TW302437B - - Google Patents
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- TW302437B TW302437B TW082105852A TW82105852A TW302437B TW 302437 B TW302437 B TW 302437B TW 082105852 A TW082105852 A TW 082105852A TW 82105852 A TW82105852 A TW 82105852A TW 302437 B TW302437 B TW 302437B
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- TW
- Taiwan
- Prior art keywords
- group
- gold
- largest
- range
- metal
- Prior art date
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- 239000000975 dye Substances 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims abstract description 23
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 238000010521 absorption reaction Methods 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims abstract description 7
- 239000000980 acid dye Substances 0.000 claims abstract description 5
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims abstract description 4
- 150000004982 aromatic amines Chemical class 0.000 claims abstract 3
- -1 aromatic amines Ammonium salt compound Chemical class 0.000 claims description 162
- 239000004065 semiconductor Substances 0.000 claims description 15
- LKKPNUDVOYAOBB-UHFFFAOYSA-N naphthalocyanine Chemical compound N1C(N=C2C3=CC4=CC=CC=C4C=C3C(N=C3C4=CC5=CC=CC=C5C=C4C(=N4)N3)=N2)=C(C=C2C(C=CC=C2)=C2)C2=C1N=C1C2=CC3=CC=CC=C3C=C2C4=N1 LKKPNUDVOYAOBB-UHFFFAOYSA-N 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 9
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 9
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 7
- 239000010931 gold Substances 0.000 claims description 7
- 229910052737 gold Inorganic materials 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 239000003550 marker Substances 0.000 claims description 4
- 230000003287 optical effect Effects 0.000 claims description 4
- 238000002372 labelling Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 230000003595 spectral effect Effects 0.000 claims description 3
- 229910052714 tellurium Inorganic materials 0.000 claims description 3
- 239000013307 optical fiber Substances 0.000 claims description 2
- 238000001228 spectrum Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims 8
- 239000002184 metal Substances 0.000 claims 8
- 150000002815 nickel Chemical class 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 239000004020 conductor Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- MJFITTKTVWJPNO-UHFFFAOYSA-N 3h-dithiole;nickel Chemical class [Ni].C1SSC=C1 MJFITTKTVWJPNO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 40
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 14
- 239000001257 hydrogen Substances 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 12
- 125000004430 oxygen atom Chemical group O* 0.000 description 12
- 125000001033 ether group Chemical group 0.000 description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 9
- 150000002431 hydrogen Chemical class 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 229910052736 halogen Inorganic materials 0.000 description 8
- 150000002367 halogens Chemical class 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 239000002283 diesel fuel Substances 0.000 description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
- 230000002079 cooperative effect Effects 0.000 description 5
- 238000001514 detection method Methods 0.000 description 5
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 230000005284 excitation Effects 0.000 description 4
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical group 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 238000000855 fermentation Methods 0.000 description 3
- 230000004151 fermentation Effects 0.000 description 3
- 125000001841 imino group Chemical group [H]N=* 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 2
- 125000005999 2-bromoethyl group Chemical group 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 2
- 125000005916 2-methylpentyl group Chemical group 0.000 description 2
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- IVJFXSLMUSQZMC-UHFFFAOYSA-N Dithiocyclopentene Natural products C1SC=CS1 IVJFXSLMUSQZMC-UHFFFAOYSA-N 0.000 description 2
- 239000005562 Glyphosate Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 206010041349 Somnolence Diseases 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- ALVFCPMBEQMVID-UHFFFAOYSA-N cyclopentene-1,2-dithiol Chemical compound SC1=C(S)CCC1 ALVFCPMBEQMVID-UHFFFAOYSA-N 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229940093499 ethyl acetate Drugs 0.000 description 2
- 235000019439 ethyl acetate Nutrition 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229940097068 glyphosate Drugs 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000010705 motor oil Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 230000007115 recruitment Effects 0.000 description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 description 1
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 125000005976 1-phenylethyloxy group Chemical group 0.000 description 1
- YPJUNDFVDDCYIH-UHFFFAOYSA-M 2,2,3,3,4,4,4-heptafluorobutanoate Chemical compound [O-]C(=O)C(F)(F)C(F)(F)C(F)(F)F YPJUNDFVDDCYIH-UHFFFAOYSA-M 0.000 description 1
- YCWRFIYBUQBHJI-UHFFFAOYSA-N 2-(4-aminophenyl)acetonitrile Chemical group NC1=CC=C(CC#N)C=C1 YCWRFIYBUQBHJI-UHFFFAOYSA-N 0.000 description 1
- 125000000143 2-carboxyethyl group Chemical group [H]OC(=O)C([H])([H])C([H])([H])* 0.000 description 1
- 125000001340 2-chloroethyl group Chemical group [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- 125000004777 2-fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 description 1
- 125000004493 2-methylbut-1-yl group Chemical group CC(C*)CC 0.000 description 1
- 125000005975 2-phenylethyloxy group Chemical group 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
- 125000004217 4-methoxybenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1OC([H])([H])[H])C([H])([H])* 0.000 description 1
- LVQFHDAKZHGEAJ-UHFFFAOYSA-M 4-methylbenzenesulfonate Chemical compound [CH2]C1=CC=C(S([O-])(=O)=O)C=C1 LVQFHDAKZHGEAJ-UHFFFAOYSA-M 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229920002581 Glucomannan Polymers 0.000 description 1
- 235000005206 Hibiscus Nutrition 0.000 description 1
- 235000007185 Hibiscus lunariifolius Nutrition 0.000 description 1
- 244000284380 Hibiscus rosa sinensis Species 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
- LIWAQLJGPBVORC-UHFFFAOYSA-N N-ethyl-N-methylamine Natural products CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- MYGOXWRECGNPFF-UHFFFAOYSA-N [Ni].C1=CCCC1 Chemical compound [Ni].C1=CCCC1 MYGOXWRECGNPFF-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000005277 alkyl imino group Chemical group 0.000 description 1
- 125000005336 allyloxy group Chemical group 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- PVWYTIFUYYJMQO-UHFFFAOYSA-O butyl(phenyl)phosphanium Chemical compound CCCC[PH2+]C1=CC=CC=C1 PVWYTIFUYYJMQO-UHFFFAOYSA-O 0.000 description 1
- 125000004744 butyloxycarbonyl group Chemical group 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 125000001721 carboxyacetyl group Chemical group 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229940046240 glucomannan Drugs 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 125000006343 heptafluoro propyl group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000006038 hexenyl group Chemical group 0.000 description 1
- 125000005935 hexyloxycarbonyl group Chemical group 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000005928 isopropyloxycarbonyl group Chemical group [H]C([H])([H])C([H])(OC(*)=O)C([H])([H])[H] 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- KBPHJBAIARWVSC-RGZFRNHPSA-N lutein Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\[C@H]1C(C)=C[C@H](O)CC1(C)C KBPHJBAIARWVSC-RGZFRNHPSA-N 0.000 description 1
- 229960005375 lutein Drugs 0.000 description 1
- ORAKUVXRZWMARG-WZLJTJAWSA-N lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C ORAKUVXRZWMARG-WZLJTJAWSA-N 0.000 description 1
- 235000012680 lutein Nutrition 0.000 description 1
- 239000001656 lutein Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- BFBPISPWJZMWJN-UHFFFAOYSA-N methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate Chemical compound COC(=O)C1=CC=CC=C1N=CCC(C)CCCC(C)(C)O BFBPISPWJZMWJN-UHFFFAOYSA-N 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005187 nonenyl group Chemical group C(=CCCCCCCC)* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 1
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000002071 phenylalkoxy group Chemical group 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-M pivalate Chemical compound CC(C)(C)C([O-])=O IUGYQRQAERSCNH-UHFFFAOYSA-M 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- KBPHJBAIARWVSC-XQIHNALSSA-N trans-lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C KBPHJBAIARWVSC-XQIHNALSSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004205 trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/003—Marking, e.g. coloration by addition of pigments
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/007—Coloured or dyes-containing lubricant compositions
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; viscous liquids; paints; inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2835—Oils, i.e. hydrocarbon liquids specific substances contained in the oil or fuel
- G01N33/2882—Markers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/13—Tracers or tags
Description
302437 A6
五、發明説明(1 ) 本發明係關於以來自於具有最大的吸收範麵在從600至 1,200毫微米及/或最大的螢光範園在從620至1,200毫 微米的酞菁,萘菁,二硫環戊烯鎳期錯合物,芳族胺的按 鹽化合物,次甲基染料或輿斯夸酸染料等分類之化合物作 為液體檷示_ (追蹤劑)的用途,為偵測在液«中的標示劑 之方法及逋合於該目的的偵测器。 常常須要依序檷示液《8,K便於接著例如在使用彼等時 可Μ適合的方法再偵测因此禰示的液體。 例如,可以這種方式使加热油與柴油區別。 本發明的目的是提供«合於當成禰示繭的化合物。檷示 髑在近紅外線中應該具有十分強的吸收及螢光*故Μ热知 在該範園中敏感的光度計偵澜吸收及/或Μ热知的儀器偵 測在可能以適當的輻射源激發之後的螢光。 吾等已發現以最初極詳细說明的化合物可達成該目的。 含金靨的酞菁或萘菁通常包括Μ鋰(兩個),鎂,鋅,鋦 •辣,VO· TiO或A1C1為中心原子。 瑭合的酞菁具有例如的化學式la (请先閱讀背面之;i意事項存i«寫本頁) —装· 訂. tt濟部中喪標準—典工消资合作杜印製
El7R3R5Ri 本紙張尺度通用中國國家標準(CNS)甲4现格(210 X 297公釐〉 82.6. 40f〇〇〇 3 u£437 A6 _B6_ 五、發明説明(2) 其中
Me1是兩個氫原子,兩個鋰原子或鎂,鋅,_,練,V0, TiO ,A1C丨或Si(OH)2 ,至少4個R1至Rie基彼此分別具 有化學式W-X1,其中W是化學鐽,硫,亞胺基,Ct-U-烷 基亞胺基或苯基亞胺基,而乂1是h-CM-焼基,可使Χ1^ 在醚官能中的從1至4個氧原子間斷,或以苯基取代,或 者是金剛烷基或纆取代,或未經取代;$;苯基,而任何其餘 的基Ri至是氫,鹵素,羥基磺醯基或匕-^-二烷基胺 磺醣基。 其它通合的酞菁具有例如的化學式lb (請先《讀背面之注意事項再塡寫本頁) .裝.
Rl5 R1·3
訂. «濟部中喪櫟準脣R工消费合作社印製
其中在一起的R17與R18或R18與Rie或1?18與1{2。在每 一個實例中具有化學式X2-C2H4-X3 *其中兩涸基X2及X3中 有一個是氧,而另—個是亞胺基或Ci_C4_烷基亞胺基,而 且Rie與R2e或R17與R2。或R17與Rie彼此分別在每一 個賁例中是氫或鹵素*而Me1是根據K上的定義。 適合的萘菁具有例如的化學式E -4- 本紙張度適用中國國家標準(CNS)甲4规格(210 X 297公釐) 82.6. 40,000 五、發明説明(3 ) v9
vi γ3 ν:2 A6 B6 (II), 其中γ1,γ2,γ3,,γΒ,γβ,丫7及γβ彼此分別是氲,羥 基,Ci-Cao-烷基或Ci-Czo-烷氧基,在此可使烷基Μ在 醚官能中的從1至4涸氧原子間斷及Μ苯基取代, Υβ,Υ1。 ,Υ11及Υ12彼此分別是氫,Ci-C2〇-烷基或 Ci-Cao-烷氧基,在此可使烷基Μ在醚官能中的從1至4 個氧原子間斷•或者是鹵素,羥基磺醢基或(^-(:4-二烷基 胺靦醣基,而 Me2是兩個氫原子,兩個鋰原子,鎂,鋅,鋦,鎳,V0, T i 0 ,A 1 C 1 或 Y1-7
Si (請先閲讀背面之注意事項再塡寫本頁) 裝· 訂· 經濟部中喪標攀看貝工消费合作社印製 v!3 其中Y17及Y18彼此分別是羥基
Ci-C; 烷氧基 -5 本紙張尺度適用中國困家標準(CNS)甲4规格(210 X 297公釐) 82.6. 40,000 烯 (請先閲讀背面之注意事項再填寫本頁) A6 _B6_ 五、發明説明(乜)
Ct-Cao-烷基,C2-C2〇-烯基· C3-C2〇-烯氧基或 v20 ί C-Si-O-Y19
I γ21 其中 Υ1β 是 Ci-Cao-烷基,c2-c2〇-嫌 Ϊ 或 C<t-C2〇 基,而Y2。及Y21彼此分別是h-Cw-烷#,C2-C12-烯 基或根據Μ上0¥19的定義。 在此特別有興趣的是化學式II的萘膂,其中”至?*中至 少一届是Μ。 適合的二硫環戊烯辣鹽錯合物具有例如的化學式Β .裝.
S s
Ni丨丄〆 、, 5 S L' (III), 訂. «濟部中_標準房R工消费合作社印製 其中L1,L2,L3及L4彼此分別是可Μ被在醚官能中的從1 至4. _涸氧原子間ϊί的C i - C 2 〇 -烷基,苯基,C\ - C 2 〇 -烷基 苯基,CrCao-烷氧基苯基,可使在此的烷基分別以在醚 官能中從1至4涸氧原子間斷*或者在一起的L1與L2及/ 或L3與L4在每一個賁例中是
6- 本紙張適用中國國家標準(CNS)甲4規格(210 X 297公釐〉 82.6. 40,000 3ϋ£437 Α6 Β6 五、發明説明(5) 適合的箝類化合物具有例如的化學式IV Θ
(IV), •請 洗 閲 讀 背 注 意 事 項 再 塡 寫 衣 頁 其中Ζ1,ζ: Z5 經濟部中喪標準局典工消费合作社印製 ζ3及ζ4彼此分別是可以被在醚官能中的從1 至4個氧原子間斷WCi-Cao-垸基,C^-Cao-烷醯基或 Z3 其中Ζβ是氫,可Μ被在醚官能中的從1至4個氧原子間» 的匕-匕。-烷基,Ca-Czo-烷醣基,Ζ7是氫,可Μ被在醚 官能中的從1至4個氧原子間斷WCi-Cao-烷基,而叾8是 氫,可Μ被在醚官能中的從1至4個氧原子間斷的 烷基或鹵素,而Arf是陰離子當量。
进合的次甲基染料具有例如的化學式V
,θ (V) 本紙張尺度適用中Β國家標準(CNS)甲4规格(210 X 297公货) 82.6. 40,000 A6 _B6_ 五、發明説明(6) 其中可使環A及B彼此分別以苯餅熔融或取代· E1及E2彼 此分別是氧,碲,亞胺基,-C(CH3)2-或-CH = CH- ,D是
£4 其中E3是氫,“-Ce-烷基,氣或溴,而E4是氫或Ci-Ce-烷 基,Q1及Q2彼此分別是苯基* Cs-C7-瑁烷基* Ci-Cw烷 基,其可以被在ϋ官能中的從1至3涸氧原子間斷及可以 被羥基,溴,氯,羰基,Ct-C4-烷氧基羰基,丙烯醣氧基 ,甲基丙烯醣氧基,羥基磺醯基,Cx-Ct-烷醣基胺基, Ci-Ce-烷基胺甲醯基,Ce-烷基胺甲醯氧基*或01〇3 取代的Ci-Cu-烷基,其中G是氮或磷,而K是苯基, C5-C7-環烷基或“吖^-烷基,Αηθ是陰離子當董,而n是 1 ,.2,或 3 。
適合的莫斯夸酸染料具有例如的化學式VI (請先閱讀背面之注意事項再塡寫本頁) 裝· 訂· 經濟部中央標準局R工消费合作社印製 0®
本紙張尺度適用中8國家標準(CNS)甲4规格(210 X 297公釐) 82.6. 40,000 經濟部中央標準局貝工消费合作社印製 A6 B6 五、發明説明(7 ) 其中J是Ct-C12-次烴基, T1是氫,鹵素,胺基,羥基,烷氧基,苯基,經 取代之苯基,羧基,Ci-Cw-烷氧基羰基,腈基, -NT7-C〇-Te - -C〇-NTeT7 m -〇~C〇-HTaT7 ,其中 Te及 T7彼 此分別是氫,Ci-Cw-烷基,c5-c7 -瑁烷基,笨基, 2.2.6.6- 四甲基呱啶-4-基或環己烯基胺基羰基,而 T2,T3,T5彼此分別是氫,可以被鹵素,胺基, h-Cw烷氧基,苯基,經取代之苯基,羧基| h-Cw 烷氧基羰基或_基等取代的Ci-Cu-烷基, 條件是如果T5是氫|則在奠環内的取代基J-T1及T4之環位 置也可Μ在一個或兩個Μ環上互相交換。 所有在Μ上化學式中出現的烷基,次烴基及烯基可能或 是直鏈,或是成支踺。 在化學式la,I * Μ及IV中•可Κ被在醚官能中的從1 至4個氧原子間斷的適合的匕吖2〇_烷基是例如甲基,乙 基,丙基,異丙基,丁基,異丁基,第二-丁基,第三-丁.基,戊基,異戊基,新戊基,第三-戊基,己基,2-甲 基戊基,庚基,辛基,2-乙基己基,異辛基,壬基,異壬 基,癸基,異癸基,十一烷基*十二烷基*十三烷基, 3.5.5.7- 四甲基壬基,異十三烷基(Μ上的異辛基,異壬 基,異癸基及異十三烷基是普通的名字*產生於來自氧化 合成所獲得的酵類-參考在相關的UlUanns E n c y k 1 〇 p a d i e d e r t e c h n i s c h e n C h e m i e ,第四版,第 7 冊,第215-217頁及第11冊•第435及436頁),十四烷 -9- 本紙張尺度通用中國國家標準(CNS)甲4规格(210 X 297公釐) 82.6. 40,000 ---------------.---,------裝------#------線 (請先閱讀背面之注意事項再塡鸾本頁) 3UC437 經濟部中央櫺準爲S工消费合作社印製 A6 B6 五、發明説明(8 ) 基,十五烷基,+六烷基,十七烷基,十八烷基,十九烷 基,二十烷基,2 -甲氧基乙基,2-乙氧基乙基,2-丙氧基 乙基,2 -異丙氧基乙基,2 -丁氧基乙基,2 -及3 -甲氧基丙 基,2-及3-乙氧基丙基,2-及3-丙氧基丙基,2-及3,丁氧 基丙基,2-^4-甲氧基丁基,2-及4-乙氧基丁基,2-及 4-丙氧基丁基,2-及4-丁氧基丁基,3,6-二噁烷基庚基, 3, 6-二噁烷基辛基,4, 8-二嗯烷基壬基,3, 7-二嗯烷基辛 基,3,7-二噁烷基壬基,4,7-二噁烷基辛基,4,7-二噁烷 基壬基,4,8-二噁烷基癸基* 3,6,8-三噁烷基癸基, 3,6,9-三嗯烷基十一烷基,3,6,9,12-四嗯烷基十三烷基 及3,6,9,12-四嗯烷基十四烷基。 在化學式I及I中,遽合的經笨基取代之(^-(:20-烷基 是例如的苄基與卜及2-苯基乙基。 在化學式I · H及IV中*可Μ被在醚官能中的從1至4 個氧原子間斷的遽合的(^-(:2〇-烷氧基是例如甲氧基,乙 氧基,丙氧基,異氧丙基,丁氧基,異丁氧基,戊氧基, 己氧基,庚氧基,辛氧基,2 -乙氧己氧基,異辛氧基,壬 氧基,異壬氧基,癸氧基,異癸氧基’十—烷氧基,十二 烷氣基,十三烷氧基,異十三烷氧基’十四垸氧基,十五 烷氣基,十六烷氧基,十七烷氧基’十八烷氧基•十九烷 氧基,二十烷氧基,2 -甲氧基乙氧基,2~乙氧基乙氧基, 2-丙氧基乙氧基,2-異丙氧基乙氧基,2-丁氧基乙氧基, 2-及3-甲氧基丙氣基,2-及3-乙氧基丙氧#,2-及3-丙氧 基丙氧基,2-及3-丁氧基丙氧基’ 2-及4-甲氧基丁氧基, -1 〇 - (请先閱讀背面之注意事項再塡寫本頁) 装_ 訂_ 衣紙張尺度適用中國®家樣毕(CNS)甲4規格(210 X 297公浼) 82.6. 40,000 娌濟部中央標準扃Λ工消費合作社印製 A6 _B6_ 五、發明説明(9 ) 2 -及4 -乙氧基丁氧基,2 -及4 -丙氧基丁氧基,2 -及4 -丁氧 基丁氧基,3,6-二烷基庚氧基,3,6-二噁烷基辛氧基, 4,8-二噁烷基壬氧基· 3, 7-二噁烷基辛氧基,3,7-二噁烷 基壬氧基,4,7-二噁烷基辛氧基,4,7-二噁烷基壬氧基, 4,8 -二噪烷基癸氧基,3,6,8 -三噁烷基癸氧基,3,6,9 -三 噁烷基十一烷氧基,3,6,9,12-四噁烷基十三烷氧基及 3,6,9,12-四噁烷基十四烷氧基。 在化學式I中*適合的經苯基取代之Ci-Czo-烷基是例 如的氧基與1-及2-苯基乙氧基。 在化學式la,B[及IV中,適合的經取代之苯基是例如Μ h-Ce-烷基,Ci-Ce-烷氧基•羥基或鹵素取代的苯基。通 常可能具有從1至3個取代基。 在化學式lb,H ,IV及VI中的鹵素是例如的氟,氯或溴 〇 在化學式la中的基W及在化學式lb中的X2與X3是例如的 甲基亞胺基*乙基亞胺基,丙基亞胺基,異丙基亞胺基或 丁基亞胺基。 在化學式la中的基R1至Rie及在化學式I中的丫°至¥12 是例如的二甲基胺磺醢基,二乙基胺磺醯基,二丙基胺磺 醣基,二丁基胺磺釀基或甲基-N-乙基胺磺醯基。 