TWI485141B - 環氧化反應的起動方法 - Google Patents
環氧化反應的起動方法 Download PDFInfo
- Publication number
- TWI485141B TWI485141B TW099144226A TW99144226A TWI485141B TW I485141 B TWI485141 B TW I485141B TW 099144226 A TW099144226 A TW 099144226A TW 99144226 A TW99144226 A TW 99144226A TW I485141 B TWI485141 B TW I485141B
- Authority
- TW
- Taiwan
- Prior art keywords
- catalyst
- ethylene
- temperature
- moderator
- silver
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/04—Ethene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28739309P | 2009-12-17 | 2009-12-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201136906A TW201136906A (en) | 2011-11-01 |
| TWI485141B true TWI485141B (zh) | 2015-05-21 |
Family
ID=44152004
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW099144226A TWI485141B (zh) | 2009-12-17 | 2010-12-16 | 環氧化反應的起動方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8530682B2 (enExample) |
| EP (2) | EP2513077B1 (enExample) |
| JP (1) | JP5946772B2 (enExample) |
| KR (1) | KR101790254B1 (enExample) |
| CN (1) | CN102666514B (enExample) |
| BR (1) | BR112012014695A2 (enExample) |
| CA (1) | CA2783604C (enExample) |
| IN (1) | IN2012DN05178A (enExample) |
| MX (1) | MX2012007043A (enExample) |
| MY (1) | MY157612A (enExample) |
| RU (1) | RU2542978C2 (enExample) |
| TW (1) | TWI485141B (enExample) |
| WO (1) | WO2011084600A2 (enExample) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI446964B (zh) | 2007-05-09 | 2014-08-01 | Shell Int Research | 環氧化催化劑,製備該催化劑之方法及製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法 |
| CA2783604C (en) * | 2009-12-17 | 2018-05-01 | Scientific Design Company, Inc. | Process for epoxidation start-up |
| US20110152073A1 (en) | 2009-12-23 | 2011-06-23 | Scientific Design Company, Inc. | Epoxidation process and microstructure |
| WO2012141942A1 (en) | 2011-04-11 | 2012-10-18 | Dow Technology Investments Llc | Process for conditioning a high efficiency ethylene oxide catalyst |
| KR20170018102A (ko) | 2011-12-30 | 2017-02-15 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 형상화 연마입자 및 이의 형성방법 |
| EP3705177A1 (en) | 2012-01-10 | 2020-09-09 | Saint-Gobain Ceramics & Plastics Inc. | Abrasive particles having complex shapes and methods of forming same |
| KR102197361B1 (ko) | 2012-05-23 | 2021-01-05 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 형상화 연마입자들 및 이의 형성방법 |
| FI2906392T3 (fi) | 2012-10-15 | 2025-06-20 | Saint Gobain Abrasives Inc | Hiomahiukkasia, joilla on erityisiä muotoja, ja menetelmiä tällaisten hiukkasten muodostamiseksi |
| CN104884443B (zh) * | 2012-12-31 | 2017-07-04 | 科学设计公司 | 用于环氧乙烷催化剂的启动方法 |
| CN105008339B (zh) * | 2013-01-11 | 2017-09-12 | 科学设计公司 | 具有后调节步骤的环氧化工艺 |
| CN105073343B (zh) | 2013-03-29 | 2017-11-03 | 圣戈班磨料磨具有限公司 | 具有特定形状的磨粒、形成这种粒子的方法及其用途 |
| RU2643004C2 (ru) | 2013-09-30 | 2018-01-29 | Сен-Гобен Серэмикс Энд Пластикс, Инк. | Формованные абразивные частицы и способы их получения |
| EP3087061B1 (en) * | 2013-12-23 | 2018-04-11 | Scientific Design Company Inc. | Epoxidation process |
| MX380754B (es) | 2013-12-31 | 2025-03-12 | Saint Gobain Abrasives Inc | Artículo abrasivo que incluye partículas abrasivas perfiladas. |
| US9771507B2 (en) | 2014-01-31 | 2017-09-26 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particle including dopant material and method of forming same |
| BR112016023838A2 (pt) | 2014-04-14 | 2017-08-15 | Saint Gobain Ceramics | artigo abrasivo incluindo partículas abrasivas moldadas |
| US9914864B2 (en) | 2014-12-23 | 2018-03-13 | Saint-Gobain Ceramics & Plastics, Inc. | Shaped abrasive particles and method of forming same |
| CN107636109A (zh) | 2015-03-31 | 2018-01-26 | 圣戈班磨料磨具有限公司 | 固定磨料制品和其形成方法 |
| TWI634200B (zh) | 2015-03-31 | 2018-09-01 | 聖高拜磨料有限公司 | 固定磨料物品及其形成方法 |
| US9776169B2 (en) * | 2015-06-02 | 2017-10-03 | Scientific Design Company, Inc. | Porous bodies with enhanced pore architecture |
| EP3307483B1 (en) | 2015-06-11 | 2020-06-17 | Saint-Gobain Ceramics&Plastics, Inc. | Abrasive article including shaped abrasive particles |
| PL3455321T3 (pl) | 2016-05-10 | 2022-12-12 | Saint-Gobain Ceramics&Plastics, Inc. | Sposób formowania cząstek ściernych |
| WO2017197002A1 (en) | 2016-05-10 | 2017-11-16 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive particles and methods of forming same |
| US11230653B2 (en) | 2016-09-29 | 2022-01-25 | Saint-Gobain Abrasives, Inc. | Fixed abrasive articles and methods of forming same |
| EP3548471B1 (en) | 2016-12-02 | 2021-05-19 | Shell Internationale Research Maatschappij B.V. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
| US10563105B2 (en) | 2017-01-31 | 2020-02-18 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive article including shaped abrasive particles |
| WO2018236989A1 (en) | 2017-06-21 | 2018-12-27 | Saint-Gobain Ceramics & Plastics, Inc. | Particulate materials and methods of forming same |
| WO2019055773A1 (en) | 2017-09-15 | 2019-03-21 | MultiPhase Solutions, Inc. | GAS PHASE CHROMATOGRAPHY OF SELECTIVE HALOGEN DETECTION FOR ONLINE ANALYSIS AND CONTROL OF SELECTIVE OXIDATION CHEMICAL PRODUCTION PROCESSES |
| CN111655368A (zh) * | 2018-02-07 | 2020-09-11 | 巴斯夫欧洲公司 | 制备银浸渍溶液的方法 |
| CN114845838B (zh) | 2019-12-27 | 2024-10-25 | 圣戈本陶瓷及塑料股份有限公司 | 磨料制品及其形成方法 |
| KR102765343B1 (ko) | 2019-12-27 | 2025-02-13 | 세인트-고바인 세라믹스 앤드 플라스틱스, 인크. | 연마 물품 및 이의 형성 방법 |
| US12129422B2 (en) | 2019-12-27 | 2024-10-29 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive articles and methods of forming same |
| CN113121474A (zh) * | 2019-12-30 | 2021-07-16 | 中国石油化工股份有限公司 | 乙烯环氧化银催化剂的开车方法 |
| CN114057669B (zh) * | 2020-07-29 | 2023-12-08 | 中国石油化工股份有限公司 | 一种乙烯环氧化恒温开车方法 |
| CN114436998A (zh) * | 2020-11-05 | 2022-05-06 | 中国石油化工股份有限公司 | 一种乙烯环氧化开车方法 |
| WO2023130052A1 (en) | 2021-12-30 | 2023-07-06 | Saint-Gobain Abrasives, Inc. | Abrasive articles and methods of forming same |
| CA3241421A1 (en) | 2021-12-30 | 2023-07-06 | Anthony MARTONE | Abrasive articles and methods of forming same |
| EP4457054A4 (en) | 2021-12-30 | 2026-01-14 | Saint Gobain Abrasives Inc | ABRASIVE ARTICLES AND THEIR FORMATION PROCESSES |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200521121A (en) * | 2003-09-29 | 2005-07-01 | Union Carbide Chem Plastic | A process for the production of alkylene oxide using a gas-phase promoter system |
| TWI283242B (en) * | 2002-06-28 | 2007-07-01 | Shell Int Research | A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin |
| TW200918513A (en) * | 2007-09-26 | 2009-05-01 | Sd Lizenzverwertungsgesell Mbh | Process for initiating a highly selective ethylene oxide catalyst |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1170663A (en) | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
| US3702259A (en) | 1970-12-02 | 1972-11-07 | Shell Oil Co | Chemical production of metallic silver deposits |
| US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4908343A (en) | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5057481A (en) | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US4874879A (en) * | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| DE68925767T2 (de) | 1988-08-30 | 1996-08-14 | Union Carbide Corp | Katalysatoren für die Herstellung von Ethylenoxid und Verfahren zur deren Herstellung |
| US5187140A (en) | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
| US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5155242A (en) | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| US5407888A (en) | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
