套入前述式
來求得。
本發明之B成分係使由70重量%~100重量%之(甲基)丙烯酸酯(B2-1成分)及0重量%~30重量%之能夠共聚合之其他的單體(B2-2成分)所構成的混合物(B2成分),與下述式(1)所示聚有機矽氧烷(B1成分),以B2成分/B1成分重量比表示時為5/95~95/5的比例接枝共聚合而構成之丙烯酸改性聚有機矽氧烷。
聚有機矽氧烷(B1成分)係如下述式(1)所示。
式中,R1
、R2
及R3
係各自獨立地表示(i)碳數1~20的烴基或(ii)碳數1~20的鹵化烴基。
(i)碳數1~20的烴基可舉出碳數1~20的烷基、碳數5~20的芳基。烷基可例示甲基、乙基、丙基、丁基等。芳基可例示苯基、甲苯基、二甲苯基、萘基。(ii)碳數1~20的鹵化烴基係表示以鹵素原子取代鍵結於(i)碳數1~20烴基的碳原子之氫原子的至少一個而成的基。取代之鹵素原子可舉出氟原子、氯原子及溴原子。
Y係選自由乙烯基、烯丙基(2-丙烯基)及γ-甲基丙烯醯丙基所組成群組之自由基反應性基。
X1
及X2
係各自獨立地表示氫原子、碳數1~4的烷基或
-SiR4
R5
R6
所示之基。碳數1~4的烷基可例示甲基、乙基、丙基、丁基等。-SiR4
R5
R6
所示之基的R4
及R5
係各自獨立地表示(i)碳數1~20的烴基或(ii)碳數1~20的鹵化烴基。該等可例示與在R1
~R3
所例示之相同之物。R6
係表示(i)碳數1~20的烴基、(ii)碳數1~20的鹵化烴基或選自由(iii)乙烯基、烯丙基及γ-甲基丙烯醯丙基所組成群組之自由基反應性基。(i)碳數1~20的烴基及(ii)碳數1~20的鹵化烴基可例示與在R1
~R3
所例示之相同之物。
m係表示10,000以下之正的整數。n係表示1~500的整數。又,在1分子中,R1
~R6
、Y之各自可以相同亦可以不同。
此種聚有機矽氧烷能夠使用眾所周知的方法製造。例如,使用具有前述基之鏈狀或環狀的低分子量聚有機矽氧烷或烷氧基矽烷,且藉由組合加水分解或聚合、平衡化的手段來製造。加水分解或聚合、平衡化係使用眾所周知的技術,亦能夠在分散於水中的狀態進行。
又,(甲基)丙烯酸酯(B2-1成分)係指丙烯酸或甲基丙烯酸的烷基酯、羥基烷基酯、烷氧基烷基酯等。具體上,可舉出丙烯酸甲酯、丙烯酸乙酯、丙烯酸異丙酯、丙烯酸正丙酯、丙烯酸正丁酯、丙烯酸異丁酯、丙烯酸2-乙基己酯、丙烯酸異辛酯、丙烯酸正辛酯、丙烯酸-2-羥基乙酯及丙烯酸-2-甲氧基乙酯等的丙烯酸酯。
又,可舉出甲基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸異丙酯、甲基丙烯酸正丙酯、甲基丙烯酸正丁酯、
甲基丙烯酸異丁酯、甲基丙烯酸正己酯、甲基丙烯酸-2-乙基己酯、甲基丙烯酸正月桂酯、甲基丙烯酸-2-羥基乙酯及甲基丙烯酸-2-乙氧基乙酯等的甲基丙烯酸酯。該等能夠使用1種或組合2種以上而使用,以甲基丙烯酸甲酯及/或甲基丙烯酸-2-羥基乙酯為特佳。
混合物(B2成分)中之(甲基)丙烯酸酯(B2-1成分)的含量係與其他的單體(B2-2成分)的合計量為100重量%時,為70~100重量%,以72~100重量%為佳,以74~100重量%為更佳。
又,能夠與(甲基)丙烯酸酯共聚合之其他的單體(B2-2成分),可舉出如苯乙烯、乙烯基甲苯、α-甲基苯乙烯之苯乙烯系化合物、如丙烯腈或甲基丙烯腈之不飽和腈、氯乙烯、偏二氯乙烯等的鹵化烯烴、如乙酸乙烯酯及丙酸乙烯酯之乙烯酯、丙烯醯胺、甲基丙烯醯胺、N-羥甲基丙烯醯胺等的不飽和醯胺、如丙烯酸、甲基丙烯酸、順丁烯二酸酐之不飽和羧酸等具有1個雙鍵之單體。此外,可舉出乙二醇二甲基丙烯酸酯、丙二醇二甲基丙烯酸酯、1,4-丁二醇二甲基丙烯酸酯、甲基丙烯酸烯丙酯、三聚異氰酸三烯丙酯及三聚異氰酸三烯丙酯等多不飽和單體為代表例。該等可使用2種以上。
混合物(B2成分)中之其他的單體(B2-2成分)的含量係與(甲基)丙烯酸酯(B2-1成分)的合計量為100重量%時,為0~30重量%,以0~28重量%為佳,以0~26重量%為更佳。
接枝共聚合能夠使用眾所周知的方法進行。例如能使聚有機矽氧烷與(甲基)丙烯酸酯或其與其他的單體之混合物在水中乳化分散,且在自由基聚合引發劑的存在下使其聚合,來進行接枝共聚合。在該方法所使用的乳化劑或自由基聚合引發劑可使用眾所周知者作為乳化聚合用。聚合結束後,能夠藉由鹽析、過濾、水洗、乾燥來得到接枝共聚物。又,在該乳化接枝共聚合,如前述地在將聚有機矽氧烷分散於水中而成的狀態製造時,能夠將所得到聚有機矽氧烷的乳化液直接作為接枝共聚合用原料使用。
丙烯酸改性聚有機矽氧烷(B成分)係對聚有機矽氧烷(B1成分)將由(甲基)丙烯酸酯及能夠共聚合的其他單體所構成的混合物(B2成分),以B2成分/B1成分之重量比表示時為5/95~95/5、較佳是10/90~80/20、更佳是15/85~70/30、特佳是20/80~60/40進行接枝共聚合而成。在該重量比,(甲基)丙烯酸酯及能夠共聚合之其他的單體為小於5時,會有與聚碳酸酯的相溶性不充分且機械強度或成形品外觀變差之情形,大於95時,會有滑動性不充分之情形。
此種丙烯酸改性聚有機矽氧烷(B成分)係例如日信化學(股)製以「SHARINU」的商品名銷售,亦能夠從市場容易地取得。
本發明的樹脂組成物中的丙烯酸改性聚有機矽氧烷(B成分)的含量係相對於100重量份之聚碳酸酯樹脂(A成分),為3.0~7.0重量份,以3.2~6.8重量份為佳,以3.4~6.6重量份為更佳。丙烯酸改性聚有機矽氧烷(B成分)的比率小於3.0重量份時,滑動性的改良效果不充分,大於7.0重量
份時,因過剩的表面移行致使外觀變差,又,機械特性亦降低,乃是不佳。
