TW432083B - Polyurethane elastomers having improved green strength and demold time, and polyoxyalkylene polyols suitable for their preparation - Google Patents

Polyurethane elastomers having improved green strength and demold time, and polyoxyalkylene polyols suitable for their preparation Download PDF

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TW432083B
TW432083B TW085107213A TW85107213A TW432083B TW 432083 B TW432083 B TW 432083B TW 085107213 A TW085107213 A TW 085107213A TW 85107213 A TW85107213 A TW 85107213A TW 432083 B TW432083 B TW 432083B
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Gary L Allen
Nigel Barksby
Stephen D Seneker
Usama E Younes
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Arco Chem Tech
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Charge And Discharge Circuits For Batteries Or The Like (AREA)

Description

M432083 四、指定代表圖: (一) 本案指定代表圖為:第(六)圖。 (二) 本代表圖之元件符號簡單說明: (101)滑鼠上殼體 (102)滑鼠下殼體 (103)銅管 (104)線圈 (105)永久磁鐵 (106)橋式電路 (107)充電電池 (108)螺絲 (109)電線 五 、新型說明: 匕-月..曰4½ 【新型所屬之技術領域】 本創作係一種無線電滑鼠,特別是利用線圈搭配永久磁鐵,以 磁生電的方式產生電力,到充電電池儲電,讓無線滑鼠不必更 換電池,即可在使用中達到充電的效果。 【先前技術】 經查如中華民國98年3月11日所公告之新型第M352723 號省電型電輯鼠判案,其係—種電職鼠原有之各處理單 凡外,增設一開關晶體及一進階感應裝置,該進階感應專制包 括一電容式進階感應器及一電荷感應板,以非接觸之方式,控 制滑鼠原有各操控單元之供電時機,達到省電之效果。 又另有中華民國93年2月21日所公告之新型第577〇12 號無線滑氣的省電裝置及其省電方法專利案,其係接漏有包含 開關及按鍵’當無線滑鼠未被使用超過一段時間後,無線滑鼠 會進入省電模式,單使用者使用無線滑鼠並碰到按鍵時,按鍵 下壓致動開關以終止中斷程序,使得無線滑鼠回到操作模式, 達到省電之效果。 市面上一般的無線滑鼠’使用到沒電的時候就必須更換 電池或者必須找插座(USB)充電,只能節省連結電腦中間線的 空間’無法達到真正的便利。 因此综合上述無線滑鼠之創作具有以下之缺點: L 一般無線滑鼠都需要更換電池或是使用USB充電,.. M432083 ίο:.. 〇 6’修正 月曰 補 在於沒有電力的狀況下無法自行充電, 保之效果。 也無法達到環 段時間使用進入省電模式,才 2. —般無線滑鼠係利用一 能達到省電效果。 【新型内容】 本創作具有下列優點:
本創作具有線圈及永久磁鐵,可用 用磁生電原理產生電力。 手動的方式將無線滑鼠利 電,不會導致開會、或是工 的問題,延誤或擔擱作業時 2.本創作具有充電電池進行即時充 程作業中S為滑鼠沒電不能使用 間。 可達到環保效果。 3.本創作具充電電池,不需一般電池, 【實施方式】 -種手動式無m充電裝置(請參考第…第四盘第丄 圖),係包含賴上殼體⑽)、滑鼠下殼體_、銅管_、_ _、水久磁聊5)、橋式電路⑽)、充電電池⑽)、螺絲陶、 電線(_所組合而成’其t,滑鼠上殼體⑽)位於本裝置之最上 方(請參考第二圖)’絲保護滑鼠内部不受外力撞擊,滑鼠下殼體 位於本裝置之最下方(請參考第喊第五圖),用來承載滑鼠内 部之元件,賴下殼體_上有1形薄壁,用以將銅管⑽)放 置其内,峨1〇3)為-卿管㈣三_細圖獅),位於滑鼠 下殼體_上之圓形薄抛,其内部設有永久磁鐵⑽),可供永 4 M432083 久磁鐵(105)在銅管⑽)内移動,且該銅管(1〇3)外侧缠k麵 (104)纟銅:(1〇3)内之永久磁鐵(1〇5)適過該線圈時即可產生電 力’經電線(109)導向橋式電路⑽),橋式電路⑽)位於滑鼠下殼 體(1〇2)上(請參考第六圖)之銅管(1〇3)環形内之空間,以電線⑼9) 連接線圈(104)與充電電池(107)之間,用於將銅管(1〇3)内永久磁鐵 (1G5)運動所產生之電源全部變為正電壓,充電電池(⑴7)位於滑鼠 下殼體(102)上’且在線圈(1〇4)與銅管之另一侧邊,用於讓橋式電 ㉞路(1〇6)所整流的電力儲存於充電電池(107)内,數個螺絲(1〇8),位 於滑鼠下殼體(102)用以將滑鼠上殼體(1〇1)與滑鼠下殼體(1〇2)組 合; 經由上述元件之組合,使用者轉動本裝置時,永久磁鐵(1〇5) 在銅官(1G3)内滑動’湘法拉第原理產生電力,將電力由電線導 向橋式電路(106)整流,在經電線⑼9)到充電電池儲電,則當無線 滑鼠暫時沒有電力時’可經由本創作之使用,自動產生電力,無 需額外電池之消耗。 【圖式簡單說明】 第一圖係本創作之完成實體圖。 第一圖傳本創作之上殼。 第二圖係本創作之銅管、線圈立體組合圖。 第四圖係本創作之内部立體組合圖。 第五圖係本創作之殼底。 第六圖係本創作之爆炸圖。 修正 補充 要元件符號說明】 (101)滑鼠上殼體 (103)銅管 (105)永久磁鐵 (107)充電電池 (102)滑鼠下殼體 (104)線圈 (106)橋式電路 (108)螺絲. (109)電線 M432083 申請專利範圍·· 1Q1 4. 0 6 年月9 ± 種手赋鱗滑鼠充職置,係包含賊上麵、滑鼠下 设體、銅管、線圈、永久磁鐵、橋式電路、充電電池、螺絲、電 線所,合而成’其中,滑鼠上殼體位於本㈣之最上方,用來保 護滑鼠内部不受外力撞擊,滑鼠下殼體位於本裝置之最下方,用 來承载滑鼠崎之元件’滑鼠下殼體上有—圓形薄壁,用以將銅 g放置其内’崎為—獅管,位於滑鼠下殼體H形薄壁内, # 其内部設有永久磁鐵,可供永久磁鐵在銅管内移動,且該銅管外 側纏繞數,由銅管内之永久磁舰職細時即可產生電 力’經電線導向橋式電路,橋式電路位於滑鼠下殼體上之銅管環 形内之郎,以電線連接_與充電電池之間,祕將銅管内永 久磁鐵運動所產生之電源全部變為正賴’充電電池位於滑鼠下 殼體上,且在線圈與銅管之另一側邊,用於讓橋式電路所整流的 電力儲存於充電電池内’數個螺絲,位於滑鼠下殼體甩以將滑鼠 ^ 上殼體與滑鼠下殼體組合; 經由上述元件之組合,使用者轉動本裝置時,永久磁鐵在銅 管内滑動,利用法拉第原理產生電力,將電力由電線導向橋式電 路整流,在經電線到充電電池儲電,則當無線滑鼠暫時沒有電力 時,可經由本創作之使用,自動產生電力,無需額外電池之消耗。
第二圖 101 8 M432083
104 9 ^432083 104
第四圖 10 M432083
第五圖 11 M432083
第六圖 12
TW085107213A 1995-06-15 1996-06-15 Polyurethane elastomers having improved green strength and demold time, and polyoxyalkylene polyols suitable for their preparation TW432083B (en)

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US08/491,007 US5670601A (en) 1995-06-15 1995-06-15 Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation

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US (4) US5670601A (zh)
EP (1) EP0748828B2 (zh)
JP (1) JPH093152A (zh)
KR (1) KR100437361B1 (zh)
CN (2) CN1079803C (zh)
AR (1) AR002489A1 (zh)
AT (1) ATE235525T1 (zh)
AU (1) AU697623B2 (zh)
BR (1) BR9602795A (zh)
CA (1) CA2178139A1 (zh)
DE (1) DE69626890T3 (zh)
DK (1) DK0748828T3 (zh)
ES (1) ES2194955T5 (zh)
HK (1) HK1044345A1 (zh)
SG (1) SG52809A1 (zh)
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Publication number Priority date Publication date Assignee Title
US5712216A (en) * 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5670601A (en) * 1995-06-15 1997-09-23 Arco Chemical Technology, L.P. Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation
US5856372A (en) * 1996-05-23 1999-01-05 Arco Chemical Technology, L.P. Microcellular elastomers with improved processability and properties
US5958994A (en) * 1997-02-25 1999-09-28 Arco Chemical Technology, L.P. Method for decreasing the propensity for phase-out of the high molecular weight component of double metal cyanide-catalyzed high secondary hydroxyl polyoxypropylene polyols
EP0881244A3 (de) * 1997-05-27 2000-01-19 Basf Aktiengesellschaft Verfahren zur Herstellung von thermoplastischen Polyurethanen
CA2312408A1 (en) 1997-12-05 1999-06-17 Bayer Ag Polyurethane and polyurethane/urea heat-cured and moisture-cured elastomers with improved physical properties
US6028158A (en) * 1997-12-31 2000-02-22 Bayer Corporation Freeze-stable allophanate-modified toluene diisocyanate trimers
US5955609A (en) * 1997-12-31 1999-09-21 Bayer Corporation Trimer catalyst system for aliphatic and aromatic isocyanates
US5990257A (en) * 1998-01-22 1999-11-23 Witco Corporation Process for producing prepolymers which cure to improved sealants, and products formed thereby
US5962619A (en) * 1998-03-16 1999-10-05 Arco Chemical Technology, L.P. Process for making clear polyurethane/urea elastomers
DE19908562A1 (de) * 1998-03-25 1999-10-07 Henkel Kgaa Polyurethan und polyurethanhaltige Zubereitung
DE19816525A1 (de) * 1998-04-15 1999-10-21 Basf Ag Verfahren zur Herstellung von thermoplastischen Polyurethanen
US6022903A (en) * 1998-07-09 2000-02-08 Arco Chemical Technology L.P. Permanent gas blown microcellular polyurethane elastomers
US6171678B1 (en) * 1998-07-14 2001-01-09 Bayer Antwerp N.V. Polyurethane carpet backings with improved tuft bind
US6100310A (en) * 1998-09-25 2000-08-08 Bayer Antwerp N.V. Process for making microcellular polyurethane elastomers
US6291538B1 (en) * 1998-12-24 2001-09-18 Kao Corporation Process for preparing polyurethane foam
CN1136246C (zh) 1999-03-17 2004-01-28 旭硝子株式会社 聚氨酯系/聚氨酯脲系树脂及其制备方法
US6673889B1 (en) 1999-06-28 2004-01-06 Omnova Solutions Inc. Radiation curable coating containing polyfuorooxetane
US6624209B2 (en) 1999-07-30 2003-09-23 Sanyo Chemical Industries, Ltd. Polymer polyol composition, process for producing the same, and process for producing polyurethane resin
US6756414B2 (en) * 1999-07-30 2004-06-29 Sanyo Chemical Industries, Ltd. Polymer polyol composition, process for producing the same, and process for producing polyurethane resin
DE19945102A1 (de) * 1999-09-21 2001-03-22 Mitex Gummifabrik Hans Knott G Formteil und Verfahren zur Herstellung des Formteils
US6569352B1 (en) * 1999-10-25 2003-05-27 Stepan Company Phthalic anhydride based polyester-ether polyols and urethane prepolymers produced therefrom
US20080108719A1 (en) * 1999-10-25 2008-05-08 Geiger Eric J Phthalic Anhydride Based Polyester-Ether Polyols and Double Metal Cyanide Catalyst System for Preparing Same
US20050085658A1 (en) * 1999-10-25 2005-04-21 Geiger Eric J. Phthalic anhydride based polyester-ether polyols and double metal cyanide catalyst system for preparing same
US20040251571A1 (en) * 1999-11-16 2004-12-16 Serman Carl J. High performance microcellular foam and manufacturing method and apparatus thereof
US6733707B1 (en) * 1999-11-16 2004-05-11 C. U. E., Inc. High performance microcellular foam and manufacturing method apparatus thereof
TWI225494B (en) 2000-02-17 2004-12-21 Mitsui Chemicals Inc Microcellular polyurethane elastomer, and method of producing the same
AU2001245601A1 (en) 2000-03-09 2001-09-17 Pbt Brands, Inc. Sealants containing multimodal polymer blends
US6201035B1 (en) 2000-05-24 2001-03-13 Basf Corporation Use of low unsaturated polyether polyols in high resilience slabstock foam applications
US6344494B1 (en) 2000-05-24 2002-02-05 Basf Corporation Use of low unsaturated polyether polyols in slabstock foam applications
EP1172387A1 (en) * 2000-07-14 2002-01-16 Huntsman International Llc Process for preparing an elastomer
EP1328564A1 (en) * 2000-10-23 2003-07-23 Huntsman International Llc High performance sealant formulations based on mdi prepolymers
US6660828B2 (en) 2001-05-14 2003-12-09 Omnova Solutions Inc. Fluorinated short carbon atom side chain and polar group containing polymer, and flow, or leveling, or wetting agents thereof
CN1209392C (zh) 2001-05-14 2005-07-06 阿姆诺洼化学有限公司 由含侧氟碳基的环状单体得到的聚合物表面活性剂
DE10142747A1 (de) 2001-08-31 2003-03-20 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
JPWO2003059980A1 (ja) * 2002-01-11 2005-05-19 旭硝子株式会社 軟質ポリウレタンフォームの製造方法
EP1329469A1 (de) * 2002-01-18 2003-07-23 Sika Schweiz AG Polyurethanzusammensetzung
US7511111B2 (en) * 2002-03-08 2009-03-31 Bayer Materialscience Llc Polyurethane elastomers having improved physical properties and a process for the production thereof
US6824703B2 (en) * 2002-03-08 2004-11-30 Bayer Materialscience Llc Polyurethane elastomers having improved physical properties and a process for the production thereof
US20040122200A1 (en) * 2002-12-20 2004-06-24 Roesler Richard R. Process for the preparation of moisture-curable, polyether urethanes with terminal cyclic urea/reactive silane groups
JP4641711B2 (ja) * 2003-08-13 2011-03-02 花王株式会社 衝撃緩衝性発泡体
US7338983B2 (en) * 2004-02-10 2008-03-04 World Properties, Inc. Low density polyurethane foam, method of producing, and articles comprising the same
JP4378624B2 (ja) * 2004-02-10 2009-12-09 株式会社イノアックコーポレーション シール部材の製造方法
JP5032841B2 (ja) * 2004-02-20 2012-09-26 出光興産株式会社 ポリウレタン組成物及びその成形品
DE102004015985A1 (de) * 2004-04-01 2005-10-20 Bayer Materialscience Ag Verfärbungsstabile Polyetherallophanate
JP3905895B2 (ja) * 2004-04-05 2007-04-18 住化バイエルウレタン株式会社 低硬度熱硬化性ポリウレタンエラストマーおよびその製造方法
DE102004028769A1 (de) * 2004-06-16 2005-12-29 Basf Ag Verfahren zur Herstellung von Polyetheralkoholen und Polyurethanen
US7417094B2 (en) * 2004-11-18 2008-08-26 Pripro Polymer, Inc. Cross-linked thermoplastic polyurethane/polyurea and method of making same
US8188208B2 (en) 2005-01-13 2012-05-29 Bayer Materialscience Llc Solid polyurethane elastomers which exhibit reduced dimensional shrinkage
US7670501B2 (en) * 2005-05-27 2010-03-02 Bayer Materialscience Llc Carbon dioxide blown low density, flexible microcellular polyurethane elastomers
DE102005047560A1 (de) * 2005-10-04 2007-04-05 Bayer Materialscience Ag Zusammensetzung zur Herstellung von Polyharnstoffbeschichtungen
US20070142610A1 (en) * 2005-12-15 2007-06-21 Harasin Stephen J Polyurethane elastomers comprising allophanate modified isocyanates
US20070142607A1 (en) * 2005-12-15 2007-06-21 Bayer Materialscience Llc Weather resistant polyurethane elastomer
EP2190894A1 (en) * 2007-09-04 2010-06-02 Dow Global Technologies Inc. Reaction injection molded polyurethanes made using high levels of natural oil-based polyols
US20090084539A1 (en) * 2007-09-28 2009-04-02 Ping Duan Downhole sealing devices having a shape-memory material and methods of manufacturing and using same
WO2009068421A1 (en) * 2007-11-26 2009-06-04 Huntsman International Llc Novel tennis ball
ITMI20101084A1 (it) 2010-06-16 2011-12-16 Dow Global Technologies Inc Suole poliuretaniche di scarpe preparate usando polioli a base di ossido di propilene
ES2715193T3 (es) * 2010-11-03 2019-06-03 Dow Global Technologies Llc Sistemas de poliuretano con capacidad de autoaplastamiento
US8975335B2 (en) * 2011-09-23 2015-03-10 Bayer Materialscience Llc Process for the production of high air flow polyether foams and the foams produced by this process
CN105829385B (zh) * 2013-11-08 2020-03-31 科思创德国股份有限公司 聚氨酯泡沫及其制备方法
EP3077439B1 (en) * 2013-12-02 2020-04-29 Dow Global Technologies LLC Storage stable polyol composition for polyurethane elastomers
US9951174B2 (en) 2015-05-20 2018-04-24 Covestro Llc Polyol compositions, a process for the production of these polyol compositions, and their use in the production of open celled polyurethane foams having high airflow
WO2018169833A1 (en) 2017-03-15 2018-09-20 Covestro Llc Viscoelastic polyurethane foams with reduced temperature sensitivity
US10903435B2 (en) * 2017-10-18 2021-01-26 Dongwoo Fine-Chem Co., Ltd. Flexible display device
US10766998B2 (en) 2017-11-21 2020-09-08 Covestro Llc Flexible polyurethane foams
JP6510098B1 (ja) * 2018-02-14 2019-05-08 Agc株式会社 ポリウレタンフォーム製造用組成物、ポリオールシステム液及びポリウレタンフォームの製造方法
US10793692B2 (en) 2018-10-24 2020-10-06 Covestro Llc Viscoelastic flexible foams comprising hydroxyl-terminated prepolymers
CN113227185A (zh) * 2018-11-29 2021-08-06 巴斯夫欧洲公司 基于ppg的tpu的连续制备
US20220025102A1 (en) 2018-12-07 2022-01-27 Covestro Intellectual Property Gmbh & Co. Kg Polyurethane microcellular elastomer, non-pneumatic tire and preparation process thereof
KR20220044207A (ko) * 2019-08-06 2022-04-06 다우 글로벌 테크놀로지스 엘엘씨 일액형 폴리우레탄 전구중합체 조성물
CN111518259B (zh) * 2020-05-06 2022-08-19 长华化学科技股份有限公司 高回弹性的聚氨酯微孔弹性体及其制备方法和应用
US11572433B2 (en) 2021-03-12 2023-02-07 Covestro Llc In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation
US11718705B2 (en) 2021-07-28 2023-08-08 Covestro Llc In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams
EP4230680A1 (en) * 2022-02-18 2023-08-23 PCC ROKITA Spolka Akcyjna A PROCESS FOR OBTAINING A POLYETHER POLYOL WITH A BIMODAL MOLECULAR WEIGHT 
DISTRIBUTION, FOR THE PRODUCTION OF FLEXIBLE POLYURETHANE FOAMS
CN115256999A (zh) * 2022-08-08 2022-11-01 宁波格林美孚新材料科技有限公司 一种微孔发泡颗粒复合弹性材料的制备方法
CN117162225B (zh) * 2023-11-03 2024-02-23 江苏神禹港务工程有限公司 一种混凝土预制构件脱模成型方法及系统

Family Cites Families (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4120850A (en) 1977-09-06 1978-10-17 E. I. Du Pont De Nemours And Company Polyether urethane polymers prepared from a copolymer of tetrahydrofuran and ethylene oxide
US4239879A (en) * 1979-06-25 1980-12-16 The General Tire & Rubber Company Thermoplastic polyurethane prepared from a poly-1,2-propylene ether glycol, a low molecular weight glycol and 2,4-tolylene diisocyanate
DE3329775A1 (de) 1983-08-18 1985-02-28 Bayer Ag, 5090 Leverkusen Thermoplastische polyurethane hoher waermestandfestigkeit auf basis von naphthylendiisocyanat, verfahren zu ihrer herstellung und ihre verwendung
US4559366A (en) * 1984-03-29 1985-12-17 Jaquelyn P. Pirri Preparation of microcellular polyurethane elastomers
JPS6213428A (ja) * 1985-07-10 1987-01-22 Toyo Tire & Rubber Co Ltd 高硬度軟質ポリウレタンフオ−ム
US4687851A (en) 1985-08-15 1987-08-18 The Dow Chemical Company Polyurethane elastomers prepared from high equivalent weight polyahls
US5300535A (en) * 1988-10-25 1994-04-05 Asahi Glass Company Ltd. Method for producing polyurethane flexible foam
AR243911A1 (es) * 1988-11-18 1993-09-30 Dow Chemical Co Un proceso para la preparacion de un poliol que tiene un peso equivalente de 200 a 4000 mediante la reaccion de un compuesto monoepoxi.
US5114619A (en) * 1989-07-14 1992-05-19 The Dow Chemical Company Production of polyether polyols with reduced unsaturation
JP2619109B2 (ja) * 1989-05-09 1997-06-11 旭硝子株式会社 柔軟性にすぐれたポリウレタン系硬化性組成物
EP0402905A3 (en) * 1989-06-13 1991-04-03 Asahi Glass Company Ltd. Method for producing a molded product of integral-skin polyurethane foam
US5106874A (en) * 1989-06-16 1992-04-21 The Dow Chemical Company Process for preparing elastomeric polyurethane or polyurethane-urea polymers, and polyurethanes so prepared
US5061254A (en) 1989-06-21 1991-10-29 Becton, Dickinson And Company Thermoplastic elastomeric hydrophilic polyetherurethane expandable catheter
DE3942329A1 (de) * 1989-12-21 1991-06-27 Basf Ag Verfahren zur herstellung von polyurethan-weichschaumstoffen mit geringer stauchhaerte und hierfuer verwendbare blockpolyoxypropylen-polyoxyethylen-polyolgemische
DE3942330A1 (de) * 1989-12-21 1991-06-27 Basf Ag Verfahren zur herstellung von flexiblen polyurethan-weichschaumstoffen mit viskoelastischen, koerperschalldaempfenden eigenschaften und hierzu verwendbare polyoxyalkylen-polyol-mischungen
US5013810A (en) 1990-02-09 1991-05-07 Mobay Corporation Impact absorbing media
US5246977A (en) 1990-05-04 1993-09-21 The Dow Chemical Company Microcellular polyurethane polymers prepared from isocyanate-terminated poly(oxytetramethylene) glycol prepolymers
US5100997A (en) * 1990-05-29 1992-03-31 Olin Corporation Preparation of elastomers using high molecular weight polyols or polyamines, said polyols prepared using a double metal cyanide complex catalyst
US5116931A (en) * 1990-09-28 1992-05-26 Olin Corporation Thermoset polyurethane elastomers and polyurea elastomers made using high functionality, low unsaturation level polyols prepared with double metal cyanide catalysts
US5096993A (en) * 1990-11-02 1992-03-17 Olin Corporation Thermoplastic polyurethane elastomers and polyurea elastomers made using low unsaturation level polyols prepared with double metal cyanide catalysts
US5185420A (en) * 1990-11-02 1993-02-09 Olin Corporation Thermoplastic polyurethane elastomers and polyurea elastomers made using low unsaturation level polyols prepared with double metal cyanide catalysts
US5231159A (en) * 1990-12-27 1993-07-27 The Gates Rubber Company High temperature resistant molded elastomer
CA2062433C (en) 1991-03-08 2000-02-29 Takashi Matsumoto Medical tube
US5158922A (en) * 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
TW264487B (zh) * 1992-02-18 1995-12-01 Takeda Pharm Industry Co Ltd
AU4384193A (en) * 1992-06-04 1993-12-30 Olin Corporation Hard thermoplastic polyurethane elastomers
US5357038A (en) * 1992-08-03 1994-10-18 Olin Corporation Process and composition for providing double metal cyanide catalyzed polyols having enhanced reactivity
US5340902A (en) * 1993-06-04 1994-08-23 Olin Corporation Spandex fibers made using low unsaturation polyols
GB9312256D0 (en) * 1993-06-15 1993-07-28 Ici Plc Novel polyols
US5470813A (en) * 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5482908A (en) * 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5677413A (en) * 1995-06-15 1997-10-14 Arco Chemical Technology, L.P. Polyurethane elastomers exhibiting improved demold green strength and water absorption and haze-free polyols suitable for their preparation
US5670601A (en) * 1995-06-15 1997-09-23 Arco Chemical Technology, L.P. Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation
US5545601A (en) * 1995-08-22 1996-08-13 Arco Chemical Technology, L.P. Polyether-containing double metal cyanide catalysts
US5648447A (en) * 1995-12-22 1997-07-15 Arco Chemical Technology, L.P. Elastomeric polyurethanes with improved properties based on crystallizable polyols in combination with low monol polyoxpropylene polyols
US5605939A (en) * 1996-01-26 1997-02-25 Arco Chemical Technology, L.P. Poly(oxypropylene/oxyethylene) random polyols useful in preparing flexible high resilience foam with reduced tendencies toward shrinkage and foam prepared therewith
US5777177A (en) * 1996-02-07 1998-07-07 Arco Chemical Technology, L.P. Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter
US5576382A (en) * 1996-05-05 1996-11-19 Arco Chemical Technology, L.P. Aqueous polyurethane dispersions based on polyether polyols of low monol content
US5696221A (en) * 1996-07-15 1997-12-09 Arco Chemical Technology, L.P. Polyurethane/urea heat-cured and moisture-cured elastomers with improved physical properties
US5689012A (en) * 1996-07-18 1997-11-18 Arco Chemical Technology, L.P. Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter
US5691441A (en) * 1996-10-11 1997-11-25 Arco Chemical Technology, L.P. Spandex elastomers
US5723563A (en) * 1996-10-11 1998-03-03 Arco Chemical Technology, L.P. Spandex elastomers
US5708118A (en) * 1996-10-11 1998-01-13 Arco Chemical Technology, L.P. Spandex elastomers
US5763642A (en) * 1997-06-19 1998-06-09 Arco Chemical Technology, L.P. Low monol polyoxy (higher) alkylene polyols with primary hydroxyl content

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DE69626890T2 (de) 2003-11-13
AR002489A1 (es) 1998-03-25
CN1148054A (zh) 1997-04-23
EP0748828B2 (en) 2006-11-29
DE69626890D1 (de) 2003-04-30
CN1347930A (zh) 2002-05-08
US5670601A (en) 1997-09-23
BR9602795A (pt) 1998-04-22
CA2178139A1 (en) 1996-12-16
DK0748828T3 (da) 2003-06-30
SG52809A1 (en) 1998-09-28
JPH093152A (ja) 1997-01-07
ES2194955T3 (es) 2003-12-01
US5965778A (en) 1999-10-12
ES2194955T5 (es) 2007-06-16
DE69626890T3 (de) 2007-04-26
ATE235525T1 (de) 2003-04-15
KR100437361B1 (ko) 2004-09-20
KR970001401A (ko) 1997-01-24
US5849944A (en) 1998-12-15
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AU5600096A (en) 1997-01-02
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