TWI299068B - - Google Patents
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- TWI299068B TWI299068B TW91106848A TW91106848A TWI299068B TW I299068 B TWI299068 B TW I299068B TW 91106848 A TW91106848 A TW 91106848A TW 91106848 A TW91106848 A TW 91106848A TW I299068 B TWI299068 B TW I299068B
- Authority
- TW
- Taiwan
- Prior art keywords
- prepolymer
- composition
- emulsion
- polymerizable
- urethane
- Prior art date
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- 239000000203 mixture Substances 0.000 claims description 323
- 239000004744 fabric Substances 0.000 claims description 139
- 229920000742 Cotton Polymers 0.000 claims description 132
- 239000000835 fiber Substances 0.000 claims description 121
- 239000000839 emulsion Substances 0.000 claims description 119
- 238000000034 method Methods 0.000 claims description 97
- 239000003999 initiator Substances 0.000 claims description 88
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 86
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 81
- 229920000126 latex Polymers 0.000 claims description 67
- 239000004816 latex Substances 0.000 claims description 66
- 239000003054 catalyst Substances 0.000 claims description 63
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 62
- 239000002202 Polyethylene glycol Substances 0.000 claims description 62
- 229920001223 polyethylene glycol Polymers 0.000 claims description 62
- 239000012141 concentrate Substances 0.000 claims description 59
- 239000000178 monomer Substances 0.000 claims description 55
- 125000004386 diacrylate group Chemical group 0.000 claims description 51
- -1 amine methyl ester Chemical class 0.000 claims description 45
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 36
- 229920001971 elastomer Polymers 0.000 claims description 34
- 239000000806 elastomer Substances 0.000 claims description 34
- 229920000728 polyester Polymers 0.000 claims description 34
- 239000012530 fluid Substances 0.000 claims description 31
- 229920000642 polymer Polymers 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 29
- 239000007787 solid Substances 0.000 claims description 27
- 239000003921 oil Substances 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 229920000459 Nitrile rubber Polymers 0.000 claims description 20
- 238000005299 abrasion Methods 0.000 claims description 20
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 20
- 229920001903 high density polyethylene Polymers 0.000 claims description 20
- 239000004700 high-density polyethylene Substances 0.000 claims description 20
- 239000004094 surface-active agent Substances 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 238000007639 printing Methods 0.000 claims description 19
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- 229940015043 glyoxal Drugs 0.000 claims description 18
- 229920000578 graft copolymer Polymers 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 238000003860 storage Methods 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- 239000000049 pigment Substances 0.000 claims description 12
- XVEUJTIZHZIHJM-UHFFFAOYSA-N a828782 Chemical compound CCOC(N)=O.CCOC(N)=O XVEUJTIZHZIHJM-UHFFFAOYSA-N 0.000 claims description 11
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- 229910052742 iron Inorganic materials 0.000 claims description 11
- 150000002978 peroxides Chemical class 0.000 claims description 11
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- 239000011248 coating agent Substances 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000004952 Polyamide Substances 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229910021645 metal ion Inorganic materials 0.000 claims description 9
- 229920002647 polyamide Polymers 0.000 claims description 9
- 239000000853 adhesive Substances 0.000 claims description 8
- 230000001070 adhesive effect Effects 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
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- 239000003381 stabilizer Substances 0.000 claims description 8
- 239000000052 vinegar Substances 0.000 claims description 8
- 235000021419 vinegar Nutrition 0.000 claims description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
- 238000004132 cross linking Methods 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229920000768 polyamine Polymers 0.000 claims description 7
- 229920003043 Cellulose fiber Polymers 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- 150000004965 peroxy acids Chemical class 0.000 claims description 6
- 230000000844 anti-bacterial effect Effects 0.000 claims description 5
- 239000003899 bactericide agent Substances 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 5
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 5
- 125000000524 functional group Chemical group 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000002243 precursor Substances 0.000 claims description 5
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 3
- QEWYKACRFQMRMB-UHFFFAOYSA-N fluoroacetic acid Chemical compound OC(=O)CF QEWYKACRFQMRMB-UHFFFAOYSA-N 0.000 claims description 3
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 3
- WGLQHUKCXBXUDV-UHFFFAOYSA-N 3-aminophthalic acid Chemical compound NC1=CC=CC(C(O)=O)=C1C(O)=O WGLQHUKCXBXUDV-UHFFFAOYSA-N 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 2
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims description 2
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims 11
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- 239000003063 flame retardant Substances 0.000 claims 3
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 2
- 235000019260 propionic acid Nutrition 0.000 claims 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 102100035353 Cyclin-dependent kinase 2-associated protein 1 Human genes 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 208000001613 Gambling Diseases 0.000 claims 1
- 206010061218 Inflammation Diseases 0.000 claims 1
- GBBDVMJBRZSBRW-UHFFFAOYSA-N OC=O.CCOC(N)=O Chemical compound OC=O.CCOC(N)=O GBBDVMJBRZSBRW-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 claims 1
- 229960005286 carbaryl Drugs 0.000 claims 1
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical compound OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
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- 239000007850 fluorescent dye Substances 0.000 claims 1
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- 230000000855 fungicidal effect Effects 0.000 claims 1
- 230000000887 hydrating effect Effects 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- 230000004054 inflammatory process Effects 0.000 claims 1
- AHYFSRXBEJICKT-UHFFFAOYSA-N phthalic acid;prop-2-enamide Chemical compound NC(=O)C=C.OC(=O)C1=CC=CC=C1C(O)=O AHYFSRXBEJICKT-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 239000001117 sulphuric acid Substances 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 claims 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims 1
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- 238000009472 formulation Methods 0.000 description 70
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- 239000000243 solution Substances 0.000 description 31
- 238000012360 testing method Methods 0.000 description 24
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 21
- 238000001035 drying Methods 0.000 description 19
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- 239000008367 deionised water Substances 0.000 description 12
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- 238000011068 loading method Methods 0.000 description 12
- 229920002675 Polyoxyl Polymers 0.000 description 11
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
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- 239000000047 product Substances 0.000 description 7
- 238000010998 test method Methods 0.000 description 7
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 6
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- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 6
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- 238000012545 processing Methods 0.000 description 6
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- 125000002091 cationic group Chemical group 0.000 description 5
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000000985 reactive dye Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 159000000014 iron salts Chemical class 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
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- 235000009566 rice Nutrition 0.000 description 2
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- 239000004759 spandex Substances 0.000 description 2