本發明的樹脂組成物係相對於芳香族聚碳酸酯樹脂(A成分)100重量份,有機金屬鹽系阻燃劑(C成分)以含有0.005~0.6重量份為佳。有機金屬鹽系阻燃劑(C成分)以有機酸之鹼(土類)金屬鹽為佳,以有機磺酸鹼(土類)金屬鹽為更佳。有機酸之鹼(土類)金屬鹽的碳原子數以1~50為佳,以1~40為更佳。
有機磺酸鹼(土類)金屬鹽可舉出如全氟烷基磺酸與鹼金屬或鹼土類金屬的金屬鹽之氟取代烷基磺酸的金屬鹽。全氟烷基磺酸的碳原子數以1~10為佳,以2~8為更佳。
有機磺酸鹼(土類)金屬鹽係含有芳香族磺酸與鹼金屬或鹼土類金屬之金屬鹽。芳香族磺酸的碳原子數以7~50為佳,以7~40為更佳。
構成有機金屬鹽之金屬以鹼金屬或鹼土類金屬為佳。鹼金屬可舉出鋰、鈉、鉀、銣及銫。鹼土類金屬可舉出鈹、鎂、鈣、鍶及鋇。以鹼金屬為更佳。因而,在本發明,C成分係以全氟烷基磺酸鹼金屬鹽為佳。此種鹼金屬之中,透明性要求較高時,以銣或銫為佳,另一方面,因為該等並非泛用且精製亦不容易,結果會有在成本方面不利之情況。另一方面,鋰及鈉在成本或難燃性方面係有利的,但是相反地,會有在透明性方面不利的情況。能夠考慮該等情況而分開使用全氟烷基磺酸鹼金屬鹽中的鹼金屬,以在任一方面的特性平衡都優良之全氟烷基磺酸鉀鹽為最佳。
亦能夠併用由此種鉀鹽與其他的鹼金屬所構成的全氟烷基磺酸鹼金屬鹽。
較佳的全氟烷基磺酸鹼金屬鹽可舉出例如三氟甲磺酸鉀、全氟丁磺酸鉀、全氟己磺酸鉀、全氟辛磺酸鉀、五氟乙磺酸鈉、全氟丁磺酸鈉、全氟辛磺酸鈉、三氟甲磺酸鋰、全氟丁磺酸鋰、全氟庚磺酸鋰、三氟甲磺酸銫、全氟丁磺酸銫、全氟辛磺酸銫、全氟己磺酸銫、全氟丁磺酸銣及全氟己磺酸銣等,該等可單獨使用1種或併用2種以上而使用。該等之中,以全氟丁磺酸鉀為特佳。
C成分能夠藉由眾所周知的方法,且降低在製造含氟有機金屬鹽時之原料中所含有的氟化物離子的量之方法;藉由反應時所產生的氣體或加熱來除去由反應所得到的氟化氫等之方法;及在製造含氟有機金屬鹽時使用再結晶及再沈澱等精製方法來降低氟化物離子的量之方法等來製造。特別是因為C成分比較容易溶解在水中,以使用離子交換水、特別是電阻值為18MΩ˙cm以上、亦即導電度滿足約0.55μS/cm以下之水,且在比常溫高的溫度使其溶解而進行洗淨,隨後並冷卻來使其再結晶化之步驟來製造為佳。
在本發明,較佳的C成分之全氟烷基磺酸鹼金屬鹽的製造,通常能夠藉由使用鹼金屬的碳酸鹽或氫氧化物等之鹼性化合物中和全氟烷基礦酸或全氟烷基礦醯氟化物之方法來進行。使用全氟烷基礦酸時,因為其本身多半為液狀,其精製係困難的,所以較大量地含有在製造該礦酸時所混入的氟化物離子。另一方面,使用全氟烷基礦醯氟時,藉
由其中和反應,會產生氟化物離子。
使用全氟烷基磺酸時,能夠依照特開平1-268671號公報所揭示之使中和反應在pH3以下的酸性區域進行之方法,來降低氟化物離子。藉由此種方法,不必更含有精製步驟亦能夠得到降低氟化物離子而成的全氟烷基磺酸鹼金屬鹽。另一方面,使用全氟烷基磺醯氟作為原料時,在金屬鹽的製造後,如上述,以藉由再結晶化來降低氟化物離子至規定量為佳。又,使用全氟烷基磺酸作為原料時,以更含有藉由再結晶化之精製步驟為佳。更具體地,以將藉由使用鹼金屬的碳酸鹽或氫氧化物中和全氟烷基磺酸之方法;及使用鹼金屬的碳酸鹽或氫氧化物中和全氟烷基磺醯氟之方法(更佳是藉由後者的方法)所製造的全氟烷基磺酸鹼金屬鹽,在40~90℃(更佳是60~85℃)的範圍溶解於該金屬鹽之2~10重量倍的離子交換水(特佳是電阻值為18MΩ˙cm以上)並攪拌0.1~3小時、更佳是0.5~2.5小時後,冷卻至0~40℃、更佳是10~35℃的範圍,藉由過濾所析出的結晶並取出,來製造本發明的較佳C成分之全氟烷基磺酸鹼金屬鹽為佳。
本發明的樹脂組成物中的有機金屬鹽系阻燃劑(C成分)的含有比率,係相對於芳香族聚碳酸酯樹脂(A成分)100重量份,為0.005~0.6重量份,以0.005~0.2重量份為較佳,以0.008~0.13重量份為更佳。在此種較佳範圍時難燃性良好。
本發明的樹脂組成物係相對於芳香族聚碳酸酯樹脂(A
成分)100重量份,以含有4.0~9.0重量份之有機磷化合物系阻燃劑(D成分)為佳。
有機磷化合物系阻燃劑(D成分)可舉出紅磷、有機磷酸酯系阻燃劑等。其中以有機磷酸酯係阻燃劑佳,特別是以下述式(2)所示之1種或2種以上的磷酸酯為特佳。
式中的X係從選自由氫醌、間苯二酚、雙(4-羥基二苯基)甲烷、雙酚A、二羥基聯苯、二羥基萘、雙(4-羥苯基)碸、雙(4-羥苯基)酮及雙(4-羥苯基)硫醚所組成群組之二羥基化合物所衍生之二元酚殘基。
j、k、l及m係各自獨立地為0或1,n為0~5的整數(但是,在聚合度n不同的磷酸酯的混合物的情況,n係表示其平均值)。
R11
、R12
、R13
及R14
係各自獨立地從選自由亦可被鹵素原子取代的苯酚、甲酚、二甲酚、異丙基苯酚、丁基苯酚及對異丙苯基苯酚所組成群組之芳基所衍生的一元酚殘基。
式(2)中的X係以從選自由氫輥、間苯二酚及雙酚A所組成群組之二羥基化合物所衍生的二元酚殘基。j、k、l及m係各自以1為佳,n以0~3的整數為佳(但是,在聚合度n不同的磷酸酯的混合物的情況,n係表示其平均值)。R11
、
R12
、R13
及R14
係各自獨立地從選自由亦可被1個以上之鹵素原子取代的苯酚、甲酚及二甲酚所組成群組之芳基所衍生的一元酚殘基。
特佳是X係從間苯二酚所衍生的二元酚殘基,j、k、l及m係各自為1,n為0或1,R11
、R12
、R13
及R14
係各自獨立地從苯酚及二甲酚所衍生的一元酚殘基。
此種有機磷酸酯中,因為耐加水分解性等亦優良,磷酸酯化合物以使用磷酸三苯酯、磷酸酯低聚物以使用間苯二酚雙(二甲苯基磷酸酯)及雙酚A雙(二苯基磷酸酯)為佳。而且,就耐熱性等而言,以間苯二酚雙(二甲苯基磷酸酯)及雙酚A雙(二苯基磷酸酯)為更佳。
相對於A成分100重量份,本發明之樹脂組成物中的有機磷化合物系阻燃劑(D成分)的含量為4.0~9.0重量份,以4.8~8.4重量份為佳,以5.2~8.0重量份為更佳。藉由此種較佳的組成比率,能夠提供具有良好的難燃性之樹脂組成物。有機磷化合物系阻燃劑(D成分)比上述範圍過少時,會有難以得到難燃效果之情況,比上述範圍過大時,會有因組成物的物性降低及耐熱性降低致使界限PV值降低之情況。
相對於芳香族聚碳酸酯樹脂(A成分)100重量份,本發明的樹脂組成物以含有0.01~1重量份含氟防滴落劑(E成分)為佳。含氟防滴落劑(E成分)可例示具有原纖維形成性能之聚四氟乙烯等。
具有原纖維形成性能之四氟乙烯(PTFE)係具有極高的
分子量,且顯示具有藉由剪切力等外在的作用,使PTFE之間鍵結而成為纖維狀的傾向者。該分子量係從標準比重所求取的數量平均分子量為100萬~1,000萬,以200萬~900萬為更佳。此種PTFE除了使用固體形狀以外,亦夠使用水性分散液形態者。又,為了提高在樹脂中的分散性,且得到更良好的難燃性及機械特性,此種具有原纖維形成性能之PTFE亦能夠使用與其他樹脂之混合形態的PTFE混合物。此種具有原纖維形成性能之PTFE的市售品可舉出例如三井‧DUPONT FLUOROCHEMICALS(股)之特夫綸(Teflon;註冊商標)6J;DAIKIN化學工業(股)之POLYFLON MPA FA500、F-201L等。作為PTFE的水性分散液之市售品可舉出旭ICI FLUOROPOLYMERS(股)製之FLUON AD-1、AD-936;DAIKIN工業(股)製的FLUON D-1、D-2、三井‧DUPONT FLUOROCHEMICALS(股)之特夫綸(Teflon;註冊商標)30J等作為代表。
混合形態之PTFE能夠使用依照(1)混合PTFE的水性分散液與有機聚合物的水性分散液或溶液並進行共沈澱來得到共凝聚混合物之方法(特開昭60-258263號公報、特開昭63-154744號公報等所記載之方法);(2)混合PTFE的水性分散液與乾燥的有機聚合物粒子之方法(特開平4-272957號公報所記載之方法);(3)均勻地混合PTFE的水性分散液與有機聚合物粒子溶液,並同時從此種混合物除去各自的介質之方法(特開平06-220210號公報、特開平08-188653號公報等所記載之方法);(4)在PTFE的水性分散液中使用以形成有機聚合物的單體聚合之方法(特開平9-95583號公
報所記載之方法);及(5)均勻地混合PTFE的水性分散液與有機聚合物分散液後,進而在該混合分散液中使乙烯系單體聚合,並隨後得到混合物之方法(特開平11-29679號公報等所記載之方法)所得到者。該等之混合形態的PTFE的市售品可舉出三菱RAYON(股)的「METABLEN A3000」(商品名)、及GE SPECIALTY CHEMICALS公司製「BLENDEX B449」(商品名)等。
在混合形態之PTFE的比率係PTFE混合物100重量%中,PTFE以1~60重量%為佳,以5~55重量%為更佳,PTFE的比率在此範圍時,能夠達成PTFE的良好分散性。
本發明的樹脂組成物中的含氟防滴落劑(E成分)的含量係相對於A成分100重量份,為0.01~1重量份,以0.03~0.8重量份為佳,以0.05~0.6重量份為更佳。E成分小於0.01重量份時難以得到難燃效果,大於1重量份時成形品外觀變差,乃是不佳。
本發明的樹脂組成物係相對於芳香族聚碳酸酯樹脂(A成分)100重量份,以含有4.0~9.0重量份之有機磷化合物系阻燃劑(D成分)及0.01~1重量份之含氟防滴落劑(E成分)為佳。
本發明的樹脂組成物以更含有磷系安定劑為佳。在製造時或在成形加工時,此種磷系安定劑能夠提升熱安定性、機械特性、色相及成形安定性。又,因為在紫外線劣化亦伴隨著很大的氧化劣化,亦能夠達成抑制此種劣化之輔助性效果。此種磷系安定劑可例示亞磷酸、磷酸、亞膦
酸、膦酸及該等的酯等。
具體上,亞磷酸酯化合物可舉出例如亞磷酸三苯酯、亞磷酸參(壬基苯基)酯、亞磷酸三癸酯、亞磷酸三辛酯、亞磷酸三個十八烷酯、亞磷酸二癸基一苯酯、亞磷酸二辛基一苯酯、亞磷酸二異丙基一苯酯、亞磷酸一丁基二苯酯、亞磷酸一癸基二苯酯、亞磷酸一辛基二苯酯、2,2-亞甲基雙(4,6-二-第三丁基苯基)辛基亞磷酸酯、亞磷酸參(二乙基苯基)酯、亞磷酸參(二-異丙基苯基)酯、亞磷酸參(二-正丁基苯基)酯、亞磷酸參(2,4-二-第三丁基苯基)酯、亞磷酸參(2,6-二-第三丁基苯基)酯、二硬脂醯基新戊四醇二亞磷酸酯、雙(2,4-二-第三丁基苯基)新戊四醇二亞磷酸酯、雙(2,6-二-第三丁基-4-甲基苯基)新戊四醇二亞磷酸酯、雙(2,6-二-第三丁基-4-乙基苯基)新戊四醇二亞磷酸酯、苯基雙酚A新戊四醇二亞磷酸酯、雙(壬基苯基)新戊四醇二亞磷酸酯及二環己基新戊四醇二亞磷酸酯等。
而且,其他的亞磷酸酯化合物亦能夠使用與二元酚類反應而具有環狀結構者。可舉出例如2,2'-亞甲基雙(4,6-二-第三丁基苯基)(2,4-二-第三丁基苯基)亞磷酸酯、2,2'-亞甲基雙(4,6-二-第三丁基苯基)(2-第三丁基-4-甲基苯基)亞磷酸酯、2,2'-亞甲雙(4-甲基-6-第三丁基苯基)(2-第三丁基-4-甲基苯基)亞磷酸酯、2,2'-亞乙基雙(4-甲基-6-第三丁基苯基)(2-第三丁基-4-甲基苯基)亞磷酸酯等。
磷酸酯化合物可舉出磷酸三丁酯、磷酸三甲酯、磷酸三甲苯基酯、磷酸三苯酯、磷酸三氯苯酯、磷酸三乙酯、磷酸二苯基甲苯酯、磷酸二苯基一鄰聯苯酯、磷酸三苯氧
基乙酯、磷酸二丁酯、磷酸二辛酯及磷酸二異丙酯等。較佳是磷酸三苯酯、磷酸三甲酯。
亞膦酸酯化合物可舉出肆(2,4-二-第三丁基苯基)-4,4'-聯苯基二亞膦酸酯、肆(2,4-二-第三丁基苯基)-4,3'-聯苯基二亞膦酸酯、肆(2,4-二-第三丁基苯基)-3,3'-聯苯基二亞膦酸酯、肆(2,6-二-第三丁基苯基)-4,4'-聯苯基二亞膦酸酯、肆(2,6-二-第三丁基苯基)-4,3'-聯苯基二亞膦酸酯、肆(2,6-二-第三丁基苯基)-3,3'-聯苯基二亞膦酸酯、雙(2,4-二-第三丁基苯基)-4-苯基-苯基亞膦酸酯、雙(2,4-二-第三丁基苯基)-3-苯基-苯基亞膦酸酯、雙(2,6-二-正丁基苯基)-3-苯基-苯基亞膦酸酯、雙(2,6-二-第三丁基苯基)-4-苯基-苯基亞膦酸酯及雙(2,6-二-第三丁基苯基)-3-苯基-苯基亞膦酸酯等。
以肆(二-第三丁基苯基)-伸聯苯二亞膦酸酯、雙(二-第三丁基苯基)-苯基-苯基亞膦酸酯為佳。以肆(2,4-二-第三丁基苯基)-伸聯苯二亞膦酸酯、雙(2,4-二-第三丁基苯基)-苯基-苯基亞膦酸酯為較佳。此種亞膦酸酯化合物以可併用上述烷基取代2個以上之具有芳基的亞磷酸酯化合物為佳。
膦酸酯化合物可舉出例如苯磺酯二甲酯、苯磺酯二乙酯及苯磺酯二丙酯等。
上述磷系安定劑不只能夠使用1種,亦可混合2種以上而使用。上述磷系安定劑之中,以亞磷酸酯化合物或亞膦酸酯化合物為佳。以亞磷酸參(2,4-二-第三丁基苯基)酯、肆(2,4-二-第三丁基苯基)-4,4'-聯苯基二亞膦酸酯及雙(2,4-二-第三丁基苯基)-苯基-苯基亞膦酸酯為佳。又,併用該等與磷酸酯化合物亦是較佳態樣。
本發明的樹脂組成物能夠更含有受阻酚系安定劑。含有受阻酚系安定劑夠防止樹脂組成物的乾熱劣化。又,因為在紫外線劣化亦伴隨著很大的氧化劣化,亦能夠有效地抑制此種劣化。此種受阻酚系安定劑可例示α-生育酚、丁基羥基甲苯、芥基醇、維生素E、正十八烷基-β-(4’-羥基-3’,5’-二-第三丁基苯基)丙酸酯、2-第三丁基-6-(3’-第三丁基-5’-甲基-2’-羥苄基)-4-甲基苯基丙烯酸酯、2,6-二-第三丁基-4-(N,N-二甲基胺基甲基)苯酚、3,5-二-第三丁基-4-羥苄基膦酸二乙酯、2,2’-亞甲基雙(4-甲基-6-第三丁基苯酚)、2,2’-亞甲基雙(4-乙基-6-第三丁基苯酚)、4,4’-亞甲基雙(2,6-二-第三丁基苯酚)、2,2’-亞甲基雙(4-甲基-6-環己基苯酚)、2,2’-二亞甲基-雙(6-α-甲基-苄基-對甲酚)、2,2’-亞乙基-雙(4,6-二-第三丁基苯酚)、2,2’-亞丁基-雙(4-甲基-6-第三丁基苯酚)、4,4’-亞丁基-雙(3-甲基-6-第三丁基苯酚)、三甘醇-N-雙-3-(3-第三丁基-4-羥基-5-甲基苯基)丙酸酯、1,6-己二醇雙[3-(3,5-二-第三丁基-4-羥苯基)丙酸酯]、雙[2-第三丁基-4-甲基-6-(3-第三丁基-5-甲基-2-羥苄基)苯基]對酞酸酯、3,9-雙{2-[3-(3-第三丁基-4-羥基-5-甲基苯基)丙醯氧基]-1,1,-二甲基乙基}-2,4,8,10-四氧雜螺[5,5]十一烷、4,4’-硫代雙(6-第三丁基-間甲酚)、4,4’-硫代雙(3-甲基-6-第三丁基苯酚)、2,2’-硫代雙(4-甲基-6-第三丁基苯酚)、雙(3,5-二-第三丁基-4-羥苄基)硫醚、4,4’-二-硫代雙(2,6-二-第三丁基苯酚)、4,4’-三-硫代雙(2,6-二-第三丁基苯酚)、2,2-硫代二伸乙基雙-[3-(3,5-二-第三丁基-4-羥苯基)
丙酸酯]、2,4-雙(正辛基硫)-6-(4-羥基-3',5'-二-第三丁基苯胺基)-1,3,5-三、N,N'-六亞甲基雙-(3,5-二-第三丁基-4-羥基氫化肉桂醯胺)、N,N'-雙[3-(3,5-二-第三丁基-4-羥苯基)丙醯]肼、1,1,3-參(2-甲基-4-羥基-5-第三丁基苯基)丁烷、1,3,5-三甲基-2,4,6-參(3,5-二-第三丁基-4-羥苄基)苯、參(3,5-二-第三丁基-4-羥苯基)三聚異氰酸酯、參(3,5-二-第三丁基-4-羥苄基)三聚異氰酸酯、1,3,5-參(4-第三丁基-3-羥基-2,6-二甲基苄基)三聚異氰酸酯、1,3,5-參2[3(3,5-二-第三丁基-4-羥苯基)丙醯氧]乙基三聚異氰酸酯及肆[亞甲基-3-(3',5'-二-第三丁基-4-羥苯基)丙酸酯]甲烷等。該等係任一者都容易取得。上述受阻酚系抗氧化劑可單獨使用或是組合2種以上而使用。
相對於芳香族聚碳酸酯樹脂(A成分)100重量份,選自磷系安定劑及受阻酚系安定劑之至少1種安定劑含量以0.001~1重量份,以0.003~0.5重量份為較佳,以0.005~0.1重量份為更佳。安定劑比上述範圍過少時,會有難以得到良好的安定化效果,比上述範圍過多時,會有產生組成物的物性降低、難燃性變差之情形。
在本發明的樹脂組成物,能在調配眾所周知的各種填料作為強化填料。此種填料可例示滑石、矽灰石、雲母、黏土、蒙脫石(montmorillonite)、膨潤石(smectite)、高嶺土、碳酸鈣、玻璃纖維、玻璃珠、玻璃球、玻璃碾磨纖維、玻璃薄片、碳纖維、碳薄片、碳珠、碳碾磨纖維、金屬薄片、金屬纖維、覆金屬玻璃纖維、覆金屬碳纖維、覆金屬玻璃
薄片、二氧化矽、陶瓷粒子、陶瓷纖維、陶瓷球、石墨、芳族醯胺纖維(Aramid fiber)及各種晶鬚(鈦酸鈣晶鬚、硼酸鋁晶鬚及鹼性硫酸鎂等)等。該等強化纖維能夠以使用1種或併用2種以上的方式而含有。相對於A成分100重量份,填料的含量以在1~50重量份的範圍為佳。
本發明的樹脂組成物亦可含有白色顏料。白色顏料係以使用二氧化鈦(尤其是藉由聚矽氧等有機表面處理劑處理過的二氧化鈦)顏料為特佳。白色顏料的含量係相對於A成分100重量份,以1~30重量份為佳,以2~20重量份為更佳。
