TW499469B - Flame-retardant coating - Google Patents
Flame-retardant coating Download PDFInfo
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- TW499469B TW499469B TW089102861A TW89102861A TW499469B TW 499469 B TW499469 B TW 499469B TW 089102861 A TW089102861 A TW 089102861A TW 89102861 A TW89102861 A TW 89102861A TW 499469 B TW499469 B TW 499469B
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- 238000000576 coating method Methods 0.000 title claims abstract description 38
- 239000011248 coating agent Substances 0.000 title claims abstract description 32
- 239000003063 flame retardant Substances 0.000 title abstract description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 27
- 239000000126 substance Substances 0.000 claims abstract description 17
- 239000000654 additive Substances 0.000 claims abstract description 8
- 239000004604 Blowing Agent Substances 0.000 claims abstract description 5
- 239000006260 foam Substances 0.000 claims abstract description 5
- 230000009970 fire resistant effect Effects 0.000 claims description 28
- 229920001577 copolymer Polymers 0.000 claims description 17
- 238000011049 filling Methods 0.000 claims description 13
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 238000009413 insulation Methods 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 230000002079 cooperative effect Effects 0.000 claims description 4
- 239000002671 adjuvant Substances 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 150000001720 carbohydrates Chemical class 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 3
- 239000004088 foaming agent Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 claims description 2
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000002557 mineral fiber Substances 0.000 claims description 2
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 2
- 235000019814 powdered cellulose Nutrition 0.000 claims description 2
- 229920003124 powdered cellulose Polymers 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 4
- 230000000996 additive effect Effects 0.000 claims 2
- 235000014633 carbohydrates Nutrition 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229920006228 ethylene acrylate copolymer Polymers 0.000 claims 1
- 229920000388 Polyphosphate Polymers 0.000 abstract description 12
- 239000001205 polyphosphate Substances 0.000 abstract description 12
- 235000011176 polyphosphates Nutrition 0.000 abstract description 12
- 239000011230 binding agent Substances 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 description 8
- 230000003750 conditioning effect Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- GUSFEBGYPWJUSS-UHFFFAOYSA-N pentaazanium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O GUSFEBGYPWJUSS-UHFFFAOYSA-N 0.000 description 7
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- 239000004408 titanium dioxide Substances 0.000 description 6
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 229920013620 Pliolite Polymers 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
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- 230000000052 comparative effect Effects 0.000 description 3
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- 239000003755 preservative agent Substances 0.000 description 3
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- 239000002253 acid Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
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- 150000007974 melamines Chemical class 0.000 description 2
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- DNTFEAHNXKUSKQ-RFZPGFLSSA-N (1r,2r)-2-aminocyclopentane-1-sulfonic acid Chemical compound N[C@@H]1CCC[C@H]1S(O)(=O)=O DNTFEAHNXKUSKQ-RFZPGFLSSA-N 0.000 description 1
- XQEVRZIQWROROX-UHFFFAOYSA-N 1-$l^{1}-oxidanyl-2,2,3,3,5,5-hexamethylpyrrolidine Chemical compound CC1(C)CC(C)(C)C(C)(C)N1[O] XQEVRZIQWROROX-UHFFFAOYSA-N 0.000 description 1
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 1
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 239000010754 BS 2869 Class F Substances 0.000 description 1
- MPVRLAWDFIGMEQ-UHFFFAOYSA-N C(CC)(=O)O.NC(=O)OCC Chemical compound C(CC)(=O)O.NC(=O)OCC MPVRLAWDFIGMEQ-UHFFFAOYSA-N 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
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- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
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- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C09D5/185—Intumescent paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Fireproofing Substances (AREA)
- Laminated Bodies (AREA)
- Building Environments (AREA)
Description
499469 A7 B7 五、發明說明（1 ) 本發明係有關防火塗料其形成一絕緣層且係以在火災 事件中會碳化形成一泡沫層的物質，膜形成性黏合劑、發 泡劑和習用輔助劑與添加劑爲基質。 形成絕緣層的防火塗料也稱爲膨脹塗料，在暴露於火 災事件中普及的溫度時會發泡’且上述防火塗料的發泡會 過止，或至少阻礙，熱量通過到鋼構造元件、天花板、牆 壁、電纜、管件和類似者。 美國專利4，965，296 A1述及一種防火材 料其包括一防火塗料和導電材料。此防火塗料包括會碳化 且形成泡末的物質，會產生氣體的物質，膜形成性黏合劑 與恰當溶劑。合意時可含有常用的其它成分。 美國專利第4，8 7 9，3 2 0號述及一種類似的防 火組成物，不過加入陶瓷纖維材料取代導電材料。 美國專利第5，2 2 5，4 6 4號述及一種水性膨脹 調配物，其係以磷酸、三聚氰胺和磷酸銨的反應產物爲基 質，其加上季戊四醇，加上氯化烴類和其它化合物時，特 別是聚乙酸乙烯酯，預期得到改良的膨脹塗料。 有非常廣多種膨脹調配物可能'' Fire Retardants Formulations Handbook 〃 （防火調配物手冊）（作者：
Vij ay Mohan Bhatnagar，1972 )得知。 D E 4 2 1 8 1 8 4 A 1述及一種水性黏合 劑混合物其包括下列所成組合的水溶液及/或分散液：a )至少一種N C 0預聚物其具有胺基甲酸酯基及經封阻的 異氰酸基且其可在b )的存在中溶於及/或分散於水中， (請先閱讀背面之注咅？事項再填寫本頁) 訂---------％ 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -4- 499469 附件二：第89102861號專利申請案中文說明書修正頁 具胤91年2 q修π： 五、發明説明（2) |平"Η補充_ 及b )多元胺成分，其包括至少一種具有至少兩個第一及 /或第二胺基之（環）脂族多元胺。 (請先閲讀背面之注意事項再填寫本頁) 最後，DE 43 43 668述及可發泡的防火 塗料組成物，其包括至少4至2 5重量％的膜形成性黏合 劑，1 0至4重量％的多聚磷酸銨，8至4 0重量％的至 少一種在暴露於熱下會碳化之物質，6至2 5重量％的發 泡劑，0至2 5重量％的分散劑，及0至2 5重量％的塡 料。 前述防火塗料的一項共同缺點爲彼等皆含有鹵素及/ 或在乾燥後具有不足的抗水性。 使用三聚氰胺作爲發泡劑係經視爲特別不利者，因其 在水漿液中係以鹼形式反應之故。所以，若一會形成絕緣 層的防火塗料具有一可在水溶液以酸形式反應的成分時， 經濟部智慧財產局員工消費合作社印製 三聚氰胺即會用爲該成分的反應偶體（reaction partner)。 已知者，三聚氰胺會與多聚磷酸銨在水溶液中反應釋出氨 (N Η 3 )。於增高的溫度和增高的溫度下，也會在乾燥的 形成絕緣層之防火塗料中發生此種反應，因而減低該塗料 的防火性質。 本發明的目的因而爲提出一種防火塗料，其可形成絕 緣層且其不用三聚氰胺，於乾燥後具有抗水性，且在增高 的溫度和增高的溫度下只釋出極少量的Ν Η 3。 此目的係經由開頭所述類型的防火塗料所達成，其可 形成一絕緣層，其中所會發泡劑包括三聚氰酸多聚磷酸鹽 本紙張尺度適用中國國家標準（CNS ) Α4規格（21〇Χ：297公釐） -5- 499469 ] /f m , ' 五、發明説明（3) 1 ---------- 該三聚氰胺多聚磷酸鹽較佳者具有式（HMPO 3) η ，其中Μ爲三聚胺且η^2，特別者2至10，00〇。 (請先閱讀背面之注意事項再填寫本頁) 三聚氰胺多聚磷酸鹽爲一種由三聚氰胺單位與磷酸根 單位所構成的聚合物，彼等係鍵聯成相當短或相當長的鏈 。三聚氰胺單位與磷酸根單位的分佈可爲規則或不規則者 ，且於合意時，彼等也在其本身內聚合。也可以含有三聚 氰胺的衍生物，例如蜜勒胺（melem )、蜜白胺（melam ) 和它者。 三聚氰胺多聚磷酸鹽的性質可能在某些限値內變異， 係因其所具有同的鏈長度及三聚氰胺單位與磷酸根單位的 分布及/或頻率所致。 三聚氰胺多聚磷酸鹽在例如P c T / W 0 9 8 / 4 5 3 6 4中有更詳細的說明，於其中也稱 之爲多聚磷酸的三聚氰胺鹽。於此的聚合物鏈包括（ HMP〇3)單位〔此處Μ爲三聚氰胺〕且η^2，特別者 5 至 1 0，0 0 0。 經濟部智慧財產局員工消費合作社印製 三聚氰胺多聚磷酸鹽通常係經由將三聚氰胺焦磷酸鹽 置於氮氣下在2 9 0 °C及更高的溫度下加熱到恆重而得（ P C T / W 0 98/08898)。 可形成一絕緣層的防火塗料較佳者包括： 5至3 0重量％的膜形成性黏合劑， 1〇至5 0重量％的泡沬層形成性物質， 5至2 5重量％的含碳化之物質， 5至5 0重量％三聚氰胺多聚磷酸鹽，及 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -6 - 499469 A7 B7 五、發明說明（4 ) 1 0至5 0重量％的習用輔助劑與添加劑。 可形成絕緣層的肪火塗料特別較佳地包括： 1 0至2 0重量％的膜形成性黏合劑， 1 5至4 0重量％的泡沬層形成性物質， 7至1 5重量％的含碳化的物質， 7至4 0重量％三聚氰胺多聚磷酸鹽，及 2 0至4 0重量％的習用輔助劑與添加劑。 在會形成絕緣層的防火塗料中所含的膜形成性黏合劑 較佳地包括： 以乙酸乙烯酯爲基的同元聚合物， 以乙酸乙烯酯，乙烯和氯乙烯爲基的共聚物， 以乙酸乙烯酯與長鏈分枝型羧酸乙烯酯爲基的共聚物 以乙酸乙烯酯與順丁烯二酸二正丁酯爲基的共聚物， 以乙酸乙烯酯和丙烯酸酯爲基的共聚物， 以苯乙烯和丙烯酸酯爲基的共聚物，及/或 以丙烯酸酯爲基的共聚物， 乙烯基甲苯一丙烯酸酯共聚物， 苯乙烯-丙烯酸酯共聚物， 乙烯基-丙烯酸酯共聚物， 自交聯性聚胺基甲酸酯分散液。 可形成絕緣層的防火塗料中所含泡沬形成性物質較佳 者包括磷酸及/或多聚磷酸的銨鹽。 可碳化且包含在可形成絕緣層的防火塗料中之物質較 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) ---;---,--訂---------線· 經濟部智慧財產局員工消費合作社印製 499469 Α7 _ Β7 五、發明說明（5 ) 佳者包括醣類。 所用醣類較佳者包括季戊四醇、二季戊四醇、三季戊 四醇、及/或季戊四醇的聚縮合物。 在可形成絕緣層的防火塗料中所含輔助劑或添加劑較 佳者包括玻璃纖維、礦物纖維、高嶺土、滑石、氧化鋁、 氫氧化鋁、氫氧化鎂、沈澱型氧化矽、矽酸鹽及/或粉化 纖維素。 該可形成絕緣層的新穎防火塗料較佳者爲不含鹵素者 〇 該可形成絕緣層而新穎的防火塗料在貯存於增高的（ 大氣壓）溫度（高達1 0 0 %相對濕度）及在增高的溫度 (約7 5 °C )之下時釋出少於2 0 0 p p m的N Η 3。 呈可散佈，噴佈或可碾軋型塗劑形式的該新穎防火塗 料（膨脹塗料）可用來保護廣多種基材，較佳者鋼、木材 、電纜或管件。 於下面諸實施例中，製備膨脹塗料並將其施加於標準 鋼板上，再測定其效用性。絕緣性質係根據D I Ν 4 1 1 2，Part 8 ( 1 9 8 6 )而檢驗的。抗水性係經 由將經塗覆的標準鋼片貯存在4 0 °C並9 5 %大氣濕度的 調理室內4週後施以絕緣性質檢驗而測試的。 要測定Ν Η 3釋出時係將乾燥後的樣品片置於一密封的 玻璃系統內，該系統包括一 5 0 0毫升玻璃燒瓶與一有2 個龍頭的玻璃蓋。爲模擬大氣濕度（約1 〇 〇 %相對濕度 )，該玻璃系統具有一玻璃水槽內裝1 〇毫升自來水。將 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) ---,------訂---------線逢 經濟部智慧財產局員工消費合作社印製 -8- 499469 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（6 ) 玻璃系統放置在7 5 °C循環空氣乾燥室內以其中一龍頭關 閉著。在該乾燥室內1 〇分鐘後同樣將第二龍頭關閉著。 ;燒瓶:在該乾燥室內的停留時間爲自該時起1 2 0分鐘，然 後從該乾燥室取出該燒瓶並使用一應接器將一 Drsger管裝 到一龍頭上。將氮氣以5升/時的速率供給到第二龍頭。 將燒瓶沖滌3 0分鐘並直接從Drsger管直接讀出釋出的氨 量。 諸實施例中用到的產物爲下面所列者： ® Pliolite (固體）（Goodyear，France ) 此爲以乙烯基甲苯-丙烯酸酯共聚物爲基的牛頓型熱塑性 樹脂。 ® Exolit AP 462 ( Clariant GmbH, Frankfurt am Main, Germany )
此爲一種經微包囊的多聚磷酸銨，其係以根據 ΕΡ — Β — 0 180 795 的方法製成之 ® Exolit AP 422爲基質且包括約1 0重量％的由經硬化的三聚氰胺-甲 醛樹脂所構成之膠囊物質。 ® Exolit AP 422 ( Clariant GmbH, Frankfurt am Main,
Germany ) 爲一種自由流動性的粉化型低水溶度多聚磷酸銨其式子爲 (ΝΗ4Ρ〇3) η， n = 2 ◦至1〇〇〇，特別者5〇〇 至1 0 0 0。粒度小於4 5微米的粒子之比例大於9 9 % (請先閱讀背面之注意事項再填寫本頁) -1 J---*--訂—-------. 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -9 - ^^469 ^^469 A7
五、發明說明（7 ) 實施例1 (比較例） 將下列物質依序混合後恰當地施加到檢驗片上： 3 8重量份數的® Exolit AP 462 1 0重量份數的® Pliolite (固體） 8重量份數的三聚氰胺 8重量份數的二季戊四醇 8重量份數的二氧化鈦 及至1 〇 〇重量份數的增稠劑、增塑劑和溶劑。 對經塗覆片的所施D I N 4 1 0 2燃燒檢驗得到燃 燒分類F 3 0。 在調理室內的貯存期之後其燃燒分類同樣爲F 3 0。 N Η 3釋出經測得爲4 6 5 2 p p m N Η 3。 實施例2 (本發明） 將下列物質依序混合後恰當地塗佈在檢驗片上： 3 2重量份數的® Exolit ΑΡ 462 1〇重量份數的® Pliolite (固體） 1 3重量份數的三聚氰胺多聚磷酸鹽 8重量份數的二季戊四醇 8重量份數的二氧化鈦 及至1 0 0重量份數的增稠劑、增塑劑和溶劑。 對經塗覆片的所施D I N 4 1 0 2燃燒檢驗得到燃 燒分類F 6 0。 在調理室內的貯存期後所得燃燒分類同樣爲F 6〇。 (請先閱讀背面之注意事項再填寫本頁) —,---·—訂---------線. 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -10- 499469 A7 _ B7 五、發明說明（8 ) N Η 3釋出經測得爲8 0 p p m Ν ϋ 3。 實施例3 (比較例） 將下列物質依序混合後恰當地塗佈到檢驗片上： 3 0重量份數的® Exolit ΑΡ 422 2 2重量份數聚乙酸乙烯酯共聚物（5 〇 %強度） 1 9重量份數的三聚氰胺 1 3重量份數的季戊四醇 5重量份數的二氧化鈦 及至1 0 0重量份數的增稠劑、塡料、水、分散劑和防腐 劑。 對塗覆片施以D I N 4 1 0 2燃燒檢驗得到燃燒分 類 F 3 Q。 在調理室內的貯存期後不再能達到燃燒分類F 3〇。 N Η 3釋出經測得爲5 2〇〇p P m N Η 3。 實施例4 (本發明） 將下列物質依序混合後恰當地塗佈到檢驗片上： 1 8重量份數的® Exolit ΑΡ 422 2 2重量份數聚乙酸乙烯酯共聚物（5 0 %強度） 3 0重量份數的三聚氰胺多聚磷鹽 1 3重量份數的季戊四醇 5重量份數的二氧化鈦 及至1 0 0重量份數的增稠劑、塡料、水、分散劑和防腐 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注咅？事項再填寫本頁) 訂---------線遽 經濟部智慧財產局員工消費合作社印製 11 - 499469 A7 B7 五、發明說明（9 ) 劑。 對塗覆片施以D I N 4 1 0 2燃燒檢驗得到燃燒分 類F 3〇。 在調理室內的貯存期後所得燃燒分類爲F 3 0。 N Η 3釋出經測得爲1 8 0 p p m N Η 3。 實施例5 (比較例） 將下列物質依序混合後恰當地施加到檢驗片上： 3〇重量份數的® Exolit ΑΡ 422 2 2重量份數的脂族胺基甲酸酯-丙烯酸系摻合體分 散液（3 0 %強度） 1 7重量份數的三聚氰胺 1 2重量份數的二季戊四醇 5重量份數的二氧化鈦 及至1 0 0重量份數的增稠劑、塡料、水、分散劑和防腐 劑。 對塗覆片施以D I N 4 1 0 2燃燒檢驗得到燃燒分 類 F 6 0。 在調理室內的貯存期後其燃燒分類仍爲F 3 0。 N Η 3釋出經測得爲4 8 5 0 ρ p m N Η 3。 實施例6 (本發明） 將下列物質依序混合後恰當地塗佈到檢驗片上： 1 9重量份數的® Exolit ΑΡ 422 (請先閱讀背面之注意事項再填寫本頁) -—I---^--訂----- 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐） -12 -
五、發明說明（1〇 ) 2 2重量份數的脂族胺基甲酸酯-丙嫌酸系慘合體分 散:液（3 Q %強度） 2 7重量份數的三聚氰胺多聚磷酸鹽 1 2重量份數的二季戊四醇 5重量份數的二氧化鈦 及至1 0 0重量份數的增稠劑、塡料、水、分散劑和防腐 劑。 對塗覆片施以D I N 4 1 0 2燃燒檢驗得到燃燒分 類 F 6 〇。 在調理室內的貯存期後其燃燒分類仍爲F 6 0 ° N Η 3釋出經測得爲1 3 0 P P m N Η 3。 從諸實施例可顯然得知三聚氰胺多聚磷酸鹽的使用可 將Ν Η 3釋出較使用三聚氰胺時減低至少2 5倍。 「—I-----—，—·—訂---------線. (請先閱讀背面之注咅？事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -13-
Claims (1)
- 499469告 •、申哥專4範圍 第89102861號專利申請案 中文申請專利範圍修正本 (請先閲讀背面之注意事項再填寫本頁) 民國91年> 月修正 1 . 一種形成絕緣層的防火塗料，其包括 5至3 0重量份的膜形成性黏合劑， 1 0至5 0重量份的在火災事件中形成泡沬層之物質 5至2 5重量份的在火災事件中碳化之物質， 5至5 0重量份之發泡劑，及 1 0至5 0重量份的習知輔助劑與添加劑， 其中該發泡劑含有三聚氰胺聚磷酸。 2 .根據申請專利範圍第1項之形成絕緣層的防火塗 料，其中該三聚氰胺聚磷酸具有式（HMP〇3) n，此處 Μ爲三聚氰胺且η$2，特別爲2至10，〇〇〇。 3 .根據申請專利範圍第1或2項之形成絕緣層的防 火塗料，其包括 Γ 0至2 0重量份的膜形成性黏合劑， 經濟部智慧財產局員工消費合作社印製 1 5至4 0重量份的泡沬層形成性物質， 7至15重量份會碳化之物質， 7至4 0重量份之三聚氰胺聚磷酸，與 . 2 0至4 0重量份的習知輔助劑與添加劑。 4 ·根據申請專利範圍第1或2項之形成絕緣層的防 火塗料，其中該膜形成性黏合劑包括 以乙酸乙烯酯爲基的同元聚合物， 本紙張尺度逋用中國國家梂準（CNS ) Α4规格（210Χ297公嫠） 499469 A8 B8 C8 D8 六、申請專利範圍 以乙酸乙烯酯，乙烯和氯乙烯爲基的共聚物， 以乙酸乙烯酯與長鏈分枝型羧酸乙烯酯爲基的共 7 以乙酸乙烯酯與順丁烯二酸二正丁酯爲基的共聚物’ 以乙酸乙烯酯和丙烯酸酯爲基的共聚物， 以苯乙烯和丙烯酸酯爲基的共聚物，及/或 以丙烯酸酯爲基的共聚物， 乙烯基甲苯-丙烯酸酯共聚物， 笨乙烯-丙烯酸酯共聚物， _ 乙烯基-丙烯酸酯共聚物， 自交聯性胺聚基甲酸酯分散液。 5 .根據申請專利範圍第1或2項之形成絕緣層的防 火塗料，其中所含之該膜形成性物質含有磷酸之銨鹽及/ 或聚磷酸之銨鹽。 6 .根據申請專利範圍第1或2項之形成絕緣層的防 火塗料，其中所含之該碳化的物質含有碳水化合物。 7 .根據申請專利範圍第6項之形成絕緣層的防火塗 料，其中所用之該碳水化合物包括異戊四醇，二異戊四醇 ，三異戊四醇，及/或異戊四醇的聚縮合物。 8 .根據申請專利範圍第1或2項之形成絕緣層的防 火塗料，其中所含之該輔助劑或添加劑包括玻璃纖維，礦 物纖維，高嶺土，滑石，氧化鋁，氫氧化鋁，.氫氧化鎂， 沉澱型氧化矽，矽酸鹽及/或粉化纖維素。 9 ·根據申請專利範圍第1或2項之形成絕緣層的防 本紙張尺度適用中國國家梂準（CNS ) A4规格（210X297公釐） 々· (請先閲讀背面之注意事項再填寫本頁) >裝- 、言 經濟部智慧財產局員工消費合作社印製 499469 A8 B8 C8 D8 々、申請專利範圍 火塗料，其係不含鹵素者。 1 ◦.根據申請專利範圍第1或2項之形成絕緣層的 防火塗料，其在貯存於高達1 0 0 %相對濕度的高濕度條 件及增高的溫度（約7 5 t.)之下，釋出少於2 0 0 p p m 之 N Η 3 〇 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -3- 本紙浪尺度適用中國國家梂準（CNS ) Α4規格（210Χ297公釐）
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19909387A DE19909387C2 (de) | 1999-03-04 | 1999-03-04 | Brandschutzbeschichtung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW499469B true TW499469B (en) | 2002-08-21 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW089102861A TW499469B (en) | 1999-03-04 | 2000-02-18 | Flame-retardant coating |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6251961B1 (zh) |
| EP (1) | EP1165706B1 (zh) |
| JP (1) | JP2002538261A (zh) |
| KR (1) | KR20010108300A (zh) |
| AR (1) | AR022808A1 (zh) |
| AT (1) | ATE294219T1 (zh) |
| AU (1) | AU3804200A (zh) |
| BR (1) | BR0008728A (zh) |
| CA (1) | CA2364509A1 (zh) |
| DE (2) | DE19909387C2 (zh) |
| ES (1) | ES2240081T3 (zh) |
| TW (1) | TW499469B (zh) |
| WO (1) | WO2000052104A1 (zh) |
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| US8330045B2 (en) | 2005-12-26 | 2012-12-11 | Industrial Technology Research Institute | Fire-resistant wire/cable |
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- 1999-03-04 DE DE19909387A patent/DE19909387C2/de not_active Expired - Fee Related
-
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- 2000-02-15 CA CA002364509A patent/CA2364509A1/en not_active Abandoned
- 2000-02-15 ES ES00916834T patent/ES2240081T3/es not_active Expired - Lifetime
- 2000-02-15 BR BR0008728-9A patent/BR0008728A/pt not_active IP Right Cessation
- 2000-02-15 DE DE50010166T patent/DE50010166D1/de not_active Expired - Fee Related
- 2000-02-15 EP EP00916834A patent/EP1165706B1/de not_active Expired - Lifetime
- 2000-02-15 WO PCT/EP2000/001211 patent/WO2000052104A1/de active IP Right Grant
- 2000-02-15 JP JP2000602720A patent/JP2002538261A/ja active Pending
- 2000-02-15 KR KR1020017011185A patent/KR20010108300A/ko not_active Application Discontinuation
- 2000-02-15 AU AU38042/00A patent/AU3804200A/en not_active Abandoned
- 2000-02-15 AT AT00916834T patent/ATE294219T1/de not_active IP Right Cessation
- 2000-02-18 TW TW089102861A patent/TW499469B/zh not_active IP Right Cessation
- 2000-03-02 US US09/517,486 patent/US6251961B1/en not_active Expired - Fee Related
- 2000-03-02 AR ARP000100920A patent/AR022808A1/es unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7875564B2 (en) | 2005-12-26 | 2011-01-25 | Industrial Technology Research Institute | Multilayer fire-resistant material |
| US8330045B2 (en) | 2005-12-26 | 2012-12-11 | Industrial Technology Research Institute | Fire-resistant wire/cable |
| US8329820B2 (en) | 2005-12-26 | 2012-12-11 | Industrial Technology Research Institute | Fire-resistant coating material |
| US8329819B2 (en) | 2005-12-26 | 2012-12-11 | Industrial Technology Research Institute | Organic/inorganic composite and fire-resistant plate utilizing the same |
| CN113367058A (zh) * | 2021-07-07 | 2021-09-10 | 湖南萌芽蔬菜产业有限公司 | 绿豆苗及培育工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2364509A1 (en) | 2000-09-08 |
| DE19909387A1 (de) | 2000-09-07 |
| ATE294219T1 (de) | 2005-05-15 |
| JP2002538261A (ja) | 2002-11-12 |
| EP1165706B1 (de) | 2005-04-27 |
| WO2000052104A1 (de) | 2000-09-08 |
| US6251961B1 (en) | 2001-06-26 |
| ES2240081T3 (es) | 2005-10-16 |
| BR0008728A (pt) | 2001-12-26 |
| DE19909387C2 (de) | 2001-01-25 |
| AU3804200A (en) | 2000-09-21 |
| DE50010166D1 (de) | 2005-06-02 |
| AR022808A1 (es) | 2002-09-04 |
| EP1165706A1 (de) | 2002-01-02 |
| KR20010108300A (ko) | 2001-12-07 |
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