TWI377227B - A membrane electrode assembly, and a fuel cell and a muiti-layer polyelectrolyte membrane comprising the same - Google Patents

A membrane electrode assembly, and a fuel cell and a muiti-layer polyelectrolyte membrane comprising the same Download PDF

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Publication number
TWI377227B
TWI377227B TW093122781A TW93122781A TWI377227B TW I377227 B TWI377227 B TW I377227B TW 093122781 A TW093122781 A TW 093122781A TW 93122781 A TW93122781 A TW 93122781A TW I377227 B TWI377227 B TW I377227B
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Taiwan
Prior art keywords
film
polymer
ionic
polyelectrolyte
acid
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TW093122781A
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English (en)
Chinese (zh)
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TW200524980A (en
Inventor
Lotfi Hedhli
Isabelle Decker
Patrick M Piccione
Holger E Amort
Scott R Gaboury
Fabienne Piroux
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Arkema Inc
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6287—Polymers of sulfur containing compounds having carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8077—Oximes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1053—Polymer electrolyte composites, mixtures or blends consisting of layers of polymers with at least one layer being ionically conductive
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0094—Composites in the form of layered products, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
TW093122781A 2003-07-30 2004-07-29 A membrane electrode assembly, and a fuel cell and a muiti-layer polyelectrolyte membrane comprising the same TWI377227B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US49100503P 2003-07-30 2003-07-30
US10/891,463 US7449111B2 (en) 2003-07-30 2004-07-14 Resins containing ionic or ionizable groups with small domain sizes and improved conductivity

Publications (2)

Publication Number Publication Date
TW200524980A TW200524980A (en) 2005-08-01
TWI377227B true TWI377227B (en) 2012-11-21

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Application Number Title Priority Date Filing Date
TW093122781A TWI377227B (en) 2003-07-30 2004-07-29 A membrane electrode assembly, and a fuel cell and a muiti-layer polyelectrolyte membrane comprising the same

Country Status (7)

Country Link
US (1) US7449111B2 (https=)
EP (1) EP1505120A1 (https=)
JP (1) JP4979188B2 (https=)
KR (1) KR101130984B1 (https=)
CN (1) CN100384925C (https=)
CA (1) CA2475964C (https=)
TW (1) TWI377227B (https=)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005020363A2 (en) * 2003-08-19 2005-03-03 E.I. Dupont De Nemours And Company Membranes of fluorinated ionomer blended with nonionomeric fluoropolymers for electrochemical cells
EP1792919B1 (en) * 2004-08-06 2014-11-12 Daikin Industries, Ltd. Method for producing homopolymer of vinylidene fluoride having i type crystal structure and thin film