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- 229920002994 synthetic fiber Polymers 0.000 description 2
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
- D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
- D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/825,287 US6638319B2 (en) | 2001-04-04 | 2001-04-04 | Polymer for printed cotton |
| US09/824,732 US6645255B2 (en) | 2001-04-04 | 2001-04-04 | Polymer-grafted stretchable cotton |
| US09/825,283 US6645256B2 (en) | 2001-04-04 | 2001-04-04 | Polymer grafted cotton |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI299068B true TWI299068B (enrdf_load_stackoverflow) | 2008-07-21 |
Family
ID=27420168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW91106848A TWI299068B (enrdf_load_stackoverflow) | 2001-04-04 | 2002-04-04 |
Country Status (10)
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1300408C (zh) * | 2005-01-17 | 2007-02-14 | 西南农业大学 | 天然绿茧丝微波接枝固色方法 |
| CN101070676B (zh) * | 2007-05-18 | 2013-03-20 | 广东德美精细化工股份有限公司 | 一种纤维材料改质的方法及其染色工艺 |
| CN104404647B (zh) * | 2014-10-15 | 2016-08-17 | 浙江恒逸高新材料有限公司 | 一种纤维素纳米晶改性的亲水聚酯纤维及其制备方法 |
| US20170022314A1 (en) * | 2015-07-24 | 2017-01-26 | Weyerhaeuser Nr Company | Grafted crosslinked cellulose |
| CN109021170B (zh) * | 2017-06-09 | 2022-05-17 | 天津科技大学 | 一种抗盐性纳米/微米纤丝纤维素凝胶的制备方法 |
| CN109023992B (zh) * | 2018-08-24 | 2020-08-25 | 江门市卓益纺织布业有限公司 | 一种提高纤维素纤维靛蓝染色湿摩擦色牢度的方法 |
| CN112813685A (zh) * | 2020-06-30 | 2021-05-18 | 应急管理部四川消防研究所 | 一种耐久性阻燃后整理织物及其制备方法 |
| CN112406214B (zh) * | 2020-11-16 | 2022-06-14 | 马孔多(北京)文化有限公司 | 一种吸湿排汗纤维面料及其制备方法 |
| CN113089321A (zh) * | 2021-04-07 | 2021-07-09 | 罗莱生活科技股份有限公司 | 乙烯基单体接枝改性的抗菌纤维及其制备方法和在抗菌袜中的用途 |
| WO2022266566A1 (en) | 2021-06-15 | 2022-12-22 | Dow Silicones Corporation | Polysiloxane-based water repellants for textiles |
| CN115947923B (zh) * | 2023-02-17 | 2023-08-04 | 广州山木新材料科技有限公司 | 一种水性聚氨酯树脂及包含其的数码烫画墨水 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2952892A (en) * | 1956-07-19 | 1960-09-20 | Bancroft & Sons Co J | Cellulosic fabric finishing |
| JPS491279B1 (enrdf_load_stackoverflow) * | 1969-09-13 | 1974-01-12 | ||
| US4052158A (en) * | 1973-11-12 | 1977-10-04 | Stauffer Chemical Company | Textile finishing process |
| JPS5653278A (en) * | 1979-09-28 | 1981-05-12 | Wakayama Prefecture | Wrinkleproof * shrinkproof and fireproof process of cellulose fiber |
| JPH0299668A (ja) * | 1988-10-04 | 1990-04-11 | Unitika Ltd | 繊維構造物の深色加工法 |
| CS408191A3 (en) * | 1990-12-27 | 1992-09-16 | Amann & Soehne | Method of changing textile substrates properties |
| JP3233224B2 (ja) * | 1992-01-30 | 2001-11-26 | 東洋紡績株式会社 | セルロース繊維含有繊維構造物及びその製造方法 |
| US5741548A (en) * | 1996-09-24 | 1998-04-21 | Sanduja; Mohan L. | Coating composition for reemay and satin acetate fabrics for laser printability |
| US6165919A (en) | 1997-01-14 | 2000-12-26 | University Of Georgia Research Foundation, Inc. | Crosslinking agents of cellulosic fabrics |
| JP2002146680A (ja) * | 2000-11-09 | 2002-05-22 | Dai Ichi Kogyo Seiyaku Co Ltd | セルロース系繊維布帛の反撥風合い加工処理剤及び加工方法 |
-
2002
- 2002-03-27 JP JP2002579563A patent/JP4647188B2/ja not_active Expired - Fee Related
- 2002-03-27 WO PCT/US2002/009438 patent/WO2002081811A1/en active Application Filing
- 2002-03-27 CN CN 02810793 patent/CN1266330C/zh not_active Expired - Fee Related
- 2002-03-27 CA CA2442836A patent/CA2442836C/en not_active Expired - Fee Related
- 2002-03-27 MX MXPA03009005A patent/MXPA03009005A/es active IP Right Grant
- 2002-03-27 EP EP02723634.8A patent/EP1377709B1/en not_active Expired - Lifetime
- 2002-04-02 EG EG20020348A patent/EG23282A/xx active
- 2002-04-04 TW TW91106848A patent/TWI299068B/zh not_active IP Right Cessation
- 2002-04-04 DO DO2002000374A patent/DOP2002000374A/es unknown
-
2003
- 2003-11-03 CR CR7133A patent/CR7133A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005503492A (ja) | 2005-02-03 |
| CN1513072A (zh) | 2004-07-14 |
| MXPA03009005A (es) | 2004-02-12 |
| CA2442836A1 (en) | 2002-10-17 |
| EP1377709B1 (en) | 2013-09-11 |
| CN1266330C (zh) | 2006-07-26 |
| JP4647188B2 (ja) | 2011-03-09 |
| WO2002081811A1 (en) | 2002-10-17 |
| DOP2002000374A (es) | 2002-12-15 |
| EP1377709A1 (en) | 2004-01-07 |
| HK1068155A1 (en) | 2005-04-22 |
| CA2442836C (en) | 2012-01-03 |
| EG23282A (en) | 2004-10-31 |
| CR7133A (es) | 2004-04-15 |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |