TWI286987B - Synthetic-resin container with high gas insulation - Google Patents
Synthetic-resin container with high gas insulation Download PDFInfo
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- TWI286987B TWI286987B TW094109251A TW94109251A TWI286987B TW I286987 B TWI286987 B TW I286987B TW 094109251 A TW094109251 A TW 094109251A TW 94109251 A TW94109251 A TW 94109251A TW I286987 B TWI286987 B TW I286987B
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- oxygen
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- 229920003002 synthetic resin Polymers 0.000 title claims abstract 6
- 239000000057 synthetic resin Substances 0.000 title claims abstract 6
- 238000009413 insulation Methods 0.000 title abstract 2
- 239000007789 gas Substances 0.000 claims abstract description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000001301 oxygen Substances 0.000 claims abstract description 16
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 silicon oxide compound Chemical class 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 14
- 230000004888 barrier function Effects 0.000 claims description 8
- 239000004575 stone Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 150000003304 ruthenium compounds Chemical class 0.000 claims description 3
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims 2
- 206010012735 Diarrhoea Diseases 0.000 claims 1
- 239000002173 cutting fluid Substances 0.000 claims 1
- 239000008267 milk Substances 0.000 claims 1
- 210000004080 milk Anatomy 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 238000007740 vapor deposition Methods 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 150000003377 silicon compounds Chemical class 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 8
- 239000005020 polyethylene terephthalate Substances 0.000 description 8
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UOACKFBJUYNSLK-XRKIENNPSA-N Estradiol Cypionate Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H](C4=CC=C(O)C=C4CC3)CC[C@@]21C)C(=O)CCC1CCCC1 UOACKFBJUYNSLK-XRKIENNPSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001622 bismuth compounds Chemical class 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 206010011469 Crying Diseases 0.000 description 1
- 206010036790 Productive cough Diseases 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 210000003679 cervix uteri Anatomy 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 210000003802 sputum Anatomy 0.000 description 1
- 208000024794 sputum Diseases 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D23/00—Details of bottles or jars not otherwise provided for
- B65D23/02—Linings or internal coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D23/00—Details of bottles or jars not otherwise provided for
- B65D23/08—Coverings or external coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D23/00—Details of bottles or jars not otherwise provided for
- B65D23/08—Coverings or external coatings
- B65D23/0807—Coatings
- B65D23/0814—Coatings characterised by the composition of the material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
- C08J7/0423—Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/048—Forming gas barrier coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Laminated Bodies (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Chemical Vapour Deposition (AREA)
- Wrappers (AREA)
Description
12869似_ 九、發明說明： 【發明所屬之技術領域】 本發明係關於-種代表聚對苯二甲酸乙二 就是所謂PET瓶之合成編製容器，係錢 = 該容器，特別是氧氣、1备石山Μ、“徑1万止礼體透過 物的品質透過，並謀求保持内容 【先前技術】 近年來，在廢棄、搬送、回收等中， 法避免=與 作马對應如此問韻 = 109076號公報中，提出在瓶1 如，開 層向氣體阻絕性之被覆(Si〇x)之容哭内=洛鑛或賴塗 於包含石夕、碳及氧之容器本_ 2另卜亦提出將位置 化合物臈之表面之之氧化面之化合物與位置於該 如此容器與未施以塗
瓶氧阻絕性)提升數倍 可以使氧阻絕性(PET 但最近卻要求應實現更^保持内容物品質的安定， 體阻絕性。 更長期保持品質安定，更-層改善氣
【發明内容J 的合成:J係提出—種具有更高氣體阻絕性之新
12869¾..doe 表面或外表面之至容11，係在容器本體的内 前述被膜至‘含Hi體阻絕性之被膜。 石夕、碳、氫及氧，位置於容物層’其係包含氮、 物層，其係以氧化石夕化合面；以及氧化石夕化合 化合物層的表面。σ為成为，位置於該有機系石夕 容哭本使含錢之有㈣魏合物層位置於 外*)作騎敵第-層，在該有機系 氧化魏膜以氧切化合物作為主成分之 二=:為第2層，以具有2種膜之複合效果可 乂”、、貝者改善軋體阻絕性。 在由上述構成所形成之容器中，有機系魏合物層及 或乳化耗合物層以作成蒸賴者較佳，其折射率特別期 望為位於1.3〜1·6之範圍者。 【實施方式】 圖1係繪示藉二軸延伸吹氣成形所形成之PET瓶之主 要部分剖面圖。參照數字1為構成容器本體之壁部，2為 防止氣體(特別是氧氣與二氧化碳)透過設置於壁部1之容 二内或谷裔外之向阻絕性之被膜。 被膜2係由有機系矽化合物層2a與氧化矽化合物層 2b所構成；該有機系矽化合物層2a，其係位置於容器本體 1的外表面，包含氮、矽、碳、氫及氧；該氧化矽化合物 層2b，其係位置於該有機系石夕化合物層2a之表面，以氧 化石夕化合物為主要成分。 6 1286^§〇7p,doc 在形】，層中’針對有機系石夕化合物層2a ’ 素)，藉物r::成=體(a:㈣有氣體元 層’形成氣·_更進—步提升^“ 在此，包含石夕、石炭、及氧之習知之有 : 法看出較大之差異。㈣魏合物相樣，針對該點無
但是，在習知之有機系石夕化合物層之表面成膜呈有氣 體阻絕性之化合物層（以氧化發作為主成分者)時，、ς化又 物層僅單顯示本來具有之氣齡絕性，藉如在样二 種膜之複合效果，是無法被期待有顯糾改善氣 <實施例1> 在PET瓶之表面，藉使用高頻脈衝之電漿法被 覆被膜，針對該PET瓶之氧阻絕性進行了調查。其結果1 別顯示於表卜2。又，電漿CVD法之脈衝放電條件為οχ77: O.lsec，OFF : O.lsec 〇 表1為當設置有機系矽化合物層使用Ar氣體時之名士 果。表2為當設置有機系矽化合物使用氮氣時之結果。^ i、2中，「DEPO」為放電時間（例如8為脈衝放^電8sec 之意思），「HMDSO」為六甲基二矽醚，氣體流量之、⑶㈤」 係指在〇°c、1氣壓之狀態氣體流動1分鐘之氣體量(cc)之 意思。 7 I286WPif.d〇c 另外，「原料氣體之組成比」係混合HMDSO、氧、 氮、氬等之氣體之狀態之比；「透溼度40°C-75%RH」為 保管環境之溫度與相對溼度；「BIF」為與未成膜品作比 較之阻絕性改良率（Barrier Improvement Factor)。 mm
備考」 透溼度 40°C-75% 5 « • 2〇〇 g/day 根 0.042 2 0.041 9 0.033 1 0.028 4 1 寸 «Ο 球吳€ g 〇 〇 —— 1 卜 氧透過 Ξ 1 1 rn 〇\ 〇 〇 0.0207 0.0203 0.00156 0.0016 成膜條件 | 原料氣體之組成比（％) J 1 Ο 〇 〇 Ο < 1 对 〇 寸 ο X a s s IT) U 1 卜 (N 卜 Ο 1 寸 <N 寸 〇\ CN a 卜 Ό 卜 真空 度 (Pa) 1 〇 oi 〇 m Ο <N 〇 ΓΟ 氣體流(seem) | 1 1 1 1 1 1 S 1 s 1 1 1 s (N HMDSO 1 20.0 Ο | 20.0 〇 in DEPO (sec) 1 〇〇 <Ν 00 (N 1 〇 m Ο «η 〇 Ο Ο <N 1 〇$〇 >1 試驗項目 未成膜 僅第一層 僅第二層 2層成膜 L^J 透溼度 40eC-75% 5 1 1 2 〇〇 g/day 根 0.042 2 0.040 0 0.033 1 0.024 2 I Tf 1 ^ Λΐ： c g VO m — On d〇 m 〇 <Ν < 口寸 氧透過 i_ Ξ a 1 口 fTi cc/day 根 0.0207 0.0214 0.00156 0.0012 成膜條件 l 原料氣體之組成比（％) | Z. a 卜 〇 卜 Ο < 1 Ο o Ο ο X 1 (N v〇 : (Ν Ό in u 1 口 卜 Ο (Ν 卜 o 1 VO (N CN 1 卜 o 卜 v〇 真空 度 (pa) 1 Ο <N o rn Ο (Ν 〇 ri 氣體流(seem) | I S 1 S ( 1 a 1 1 1 1 1 (Ν HMDSO 1 20.0 〇 20.0 〇 DEPO (sec) 1 00 (N 〇〇 (N s -¾ § • o m 〇 寸 ο 〇 α$αι ^ ΓΝ 第一層 Ί 試驗項目 未成膜 僅第一層 僅第二層 2層成膜 9 I2869i&2pif.doc 膜#由t卜2可^解’在本發明之容器(表2之2層成 、，/、添加Ar氣體成膜有機系 二氧:爾_值)提升丨.3倍左右,另外， ，度’ BIF值)提升12倍左右，可以確認氧阻二5 比PET瓶單體之容_魏膜錢 物 為主成分之層之PET瓶更提升。 1匕“句 丄由上述可以瞭解，若依據本發明，可以提供— ί錢體阻絕性’且内容物之保存性優良之合戍樹 【圖式簡單說明】 圖1係繪示本發明之合成樹脂製容器之 【主要元件符號說明】 °卩剖面圖。 1 :壁部 2 :被犋 2a :有機系矽化合物層 b 氣化石夕化合物層
Claims (1)
128 輒7_〇c 十、申請專利範圍： 1 · 一種合成樹脂製之容器 外表面之至少一方具有高氣體 少包含： ，係在容器本體的内表面或 阻絕性之被膜，前述被膜至 位於合物層’其係包含氮、石夕、碳、氫及氧， 证於各态本體表面；以及 乳
於該ΐίΓ化合物層’其係以氧切化合物為主成分，位 杜1系石夕化合物層的表面。 其中t、巾請專利範圍第1項所述之合成樹脂製之容器， 層。則处有機系矽化合物層及/或氧化矽化合物層為蒸鍍 器，其專利範圍第1或2項所述之合成樹脂製之容 ^射/述有機系矽化合物層及/或氧化矽化合物物層之 為u〜：u之範圍。
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004093263A JP2005280718A (ja) | 2004-03-26 | 2004-03-26 | 高いガスバリア性を有する合成樹脂製容器 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200602234A TW200602234A (en) | 2006-01-16 |
| TWI286987B true TWI286987B (en) | 2007-09-21 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW094109251A TWI286987B (en) | 2004-03-26 | 2005-03-25 | Synthetic-resin container with high gas insulation |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20070197026A1 (zh) |
| EP (1) | EP1728724A4 (zh) |
| JP (1) | JP2005280718A (zh) |
| KR (1) | KR20060127242A (zh) |
| CN (1) | CN1934003A (zh) |
| AU (1) | AU2005226337A1 (zh) |
| CA (1) | CA2561359A1 (zh) |
| TW (1) | TWI286987B (zh) |
| WO (1) | WO2005092714A1 (zh) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4711285B2 (ja) * | 2004-03-26 | 2011-06-29 | 株式会社吉野工業所 | 高いガスバリア性を有する合成樹脂製容器 |
| JP5075527B2 (ja) * | 2007-08-21 | 2012-11-21 | 株式会社吉野工業所 | ボトルの製造方法およびボトル |
| JP5781350B2 (ja) * | 2011-03-30 | 2015-09-24 | リンテック株式会社 | ガスバリア積層体、その製造方法、電子デバイス用部材及び電子デバイス |
| DE102011100635A1 (de) * | 2011-05-05 | 2012-11-08 | Beiersdorf Ag | Behältnisse für kosmetische und dermatologische Produkte |
| JP6704239B2 (ja) * | 2015-10-29 | 2020-06-03 | 株式会社吉野工業所 | 合成樹脂製容器 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX9303141A (es) * | 1992-05-28 | 1994-04-29 | Polar Materials Inc | Metodos y aparatos para depositar recubrimientos de barrera. |
| US5641559A (en) * | 1992-10-23 | 1997-06-24 | Toyo Seikan Kaisha, Ltd. | Gas-tight laminated plastic film containing polymer of organosilicic compound |
| JP3022229B2 (ja) * | 1994-12-26 | 2000-03-15 | 東洋製罐株式会社 | プラスチックス材料からなる立体形状の容器に均一の膜厚の珪素酸化物被膜を形成する方法 |
| WO1996033098A2 (en) * | 1995-04-13 | 1996-10-24 | Xmx Corporation | Gas-impermeable, chemically inert container structure and method of producingthe same |
| DE19802333A1 (de) * | 1998-01-23 | 1999-07-29 | Leybold Systems Gmbh | Barriereschicht für Verpackungsmaterial und Verfahren zur Herstellung einer Barriereschicht für Verpackungsmaterial |
| JP3678361B2 (ja) * | 2001-06-08 | 2005-08-03 | 大日本印刷株式会社 | ガスバリアフィルム |
| JP2003104352A (ja) * | 2001-09-28 | 2003-04-09 | Toppan Printing Co Ltd | バリア性プラスチック容器 |
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2004
- 2004-03-26 JP JP2004093263A patent/JP2005280718A/ja active Pending
-
2005
- 2005-03-23 US US10/593,241 patent/US20070197026A1/en not_active Abandoned
- 2005-03-23 AU AU2005226337A patent/AU2005226337A1/en not_active Abandoned
- 2005-03-23 CN CNA2005800095462A patent/CN1934003A/zh active Pending
- 2005-03-23 EP EP05727188A patent/EP1728724A4/en not_active Withdrawn
- 2005-03-23 WO PCT/JP2005/005231 patent/WO2005092714A1/ja active Application Filing
- 2005-03-23 KR KR1020067020666A patent/KR20060127242A/ko not_active Application Discontinuation
- 2005-03-23 CA CA002561359A patent/CA2561359A1/en not_active Abandoned
- 2005-03-25 TW TW094109251A patent/TWI286987B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1934003A (zh) | 2007-03-21 |
| US20070197026A1 (en) | 2007-08-23 |
| WO2005092714A1 (ja) | 2005-10-06 |
| EP1728724A1 (en) | 2006-12-06 |
| KR20060127242A (ko) | 2006-12-11 |
| CA2561359A1 (en) | 2005-10-06 |
| EP1728724A4 (en) | 2008-04-23 |
| AU2005226337A1 (en) | 2005-10-06 |
| JP2005280718A (ja) | 2005-10-13 |
| TW200602234A (en) | 2006-01-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |