CN104312423B - 一种uv固化阻燃涂料 - Google Patents

一种uv固化阻燃涂料 Download PDF

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CN104312423B
CN104312423B CN201410624571.2A CN201410624571A CN104312423B CN 104312423 B CN104312423 B CN 104312423B CN 201410624571 A CN201410624571 A CN 201410624571A CN 104312423 B CN104312423 B CN 104312423B
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彭健华
吴勇
蒋卫华
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Guangdong Xigui UV Curing Materials Co Ltd
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Abstract

本发明属于涂料领域，特别涉及一种UV固化阻燃涂料，该涂料的质量百分比组成为：燃烧时能原位生成酸的化合物30‑50％，具有多个羟基的有机化合物5‑15％，UV光固化树脂20‑40％，活性稀释剂20‑35％，光引发剂1‑3％。本发明的目的是针对现有技术中的不足，提供了一种UV固化阻燃涂料，本发明的UV固化阻燃涂料阻燃性能优异，遇火时发生泡沫膨胀，形成蜂窝状防火隔热层，能有效地保护材料，达到高阻燃效果；摒弃了传统的三聚氰胺作为氮源的阻燃体系，制备出了高透明性的UV固化阻燃涂料，能够适用于木地板、纤维板、胶合板、内外墙水泥板等，扩大了其适用范围。

Description

一种UV固化阻燃涂料
技术领域
本发明属于涂料领域，特别涉及一种UV固化阻燃涂料。
背景技术
火灾是人类的重大危害之一，为防止火灾事故的发生，应用防火涂料对建筑、可燃性材料进行涂覆是一种有效的措施。防火涂料又称阻燃涂料，既具有装饰作用，更重要的是具有防火阻燃的功能。
常用的防火涂料多为水性或油性防火涂料，但普遍存在着一些问题。普通防火涂料一般需涂2-3遍，每遍间隔6-8小时，干燥需要几天时间；在干燥过程中，挥发性有机化合物会危害人们的身体健康；存在着对不同基材的附着力不够好、硬度不高等问题。
膨胀型阻燃剂(IFR)是近年来阻燃领域最为活跃的研究热点之一，以磷、氮为主要成分，不含卤素和锑化物，对多种易燃聚合物都具有十分良好的阻燃效果。用此类阻燃剂处理的聚合物在燃烧或热裂解时，会在聚合物表面形成一层均匀的泡沫炭质层，该炭层具有隔热、隔氧、防止融滴产生的作用，能有效阻止有毒烟气和腐蚀性气体的产生及扩散，是一种可以实现无卤化的环保型阻燃剂。
紫外光固化技术因其具有节能、环保、高效等特点，被广泛应用于涂层、油墨和粘合剂等领域。
中国专利CN100376645公开了一种阻燃型紫外光固化聚氨酯丙烯酸酯及其制备方法，该方法采用了三聚氰胺作为阻燃剂，增加织物的阻燃性能，以及延缓织物的燃烧进程，该涂料的颜色为白色。
发明内容
本发明的目的是针对现有技术中的不足，提供了一种UV固化阻燃涂料，本发明的UV固化阻燃涂料阻燃性能优异，遇火时发生泡沫膨胀，形成蜂窝状防火隔热层，能有效地保护材料，达到高阻燃效果；同时具有UV固化速度快、环保无毒、附着力好、抗划伤耐磨等优点；摒弃了传统的三聚氰胺作为氮源的阻燃体系，制备出了高透明性的UV固化阻燃涂料，能够适用于木地板、纤维板、胶合板、内外墙水泥板等，扩大了其适用范围；同时阻燃体系的氮源是光固化树脂，参与光固化反应，有效增加了光固化体系的与阻燃体系的相容性。
本发明解决其技术问题所采用的技术方案是：
一种UV固化阻燃涂料，该组合物的质量百分比组成为：
燃烧时能原位生成酸的化合物30-50％，
具有多个羟基的有机化合物5-15％，
UV光固化树脂20-40％，
活性稀释剂20-35％，
光引发剂1-3％。
作为优选，所述UV光固化树脂中含有含氮的UV光固化树脂。
具体地，所述含氮的UV光固化树脂为聚氨酯丙烯酸酯或氨基丙烯酸酯。
进一步的，所述UV固化阻燃涂料还包括0.2-1％的防沉剂。
具体地，所述燃烧时能原位生成酸的化合物为聚磷酸铵、磷酸铵、脲磷酸盐、焦磷酸铵或磷酸二氢铵中的一种或几种。
具体地，所述具有多个羟基的有机化合物为季戊四醇、三季戊四醇、甘露醇、木糖醇、焦糖、纤维素及其衍生物或双季戊四醇中的一种或几种。
具体地，所述活性稀释剂为单官能丙烯酸酯单体和双官能丙烯酸酯单体的混合物，所述单官能丙烯酸酯单体的质量百分比为UV固化阻燃涂料的5-10％，所述双官能丙烯酸酯单体的质量百分比为UV固化阻燃涂料的15-25％。
具体地，所述单官能丙烯酸酯单体为丙烯酸异冰片酯、乙氧基乙氧基乙基丙烯酸酯、2-苯氧乙基丙烯酸酯中的一种或几种；所述双官能丙烯酸酯单体为1，6-己二醇二丙烯酸酯、二丙二醇二丙烯酸酯、三丙二醇二丙烯酸酯中的一种或几种。
具体地，所述光引发剂为1-羟基环己基苯基甲酮、2-羟基-2-甲基-1-苯基-1-丙酮、二苯基-(2,4,6-三甲基苯甲酰)氧磷、二苯甲酮中的一种或几种。
一种上述的UV固化阻燃涂料的用途，所述UV固化阻燃涂料用于木地板、纤维板、胶合板、内外墙水泥板的涂装。
具体实施方式
实施例1
UV固化阻燃涂料的质量百分比组成为：环氧丙烯酸脂(江门恒光9104产品)15％，氨基丙烯酸酯(江门恒光2600产品)15％，丙烯酸异冰片酯(南京金鹿化工)7％，1，6-己二醇二丙烯酸酯(南京金鹿化工)20％，聚磷酸铵30％，季戊四醇10％，1-羟基环己基苯基甲酮(184CIBA公司产品)2％，防沉剂(BYK410产品)1％。
实施例2
UV固化阻燃涂料的质量百分比组成为：环氧丙烯酸脂(江门恒光6800产品)20％，聚氨酯丙烯酸树脂(江门恒光7162产品)20％，乙氧基乙氧基乙基丙烯酸酯(南京金鹿化工)5％，1，6-己二醇二丙烯酸酯(南京金鹿化工)15％，磷酸铵30％，三季戊四醇6％，2-羟基-2-甲基-1-苯基-1-丙酮(1173，北京英力)3％，防沉剂(BYK410产品)1％。
实施例3
UV固化阻燃涂料的质量百分比组成为：环氧丙烯酸脂(江门恒光6801产品)12％，聚氨酯丙烯酸树脂(江门恒光7162产品)20％，丙烯酸异冰片酯(南京金鹿化工)5％，1，6-己二醇二丙烯酸酯(南京金鹿化工)16％，脲磷酸盐30％，甘露醇15％，二苯甲酮(长沙新宇)1％，防沉剂(BYK410产品)1％。
实施例4
UV固化阻燃涂料的质量百分比组成为：聚酯丙烯酸脂(沙多玛CN2203产品)10％，氨基丙烯酸酯(江门恒光2600产品)20％，2-苯氧乙基丙烯酸酯(南京金鹿化工)10％，二丙二醇二丙烯酸酯(南京金鹿化工)15％，焦磷酸铵15％，磷酸二氢铵15％，木糖醇12％，1-羟基环己基苯基甲酮(184CIBA公司产品)2％，防沉剂(BYK410产品)1％。
实施例5
UV固化阻燃涂料的质量百分比组成为：聚酯丙烯酸脂(沙多玛CN2252产品)10％，氨基丙烯酸酯(江门恒光2600产品)10％，2-苯氧乙基丙烯酸酯(南京金鹿化工)7％，三丙二醇二丙烯酸酯(南京金鹿化工)16.8％，聚磷酸铵27％，脲磷酸盐23％，双季戊四醇5％，二苯基-(2,4,6-三甲基苯甲酰)氧磷(TPO，CIBA公司产品)1％，防沉剂(BYK410产品)0.2％。
实施例6
UV固化阻燃涂料的质量百分比组成为：氨基丙烯酸酯(江门恒光2600产品)30％，丙烯酸异冰片酯(南京金鹿化工)7％，1，6-己二醇二丙烯酸酯(南京金鹿化工)20％，聚磷酸铵30％，季戊四醇10％，1-羟基环己基苯基甲酮(184CIBA公司产品)2％，防沉剂(BYK410产品)1％。
实施例7
UV固化阻燃涂料的质量百分比组成为：聚氨酯丙烯酸树脂(江门恒光7162产品)32％，丙烯酸异冰片酯(南京金鹿化工)5％，1，6-己二醇二丙烯酸酯(南京金鹿化工)16％，脲磷酸盐30％，甘露醇15％，二苯甲酮(长沙新宇)1％，防沉剂(BYK410产品)1％。
对比例1
UV固化阻燃涂料的质量百分比组成为：环氧丙烯酸脂(江门恒光9104产品)30％，丙烯酸异冰片酯(南京金鹿化工)7％，1，6-己二醇二丙烯酸酯(南京金鹿化工)20％，聚磷酸铵30％，季戊四醇10％，1-羟基环己基苯基甲酮(184CIBA公司产品)2％，防沉剂(BYK410产品)1％。
对比例2
UV固化阻燃涂料的质量百分比组成为：环氧丙烯酸脂(江门恒光6801产品)32％，丙烯酸异冰片酯(南京金鹿化工)5％，1，6-己二醇二丙烯酸酯(南京金鹿化工)16％，脲磷酸盐30％，甘露醇15％，二苯甲酮(长沙新宇)1％，防沉剂(BYK410产品)1％。
将木地板除尘，辊涂UV固化阻燃涂料，涂布量共100g/m2，紫外灯固化完全(一般固化时间为3-5s)，固化能量150-250mJ/cm2，得到辊涂有阻燃层的木地板。
测试方法：
硬度测试：根据GB/T6739测试标准进行。
附着力测试：根据GB/T9286测试标准进行。
阻燃等级测试：根据GB8624测试标准进行。
测试结果如下：
检测项目 硬度 附着力(级) 阻燃等级
实施例1 HB ≤1 B1
实施例2 HB ≤1 B1
实施例3 HB ≤1 B1
实施例4 HB ≤1 B1
实施例5 HB ≤1 B1
实施例6 HB ≤1 B1
实施例7 HB ≤1 B1
对比例1 HB ≤1 B3
对比例2 HB ≤1 B3
测试标准 GB/T6739 GB/T9286 GB8624
以上述依据本发明的理想实施例为启示，通过上述的说明内容，相关工作人员完全可以在不偏离本项发明技术思想的范围内，进行多样的变更以及修改。本项发明的技术性范围并不局限于说明书上的内容，必须要根据权利要求范围来确定其技术性范围。

Claims (9)

1.一种UV固化阻燃涂料，该组合物的质量百分比组成为：
燃烧时能原位生成酸的化合物30-50％，
具有多个羟基的有机化合物5-15％，
UV光固化树脂20-40％，
活性稀释剂20-35％，
光引发剂1-3％,
所述UV光固化树脂中含有含氮的UV光固化树脂。
2.如权利要求1所述的一种UV固化阻燃涂料，其特征在于：所述含氮的UV光固化树脂为聚氨酯丙烯酸酯或氨基丙烯酸酯。
3.如权利要求1所述的一种UV固化阻燃涂料，其特征在于：所述UV固化阻燃涂料还包括0.2-1％的防沉剂。
4.如权利要求1-3任一项所述的一种UV固化阻燃涂料，其特征在于：所述燃烧时能原位生成酸的化合物为聚磷酸铵、磷酸铵、脲磷酸盐、焦磷酸铵或磷酸二氢铵中的一种或几种。
5.如权利要求1-3任一项所述的一种UV固化阻燃涂料，其特征在于：所述具有多个羟基的有机化合物为季戊四醇、三季戊四醇、甘露醇、木糖醇、焦糖、纤维素及其衍生物或双季戊四醇中的一种或几种。
6.如权利要求1-3任一项所述的一种UV固化阻燃涂料，其特征在于：所述活性稀释剂为单官能丙烯酸酯单体和双官能丙烯酸酯单体的混合物，所述单官能丙烯酸酯单体的质量百分比为UV固化阻燃涂料的5-10％，所述双官能丙烯酸酯单体的质量百分比为UV固化阻燃涂料的15-25％。
7.如权利要求6所述的一种UV固化阻燃涂料，其特征在于：所述单官能丙烯酸酯单体为丙烯酸异冰片酯、乙氧基乙氧基乙基丙烯酸酯、2-苯氧乙基丙烯酸酯中的一种或几种；所述双官能丙烯酸酯单体为1，6-己二醇二丙烯酸酯、二丙二醇二丙烯酸酯、三丙二醇二丙烯酸酯中的一种或几种。
8.如权利要求1-3任一项所述的一种UV固化阻燃涂料，其特征在于：所述光引发剂为1-羟基环己基苯基甲酮、2-羟基-2-甲基-1-苯基-1-丙酮、二苯基-(2,4,6-三甲基苯甲酰)氧磷、二苯甲酮中的一种或几种。
9.一种如权利要求1-8任一项所述的UV固化阻燃涂料的用途，其特征在于：所述UV固化阻燃涂料用于木地板、纤维板、胶合板、内外墙水泥板的涂装。
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