| US5856534A (en) * | 1997-12-18 | 1999-01-05 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts treated with carbon dioxide |
| JP4042332B2 (ja) | 2001-02-27 | 2008-02-06 | 三菱化学株式会社 | レニウム含有触媒を用いるオレフィンオキシドの製造方法 |
| AU2003243757A1 (en) | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| MX257124B (es) * | 2002-06-28 | 2008-05-14 | Shell Int Research | Metodo para iniciar un proceso de epoxidacion, catalizador y proceso de epoxidacion de una olefina. |
| US8791280B2 (en) | 2005-08-10 | 2014-07-29 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for preparation of catalyst carrier and its use in catalyst preparation |
| US7696368B2 (en) * | 2007-05-11 | 2010-04-13 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Start-up of high selectivity catalysts in olefin oxide plants |
| CN102056909B (zh) * | 2008-05-07 | 2014-03-05 | 国际壳牌研究有限公司 | 环氧化工艺的开车方法及环氧乙烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法 |
| CA2783604C (en) * | 2009-12-17 | 2018-05-01 | Scientific Design Company, Inc. | Process for epoxidation start-up |
| US20110152073A1 (en) | 2009-12-23 | 2011-06-23 | Scientific Design Company, Inc. | Epoxidation process and microstructure |
-
2010
- 2010-12-16 CA CA2783604A patent/CA2783604C/en not_active Expired - Fee Related
- 2010-12-16 TW TW099144226A patent/TWI485141B/zh not_active IP Right Cessation
- 2010-12-16 WO PCT/US2010/060769 patent/WO2011084600A2/en not_active Ceased
- 2010-12-16 MY MYPI2012002389A patent/MY157612A/en unknown
- 2010-12-16 KR KR1020127018627A patent/KR101790254B1/ko not_active Expired - Fee Related
- 2010-12-16 US US12/970,392 patent/US8530682B2/en not_active Expired - Fee Related
- 2010-12-16 RU RU2012130065/04A patent/RU2542978C2/ru not_active IP Right Cessation
- 2010-12-16 BR BR112012014695A patent/BR112012014695A2/pt not_active IP Right Cessation
- 2010-12-16 MX MX2012007043A patent/MX2012007043A/es active IP Right Grant
- 2010-12-16 CN CN201080057763.XA patent/CN102666514B/zh not_active Expired - Fee Related
- 2010-12-16 JP JP2012544826A patent/JP5946772B2/ja not_active Expired - Fee Related
- 2010-12-16 EP EP10842602.4A patent/EP2513077B1/en not_active Revoked
- 2010-12-16 EP EP20140171850 patent/EP2778157A1/en not_active Withdrawn
- 2010-12-16 IN IN5178DEN2012 patent/IN2012DN05178A/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI283242B (en) * | 2002-06-28 | 2007-07-01 | Shell Int Research | A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin |
| TW200521121A (en) * | 2003-09-29 | 2005-07-01 | Union Carbide Chem Plastic | A process for the production of alkylene oxide using a gas-phase promoter system |
| TW200918513A (en) * | 2007-09-26 | 2009-05-01 | Sd Lizenzverwertungsgesell Mbh | Process for initiating a highly selective ethylene oxide catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| MY157612A (en) | 2016-06-30 |
| CA2783604C (en) | 2018-05-01 |
| KR20120106809A (ko) | 2012-09-26 |
| EP2513077B1 (en) | 2014-06-11 |
| CN102666514A (zh) | 2012-09-12 |
| TW201136906A (en) | 2011-11-01 |
| EP2778157A1 (en) | 2014-09-17 |
| KR101790254B1 (ko) | 2017-10-26 |
| RU2542978C2 (ru) | 2015-02-27 |
| US8530682B2 (en) | 2013-09-10 |
| CA2783604A1 (en) | 2011-07-14 |
| EP2513077A2 (en) | 2012-10-24 |
| MX2012007043A (es) | 2012-07-20 |
| JP2013514387A (ja) | 2013-04-25 |
| WO2011084600A3 (en) | 2011-11-17 |
| CN102666514B (zh) | 2015-11-25 |
| IN2012DN05178A (enExample) | 2015-10-23 |
| WO2011084600A2 (en) | 2011-07-14 |
| JP5946772B2 (ja) | 2016-07-06 |
| EP2513077A4 (en) | 2013-05-22 |
| BR112012014695A2 (pt) | 2015-09-15 |
| US20110152548A1 (en) | 2011-06-23 |
| RU2012130065A (ru) | 2014-01-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |