TWI466944B - 衝擊改質之聚碳酸酯組成物 - Google Patents
衝擊改質之聚碳酸酯組成物 Download PDFInfo
- Publication number
- TWI466944B TWI466944B TW98144044A TW98144044A TWI466944B TW I466944 B TWI466944 B TW I466944B TW 98144044 A TW98144044 A TW 98144044A TW 98144044 A TW98144044 A TW 98144044A TW I466944 B TWI466944 B TW I466944B
- Authority
- TW
- Taiwan
- Prior art keywords
- rubber
- weight
- component
- parts
- composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 73
- 229920000515 polycarbonate Polymers 0.000 title claims description 27
- 239000004417 polycarbonate Substances 0.000 title claims description 27
- 229920001971 elastomer Polymers 0.000 claims description 109
- 239000005060 rubber Substances 0.000 claims description 109
- -1 polyparaphenylene Polymers 0.000 claims description 39
- 239000000178 monomer Substances 0.000 claims description 32
- 125000003118 aryl group Chemical group 0.000 claims description 30
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
- 229920000578 graft copolymer Polymers 0.000 claims description 28
- 229920001577 copolymer Polymers 0.000 claims description 25
- 239000002131 composite material Substances 0.000 claims description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 20
- 229920002379 silicone rubber Polymers 0.000 claims description 20
- 239000004945 silicone rubber Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 229920002554 vinyl polymer Polymers 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 15
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 15
- 229920000728 polyester Polymers 0.000 claims description 14
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 13
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 13
- 150000002923 oximes Chemical class 0.000 claims description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 9
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 150000001491 aromatic compounds Chemical class 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 7
- 150000001735 carboxylic acids Chemical class 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 229920006163 vinyl copolymer Polymers 0.000 claims description 7
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 6
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 5
- DQMHLATYRAKWIQ-UHFFFAOYSA-N 3-(oxiran-2-yl)prop-2-enoic acid Chemical compound OC(=O)C=CC1CO1 DQMHLATYRAKWIQ-UHFFFAOYSA-N 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 5
- 229920003244 diene elastomer Polymers 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000002216 antistatic agent Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 3
- 230000009477 glass transition Effects 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000012779 reinforcing material Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 2
- VWQMVURBILHJJF-UHFFFAOYSA-N O.OC(=O)C=C.OC(=O)C=C Chemical compound O.OC(=O)C=C.OC(=O)C=C VWQMVURBILHJJF-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 125000005907 alkyl ester group Chemical group 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- 239000002667 nucleating agent Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims 1
- 229920000265 Polyparaphenylene Polymers 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- 239000006082 mold release agent Substances 0.000 claims 1
- 230000035515 penetration Effects 0.000 claims 1
- 238000010558 suspension polymerization method Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 description 18
- 239000004615 ingredient Substances 0.000 description 17
- 239000003431 cross linking reagent Substances 0.000 description 15
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 13
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000006085 branching agent Substances 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- 229920001169 thermoplastic Polymers 0.000 description 7
- 239000004416 thermosoftening plastic Substances 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 238000012662 bulk polymerization Methods 0.000 description 6
- 238000005227 gel permeation chromatography Methods 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 229960003742 phenol Drugs 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 5
- 150000008064 anhydrides Chemical class 0.000 description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Substances OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 150000002825 nitriles Chemical class 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 3
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 3
- DEIVKRHCGHVUCY-UHFFFAOYSA-N C=CC(O)=O.C=CC(O)=O.[He].O Chemical compound C=CC(O)=O.C=CC(O)=O.[He].O DEIVKRHCGHVUCY-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 3
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000010559 graft polymerization reaction Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 2
- WJMXTYZCTXTFJM-UHFFFAOYSA-N 1,1,1,2-tetraethoxydecane Chemical compound C(C)OC(C(OCC)(OCC)OCC)CCCCCCCC WJMXTYZCTXTFJM-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 2
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 125000005587 carbonate group Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229920003049 isoprene rubber Polymers 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- BDJAEZRIGNCQBZ-UHFFFAOYSA-N methylcyclobutane Chemical compound CC1CCC1 BDJAEZRIGNCQBZ-UHFFFAOYSA-N 0.000 description 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- MHJIJZIBANOIDE-UHFFFAOYSA-K neodymium(3+);prop-2-enoate Chemical compound [Nd+3].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C MHJIJZIBANOIDE-UHFFFAOYSA-K 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
- 229920001281 polyalkylene Polymers 0.000 description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 2
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- ZNRPUQQOHLCOMC-UHFFFAOYSA-N 10,10,10-triethoxydecylbenzene Chemical compound C(C)OC(CCCCCCCCCC1=CC=CC=C1)(OCC)OCC ZNRPUQQOHLCOMC-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- WLRWTEIAYJHXDW-UHFFFAOYSA-N 2,2,3,3,4,4,4a,5,5,6-decamethyl-6H-cyclopenta[b]pyran Chemical compound CC1C=C2C(C(C(C(O2)(C)C)(C)C)(C)C)(C1(C)C)C WLRWTEIAYJHXDW-UHFFFAOYSA-N 0.000 description 1
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- VXHYVVAUHMGCEX-UHFFFAOYSA-N 2-(2-hydroxyphenoxy)phenol Chemical class OC1=CC=CC=C1OC1=CC=CC=C1O VXHYVVAUHMGCEX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 description 1
- KAIRTVANLJFYQS-UHFFFAOYSA-N 2-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=CC=C1O KAIRTVANLJFYQS-UHFFFAOYSA-N 0.000 description 1
- YQPCHPBGAALCRT-UHFFFAOYSA-N 2-[1-(carboxymethyl)cyclohexyl]acetic acid Chemical compound OC(=O)CC1(CC(O)=O)CCCCC1 YQPCHPBGAALCRT-UHFFFAOYSA-N 0.000 description 1
- AHPDOFFCLXXLRF-UHFFFAOYSA-N 2-[10-(2-hydroxyphenyl)anthracen-9-yl]phenol Chemical class OC1=CC=CC=C1C(C1=CC=CC=C11)=C(C=CC=C2)C2=C1C1=CC=CC=C1O AHPDOFFCLXXLRF-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- ICPXIRMAMWRMAD-UHFFFAOYSA-N 2-[3-[2-[3-(2-hydroxyethoxy)phenyl]propan-2-yl]phenoxy]ethanol Chemical compound C=1C=CC(OCCO)=CC=1C(C)(C)C1=CC=CC(OCCO)=C1 ICPXIRMAMWRMAD-UHFFFAOYSA-N 0.000 description 1
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 1
- JHZKGBJXCWZQHF-UHFFFAOYSA-N 2-chloro-4-[2-(3-chloro-4-hydroxyphenyl)propan-2-yl]phenol;2,6-dichloro-4-[2-(3,5-dichloro-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(Cl)=CC=1C(C)(C)C1=CC=C(O)C(Cl)=C1.C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 JHZKGBJXCWZQHF-UHFFFAOYSA-N 0.000 description 1
- WHBAYNMEIXUTJV-UHFFFAOYSA-N 2-chloroethyl prop-2-enoate Chemical class ClCCOC(=O)C=C WHBAYNMEIXUTJV-UHFFFAOYSA-N 0.000 description 1
- AJKXDPSHWRTFOZ-UHFFFAOYSA-N 2-ethylhexane-1,6-diol Chemical compound CCC(CO)CCCCO AJKXDPSHWRTFOZ-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- HYFFNAVAMIJUIP-UHFFFAOYSA-N 2-ethylpropane-1,3-diol Chemical compound CCC(CO)CO HYFFNAVAMIJUIP-UHFFFAOYSA-N 0.000 description 1
- VOQDCMULDZDDLP-UHFFFAOYSA-N 2-methoxy-2,3-dimethyloxane Chemical compound CC1C(OCCC1)(C)OC VOQDCMULDZDDLP-UHFFFAOYSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- ZDWSNKPLZUXBPE-UHFFFAOYSA-N 3,5-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1 ZDWSNKPLZUXBPE-UHFFFAOYSA-N 0.000 description 1
- CPHURRLSZSRQFS-UHFFFAOYSA-N 3-[4-[2-[4-(3-hydroxypropoxy)phenyl]propan-2-yl]phenoxy]propan-1-ol Chemical compound C=1C=C(OCCCO)C=CC=1C(C)(C)C1=CC=C(OCCCO)C=C1 CPHURRLSZSRQFS-UHFFFAOYSA-N 0.000 description 1
- RBQLGIKHSXQZTB-UHFFFAOYSA-N 3-methylpentane-2,4-diol Chemical compound CC(O)C(C)C(C)O RBQLGIKHSXQZTB-UHFFFAOYSA-N 0.000 description 1
- HSSYVKMJJLDTKZ-UHFFFAOYSA-N 3-phenylphthalic acid Chemical compound OC(=O)C1=CC=CC(C=2C=CC=CC=2)=C1C(O)=O HSSYVKMJJLDTKZ-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- CUAUDSWILJWDOD-UHFFFAOYSA-N 4-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=C(O)C=C1 CUAUDSWILJWDOD-UHFFFAOYSA-N 0.000 description 1
- HVXRCAWUNAOCTA-UHFFFAOYSA-N 4-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=C(O)C=C1 HVXRCAWUNAOCTA-UHFFFAOYSA-N 0.000 description 1
- KJWMCPYEODZESQ-UHFFFAOYSA-N 4-Dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=C(O)C=C1 KJWMCPYEODZESQ-UHFFFAOYSA-N 0.000 description 1
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 1
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 description 1
- CDBAMNGURPMUTG-UHFFFAOYSA-N 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol Chemical compound C1CC(O)CCC1C(C)(C)C1CCC(O)CC1 CDBAMNGURPMUTG-UHFFFAOYSA-N 0.000 description 1
- RQTDWDATSAVLOR-UHFFFAOYSA-N 4-[3,5-bis(4-hydroxyphenyl)phenyl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC(C=2C=CC(O)=CC=2)=CC(C=2C=CC(O)=CC=2)=C1 RQTDWDATSAVLOR-UHFFFAOYSA-N 0.000 description 1
- NIRYBKWMEWFDPM-UHFFFAOYSA-N 4-[3-(4-hydroxyphenyl)-3-methylbutyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)CCC1=CC=C(O)C=C1 NIRYBKWMEWFDPM-UHFFFAOYSA-N 0.000 description 1
- IQNDEQHJTOJHAK-UHFFFAOYSA-N 4-[4-[2-[4,4-bis(4-hydroxyphenyl)cyclohexyl]propan-2-yl]-1-(4-hydroxyphenyl)cyclohexyl]phenol Chemical compound C1CC(C=2C=CC(O)=CC=2)(C=2C=CC(O)=CC=2)CCC1C(C)(C)C(CC1)CCC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 IQNDEQHJTOJHAK-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- DFYWGYZVNKGYAA-UHFFFAOYSA-N C(C(=C)C)(=O)OC(=O)C(C(C(OC)OC)CC)CCCCCCCC Chemical compound C(C(=C)C)(=O)OC(=O)C(C(C(OC)OC)CC)CCCCCCCC DFYWGYZVNKGYAA-UHFFFAOYSA-N 0.000 description 1
- QCRZZRWLDBCTGX-UHFFFAOYSA-N C(C(=C)C)(=O)OC(=O)C(CC(C(OC)OC)CCC)CCCCCCC Chemical compound C(C(=C)C)(=O)OC(=O)C(CC(C(OC)OC)CCC)CCCCCCC QCRZZRWLDBCTGX-UHFFFAOYSA-N 0.000 description 1
- BBRGNXKXVKJQHM-UHFFFAOYSA-N CCC=COC(C(C)(C)OC)(CCCCCCCC)CCC Chemical compound CCC=COC(C(C)(C)OC)(CCCCCCCC)CCC BBRGNXKXVKJQHM-UHFFFAOYSA-N 0.000 description 1
- UAVOVKJRCMRKNL-UHFFFAOYSA-N CCC=COC(C(CC)(CC)OCC)(CCCCCCCC)CCC Chemical compound CCC=COC(C(CC)(CC)OCC)(CCCCCCCC)CCC UAVOVKJRCMRKNL-UHFFFAOYSA-N 0.000 description 1
- LSSBHFVOQXIVQG-UHFFFAOYSA-N CCC=COC(C(OC)(OC)OC)(CCCCCCCC)CCC Chemical compound CCC=COC(C(OC)(OC)OC)(CCCCCCCC)CCC LSSBHFVOQXIVQG-UHFFFAOYSA-N 0.000 description 1
- XWMVGGIANCOFKR-UHFFFAOYSA-N CCC=COC(CCCCCCCCC)(C(OCC)OCC)CCC Chemical compound CCC=COC(CCCCCCCCC)(C(OCC)OCC)CCC XWMVGGIANCOFKR-UHFFFAOYSA-N 0.000 description 1
- ZCRHCHOHWXDDGH-UHFFFAOYSA-N CCCCCCCCCCC(OC)(OC)OC Chemical compound CCCCCCCCCCC(OC)(OC)OC ZCRHCHOHWXDDGH-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- AMZASIBHIMTFKP-UHFFFAOYSA-N OC1=C(C=CC=C1)C1=C(NC2=CC=CC=C12)C1=C(C=CC=C1)O Chemical class OC1=C(C=CC=C1)C1=C(NC2=CC=CC=C12)C1=C(C=CC=C1)O AMZASIBHIMTFKP-UHFFFAOYSA-N 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- VIKNTNNBXFFVAM-UHFFFAOYSA-N [Ru].C(C=C)(=O)OCCCC Chemical compound [Ru].C(C=C)(=O)OCCCC VIKNTNNBXFFVAM-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- RIBBZUAGJAUAPM-UHFFFAOYSA-K bismuth;prop-2-enoate Chemical compound [Bi+3].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C RIBBZUAGJAUAPM-UHFFFAOYSA-K 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical class OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000006612 decyloxy group Chemical group 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 238000004870 electrical engineering Methods 0.000 description 1
- 238000010616 electrical installation Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- AKIDPNOWIHDLBQ-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarbonyl chloride Chemical compound C1=CC(C(Cl)=O)=C2C(C(=O)Cl)=CC=C(C(Cl)=O)C2=C1C(Cl)=O AKIDPNOWIHDLBQ-UHFFFAOYSA-N 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- CJJMLLCUQDSZIZ-UHFFFAOYSA-N oxobismuth Chemical compound [Bi]=O CJJMLLCUQDSZIZ-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 229950006800 prenderol Drugs 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000004060 quinone imines Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 150000003527 tetrahydropyrans Chemical class 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 238000005199 ultracentrifugation Methods 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
- C08F267/06—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/04—Aromatic polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本發明申請案主張2008年12月23日提出申請之德國專利10 2008 062904(其內容整體合併於此作為參考)及於2009年1月23日提出申請之德國專利10 2009 005762之優先權。
本發明揭示係關於衝擊改質之聚碳酸酯組成物,該等組成物包括一種包含矽氧-丙烯酸酯複合橡膠之第一接枝聚合物作為接枝基(其中矽氧橡膠之量係65至95wt.%(以該接枝基計))、及一種包含自由態共聚物(即不是化學鍵結於橡膠之共聚物)並且具有60,000至150,000克/莫耳之重量平均分子量之第二接枝聚合物。亦揭示該等聚碳酸酯組成物於模製物件之製造中、及對於模製物件本身之用途。
US 2002/077417 A1揭示火焰-保護之組成物,其等包含(a)聚碳酸酯、(b)具有一種矽氧-丙烯酸酯複合橡膠之接枝聚合物(其中矽氧對於丙烯酸酯之比率係從99:1至1:99)、(c)可選的填充劑(例如滑石粉)、(d)作為防火劑(flame-proofing agents)之磷酸酯類、(e)可選的額外添加劑(例如丙烯腈-丁二烯-苯乙烯三元共聚物(ABS)、苯乙烯-丙烯腈共聚物(SAN)及防滴劑)。有揭示包含S-2001之組成物作為實例,S-2001係具有矽氧-丙烯酸丁酯複合橡膠之接枝基的接枝聚合物,其係由約17wt.%之甲基丙烯酸甲酯、約9wt.%之有機矽氧烷及約74wt.%之丙烯酸丁酯組成。然而,US 2002/077417 A1未揭示包含一種具有矽氧-丙烯酸酯複合橡膠作為接枝基之接枝聚合物的組成物,其中矽氧橡膠之量係從65至95wt.%(以該接枝基計)。
JP-A-08-259791揭示火焰防護組成物,該等組成物包含聚碳酸酯及一種具有30至99%之矽氧烷之矽氧-丙烯酸酯橡膠。
JP-A-2000-017136揭示組成物包含聚碳酸酯、1至40wt.%之寡聚合磷酸酯類及具有矽氧-丙烯酸酯橡膠之接枝基之接枝聚合物,該矽氧-丙烯酸酯橡膠包含60至99wt.%之聚有機矽氧烷、可選的聚四氟乙烯及可選的滑石粉。
JP-A-2002-069282揭示包含聚碳酸酯、複合橡膠(例如SX-005)、寡聚合之磷酸酯類、矽氧油、可選的聚四氟乙烯及可選的添加劑之組成物。
WO-A 00/39210揭示包含聚碳酸酯、共聚物、寡聚合之磷酸酯類、具有一種矽氧-丙烯酸酯橡膠作為接枝基之接枝聚合物(例如Metablen S-2001)(於該矽氧-丙烯酸酯橡膠中之聚有機矽氧烷的量係從3wt.%至90wt.%)、可選的聚四氟乙烯及一種強化材料(例如滑石粉)之組成物。
EP-A 0 641 827揭示組成物包含芳族聚碳酸酯、乙烯型單體接枝於二烯橡膠上之接枝聚合物、磷酸酯類、聚四氟乙烯、無機之填充劑(例如滑石粉)、及矽氧與丙烯酸酯橡膠之複合橡膠。
JP-A 07316409揭示組成物,該等組成物包含聚碳酸酯、磷酸酯類、具有一種矽氧-丙烯酸酯橡膠作為接枝基之接枝聚合物,於該矽氧-丙烯酸酯橡膠中之聚有機矽氧烷的量係1至99wt.%及聚(甲基)丙烯酸烷基酯橡膠的量係99至1wt.%。
前述之先前技術未提及包含一種具有自由態共聚物(即不是化學鍵結於橡膠之共聚物)、具有60,000至150,000之重量平均分子量之第二接枝聚合物的組成物。
本發明之目的係提供衝擊改質之聚碳酸酯模製組成物,該等組成物具有良好之斷裂延伸率、良好之水解安定性及低熔化黏度的最適化組合。
於是令人驚訝地發現前述之技術目的及其他目的能夠達成,例如經由下列之組成物,包括
A) 40至99重量份,較佳的是50至90重量份,特別較佳的是60至80重量份(於每一種情況中以成分A+B+C+D之重量份之和計)之芳族聚碳酸酯及/或芳族聚酯碳酸酯,
B) 0.5至20重量份,較佳的是3至13重量份,特別較佳的是8至13重量份(於每一種情況中以成分A+B+C+D之重量份之和計)之第一接枝聚合物,其特徵為接枝基係矽氧-丙烯酸酯複合橡膠,於一種較佳具體實施例中係互相滲透(interpenetrating)之矽氧橡膠與聚(甲基)丙烯酸烷基酯橡膠之矽氧-丙烯酸酯複合橡膠,其中矽氧橡膠之量係65至95wt.%,較佳的是75至95wt.%,特定言之80至95wt.%(以該接枝基計),
C) 0.5至40重量份,較佳的是3至20重量份,特別較佳的是3至7重量份(以成分A+B+C+D之重量份之和計)之第二接枝聚合物,其包含自由態共聚物(即不是化學鍵結於橡膠之共聚物)具有60,000至150,000克/莫耳(較佳的是70,000至130,000克/莫耳,特別較佳的是70,000至90,000克/莫耳)之重量平均分子量,
D) 0至20重量份,較佳的是0至16重量份,特別較佳的是3至16重量份(以成分A+B+C+D之重量份之和計),選自於由不含橡膠之乙烯型(共)聚合物及聚對酞酸伸烷基酯(polyalkylene terephthalate)組成之群中之一種或一種以上聚合物,
E) 0至50重量份,較佳的是0.5至25重量份,特別較佳的是0.5至5重量份(於每一種情況中以成分A+B+C+D之重量份之和計)之添加劑,
其中該組成物不含或實質地不含防火劑,及其中於本發明申請案中之所有重量份皆標準化,致使於該組成物中之成分A+B+C+D之重量份之和係100。
該組成物亦可係實質上由列出之成分組成。該組成物亦可係完全由列出之成分組成。
本發明揭示之前述及其他態樣係於以下記載之詳細說明及實例中詳細地解釋。
適合之根據成分A之芳族聚碳酸酯及/或芳族聚酯碳酸酯通常係於文獻中已知的及/或可係經由於文獻中已知之方法而製備(對於芳族聚碳酸酯之製備,參見,例如,Schnell,“Chemistry and Physics of Polycarbonates”,Interscience Publishers,1964及DE-AS 1 495 626、DE-A 2 232 877、DE-A 2 703 376、DE-A 2 714 544、DE-A 3 000 610、DE-A 3 832 396;對於芳族聚酯碳酸酯之製備,參見例如德DE-A 3 077 934)。
芳族聚碳酸酯之製備可以進行,例如,經由二酚類與碳酸鹵化物類(較佳的是光氣)、及/或與芳族二羧酸二鹵化物類(較佳的是苯二羧酸二鹵化物類)根據界面方法之反應,可選擇性使用鏈終止劑(例如單酚類),及可選擇性使用具有三或超過三之官能度之分枝劑(例如三酚類或四酚類)而進行。例如經由以二酚類與碳酸二苯酯之反應之熔化聚合作用方法之製備亦係可能的。
用於芳族聚碳酸酯及/或芳族聚酯碳酸酯之製備之二酚類較佳的係式(Ⅰ)者
其中A 係單鍵、C1
-至C5
-伸烷基(alkylene)、C2
-至C5
-亞烷基(alkylidene)、C5
-至C6
-亞環烷基(cycloalkylidene)、-O-、-SO-、-CO-、-S-、-SO2
-、C6
-至C12
-伸芳基(arylene),其可進一步稠合於可選地包含雜原子之芳族環),或式(Ⅱ)或式(Ⅲ)之自由基
B 於每一種情況中係C1
-至C12
-烷基(較佳的是甲基)、鹵素(較佳的是氯及/或溴),x 每一種互相獨立地係0、1或2,p 係1或0,及R5
及R6
可係對於每一個X1
個別地選擇及每一種互相獨立地係氫或C1
-至C6
-烷基,較佳的是氫、甲基或乙基,X1
係碳及m 係4至7之整數,較佳的是4或5,其限制條件為於至少一個原子X1
上,R5
及R6
同時係烷基。
較佳之二酚類包括氫醌、間苯二酚、二羥基二酚類、雙-(羥基苯基)-C1
-C5
-烷類、雙-(羥基苯基)-C5
-C6
-環烷類、雙-(羥基苯基)-醚類、雙-(羥基苯基)亞碸類、雙-(羥基苯基)酮類、雙-(羥基苯基)-碸類及α,α-雙-(羥基苯基)-二異丙基-苯類、及其等之於環上經溴化及/或經氯化之衍生物類。
特別較佳之二酚類包括4,4’-二羥基聯苯、雙酚A、2,4-雙(4-羥基苯基)-2-甲基丁烷、1,1-雙-(4-羥基苯基)-環己烷、1,1-雙-(4-羥基苯基)-3,3,5-三甲基環己烷、4,4’-二羥基二苯硫醚、4,4’-二羥基二苯基碸及其等之二-及四-經溴化或經氯化之衍生物類,例如2,2-雙-(3-氯-4-羥基苯基)-丙烷、2,2-雙-(3,5-二氯-4-羥基苯基)-丙烷或2,2-雙-(3,5-二溴-4-羥基苯基)-丙烷。2,2-雙-(4-羥基苯基)-丙烷(雙酚A)係特別較佳的。該等二酚類可單獨地及/或以任何隨意之混合物之形式使用。該等二酚類係於文獻中已知的及/或係根據於文獻中已知之方法可獲得的。
適合於熱塑性芳族聚碳酸酯之製備的鏈終止劑包括,例如,酚、對-氯酚、對-第三丁基酚或2,4,6-三溴酚,但亦長鏈之烷基酚類,諸如根據DE-A 2 842 005之4-[2-(2,4,4-三甲基戊基)]-酚、4-(1,3-四甲基丁基)-酚或者於烷基取代基中具有總數為8至20個碳原子之單烷基酚或二烷基酚類,諸如3,5-二第三丁基酚、對-異辛基酚、對-第三辛基酚、對-十二基酚及2-(3,5-二甲基庚基)-酚及4-(3,5-二甲基庚基)-酚。以於特定情況中使用之二酚類之莫耳總和計,所使用之鏈終止劑之量通常係0.5莫耳%至10莫耳%。
熱塑性芳族聚碳酸酯通常具有10,000至20,000克/莫耳,較佳的是15,000至80,000克/莫耳,特別較佳的是24,000至32,000克/莫耳之重量平均分子量(Mw
,例如,經由膠透層析術(GPC)、超離心作用或散射之光測量法而測量)。
熱塑性芳族聚碳酸酯可係以任何已知之方法分枝,較佳地經由以使用之二酚類之和計之0.05至2.0莫耳%之具有三、或超過三之官能度之化合物(例如,具有三個或三個以上之酚基者)之組合而分枝。
同元聚碳酸酯及/或共聚碳酸酯皆係適合的。對於成分A之共聚碳酸酯之製備,基於以所使用之二酚類之總量計之1至25wt.%(較佳的是2.5至25wt.%)之具有羥基芳基氧基端基之聚二有機基矽氧烷類,亦係可能的。此等係已知的(見美國專利號3,419,634)及/或可係根據於文獻中已知之方法而製備。包含聚二有機基矽氧烷之共聚碳酸酯之製備係於DE-A 3 334 782中敍述。
除了雙酚A同元聚碳酸酯以外,較佳之聚碳酸酯包括具有雙酚A以及以二酚類之莫耳數之和計高達15莫耳%之二酚類(不僅包括上述較佳或特別較佳者)的共聚碳酸酯,特定言之2,2-雙(3,5-二溴-4-羥基苯基)-丙烷。
用於芳族聚酯碳酸酯之製備之芳族二羧酸二鹵化物較佳的係異酞酸、對酞酸、二苯基醚4,4’-二羧酸及萘-2,6-二羧酸之二酸二氯化物類。具有異酞酸與對酞酸之二酸二氯化物以1:20至20:1之比率混合的混合物係特別較佳的。
於聚酯碳酸酯之製備中,可另外伴隨地使用一種碳酸鹵化物(較佳的是光氣)作為雙官能之酸衍生物。
對於芳族聚酯碳酸酯之製備,適合之鏈終止劑,除了已經提及之單酚類之外,亦包括其等之氯碳酸酯類及芳族單羧酸之酸氯化物類,其等可選擇性地經由C1
-至C22
-烷基或經由鹵素原子以及脂族C2
-至C22
-單羧酸氯化物類而取代。
鏈終止劑之量於每一情況中較佳的係0.1至10莫耳%,於酚系鏈終止劑之情況中以二酚之莫耳數計,及於單羧酸氯化物鏈終止劑之情況中以二羧酸二氯化物之莫耳數計。
芳族聚酯碳酸酯亦可選擇性地包含於其中組合之芳族羥基羧酸類。
在已知之方式中芳族聚酯碳酸酯可係線性的及分枝的(關於此點參見DE-A 2 940 024及DE-A 3 007 934)。
可使用作為分枝劑者係,例如,於0.01至1.0莫耳%量(以所使用之二羧酸二氯化物計)之具有三或三以上之官能度之羧酸氯化物類,諸如1,3,5-苯三醯三氯化物(trimesic acid trichloride)、三聚氯化氰(cyanuric acid trichloride)、3,3’-二苯基酮-四羧酸四氯化物、4,4’-二苯基酮-四羧酸四氯化物、1,4,5,8-萘四羧酸四氯化物或1,2,4,5-苯四羧酸四氯化物(pyromellitic acid tetrachloride),或於0.01至1.0莫耳%量(以所使用之二酚類計)之具有三或三以上之官能度之酚類,諸如根皮三酚(phloroglucinol)、4,6-二甲基-2,4,6-三-(4-羥基苯基)-庚-2-烯、4,6-二甲基-2,4,6-三-(4-羥基苯基)-庚烷、1,3,5-三-(4-羥基苯基)-苯、1,1,1-三-(4-羥基苯基)-乙烷、三-(4-羥基苯基)-苯基甲烷、2,2-雙[4,4-雙(4-羥基-苯基)-環己基]-丙烷、2,4-雙(4-羥基苯基-異丙基)-酚、四-(4-羥基苯基)-甲烷、2,6-雙(2-羥基-5’-甲基-苄基)-4-甲基-酚、2-(4-羥基苯基)-2-(2,4-二羥基苯基)-丙烷、四-(4-[4-羥基苯基-異丙基])-苯氧基)-甲烷、1,4-雙[4’,4”-二羥基三苯基)-甲基]-苯。酚系分枝劑可連同二酚類一起置於容器中;酸氯化物分枝劑可係連同酸二氯化物類一起引進。
於熱塑性芳族聚酯碳酸酯中,碳酸酯結構單位之含量可依需要變動。以酯基與碳酸酯基之和計,碳酸酯基之含量較佳的是係高達100莫耳%,特定言之高達80莫耳%,特別較佳的是高達50莫耳%。於芳族聚酯碳酸酯中包含之酯及碳酸酯皆可係以嵌段(blocks)之形式存在或隨機地分布於聚縮作用產物中。
芳族聚碳酸酯及聚酯碳酸酯之相對溶液黏度(ηrel
)有利地係於1.18至1.4之範圍內,較佳的是1.20至1.32(對於0.5克之聚碳酸酯或聚酯碳酸酯於100毫升之二氯甲烷溶液中之溶液於25℃測量)
熱塑性芳族聚碳酸酯及聚酯碳酸酯可係單獨地及/或以任何隨意之混合物使用。
成分B較佳地包含一種或一種以上之下列接枝聚合物
B.1 5至95wt.%,較佳的是10至90wt.%,特定言之10至50wt.%之接枝於下列之一種或一種以上之乙烯型單體
B.2 95至5wt.%,較佳的是90至10wt.%,特定言之50至90wt.%之一種或一種以上之矽氧-丙烯酸酯複合橡膠作為接枝基,該矽氧-丙烯酸酯複合橡膠包含
B.2.1 65至95wt.%,較佳的是75至95wt.%,特定言之80至95wt.%之矽氧橡膠及
B.2.2 5至35wt.%,較佳的是5至25wt.%,特定言之5至20wt.%之聚(甲基)丙烯酸烷基酯橡膠,
其中於一種較佳具體實施例中,該等兩種提及之橡膠成分B.2.1及B.2.2於複合橡膠中以致使彼等實質上不能互相分離之方式互相滲透。
接枝共聚物B可係經由自由基聚合作用而製備,例如,經由乳化、懸浮、溶液或總體聚合作用,較佳地經由乳化聚合作用。
於一種較佳具體實施例中,該接枝聚合物具有一種核心-外殼結構,該結構具有一種橡膠核心及一種乙烯型聚合物外殼。
適合之單體B.1包括乙烯型單體諸如乙烯型芳族化合物類及/或於環上經取代之乙烯型芳族化合物類(諸如苯乙烯、α-甲基苯乙烯、對-甲基苯乙烯、對-氯苯乙烯)、甲基丙烯酸(C1
-C8
)-烷基酯類(諸如甲基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸2-乙基己酯、甲基丙烯酸烯丙酯)、丙烯酸(C1
-C8
)-烷基酯類(諸如丙烯酸甲酯、丙烯酸乙酯、丙烯酸正丁酯、丙烯酸第三丁酯)、有機酸類(諸如丙烯酸、甲基丙烯酸)及/或乙烯型氰化物類(諸如丙烯腈及甲基丙烯腈)及/或不飽和之羧酸之衍生物類(諸如酐類及醯亞胺類)(諸如順丁烯二酐及N-苯基順丁烯二醯亞胺)。此等乙烯型單體可係單獨地及/或以至少兩種單體之混合物使用。
較佳之單體B.1可係由單體苯乙烯、α-甲基苯乙烯、甲基丙烯酸甲酯、丙烯酸正丁酯及丙烯腈之至少一種選出。特別較佳地使用苯乙烯與丙烯腈或甲基丙烯酸甲酯之混合物作為單體B.1。於一種特別較佳之具體實施例中,使用甲基丙烯酸甲酯作為單體B.1。
接枝基B.2之玻璃轉移溫度通常係<10℃,較佳的是<0℃,特別較佳的是<-20℃。接枝基B.2通常具有0.05至10微米之平均粒度(d50
值),較佳的是0.06至1微米,特別較佳的是0.08至0.5微米,特定言之0.08至0.25微米。
平均粒度d50
係於每一種情況中高於其值或低於其值的各有50wt.%之粒子。其可係藉由超離心作用測量而測定(W. Scholtan,H. Lange,Kolloid-Z. und Z. Polymere 250(1972),782-796)。
適合之接枝基B.2包括具有高矽氧含量之矽氧-丙烯酸酯橡膠。此等矽氧-丙烯酸酯橡膠係具有接枝-活性之位置,包含65至95wt.%(較佳的是75至95wt.%,特定言之80至95wt.%)之矽氧橡膠成分及5至35wt.%(較佳的是5至25wt.%,特定言之5至20wt.%)之聚(甲基)丙烯酸烷基酯橡膠成分之複合橡膠,該等兩種提及之橡膠成分,於一種較佳具體實施例中,以致使彼等實質上不能互相分離之方式於複合橡膠中互相滲透。
矽氧-丙烯酸酯橡膠係已知的且已經在如US 5,807,914、EP 430134及US 4,888,388中敍述。
矽氧-丙烯酸酯橡膠之適合之矽氧橡膠成分係具有接枝-活性之位置的矽氧橡膠,其等之製備方法係如於US 2,891,920、US 3,294,725、DE-OS 3 631 540、EP 249964、EP 430134及US 4,888,388中敍述。
矽氧橡膠較佳地係經由乳化聚合作用而製備,其中使用矽氧烷單體結構單位、交聯劑或分枝劑(Ⅳ)及可選的接枝劑(Ⅴ)。
可使用作為矽氧烷單體結構單位者係,例如及較佳地,二甲基矽氧烷或具有至少3環結構(較佳的是3至6環結構)之環狀有機矽氧烷類,諸如,例如及較佳地,六甲基環三矽氧烷、八甲基環四矽氧烷、十甲基環五矽氧烷、十二甲基環六矽氧烷、三甲基-三苯基-環三矽氧烷、四甲基-四苯基-環四矽氧烷、八苯基環四矽氧烷。有機矽氧烷單體可係單獨地及/或以兩種或更多單體之混合物之形式使用。以矽氧烷橡膠成分之總重量計,矽氧橡膠較佳地包含不低於50wt.%及特別較佳地不低於60wt.%之有機矽氧烷。
作為交聯劑或分枝劑(Ⅳ),較佳地使用具有3或4(特別較佳的是4)之官能度以矽烷為基礎之交聯劑。可提及之較佳實例包括:三甲氧基甲基矽烷、三乙氧基苯基矽烷、四甲氧基矽烷、四乙氧基矽烷、四正丙氧基矽烷及四丁氧基矽烷。交聯劑可係單獨地及/或以兩種或更多之混合物使用。四乙氧基矽烷係特別較佳的。
以矽氧橡膠成分之總重量計,交聯劑通常可係以0.1至40wt.%之範圍內之量使用。較佳地選擇交聯劑之量,致使矽氧橡膠於甲苯中測量之澎潤度係3至30,較佳的是3至25及特別較佳的是3至15。澎潤度係定義為當矽氧橡膠係以甲苯於25℃飽和及矽氧橡膠之量係於乾燥狀態時,由矽氧橡膠吸收之甲苯量的重量比率。澎潤度之測定係於EP249964中詳細地敍述。
倘若澎潤度係低於3,即倘若交聯劑之含量係太高,則矽氧橡膠可能不具有足夠之橡膠彈性。倘若潤脹指數係大於30,則矽氧橡膠可能不能於基質聚合物中形成區域(domain)結構及因此亦可能無法顯著地改良衝擊強度;該效應因此潛在地相似於單純地將聚二甲基矽氧烷加入之效應。
於某些情況中,四官能之分枝劑係比三官能之分枝劑較佳,此由於澎潤度較容易控制於上述有利界限內之緣故。
適合之接枝劑(Ⅴ)包括具有形成下列式之結構能力的化合物:
CH2
=C(R2
)-COO-(CH2
)p
-SiR1 n
O(3-n)/2
(V-1)
CH2
=CH-SiR1 n
O(3-n)/2
(V-2)
HS-(CH2
)p
-SiR1 n
O(3-n)/2
(V-3)
其中R1
代表C1
-C4
-烷基(較佳的是甲基、乙基或丙基)、或苯基,R2
代表氫或甲基,n 表示0、1或2及p 表示1至6之整數。
丙烯醯基-或甲基丙烯醯基-氧基矽烷類係特別適合於形成以上提及之結構(Ⅴ-1)及具有高之接枝效率。藉此通常確保接枝鏈之有效形成,及於是及通常促進所生成之樹脂組成物的衝擊強度。
可提及之較佳實例包括:β-甲基丙烯醯基氧基-乙基二甲氧基甲基-矽烷、γ-甲基丙烯醯基氧基-丙基甲氧基二甲基-矽烷、γ-甲基丙烯醯基氧基-丙基二甲氧基甲基-矽烷、γ-甲基丙烯醯基氧基-丙基三甲氧基-矽烷、γ-甲基丙烯醯基氧基-丙基乙氧基二乙基-矽烷、γ-甲基丙烯醯基氧基-丙基二乙氧基甲基-矽烷、δ-甲基丙烯醯基-氧基-丁基二乙氧基甲基-矽烷或其等之混合物。
較佳地使用,以矽氧橡膠之總重量計,0至20wt.%之接枝劑。
矽氧-丙烯酸酯橡膠之適合之聚(甲基)丙烯酸烷基酯橡膠成分可係自甲基丙烯酸烷基酯類及/或丙烯酸烷基酯類、一種交聯劑(Ⅵ)及一種接枝劑(Ⅶ)製備。較佳之甲基丙烯酸烷基酯類及/或丙烯酸烷基酯類之實例包括C1
-至C8
-烷基酯類,例如甲酯、乙酯、正丁酯、第三丁酯、正丙酯、正己酯、正辛酯、正十二酯及2-乙基己酯;鹵基烷基酯類,較佳的是鹵基-C1
-C8
-烷基酯類,諸如丙烯酸氯乙酯,及此等單體之混合物。丙烯酸正丁酯係特別較佳的。
可使用作為用於矽氧-丙烯酸酯橡膠之聚(甲基)丙烯酸烷基酯橡膠成分之交聯劑(Ⅵ)係,例如,具有超過1個可聚合之雙鍵之單體。交聯單體之較佳實例係具有3至8個碳原子之不飽和單羧酸與具有3至12個碳原子之不飽和一元醇類、或具有2至4個OH基及2至20個碳原子之飽和多元醇類之酯類,諸如乙二醇二甲基丙烯酸酯、丙二醇二甲基丙烯酸酯、1,3-丁二醇二甲基丙烯酸酯及1,4-丁二醇二甲基丙烯酸酯。交聯劑可單獨地及/或以至少兩種交聯劑之混合物使用。
較佳之接枝劑(Ⅶ)之實例包括甲基丙烯酸烯丙酯、三聚氰酸三烯丙酯(triallyl cyanurate)、異三聚氰酸三烯丙酯(triallyl isocyanurate)或其等之混合物。亦可使用甲基丙烯酸烯丙酯作為交聯劑(Ⅵ)。接枝劑可單獨地及/或以至少兩種接枝劑之混合物使用。
以矽氧-丙烯酸酯橡膠之聚(甲基)丙烯酸烷基酯橡膠成分之總重量計,交聯劑(Ⅵ)及接枝劑(Ⅶ)之量係0.1至20wt.%。
理論上,矽氧-丙烯酸酯橡膠可如期望地經由矽氧橡膠於第一聚合作用階段中之聚合作用及丙烯酸酯橡膠成分於第二聚合作用階段中之聚合作用,或者以相反之次序,而製備。
於一種較佳具體實施例中,矽氧-丙烯酸酯橡膠可係經由首先製備於水性橡漿形式之矽氧橡膠而製備。該矽氧橡膠可係經由乳化聚合作用而製備,例如於US 2,891,920及US 3,294,725中敍述。對於該目的,於一種乳化劑(較佳的是一種以磺酸為基礎之乳化劑,例如烷基苯磺酸或烷基磺酸)之存在下,將包含有機矽氧烷、交聯劑及可選的接枝劑之混合物以剪切方式(例如藉由均質機)與水混合,該混合物完全地聚合以產生矽氧橡膠橡漿。一種烷基苯磺酸係特別適合的,此由於其不僅作為乳化劑而且亦作為聚合作用起始劑之緣故。於此種情況中,磺酸與烷基苯磺酸之金屬鹽或與烷基磺酸之金屬鹽之組合係有利的,此因為於其後之接枝聚合作用期間該聚合物係藉此安定化之緣故。
於聚合作用之後,反應係經由添加鹼性水溶液以中和該反應混合物而終止,例如經由添加氫氧化鈉、氫氧化鉀及/或碳酸鈉水溶液。
於該較佳具體實施例中,之後橡漿係以所使用之甲基丙烯酸烷基酯類及/或丙烯酸烷基酯類、交聯劑(Ⅵ)及接枝劑(Ⅶ)加強,及進行一種聚合作用。較佳者係由自由基引發之乳化聚合作用,例如經由過氧化物、偶氮化合物或氧化還原起始劑。特別較佳者係氧化還原起始劑系統之使用,特別地屬於經由組合硫酸亞鐵、伸乙二胺四乙酸二鈉(disodium ethylenediaminetetraacetate)、雕白粉(ronglite)及過氧化氫而製備的一種羥硫酸鹽起始劑系統。
於矽氧橡膠之製備中使用之接枝劑(Ⅴ)通常具有將聚(甲基)丙烯酸烷基酯橡膠成分共價地鍵結至矽氧橡膠成分之效應。於聚合作用中,該等兩種橡膠互相滲透及因此形成複合橡膠,於聚合作用之後其不再能夠容易地分離成為矽氧橡膠成分與聚(甲基)丙烯酸烷基酯橡膠成分的組成要素,。
對於矽氧-丙烯酸酯接枝橡膠B之製備,單體B.1係接枝於橡膠基B.2之上。
可使用,例如,於EP 249964、EP430134及US 4,888,388中敍述之聚合作用方法。
例如,根據下列之聚合作用方法,可適合地進行接枝聚合作用。於一種由自由基起始之單階段或多階段乳化聚合作用中,該合適之乙烯型單體B.1係於接枝基上聚合,該接枝基係以水性橡漿之形式存在。接枝效率藉此應盡可能地高及較佳的係高於或等於10%。接枝效率係顯著地視所使用之接枝劑(Ⅴ)或(Ⅶ)而定。於對於矽氧-丙烯酸酯接枝橡膠之聚合作用之後,將該水性橡漿加入,例如,加入先前已溶解金屬鹽類(例如氯化鈣或硫酸鎂)之熱水中。矽氧-丙烯酸酯接枝橡膠藉此凝聚及隨後係分離及可選地於一種較佳具體實施例中洗滌。
成分C係一種或一種以上之下列之接枝聚合物
C.1)以成分C計之5至95wt.%,較佳的是30至90wt.%,特別較佳的是80至90wt.%,特定言之85至90wt.%之一種下列之混合物
C.1.1) 以C.1計之65至85wt.%,較佳的是70至80wt.%之至少一種由乙烯型芳族化合物類(例如苯乙烯、α-甲基苯乙烯)、於環上經取代之乙烯型芳族化合物類(例如對-甲基苯乙烯、對-氯苯乙烯)及甲基丙烯酸(C1
-C8
)-烷基酯類(例如甲基丙烯酸甲酯、甲基丙烯酸乙酯)之群中選出之單體,及
C.1.2) 以C.1計之15至35wt.%,較佳的是20至30wt.%之至少一種由乙烯型氰化物類(例如不飽和之腈類諸如丙烯腈及甲基丙烯腈)、(甲基)丙烯酸(C1
-C8
)-烷基酯類(例如甲基丙烯酸甲酯、丙烯酸正丁酯、丙烯酸第三丁酯)及不飽和羧酸之衍生物類(例如酐類及醯亞胺類)(例如順丁烯二酐及N-苯基-順丁烯二醯亞胺)之群中選出之單體
接枝於下列之上
C.2)95至5wt.%,較佳的是70至10wt.%,特別較佳的是20至10wt.%,特定言之15至10wt.%之至少一種具有<0℃(較佳的是<-20℃)之玻璃轉移溫度的接枝基,該接枝基C.2)通常具有0.05至10微米(較佳的是0.1至5微米,特別較佳的是0.15至2微米,特定言之0.5至1.5微米)之平均粒度(d50
值)。
平均粒度d50
係於每一種情況中高於其值或低於其值的各有50wt.%之粒子。其可係藉由超離心作用測量而測定(W. Scholtan,H. Lange,Kolloid,Z. und Z. Polymere 250(1972),782-1796)。
較佳之單體C.1.1可係選自於單體苯乙烯、α-甲基苯乙烯及甲基丙烯酸甲酯之至少一種;較佳之單體C.1.2係選自於單體丙烯腈、順丁烯二酐及甲基丙烯酸甲酯之至少一種。
特別較佳之單體包括C.1.1苯乙烯及C.1.2丙烯腈。
除了矽氧-丙烯酸酯(複合)橡膠以外,對於接枝聚合物C之適合接枝基C.2係,例如,二烯橡膠類、二烯-乙烯基嵌段共聚物橡膠類、乙烯-丙烯(二烯)單體(EP(D)M)橡膠類(即以乙烯/丙烯及可選的二烯為基礎之橡膠類)、丙烯酸酯、聚胺基甲酸酯、矽氧、氯平(chloroprene)及乙烯/乙酸乙烯酯橡膠類、以及此等橡膠之混合物。
較佳之接枝基C.2包括由丁二烯橡膠、異戊二烯橡膠、二烯橡膠之共聚物類、丁二烯橡膠與另外之可共聚合之單體(例如根據C.1.1及C.1.2)之共聚物類及異戊二烯橡膠與另外之可共聚合之橡膠(例如根據C.1.1及C.1.2)之共聚物類組成之群中之至少一種二烯橡膠選出之二烯橡膠類。純的聚丁二烯橡膠及苯乙烯-丁二烯嵌段共聚物橡膠係特別較佳的。
接枝聚合物之凝膠含量係至少15wt.%,較佳的是至少20wt.%,特別較佳的是20至40wt.%(於丙酮中測量)。接枝聚合物之凝膠含量係於25℃在一種適合之溶劑中測定(M. Hoffmann,H. Krmer,R. Kuhn,Polymeranalytik Ⅰund Ⅱ,Georg Thieme-Verlag,Stuttgart 1977)。
特別較佳之聚合物C係,例如,經由自由基聚合作用而製備之丙烯腈-丁二烯-苯乙烯(ABS)聚合物(乳化、總體(mass)、溶液及懸浮聚合之ABS),例如,於DE-A 2 035 390(=US-PS 3 644 574)中或於DE-A 2 248 242(=GB-PS 1 409 275)中或者於Ullmanns Enzyklopdie der Technischen Chemie,Vol. 19(1980),p. 280 ff中敍述。特別較佳之聚合物C係經由總體、溶液或懸浮聚合作用而製備之ABS。
接枝聚合物C包含C.1.1與C.1.2之自由態共聚物,即不是化學鍵結於橡膠基之共聚物,其係以其可溶解於適合之溶劑(例如丙酮)中之事實而區分。
成分C較佳地包含C.1.1與C.1.2之一種自由態共聚物,其具有60,000至150,000克/莫耳之重量平均分子量(Mw)(較佳的是70,000至130,000克/莫耳,特別較佳的是70,000至90,000克/莫耳),經由膠透層析術測定。
成分D較佳地包含一種或一種以上之熱塑性乙烯型(共)聚合物類D.1及/或聚對酞酸伸烷基酯類(polyalkylene terephthalates)D.2。
適合之乙烯型(共)聚合物類D.1包括來自乙烯型芳族化合物類、乙烯型氰化物類(不飽和之腈類)、(甲基)丙烯酸(C1
-C8
)-烷基酯類、不飽和之羧酸類及不飽和之羧酸之衍生物類(諸如酐類及醯亞胺類)之群之至少一種單體的聚合物類。特別適合者係下列之(共)聚合物類
D.1.1 50至99重量份,較佳的是60至80重量份,特定言之70至80重量份之乙烯型芳族化合物類及/或於環上經取代之乙烯型芳族化合物類(諸如苯乙烯、α-甲基苯乙烯、對-甲基苯乙烯、對-氯苯乙烯)及/或(甲基)丙烯酸(C1
-C8
)-烷基酯類(諸如甲基丙烯酸甲酯、甲基丙烯酸乙酯),及
D.1.2 1至50重量份,較佳的是20至40重量份,特定言之20至30重量份之乙烯型氰化物類(不飽和之腈類)(諸如丙烯腈及甲基丙烯腈)、及/或(甲基)丙烯酸(C1
-C8
)-烷基酯類(諸如甲基丙烯酸甲酯、丙烯酸正丁酯、丙烯酸第三丁酯)、及/或不飽和之羧酸類(諸如順丁烯二酸)及/或不飽和之羧酸之衍生物類(諸如酐類及醯亞胺類)(例如順丁烯二酐及N-苯基順丁烯二醯亞胺)。
乙烯型(共)聚合物類D.1通常係類似於樹脂,熱塑性並且不含橡膠的。特別較佳者係D.1.1苯乙烯及D.1.2丙烯腈之共聚物。
根據D.1之(共)聚合物類係已知的及例如可經由自由基聚合作用(特定言之經由乳化、懸浮、溶液或總體聚合作用)而製備。該等(共)聚合物類較佳的是具有15,000至200,000克/莫耳,特別較佳的是60,000至150,000克/莫耳,特定言之70,000至130,000克/莫耳之平均分子量Mw(重量平均,經由光散射或沈降作用而測定)。
成分D.2之聚對酞酸伸烷基酯類較佳的係芳族二羧酸類或彼等之反應性衍生物類(諸如二甲基酯類或酐類)與脂族、環脂族或芳脂族二醇類之反應產物,以及此等反應產物之混合物。
較佳之聚對酞酸伸烷基酯類通常包含,以該二羧酸成分計,至少80wt.%(較佳的是至少90wt.%)之對酞酸自由基及以該二醇成分計,至少80wt.%(較佳的是至少90wt.%)之乙二醇及/或1,4-丁二醇自由基。
除了包含對酞酸自由基以外,較佳之聚對酞酸伸烷基酯類可包含,例如,高達20莫耳%(較佳的是高達10莫耳%)之具有8至14個碳原子之其他芳族或環脂族二羧酸類或具有4至12個碳原子之脂族二羧酸類的自由基,例如酞酸、異酞酸、萘-2,6-二羧酸、4,4’-聯苯二羧酸、丁二酸、己二酸、癸二酸、壬二酸、環己烷二乙酸之自由基。
除了包含乙二醇或1,3-丙二醇或1,4-丁二醇自由基以外,較佳之聚對酞酸伸烷基酯類可包含高達20莫耳%之具有3至12個碳原子之其他脂族二醇類或具有6至21個碳原子之環脂族二醇類,例如1,3-丙二醇、2-乙基-1,3-丙二醇、新戊二醇、1,5-戊二醇、1,6-己二醇、環己烷-1,4-二甲醇、3-甲基-2,4-戊二醇、2-甲基-2,4-戊二醇、2,2,4-三甲基-1,3-戊二醇及2-乙基-1,6-己二醇、2,2-二乙基-1,3-丙二醇、2,5-己二醇、1,4-二-(β-羥基乙氧基)-苯、2,2-雙-(4-羥基環己基)-丙烷、2,4-二羥基-1,1,3,3-四甲基-環丁烷、2,2-雙-(3-β-羥基乙氧基苯基)-丙烷及2,2-雙-(4-羥基丙氧基苯基)-丙烷之自由基(DE-A 24 07 674、24 07 776、27 15 932)。
該等聚對酞酸伸烷基酯類可係,例如,經由相對少量之三元醇類或四元醇類或者三鹼式羧酸類或四鹼式羧酸類之組合而分枝,例如根據DE-A 1 900 270及US-PS 3 692 744。較佳之分枝劑之實例包括1,3,5-苯三甲酸、1,2,4-苯三甲酸、三羥甲基乙烷、三羥甲基丙烷及新戊四醇。
於某些具體實施例中,特別較佳者係已經完全地(solely)自對酞酸及其反應性衍生物(例如其之二烷基酯類)與乙二醇及/或1,4-丁二醇製備之聚對酞酸伸烷基酯類、及此等聚對酞酸伸烷基酯類之混合物。
聚對酞酸伸烷基酯類之混合物較佳地包含1至50wt.%(較佳的是1至30wt.%)之聚對酞酸乙二酯及50至99wt.%(較佳的是70至99wt.%)之聚對酞酸丁二酯。
較佳使用之聚對酞酸伸烷基酯類通常具有於酚/鄰-二氯苯(1:1重量份)中於25℃於一種Ubbelohde黏度計中測量之0.4至1.5分升/克(dl/g),較佳的是0.5至1.2分升/克之限制黏度。
該等聚對酞酸伸烷基酯類可係經由已知之方法而製備(見例如Kunststoff-Handbuch,Volume Ⅷ,p. 695ff,Carl-Hanser-Verlag,Munich 1973)。
組成物可選擇性地另外包含一種或一種以上根據成分E之市售添加劑,諸如潤滑劑、脫模劑(例如新戊四醇四硬脂酸酯)、晶核形成劑、安定劑、抗靜電劑(例如導電之碳黑、碳纖維、碳奈米管及有機抗靜電劑諸如聚伸烷基醚類、烷基磺酸酯類或包含聚醯胺之聚合物類)、酸類、填充劑及強化材料(例如玻璃或碳纖維、雲母、高嶺土、滑石粉、CaCO3
及玻璃薄片)以及著色劑及顏料。倘若為了任何理由而需要,則亦可包含於此技術領域中或其他已知的其他添加劑。
熱塑性模製組成物可係,例如,經由以一種已知之方法混合個別之成分及熔解調配、及於220℃至320℃(較佳的是240℃至300℃)之溫度於既有裝置(諸如內揑合機、擠出機及雙軸螺旋(twin-shaft screw))中熔解擠出該混合物而製備。
個別成分之混合可係以已知之方法進行,即,連續地或同時地,於約20℃(室溫)或於較高之溫度。
亦提供一種用於模製組成物之製備方法及該等模製組成物於模製物件製造中之用途,及該等模製物件本身。
該等模製組成物可使用於任何種類之模製物件之製造中。此等可係經由射入模製、擠出及吹氣模造方法而製造。加工之另外一種形式係經由自先前製造之板或膜深引伸(deep-drawing)而製造模製物件。
此等模製物件之實例係膜、型材(profiles)、任何種類之澆鑄零件(例如用於家庭用具諸如電視、榨汁機、咖啡機、混合機;用於辦公室設備諸如顯示器、平面銀幕、筆記型電腦、印表機、複印機)、片板、管、用於電裝置之導管、窗、門及用於建築部門之其他型材(內部裝配及外部用途)以及用於電子學及電機工程之零件(諸如開關、插頭及插座)、以及用於商用車輛(特定言之用於汽車部門)之車身及內部組件。
特定言之,模製組成物亦可使用於,例如,下列之模製物件或模製品之製造中:用於鐵路車輛、船、飛機、公共汽車及其他機動車輛之內部拋光(finishing)之零件,用於包含小型電壓器之電裝置的外殼,用於散佈及傳送資訊之裝置的外殼,用於醫療裝置之外殼及包覆料,按摩裝置及其外殼,孩童之玩具車輛,預先製造之牆板,用於安全裝置及用於電視之外殼,熱絕緣之運輸貨櫃,用於衛生及浴室裝配之模製品,用於通風器開口之覆蓋格網,及用於園藝設備之外殼。
下列之實例發揮作用以進一步解釋本發明。
以雙酚A為基礎具有ηrel
=1.28之相對溶液黏度(於作為溶劑之CH2
Cl2
中於25℃及於0.5克/100毫升之濃度測量)之未分枝的聚碳酸酯。
衝擊改質劑,下列之接枝聚合物
B-1.1 接枝於下列之上之11wt.%之甲基丙烯酸甲酯
B-1.2 89wt.%之一種矽氧-丙烯酸酯複合橡膠作為接枝基,該矽氧-丙烯酸酯橡膠包含
B-1.2.1 92wt.%之矽氧橡膠及
B-1.2.2 8wt.%之聚丙烯酸丁酯橡膠,及
該等兩種提及之橡膠成分B-1.2.1及B-1.2.2於複合橡膠中互相滲透致使彼等實質上不能自互相分離。
衝擊改質劑,下列之接枝聚合物
B-2.1 接枝於下列之上之17wt.%之甲基丙烯酸甲酯
B-2.2 83wt.%之一種矽氧-丙烯酸酯複合橡膠作為接枝基,該矽氧-丙烯酸酯橡膠包含
B-2.2.1 11wt.%之矽氧橡膠及
B-2.2.2 89wt.%之聚丙烯酸丁酯橡膠,及
該等兩種提及之橡膠成分B-2.2.1及B-2.2.2於複合橡膠中互相滲透致使彼等實質上不能自互相分離。
於以丙烯腈-丁二烯-苯乙烯三元聚合物計之18wt.%之一種具有26wt.%之苯乙烯含量之聚丁二烯-苯乙烯嵌段共聚物橡膠之存在下,經由以丙烯腈-丁二烯-苯乙烯三元聚合物計之82wt.%之由24wt.%之丙烯腈與76wt.%之苯乙烯組成之混合物的總體聚合作用而製備丙烯腈-丁二烯-苯乙烯三元聚合物。於該丙烯腈-丁二烯-苯乙烯三元聚合物中之自由態苯乙烯-丙烯腈(SAN)共聚物成分之重量平均分子量Mw
係80,000克/莫耳(由膠透層析術於四氫呋喃(THF)中測量)。該丙烯腈-丁二烯-苯乙烯三元聚合物之凝膠含量係24wt.%(於丙酮中測量)。
經由總體聚合作用而製備丙烯腈-丁二烯-苯乙烯三元聚合物,其中丙烯腈:丁二烯:苯乙烯之重量比係20:16:64。於該丙烯腈-丁二烯-苯乙烯三元聚合物中之自由態苯乙烯-丙烯腈共聚物成分之重量平均分子量Mw
係168,000克/莫耳(由膠透層析術於四氫呋喃中測量)。該丙烯腈-丁二烯-苯乙烯三元聚合物之凝膠含量係30wt.%(於丙酮中測量)。
具有130公斤/莫耳之重量平均分子量Mw
(由膠透層析術測定)之77wt.%之丙烯腈與23wt.%之苯乙烯的共聚物,經由總體聚合作用而製備。
成分E-1:新戊四醇四硬脂酸酯成分E-2:B900(製造商:Ciba Specialty Chemicals Inc.,Basel,Switzerland)
於表1-2中列出之個別物質係以每分鐘225轉之速率及以20公斤/小時之通過料量,於260℃之機器溫度,於一種雙螺桿擠出機(ZSK-25)(Werner und Pfleiderer)中調配然後粒化。
完成之顆粒係於一種射入模製機中加工成為對應之試驗樣本(熔解溫度260℃,工具溫度80℃,流動頭速度(flow front speed)240毫米/秒)。根據DIN EN ISO 527(斷裂延伸率,經由抗張試驗而測定)、ISO 11443(於260℃之熔化黏度及1,000秒-1
(s-1
)之切變速率)、及DIN EN ISO 1133(於260℃之熔體體積流動速度(MVR)及5公斤之立方塊負荷)作性質描述。
使用根據ISO 1133於260℃以5公斤之立方塊負荷對於95℃及100%相對濕度下儲存(“FWL儲存”)歷時7日之顆粒測量於MVR中之改變,作為所製備之組成物的水解安定性量度。比較於儲存前之MVR值,MVR值之增加係以ΔMVR(水解)所量測,其係由下列式定義:
與比較實例之組成物比較,實例1
及3
之組成物具有較高之水解安定性、較高之斷裂延伸率及較低之熔化黏度,此自表1觀之係清楚的。
丙烯腈-丁二烯-苯乙烯三元聚合物C-2包含自由態之共聚物,即不是化學鍵結於橡膠之共聚物,具有比於丙烯腈-丁二烯-苯乙烯三元聚合物C-1者高之莫耳質量。與包含成分C-2之比較實例6
及8
之組成物比較,包含成分C-1之組成物(實例5
及7
)具有較高之水解安定性、較高之斷裂延伸率及較低之熔化黏度。
已經掲示本發明之標的,由此所進行的許多修飾、替代及變化係可能的,此將係明顯的。應了解,具體實施例可不同於特定地敍述而實施。此等修飾、替代及變化係涵蓋於本專利申請案之範圍之內。如於本揭示及下列之申請專利範圍中使用,冠詞諸如“一”、“該”及其他可包含單數或複數之後述事物。
Claims (20)
- 一種組成物,包含:A)於每一種情況中以成分A+B+C之重量份之和計,40至99重量份之芳族聚碳酸酯及/或芳族聚酯碳酸酯,B)於每一種情況中以成分A+B+C之重量份之和計,0.5至20重量份之第一接枝聚合物,其中該接枝基係矽氧橡膠與聚(甲基)丙烯酸烷基酯橡膠之矽氧-丙烯酸酯複合橡膠,及其中該矽氧橡膠係以該接枝基計之65至95wt.%之量存在,C)於每一種情況中以成分A+B+C之重量份之和計,0.5至40重量份之一種包含一種非化學鍵結於橡膠、及具有60,000至150,000克/莫耳之重量平均分子量之共聚物的第二接枝聚合物,其中該組成物不含防火劑。
- 如申請專利範圍第1項之組成物,其包含一種下列之接枝聚合物作為成分B:B.1 5至95wt.%之接枝於下列之一種或一種以上之乙烯型單體B.2 95至5wt.%之一種或一種以上之矽氧-丙烯酸酯複合橡膠作為接枝基,其中該矽氧-丙烯酸酯橡膠包含 B.2.1 65至95wt.%之矽氧橡膠及B.2.2 35至5wt.%之聚(甲基)丙烯酸烷基酯橡膠,其中該等兩種提及之橡膠成分B.2.1及B.2.2於該複合橡膠中互相滲透致使B.2.2及B.2.2實質上不能自互相分離。
- 如申請專利範圍第2項之組成物,其中該乙烯型單體B.1係至少一種由苯乙烯、α-甲基苯乙烯、甲基丙烯酸甲酯、丙烯酸正丁酯及丙烯腈組成之群中選出者。
- 如申請專利範圍第1項之組成物,其包含一種下列之接枝聚合物作為成分C:C.1)以成分C計之5至95wt.%之一種下列之混合物C.1.1)以C.1計之65至85wt.%之至少一種由乙烯型芳族化合物類、於環上經取代之乙烯型芳族化合物類、及甲基丙烯酸(C1 -C8 )-烷基酯類組成之群中選出之單體,及C.1.2)以C.1計之15至35wt.%之至少一種由乙烯型氰化物類、(甲基)丙烯酸(C1 -C8 )-烷基酯類及不飽和羧酸之衍生物類組成之群中選出之單體,及接枝於下列之上C.2)95至5wt.%之至少一種具有<0℃之玻璃轉移 溫度的接枝基,該接枝基C.2)具有0.05至10微米之平均粒度,d50 值。
- 如申請專利範圍第4項之組成物,其中該接枝基C.2係由二烯橡膠類、二烯-乙烯基嵌段共聚物橡膠類、乙烯/丙烯橡膠類、乙烯/丙烯/二烯橡膠類、丙烯酸酯、聚胺基甲酸酯、矽氧、氯平及乙烯/乙酸乙烯酯橡膠類組成之群中選出,其限制條件為不包括其中具有矽氧橡膠與丙烯酸酯橡膠之混合物。
- 如申請專利範圍第1項之組成物,其包含一種非化學鍵結於橡膠、具有70,000至90,000克/莫耳之重量平均分子量的共聚物,作為成分C。
- 如申請專利範圍第4項之組成物,其包含一種經由總體、溶液及/或總體-懸浮聚合作用方法而製備及具有橡膠含量,即成分C.2於接枝聚合物C中之含量為10至20wt.%之接枝聚合物、以及一種接枝殼作為成分C,該接枝殼包含,於每一種情況中以接枝殼之單體計,20至30wt.%之至少一種根據C.1.2之單體、及70至80wt.%之至少一種根據C.1.1之單體。
- 如申請專利範圍第1項之組成物,其包含以成分A+B+C+D之重量份之和計,3至16重量份之至少一種由不含橡膠之乙烯型(共)聚合物及聚對酞酸伸烷基酯組成之群中選出之聚合物,作為成分D。
- 如申請專利範圍第1項之組成物,其包含,以成分 A+B+C+D之重量份之和計,3至16重量份之至少一種由不含橡膠之乙烯型(共)聚合物D.1及聚對酞酸伸烷基酯D.2組成之群中選出之聚合物,作為成分D。
- 如申請專利範圍第1項之組成物,其包含,於每一種情況中以成分A+B+C之重量份之和計,0至50重量份至少一種由潤滑劑、脫模劑、晶核形成劑、安定劑、抗靜電劑、酸、填充劑、強化材料、著色劑及顏料組成之群中選出之添加劑。
- 一種組成物,係由下列所組成:A)於每一種情況中以成分A+B+C+D之重量份之和計,40至99重量份之芳族聚碳酸酯及/或芳族聚酯碳酸酯,B)於每一種情況中以成分A+B+C+D之重量份之和計,0.5至20重量份之第一接枝聚合物,其中該接枝基係互相滲透之矽氧橡膠與聚(甲基)丙烯酸烷基酯橡膠之矽氧-丙烯酸酯複合橡膠,其中矽氧橡膠之量係以該接枝基計之65至95wt.%,C)以成分A+B+C+D之重量份之和計,0.5至20重量份之一種包含非化學鍵結於橡膠之共聚物、及具有60,000至150,000克/莫耳之重量平均分子量之第二接枝聚合物,D)以成分A+B+C+D之重量份之和計,3至16 重量份之至少一種由不含橡膠之乙烯型(共)聚合物及聚對酞酸伸烷基酯組成之群中選出之聚合物,及E)可選擇地0.5至25重量份(於每一種情況中以成分A+B+C+D之重量份之和計)之至少一種添加劑,其係選自由潤滑劑、脫模劑、晶核形成劑、安定劑、抗靜電劑、酸、填充劑、強化材料、著色劑及顏料組成之群。
- 如申請專利範圍第11項之組成物,其中成分B之量,以成分A+B+C+D之重量份之和計係8至13重量份,及成分C之量,以成分A+B+C+D之重量份之和計係7至16重量份。
- 如申請專利範圍第11項之組成物,其係由A、B、C、D組成。
- 如申請專利範圍第11項之組成物,其係由A、B、C、D及E組成。
- 一種包含如申請專利範圍第1項之組成物的模製物件。
- 一種包含如申請專利範圍第11項之組成物的模製物件。
- 如申請專利範圍第16項之模製物件,其中該模製物件係機動車輛、鐵路車輛、飛機、船舶之零件、膜、型材、及/或任何種類之外殼零件。
- 一種用於製備如申請專利範圍第15項之模製物件的方法,其包含混合A、B、C與D以形成一種混合物,及熔解調配及熔解擠出該混合物。
- 如申請專利範圍第18項之方法,其中該方法係於220℃至320℃之溫度進行。
- 如申請專利範圍第18項之方法,其中該方法係使用一內揑合機、一擠出機及/或一雙軸螺旋而進行。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008062904 | 2008-12-23 | ||
DE102009005762A DE102009005762A1 (de) | 2008-12-23 | 2009-01-23 | Schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201035234A TW201035234A (en) | 2010-10-01 |
TWI466944B true TWI466944B (zh) | 2015-01-01 |
Family
ID=42194237
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW98144044A TWI466944B (zh) | 2008-12-23 | 2009-12-22 | 衝擊改質之聚碳酸酯組成物 |
Country Status (12)
Country | Link |
---|---|
US (1) | US8461260B2 (zh) |
EP (1) | EP2382266B1 (zh) |
JP (1) | JP5752603B2 (zh) |
KR (1) | KR101703364B1 (zh) |
CN (1) | CN102264830B (zh) |
BR (1) | BRPI0923590A2 (zh) |
CA (1) | CA2748221A1 (zh) |
DE (1) | DE102009005762A1 (zh) |
ES (1) | ES2440749T3 (zh) |
MX (1) | MX2011006318A (zh) |
TW (1) | TWI466944B (zh) |
WO (1) | WO2010072335A1 (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2360206A1 (de) | 2010-02-13 | 2011-08-24 | Bayer MaterialScience AG | Verwendung von Mischungen zur Herstellung schlagzähmodifizierter thermoplastischer Zusammensetzungen |
EP3056536A4 (en) * | 2013-10-24 | 2016-10-26 | Zeon Corp | LATEX COMPOSITION, MANUFACTURING METHOD, COMPOSITE MATERIAL AND CONDUCTIVE PRESSURE BODY |
EP3636683B1 (en) * | 2017-06-06 | 2023-09-06 | Mitsubishi Chemical Corporation | Polyorganosiloxane-containing graft copolymer, thermoplastic resin composition, and molded article |
EP3828236B1 (de) * | 2019-11-27 | 2022-06-01 | Covestro Intellectual Property GmbH & Co. KG | Flammgeschützter polycarbonat-polyester blend |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI227723B (en) * | 1998-10-23 | 2005-02-11 | Gen Electric | Polycarbonate resin/ABS graft copolymer/SAN blends |
US20080108751A1 (en) * | 2006-11-03 | 2008-05-08 | Marina Rogunova | Thermoplastic composition having low gloss and low temperature impact performance |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2891920A (en) | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
DE1495626B1 (de) | 1960-03-30 | 1971-06-09 | Bayer Ag | Verfahren zum herstellen von polyestern |
GB1024024A (en) | 1963-04-08 | 1966-03-30 | Dow Corning | Improvements in or relating to polymerising or co-polymerising organosilicon compounds |
US3419634A (en) | 1966-01-03 | 1968-12-31 | Gen Electric | Organopolysiloxane polycarbonate block copolymers |
FR1580834A (zh) | 1968-01-04 | 1969-09-12 | ||
US3644574A (en) | 1969-07-17 | 1972-02-22 | Eastman Kodak Co | Shaped articles of blends of polyesters and polyvinyls |
US4013613A (en) | 1971-10-01 | 1977-03-22 | General Electric Company | Reinforced intercrystalline thermoplastic polyester compositions |
DE2232877B2 (de) | 1972-07-05 | 1980-04-10 | Werner & Pfleiderer, 7000 Stuttgart | Verfahren zur Herstellung von Polyestern |
JPS5039599B2 (zh) | 1973-03-30 | 1975-12-18 | ||
DE2407776A1 (de) | 1974-02-19 | 1975-09-04 | Licentia Gmbh | Schaltung zur regelung der betriebsspannung fuer die transistor-zeilenendstufe eines fernsehempfaengers |
JPS5292295A (en) | 1976-01-29 | 1977-08-03 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester |
IT1116721B (it) | 1976-04-02 | 1986-02-10 | Allied Chem | Copolimero bisfenolo a tereftalato carbonato lavorabili in massa fusa |
DE2715932A1 (de) | 1977-04-09 | 1978-10-19 | Bayer Ag | Schnellkristallisierende poly(aethylen/alkylen)-terephthalate |
DE2842005A1 (de) | 1978-09-27 | 1980-04-10 | Bayer Ag | Polycarbonate mit alkylphenyl-endgruppen, ihre herstellung und ihre verwendung |
JPS5594930A (en) | 1979-01-10 | 1980-07-18 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester by improved bulk polymerization process |
DE2940024A1 (de) | 1979-10-03 | 1981-04-16 | Bayer Ag, 5090 Leverkusen | Aromatische polyester, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von spritzgussartikeln, folien und ueberzuegen |
DE3007934A1 (de) | 1980-03-01 | 1981-09-17 | Bayer Ag, 5090 Leverkusen | Aromatische polyestercarbonate, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von spritzgussartikeln, folien und ueberzuegen |
DE3334782A1 (de) | 1983-04-19 | 1984-10-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von polydiorganosiloxanen mit hydroxyaryloxy-endgruppen |
EP0249964A3 (en) | 1986-06-17 | 1988-07-20 | Mitsubishi Rayon Co., Ltd. | Polycarbonate resin composition |
DE3631540A1 (de) | 1986-09-17 | 1988-03-24 | Bayer Ag | Thermoplastische formmassen mit hoher alterungsbestaendigkeit und guter tieftemperaturzaehigkeit |
EP0307963B1 (en) | 1987-09-21 | 1995-02-15 | Mitsubishi Rayon Co., Ltd. | Polycarbonate resin composition |
DE3844633A1 (de) | 1988-08-12 | 1990-04-19 | Bayer Ag | Dihydroxydiphenylcycloalkane, ihre herstellung und ihre verwendung zur herstellung von hochmolekularen polycarbonaten |
DE69027976T2 (de) | 1989-11-27 | 1997-03-06 | Mitsubishi Rayon Co | Hochschlagfeste Pfropfkopolymere und Harzzusammensetzungen |
AU676590B2 (en) | 1993-09-08 | 1997-03-13 | Teijin Chemicals Ltd | Resin composition and molded article |
JPH07207085A (ja) * | 1994-01-12 | 1995-08-08 | Nippon G Ii Plast Kk | 耐衝撃性樹脂組成物 |
JP3841312B2 (ja) | 1994-05-27 | 2006-11-01 | 三菱レイヨン株式会社 | 難燃性樹脂組成物 |
JPH08259791A (ja) | 1995-01-23 | 1996-10-08 | Mitsubishi Rayon Co Ltd | 難燃性樹脂組成物 |
US5807914A (en) | 1995-07-05 | 1998-09-15 | Mitsubishi Engineering-Plastics Corporation | Glass fiber-reinforced polycarbonate resin composition |
TWI234574B (en) | 1997-05-06 | 2005-06-21 | Idemitsu Kosan Co | Battery pack obtained from a flame-retardant polycarbonate resin composition |
US6613820B2 (en) | 1997-08-29 | 2003-09-02 | General Electric Company | Polycarbonate resin composition |
JP3471225B2 (ja) | 1998-06-29 | 2003-12-02 | 三菱レイヨン株式会社 | 難燃性熱可塑性樹脂組成物 |
JP2001247759A (ja) * | 2000-03-09 | 2001-09-11 | Asahi Kasei Corp | ゼオライトにより安定化されたポリカーボネート系難燃性樹脂組成物 |
JP2002069282A (ja) | 2000-08-25 | 2002-03-08 | Mitsubishi Engineering Plastics Corp | ポリカーボネート樹脂組成物 |
JP4361205B2 (ja) * | 2000-11-29 | 2009-11-11 | Sabicイノベーティブプラスチックスジャパン合同会社 | 難燃性樹脂組成物およびその成形品 |
DE10152317A1 (de) * | 2001-10-26 | 2003-05-08 | Bayer Ag | Mineralverstärkte schlagzähmodifizierte Polycarbonat-Blends |
DE10234420A1 (de) * | 2002-07-29 | 2004-02-12 | Bayer Ag | Schlagzähmodifizierte Polycarbonat Blends |
JP2004359889A (ja) * | 2003-06-06 | 2004-12-24 | Mitsubishi Rayon Co Ltd | シリコーン/アクリル複合ゴム系グラフト共重合体および熱可塑性樹脂組成物 |
US20060004154A1 (en) * | 2004-07-02 | 2006-01-05 | Derudder James L | Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof |
JP2006249163A (ja) * | 2005-03-09 | 2006-09-21 | Sumitomo Dow Ltd | 熱可塑性樹脂組成物 |
JP2006335882A (ja) * | 2005-06-02 | 2006-12-14 | Sumitomo Dow Ltd | 難燃性熱可塑性樹脂組成物 |
DE102005058836A1 (de) * | 2005-12-09 | 2007-06-14 | Bayer Materialscience Ag | Polycarbonat-Formmassen |
DE102006012990A1 (de) * | 2006-03-22 | 2007-09-27 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
-
2009
- 2009-01-23 DE DE102009005762A patent/DE102009005762A1/de not_active Withdrawn
- 2009-12-10 MX MX2011006318A patent/MX2011006318A/es active IP Right Grant
- 2009-12-10 EP EP09767987.2A patent/EP2382266B1/de active Active
- 2009-12-10 KR KR1020117014359A patent/KR101703364B1/ko active IP Right Grant
- 2009-12-10 JP JP2011542694A patent/JP5752603B2/ja active Active
- 2009-12-10 CN CN200980151970.9A patent/CN102264830B/zh active Active
- 2009-12-10 WO PCT/EP2009/008817 patent/WO2010072335A1/de active Application Filing
- 2009-12-10 ES ES09767987.2T patent/ES2440749T3/es active Active
- 2009-12-10 BR BRPI0923590A patent/BRPI0923590A2/pt not_active IP Right Cessation
- 2009-12-10 CA CA2748221A patent/CA2748221A1/en not_active Abandoned
- 2009-12-17 US US12/640,328 patent/US8461260B2/en active Active
- 2009-12-22 TW TW98144044A patent/TWI466944B/zh not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI227723B (en) * | 1998-10-23 | 2005-02-11 | Gen Electric | Polycarbonate resin/ABS graft copolymer/SAN blends |
US20080108751A1 (en) * | 2006-11-03 | 2008-05-08 | Marina Rogunova | Thermoplastic composition having low gloss and low temperature impact performance |
Also Published As
Publication number | Publication date |
---|---|
DE102009005762A1 (de) | 2010-06-24 |
US8461260B2 (en) | 2013-06-11 |
MX2011006318A (es) | 2011-06-24 |
US20100160534A1 (en) | 2010-06-24 |
JP2012513503A (ja) | 2012-06-14 |
EP2382266B1 (de) | 2013-11-27 |
ES2440749T3 (es) | 2014-01-30 |
KR101703364B1 (ko) | 2017-02-06 |
BRPI0923590A2 (pt) | 2016-01-26 |
CN102264830A (zh) | 2011-11-30 |
EP2382266A1 (de) | 2011-11-02 |
TW201035234A (en) | 2010-10-01 |
CA2748221A1 (en) | 2010-07-01 |
WO2010072335A1 (de) | 2010-07-01 |
CN102264830B (zh) | 2014-08-06 |
KR20110103399A (ko) | 2011-09-20 |
JP5752603B2 (ja) | 2015-07-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI466945B (zh) | 耐火的衝擊性改質之聚碳酸酯組成物 | |
TWI466946B (zh) | 阻燃的經衝擊性改質之聚碳酸酯組成物 | |
CN100408629C (zh) | 阻燃的聚碳酸酯模塑组合物 | |
TWI441872B (zh) | 具有良好之自然色、水解穩定度及熔融穩定度組合之經衝擊改良之聚碳酸酯組成物 | |
CN104812825B (zh) | 防火的聚碳酸酯模塑料vi | |
TWI461481B (zh) | 聚碳酸酯模塑組成物 | |
US8318857B2 (en) | Impact-modified polycarbonate compositions | |
US8779050B2 (en) | Impact modified polycarbonate compositions | |
TWI481662B (zh) | 防火的經衝擊性改質之聚碳酸酯組成物 | |
CN107735448B (zh) | 阻燃的聚碳酸酯-聚酯组合物 | |
TWI466944B (zh) | 衝擊改質之聚碳酸酯組成物 | |
KR102329692B1 (ko) | 가수분해-안정성 폴리카르보네이트-폴리에스테르 조성물 | |
KR20200090805A (ko) | 우수한 안정성을 갖는 열가소성 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Annulment or lapse of patent due to non-payment of fees |