JP4526352B2 (ja) * 2004-11-08 2010-08-18 日東電工株式会社 電池用セパレータのための反応性ポリマー担持多孔質フィルムとそれを用いた電池の製造方法
US7396880B2 (en) 2005-05-24 2008-07-08 Arkema Inc. Blend of ionic (co)polymer resins and matrix (co)polymers
US20070119302A1 (en) * 2005-11-14 2007-05-31 Maciej Radosz Polymers containing ionic groups for gas separation and storage
US7368200B2 (en) * 2005-12-30 2008-05-06 Tekion, Inc. Composite polymer electrolyte membranes and electrode assemblies for reducing fuel crossover in direct liquid feed fuel cells
JP4514718B2 (ja) * 2006-01-20 2010-07-28 株式会社豊田中央研究所 膜電極接合体及び固体高分子型燃料電池
JP5266617B2 (ja) * 2006-03-20 2013-08-21 株式会社豊田中央研究所 電解質／非電解質ブレンド膜及びその製造方法
WO2007139550A1 (en) * 2006-05-30 2007-12-06 Utc Power Corporation Fuel cell employing hydrated non-perfluorinated hydrocarbon lon exchange membrane
EP2053673A4 (en) * 2006-08-07 2011-07-06 Mitsubishi Gas Chemical Co ELECTRODE FOR A FUEL CELL, MANUFACTURING METHOD AND FUEL CELL
EP2117678A4 (en) * 2006-12-14 2012-03-07 Arkema Inc HIGH TEMPERATURE STABLE POLYELECTROLYTES HAVING SKELETAL AROMATIC GROUPS
WO2008127645A1 (en) * 2007-04-13 2008-10-23 Michigan Molecular Institute Improved fuel cell proton exchange membranes
KR100986493B1 (ko) * 2008-05-08 2010-10-08 주식회사 동진쎄미켐 연료전지용 고분자 전해질 막
EP2443195B1 (en) 2009-06-15 2014-01-15 Arkema Inc. Organic/inorganic composite blend membrane compositions of polyelectrolye blends with nanoparticles
SG169305A1 (en) * 2009-08-26 2011-03-30 Siemens Pte Ltd Ion exchange membranes
JP5244148B2 (ja) * 2010-04-14 2013-07-24 株式会社豊田中央研究所 膜電極接合体及び固体高分子型燃料電池
CN102905780B (zh) * 2010-04-28 2016-09-28 东丽株式会社 复合半透膜
US9708254B2 (en) * 2010-08-06 2017-07-18 Arkema Inc. Superacid functional compounds
JP5889907B2 (ja) 2010-10-15 2016-03-22 エヴォクア ウォーター テクノロジーズ エルエルシーＥｖｏｑｕａ Ｗａｔｅｒ Ｔｅｃｈｎｏｌｏｇｉｅｓｌｌｃ カチオン交換膜を製造するためのモノマー溶液の製造方法
CN103237600B (zh) 2010-10-15 2016-07-13 伊沃夸水处理技术有限责任公司 阴离子交换膜及制造方法
EP2572736A1 (en) * 2011-09-23 2013-03-27 Spago Imaging AB Nanostructures comprising manganese
KR20150001816A (ko) * 2012-04-13 2015-01-06 가부시키가이샤 유에이씨제이 집전체, 전극 구조체, 비수전해질 전지 및 축전 부품
WO2014055123A1 (en) 2012-10-04 2014-04-10 Evoqua Water Technologies Llc High-performance anion exchange membranes and methods of making same
CA2887132C (en) 2012-10-11 2020-07-21 Evoqua Water Technologies Llc Coated ion exchange membranes
US10722743B2 (en) * 2015-05-15 2020-07-28 Rutgers, The State University Of New Jersey Multicatalyst polyelectrolyte membranes and materials and methods utilizing the same
CN106299163A (zh) * 2016-08-22 2017-01-04 无锡华盈锂能新材有限公司 锂离子电池软包装用内层共挤膜及其制备方法
JP7404349B2 (ja) 2018-09-25 2023-12-25 エヴォクア ウォーター テクノロジーズ エルエルシー 一価選択性カチオン交換膜
US20220021026A1 (en) * 2018-12-21 2022-01-20 Solvay Sa Fluorinated gel polymer electrolyte for a lithium electrochemical cell
US20220297085A1 (en) * 2019-06-25 2022-09-22 Arkema Inc. Crosslinked binder composition
FR3155532A1 (fr) * 2023-11-21 2025-05-23 Compagnie Generale Des Etablissements Michelin Procédé de fabrication d’un film par enduction d’un ionomère polymère à blocs
CN119505168B (zh) * 2024-11-13 2025-08-15 惠州市振有新材料科技有限公司 Tpu抗静电母粒配方及方法

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1078329B (de) * 1955-04-27 1960-03-24 Du Pont Verfahren zur Herstellung eines elastischen Mischpolymerisats aus Vinylidenfluorid und einem anderen Fluorolefin
US3178399A (en) * 1961-08-10 1965-04-13 Minnesota Mining & Mfg Fluorine-containing polymers and preparation thereof
US3475396A (en) * 1966-07-06 1969-10-28 Diamond Shamrock Corp Process for polymerizing vinylidene fluoride
US3857827A (en) * 1974-01-25 1974-12-31 Pennwalt Corp Method of preparing high-quality vinylidene fluoride polymer in aqueous emulsion
FR2268094B1 (https=) * 1974-04-16 1976-10-08 Rhone Poulenc Textile
US4189369A (en) * 1975-05-20 1980-02-19 E. I. Du Pont De Nemours And Company Diaphragm of hydrophilic fluoropolymers
JPS52107045A (en) * 1976-03-05 1977-09-08 Japan Exlan Co Ltd Stable aqueous emulsions of acrylonitrile polymers, their preparation, and dyeability improvers therefrom
IT1166581B (it) * 1979-01-17 1987-05-05 Oronzio De Nora Impianti Membrane cationiche a base di copolimeri solfonati di stirene divinilbenzene e 2- o 4-vinilpiridina o acido acrilico, procedimento per la loro preparazione ed uso in celle di elettrolisi
JPS6024812B2 (ja) 1979-11-09 1985-06-14 呉羽化学工業株式会社 塩化ビニリデン系樹脂ケ−シング
US4596858A (en) * 1981-11-27 1986-06-24 Gregor Harry P Solid state cross-linked polymer
EP0240586B1 (en) * 1986-04-09 1993-01-20 Harry P. Gregor Post-cross-linked polymeric gels
GB8331860D0 (en) * 1983-11-29 1984-01-04 Ici Plc Exchange membrane
US4569978A (en) * 1984-07-25 1986-02-11 Pennwalt Corporation Emulsion polymerization of vinylidene fluoride polymers in the presence of trichlorofluoromethane as chain transfer agent
US5306539A (en) * 1988-08-05 1994-04-26 Masonite Corporation Scored fiberboard having improved moldability
US5093427A (en) * 1990-05-10 1992-03-03 Atochem North America, Inc. Copolymers of vinylidene fluoride and hexafluoropropylene and process for preparing the same
US5272186A (en) * 1992-05-01 1993-12-21 E. I. Du Pont De Nemours And Company Concentration of fluoropolymer dispersions using acrylic polymers of high acid content
DE4243995C2 (de) * 1992-12-23 1996-07-25 Gore W L & Ass Gmbh Permanente hydrophile Modifizierung für Fluorpolymere und Verfahren zur Erzeugung der Modifizierung
DE4326130A1 (de) * 1993-08-04 1995-02-09 Huels Chemische Werke Ag Thermoplastische Mehrschichtverbunde
DE4410148A1 (de) * 1994-03-24 1995-09-28 Huels Chemische Werke Ag Mehrschichtiges Kunststoffrohr
US5468574A (en) * 1994-05-23 1995-11-21 Dais Corporation Fuel cell incorporating novel ion-conducting membrane
US5795668A (en) * 1994-11-10 1998-08-18 E. I. Du Pont De Nemours And Company Fuel cell incorporating a reinforced membrane
US5880204A (en) * 1995-09-27 1999-03-09 Alliedsignal Inc. Room temperature coalescable aqueous fluoropolymer dispersions and method for their manufacture
EP0900249B1 (en) 1996-04-30 2003-10-22 W.L. Gore & Associates, Inc. Integral multi-layered ion-exchange composite membranes
US5962140A (en) * 1996-06-25 1999-10-05 Acushnet Company Golf ball comprising fluoropolymer
AU5099498A (en) 1996-11-01 1998-05-29 E.I. Du Pont De Nemours And Company Highly conductive ion exchange polymer and process
US6444343B1 (en) 1996-11-18 2002-09-03 University Of Southern California Polymer electrolyte membranes for use in fuel cells
US5747546A (en) * 1996-12-31 1998-05-05 The Dow Chemical Company Ion-exchange polymers having an expanded microstructure
US6218534B1 (en) * 1997-10-06 2001-04-17 Dupont Pharmaceuticals Company Preparation of asymmetric cyclic ureas through a monoacylated diamine intermediate
US6294612B1 (en) * 1998-02-02 2001-09-25 E. I. Du Pont De Nemours And Company Highly fluorinated ion exchange/nonfunctional polymer blends
US6025092A (en) * 1998-02-13 2000-02-15 E. I. Du Pont De Nemours And Company Fluorinated ionomers and their uses
US6495209B1 (en) * 1998-02-20 2002-12-17 Lynntech, Inc. Process of making a composite membrane
CA2330792A1 (en) 1998-06-25 1999-12-29 E.I. Du Pont De Nemours And Company Aromatic polymers with pendant fluorinated ionic groups
US6783937B1 (en) * 1999-02-25 2004-08-31 Pall Corporation Negatively charged membrane
AU2831000A (en) 1999-03-08 2000-09-28 Center For Advanced Science And Technology Incubation, Ltd. Electrolytic membrane for fuel cell and its manufacturing method, and fuel cell and its manufacturing method
US6680357B1 (en) * 1999-07-14 2004-01-20 Atofina Chemicals, Inc. Crosslinkable aqueous fluoropolymer based dispersions
US6780935B2 (en) * 2000-02-15 2004-08-24 Atofina Chemicals, Inc. Fluoropolymer resins containing ionic or ionizable groups and products containing the same
IT1317834B1 (it) * 2000-02-15 2003-07-15 Ausimont Spa Fluoropolimeri termoplastici.
US6803446B2 (en) * 2000-07-13 2004-10-12 The Board Of Governors For Higher Education, State Of Rhode Island And Providence Plantations Functionalized and processable conducting polymers
ITMI20010384A1 (it) * 2001-02-26 2002-08-26 Ausimont Spa Membrane idrofiliche porose
AU2002241152B2 (en) 2001-03-21 2008-02-28 Victrex Manufacturing Limited Polymer electrolyte membrane fuel cell
JP2003059512A (ja) * 2001-08-22 2003-02-28 Asahi Glass Co Ltd 固体高分子型燃料電池用電解質膜の製造方法
US6833414B2 (en) * 2002-02-12 2004-12-21 Arkema Inc. Cross-linkable aqueous fluoropolymer based dispersions containing silanes
DE10240797A1 (de) * 2002-08-30 2004-03-11 Stockhausen Gmbh & Co. Kg Kationische Polyelektrolyte mit guter Umweltverträglichkeit
US20040175625A1 (en) * 2003-03-06 2004-09-09 Lotfi Hedhli Non-perfluorinated resins containing ionic or ionizable groups and products containing the same
US20040175498A1 (en) * 2003-03-06 2004-09-09 Lotfi Hedhli Method for preparing membrane electrode assemblies
JP2004319353A (ja) * 2003-04-18 2004-11-11 Toray Ind Inc 固体電解質およびそれを用いた燃料電池

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CA2475964C (en) 2010-09-21
CN1590448A (zh) 2005-03-09
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KR20050014763A (ko) 2005-02-07
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