本發明的樹脂組成物能夠含有自由基產生劑。較佳的自由基產生劑可舉出2,5-二甲基-2,5-二(第三丁基過氧化)己炔-3、過氧化二異丙苯等有機過氧化物、2,3-二甲基-2,3-二苯基甲烷(二異丙苯)等,該等係日本油脂(股)製以PERHEXYNE 25B、PERCUMYL D、NOFMA BC等的商品名市售,能夠容易取得。特別是因為在熔融混煉時自由基的產生極少且燃燒時產生有效程度之安定的自由基者為佳,更佳的自由基產生劑可舉出2,3-二甲基-2,3-二苯基丁烷(二異丙苯)。難燃性係必要時,能夠藉由此種自由基產生劑更提高難燃性。自由基產生劑的含量係相對於A成分100重量份,以0.001~0.3重量份為佳,以0.01~0.1重量份為更佳。
又,本發明的樹脂組成物亦能夠含有雙(2,2,6,6-四甲基
-4-哌啶基)癸二酸酯、雙(1,2,2,6,6-五甲基-4-哌啶基)癸二酸酯、肆(2,2,6,6-四甲基-4-哌啶基)-1,2,3,4-丁烷四羧酸酯、肆(1,2,2,6,6-五甲基-4-哌啶基)-1,2,3,4-丁烷四羧酸酯、聚{[6-(1,1,3,3-四甲基丁基)胺基-1,3,5-三-2,4-二基][(2,2,6,6-四甲基哌啶基)亞胺基]六亞甲基[(2,2,6,6-四甲基哌啶基)亞胺基]}及聚甲基丙基3-氧基-[4-(2,2,6,6-四甲基)哌啶基]矽氧烷等為代表之受阻胺系的光安定劑。
光安定劑可以是單獨亦能夠使用2種以上的混合物。光安定劑的含量係相對於芳香族聚碳酸酯樹脂(A成分)100重量份,以0.0005~3重量份為佳,以0.01~2重量份為較佳,以0.02~1重量份為更佳。
本發明的樹脂組成物在不損害本發明的目的之範圍,亦能夠以少量比率使用其他樹脂。
此種其他的樹脂可舉出例如聚對酞酸乙二酯、聚對酞酸丁二酯等的聚酯樹脂、聚醯胺樹脂、聚醯亞胺樹脂、聚醚醯亞胺樹脂、聚胺基甲酸酯、聚矽氧樹脂、聚苯醚樹脂、聚苯硫醚樹脂、聚碸樹脂、聚乙烯、聚丙烯等聚烯烴樹脂、聚苯乙烯樹脂、丙烯腈/苯乙烯共聚物(AS樹脂)、丙烯腈/丁二烯/苯乙烯共聚物(ABS樹脂)、聚甲基丙烯酸酯樹脂、酚樹脂及環氧樹脂等樹脂。
又,彈性體可舉出例如異丁烯/異戊二烯橡膠、苯乙烯/丁二烯橡膠、乙烯/丙烯橡膠、丙烯酸系彈性體、聚酯系彈性體、聚醯胺系彈性體、芯殼型的彈性體之MBS(甲基丙烯酸甲酯/苯乙烯/丁二烯)橡膠、MAS(甲基丙烯酸甲酯/丙烯腈
/苯乙烯)橡膠等。
此外,為了賦予成形品各種功能或改善特性,在本發明的樹脂組成物亦能夠以少量比率調配其本身已被知悉的添加物。該等添加物只要不損害本發明的目的,係通常的調配量。
此種添加劑可舉出以著色劑(例如碳黑、氧化鈦等的顏料、染料)、無機系螢光體(例如以鋁酸鹽為母結晶之螢光體)、防靜電劑、流動改性劑、結晶核劑、無機及有機的抗菌劑、光觸媒系防污劑(例如微粒子氧化鈦、微粒子氧化鋅)、接枝橡膠為代表之衝擊改性劑、紅外線吸收劑(熱線吸收劑)及光致變色劑。
本發明的樹脂組成物例如能夠將A成分、B成分及C成分、D成分、E成分等其他的成分,各自使用V型摻合器、亨謝爾混合器、機械化學裝置、擠壓混合機等預混合手段充分地混合後,並依照情況使用擠壓造粒器或壓塊機器等進行造粒,且隨後使用以排氣口式雙軸擠壓機為代表之熔融混煉機熔融混煉,及使用造粒器等機器加以顆粒化來製造。
各成分之供給至熔融混煉機的方法可例示(i)將A成分、B成分及其他成分各自獨立地供給至熔融混煉機之方法;及(ii)將A成分、B成分及其他成分的一部分預混合後,將剩餘的成分獨立地供給至熔融混煉機之方法等。
擠壓機較佳是能使用具有排氣口者,能將從原料中之水分或熔融混煉樹脂產生的揮發氣體脫氣。以設置有真空
泵為佳,用以效率良好地將所產生的水分或揮發氣體從排氣口排出至擠壓機外部。又,亦可在擠壓機模頭部前的區域設置網篩,用以除去混入擠壓原料中之異物等,且亦能夠將異物從樹脂組成物除去。此種網篩可舉出金屬網、網篩交換器、燒結金屬板(盤式過濾機等)等。熔融混煉機除了雙軸擠壓機以外,亦可舉出班伯里混煉機、混煉輥、單軸擠壓機及三軸以上的多軸擠壓機等。
如上述所擠出的樹脂係直接切斷而顆粒化,或是形成股線後使用造粒機將此種股線切斷來加以顆粒化。顆粒化時為了降低外部塵埃的影響,必要時以將擠壓機周圍的環境清淨化為佳。所得到顆粒的形狀能夠採取圓柱、角柱及球狀等通常的形狀,以圓柱為更佳。此種圓柱的直徑以1~5毫米為佳,以1.5~4毫米為更佳,以2~3.3毫米為更佳。另一方面,圓柱的長度以1~30毫米為佳,以2~5毫米為較佳,以2.5~3.5毫米為更佳。
由本發明的樹脂組成物所構成的成形品,通常能夠將該顆粒射出成形而得到。在此種射出成形,不只是通常的成形方法,亦可舉出射出壓縮成形、射出加壓成形、氣體輔助射出成形、發泡成形(包含注入超臨界流體之方法)、嵌入成形、模具內塗布成形、絕熱模具成形、急速加熱冷卻模具成形、雙色成形、夾層結構成形及超高速射出成形等。又,成形能夠選擇冷流道方式及熱流道方式之任一者。
又,依照本發明,亦能夠將樹脂組成物擠壓成形,而成為各種異形擠壓成形品、薄片、薄膜等的形狀。又,薄
片、薄膜的成形亦能夠使用吹塑法、壓延法及鑄塑法等。而且亦能夠藉由施行特定的拉伸操作來成形作為熱收縮管。又,亦能夠使用旋轉成形或吹氣成形等來將本發明之樹脂組成物製造成形品。
而且,亦能夠對本發明的成形品進行各種表面處理。表面處理可舉出硬塗、拒水拒油塗布、親水性塗布、防靜電塗布、紫外線吸收塗布、紅外線吸收塗布及金屬化(蒸鍍等)等各種處理。又,表面處理方法除了塗布液劑以外,可舉出蒸鍍法、火焰噴塗法及鍍敷法。蒸鍍法能夠使用物理蒸鍍法及化學蒸鍍法之任一者。物理蒸鍍法可例示真空蒸鍍法、濺鍍及離子噴鍍等。化學蒸鍍(CVD)法可例示熱CVD、電漿CVD及光CVD法等。
以下舉出實施例來進一步說明,但是本發明未限定於此。評價係依照以下方法進行。
評價機器係使用ORIENTEC(股)製、往復動摩擦摩耗試驗機AFT-15M。將直徑5毫米Φ的半球與直徑5毫米Φ、長度30毫米的圓柱在圓剖面部分結合而成之前端具有球面之銷(pin)狀試片(材質:鋼),安裝在固定側試片保持器。另一方面,從實施例及比較例的樹脂組成物使用射出成形製造長度150毫米×寬度150毫米×厚度2毫米的平板狀試片(澆口係從邊的一端之寬度40毫米×厚度1毫米的凸片澆口(fingate)),並將中心部切削成長度50毫米×寬度100毫
米,且將此切削試片固定在往復動作之底座上。使上述銷狀試片的前端球面部分,以銷狀試片的圓柱軸方向與平板狀試片的平面法線方向為平行狀態,且施加負荷荷重為9.8N的負荷狀態,使其接觸此平板狀試片的切削試片的平面部分。在此接觸狀態,於23℃、相對濕度為50%RH的環境中,在平面內的1直線上,以1往復2秒的比例且單程為25毫米的距離使其進行1,000次往復動作,並藉由連接於銷狀試片側之容量為49N的測力傳感器測定1,000次動作後的摩擦力,並從與前述負荷荷重的關係算出動摩擦係數。
成形得到外徑25毫米、內徑20毫米之圓筒狀試片,並使用摩擦試驗機[ORIENTEC(股)製FRICTRON摩擦摩耗試驗機]來進行推力摩擦摩耗試驗(在一定負荷下,使圓筒狀試片接觸對方材料的端面並使其旋轉)。對方材料係使用機械結構用碳鋼(S-45C)且在無潤滑狀態下進行,在滑動速度為20公分/秒(轉數為167rpm)的條件下,每3分鐘從0至500公斤階段地變化加壓負荷來進行測定臨界PV值。在此所稱之臨界PV值係材料之滑動表面由於摩擦發熱而變形,表示發生破壞之臨界加壓負荷(P)和滑動速度(V)相乘的值。
依據ISO 179,實施附帶凹口之查拜式衝擊強度的測定。
依據ISO 75-1及75-2,來測定負荷彎曲溫度。又,測定負荷係以1.80MPa實施。
使用依據UL規格製成之1.5毫米厚度的試片,並依據UL規格94藉由垂直燃燒試驗來進行評價。
目視測定寬度50毫米×長度80毫米×厚度2毫米的四方板。將表面外觀良好者評價為○,將成形品表面相分離致使產生光澤不均等、或是射出成形時丙烯酸改性聚有機矽氧烷成分從成形品表面剝離者評價為×。
又,表1所記載之使用原材料等係如下。
PC-1:芳香族聚碳酸酯樹脂[帝人化成(股)製L-1225WP、黏度平均分子量22,400]
PC-2:芳香族聚碳酸酯樹脂[帝人化成(股)製L-1225WX、黏度平均分子量19,700]
R-170:丙烯酸改性聚有機矽氧烷[日信化學工業(股)製SHARINU R-170、聚二甲基矽氧烷含量70重量%]
PTFE:聚四氟乙烯樹脂[DAIKIN工業(股)製RUPRON L-5、平均粒徑為約7微米]
F-114P:全氟丁磺酸鉀鹽[大日本油墨(股)製MEGAFAC F-114P]
PX-200:間苯二酚雙[二(2,6-二甲基苯基)磷酸酯作為主成分之磷酸酯[大八化學工業(股)製PX-200]
FA500:具有原纖維形成性能之聚四氟乙烯[DAIKIN工業(股)製POLYFRON MP FA500]
IRX:亞磷酸酯化合物[CIBA SPECIALTY CHEMICALS公司製Irgafos168]
依照以下要領,製成表1~3所記載之樹脂組成物。計量表1~3之比率的各成分,並使用轉鼓機均勻地混合,且將該混合物投入擠壓機來進行製造樹脂組成物。擠壓機係使用直徑30毫米Φ的排氣口式雙軸擠壓機(神戶製鋼所(股)製KTX-30)。在圓筒溫度及模頭溫度為280℃、且排氣口吸引度為3,000Pa的條件擠壓股線,在水浴冷卻後使用造粒機進行股線切割,來加以顆粒化。所得到的顆粒係藉由使用熱風循環式乾燥機在120℃進行乾燥6小時,且使用射出成形機[東芝機械(股)製IS 150EN-5Y]於圓筒溫度為280℃、模具溫度為70℃成形試片,並依照上述方法來進行評價。
比較表1~3之實施例及比較例,得知本發明的樹脂組成物係滑動性、耐衝擊性、耐熱性、難燃性及表面外觀優良。
本發明的樹脂組成物係未使用氟系滑動劑,且具有優良的滑動性及表面外觀。又,本發明的樹脂組成物,能夠保持聚碳酸酯樹脂本來的性質之衝擊強度、耐熱性、難燃性及尺寸安定性。
由本發明的樹脂組成物所產生的成形品,在對應環境要求強烈之電氣電子機器、事務機器等的內部機構組件係有用的。
Claims (11)
- 一種樹脂組成物,其特徵係相對於芳香族聚碳酸酯樹脂(A成分)100重量份,含有3.2~6.8重量份之丙烯酸改性聚有機矽氧烷(B成分),不含有矽油,該丙烯酸改性聚有機矽氧烷(B成分)係使由70重量%~100重量%之(甲基)丙烯酸酯(B2-1成分)及0重量%~30重量%之能夠共聚合之其他的單體(B2-2成分)所構成的混合物(B2成分),與下述式(1)所示聚有機矽氧烷(B1成分),以B2成分/B1成分重量比表示時為5/95~95/5的比例接枝共聚合而構成之丙烯酸改性聚有機矽氧烷,
- 如申請專利範圍第1項之樹脂組成物,其中B2-1成分係甲基丙烯酸甲酯及/或甲基丙烯酸-2-羥基乙酯。
- 如申請專利範圍第1項之樹脂組成物,其中B2成分/B1成分的重量比為20/80~60/40之比例。
- 如申請專利範圍第1項之樹脂組成物,其中相對於芳香族聚碳酸酯樹脂(A成分)100重量份,含有0.005~0.6重量份之有機金屬鹽系阻燃劑(C成分)。
- 如申請專利範圍第4項之樹脂組成物,其中有機金屬鹽系阻燃劑(C成分)係有機酸之鹼金屬鹽或有機酸之鹼土類金屬鹽。
- 如申請專利範圍第5項之樹脂組成物,其中有機酸之鹼金屬鹽或有機酸之鹼土類金屬鹽(C成分)係有機磺酸鹼金屬鹽或有機磺酸鹼土類金屬鹽。
- 如申請專利範圍第1項之樹脂組成物,其中相對於芳香族聚碳酸酯樹脂(A成分)100重量份,含有4.0~9.0重量份之有機磷化合物系阻燃劑(D成分)。
- 如申請專利範圍第1項之樹脂組成物,其中相對於芳香族聚碳酸酯樹脂(A成分)100重量份,含有0.01~1重量份之含氟防滴落劑(E成分)。
- 如申請專利範圍第1項之樹脂組成物,其中相對於芳香族聚碳酸酯樹脂(A成分)100重量份,含有4.0~9.0重量份之有機磷化合物系阻燃劑(D成分)及0.01~1重量份之含氟防滴落劑(E成分)。
- 如申請專利範圍第7項之樹脂組成物,其中有機磷化合物系阻燃劑(D成分)係下述式(2)所示之磷酸酯,
- 一種成形品,其係由如申請專利範圍第1項之樹脂組成物所構成。
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10182987A (ja) * | 1996-12-27 | 1998-07-07 | Shin Etsu Chem Co Ltd | 摺動性樹脂組成物 |
JP2000302958A (ja) * | 1999-04-23 | 2000-10-31 | Mitsubishi Engineering Plastics Corp | ポリカーボネート樹脂組成物 |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3420002A1 (de) | 1984-05-29 | 1985-12-05 | Bayer Ag, 5090 Leverkusen | Tetrafluorethylenpolymerisat enthaltende polymerisatpulverkompositionen |
US4828921A (en) * | 1986-10-17 | 1989-05-09 | Mobay Corporation | Polycarbonate molding compositions |
US4753994A (en) | 1986-12-02 | 1988-06-28 | Mobay Corporation | Flame retardant polycarbonate compositions |
JPH01268671A (ja) | 1988-04-21 | 1989-10-26 | Central Glass Co Ltd | 高純度フルオルアルキルスルホン酸塩の製造方法 |
US4939206A (en) * | 1988-11-14 | 1990-07-03 | General Electric Company | Flame retardant polyorganosiloxane-based graft polymers |
JP2977261B2 (ja) | 1990-09-28 | 1999-11-15 | 旭化成工業株式会社 | 樹脂組成物 |
EP0483510A3 (en) | 1990-10-31 | 1992-09-02 | General Electric Company | Polycarbonate compositions with improved appearance and flammability characteristics |
JP2632115B2 (ja) | 1991-08-12 | 1997-07-23 | 竹本油脂株式会社 | 合成樹脂型内成形用離型剤及び該離型剤を用いる合成樹脂型内成形物への離型性付与方法 |
JP2708660B2 (ja) | 1992-04-30 | 1998-02-04 | 帝人化成株式会社 | ポリカーボネート樹脂の製造方法 |
CA2108411A1 (en) | 1992-11-17 | 1994-05-18 | Wie-Hin Pan | Method of dispersing solid additives in polymeric resins |
JP3157316B2 (ja) | 1992-12-03 | 2001-04-16 | 帝人化成株式会社 | 芳香族ポリカーボネート共重合体 |
JPH07216240A (ja) * | 1994-02-07 | 1995-08-15 | Nippon Oil & Fats Co Ltd | 熱可塑性樹脂組成物 |
JP3830983B2 (ja) | 1994-07-12 | 2006-10-11 | 帝人化成株式会社 | 芳香族ポリカーボネート組成物 |
JPH08188653A (ja) | 1995-01-10 | 1996-07-23 | General Electric Co <Ge> | 固体の添加剤をポリマー中に分散させる方法およびそれによって得られる製品 |
FR2733504A1 (fr) | 1995-04-28 | 1996-10-31 | Gen Elec Plastics Abs Euro Bv | Nouveaux alliages polymeres a base de polymerisat comprenant des motifs de derives de tetrafluoroethylene, procede de fabrication, articles obtenus a partir de tels alliages et utilisation de ces alliages dans des compositions polymeres |
JP3254375B2 (ja) | 1996-05-16 | 2002-02-04 | 信越化学工業株式会社 | 熱可塑性樹脂組成物 |
JP3747518B2 (ja) | 1996-05-27 | 2006-02-22 | Jsr株式会社 | 熱可塑性樹脂組成物 |
JP3272985B2 (ja) | 1996-07-31 | 2002-04-08 | 三菱レイヨン株式会社 | ポリテトラフルオロエチレン含有混合粉体の製造方法 |
JPH1149961A (ja) * | 1997-07-30 | 1999-02-23 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物およびそれを含むマスターバッチ |
JP4507287B2 (ja) | 1997-11-28 | 2010-07-21 | 住友ダウ株式会社 | 難燃性ポリカーボネート樹脂組成物 |
TW544462B (en) | 1997-11-28 | 2003-08-01 | Sumitomo Dow Ltd | Flame-retardant polycarbonate resin compositions |
JP4136065B2 (ja) | 1998-04-21 | 2008-08-20 | 本田技研工業株式会社 | エンジン停止始動制御装置を搭載した車両 |
EP1026205B1 (en) * | 1998-08-28 | 2006-07-19 | Teijin Chemicals, Ltd. | Polycarbonate resin composition and molded article |
JP3685640B2 (ja) | 1999-03-16 | 2005-08-24 | 株式会社カネカ | 難燃性樹脂を含有する難燃性樹脂組成物 |
JP2001055435A (ja) | 1999-08-19 | 2001-02-27 | Mitsubishi Gas Chem Co Inc | 光記録媒体用成形材料 |
JP5290483B2 (ja) | 2000-09-06 | 2013-09-18 | 帝人株式会社 | 難燃性芳香族ポリカーボネート樹脂組成物 |
JP2002117580A (ja) | 2000-10-03 | 2002-04-19 | Teijin Chem Ltd | 光ディスク基板および光ディスク |
JP2003089749A (ja) | 2001-09-18 | 2003-03-28 | Kanegafuchi Chem Ind Co Ltd | 難燃性ポリカーボネート樹脂組成物 |
EP1500682A4 (en) * | 2002-04-30 | 2006-09-27 | Kaneka Corp | POLYORGANOSILOXAN-CONTAINING PFROPOPOPOLYMER COMPOSITION |
DE10304159A1 (de) * | 2003-02-03 | 2004-08-05 | Bayer Ag | Flammwidrige Polycarbonat-Blends |
TW200504153A (en) | 2003-04-11 | 2005-02-01 | Kaneka Corp | Graft copolymer containing polyorganosiloxane, resin composition containing the same and process for preparing emulsion of polyorganosiloxane |
JP4778686B2 (ja) | 2004-05-06 | 2011-09-21 | 帝人化成株式会社 | 摺動性ポリカーボネート樹脂組成物およびその成形品 |
WO2006070664A1 (ja) | 2004-12-28 | 2006-07-06 | Kaneka Corporation | グラフト共重合体およびその製造方法、並びに該グラフト共重合体含有樹脂組成物 |
JP5209129B1 (ja) | 2012-04-26 | 2013-06-12 | 株式会社東芝 | 情報処理装置、放送受信装置及び情報処理方法 |
-
2008
- 2008-05-20 EP EP08764647.7A patent/EP2149590B1/en active Active
- 2008-05-20 US US12/451,630 patent/US8697796B2/en active Active
- 2008-05-20 KR KR1020097021729A patent/KR101457729B1/ko active IP Right Grant
- 2008-05-20 WO PCT/JP2008/059612 patent/WO2008143356A1/ja active Application Filing
- 2008-05-23 TW TW097118992A patent/TWI495683B/zh active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10182987A (ja) * | 1996-12-27 | 1998-07-07 | Shin Etsu Chem Co Ltd | 摺動性樹脂組成物 |
JP2000302958A (ja) * | 1999-04-23 | 2000-10-31 | Mitsubishi Engineering Plastics Corp | ポリカーボネート樹脂組成物 |
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