在化學式la及][中的C2-C2〇-烯基及C4-C2〇-烷鐽二烯 基是例如的ί烯基,烯丙基•丙-卜烯-1-基,甲代烯丙基 *乙代烯丙基,丁 - 3-烯-卜基,戊烯基•戊二烯基,己二 烯基,3 , 7-二甲基辛-1 , 6-二烯-1-基,-(---10-烯-1-基 -11- 本纸張尺度遴用中國國家標準(CNS>甲4規格(210 X 297公釐> 82.6. 40,000 (請先閱讀背面之注意事項再塡寫本頁) -裝. 訂. 經濟部中兴標準易貝工消费合作社印製 A6 ___B6_ 五、發明説明(10 ) • 6,10-二甲基 Ί---5,9-二烯.-2-基,十八-9-烯-1- 基•十八-9 ,12-二烯-1-基,3,7,11,15-四甲基十六-卜 烯-3-基或二十-9-烯-1-基。 在化學式I中的C3-C20-烯氧基是例如的烯丙氧基,甲 代烯丙氧基,丁 -3-烯-1-氧基,十--1〇_烯氧基, 十八-9-烯-1-氧基或二十-9-烯-1-氧基。 在化學式IV中的之8是例如的甲醣基,乙醢基,丙醯基, 丁醢基,異丁藤基,戊醣基,己醯基,庚醢基,辛醯基或 2-乙基己醜基。 如果在化學式V中的A及/或B被取代時,則遘合的取 代基是例如的“-Ce-烷基,苯基烷氧基,苯氧基 ,鹵素,羥基,胺基,Ci-Ce-單或二烷基胺基,或脯基。 通常使環受到一次取代至三次取代。 在化學式V中的基E3,E4, Q1及Q2是例如的甲基,乙基 ,丙基,異丙基,丁基,異丁基,第二-丁基,戊基,異 戊基,新戊基,第三-戊基或己基。 而且基Q1及02¾是例如的己基.2-甲基丙基,庚基,辛 基,2-乙基己基*異辛基,壬基,異壬基,癸基,異癸基 ,十一烷基•十二烷基,環戊基,環己基,2 -甲氧基乙基 • 2-乙氧基乙基,2-或3-甲氧基丙基,2-或3-乙氧基丙基 ,2-羥基乙基,2-或3-羥基丙基,2-氛乙基,2-溴乙基, 2-或3-氛丙塞,2-或3-溴丙基,2-羧乙基,2-或3-羧丙基 • 2-甲氧基羰乙基,2-乙氧基羰乙基,2-或3-甲氣基羰丙 基,2-或3-乙氧基羰丙基,2-丙烯醢氧基乙基· 2-或3-丙 本紙張尺度適用中a國家標準(CNS)甲4规格(210 X 297 «釐〉 82.6. 40,000 <請先《讀背面之注意事項#塡寫本頁) -装- 訂. »濟部中央標準局霣工消费合作杜印製 A6 _B6_ 五、發明説明(1 1) 烯醢氣基丙基,2 -甲基丙烯醯氧基乙基,2-或3 -甲基丙烯 醯氧基丙基* 2-羥基磺醯基乙基,2-或3-羥基磺醯基丙基 ,2-乙醯基胺基乙基,2-或3-乙醢基胺基丙基,2 -甲基胺 甲醢基乙基,2-乙基胺甲醯基乙基,2-或3 -甲基胺甲醢基 丙基,2-或3-乙基胺甲醯基丙基,2-甲基胺甲醣氧基乙基 ,2-乙基胺甲醣氧基乙基,2-或3-甲基胺甲醯氧基丙基· 2-或3-乙基胺甲醯氧基丙基,2-(三甲基乙基,2-(三 乙基銨)乙基,2-或3-(三甲基铵)丙基,2-或3-(三乙基 銨)丙基,2-(三笨基鳞)乙基,2-或3-(三笨基級)丙基。 在化學式IV及V中的Ar?衍生自例如有機或無櫬酸的險離 子。提出特別偏好的例子是甲烷-磺酸鹽,4 -甲基苯磺酸 鹽,醋酸鹽,三氟醋酸鹽,七氟丁酸鹽,氯化物,溴化物 ,碘化物,過氛化物,四氟硼酸鹽,硝酸鹽,六氟磷酸鹽 及四苯基硼酸鹽。 在化學式VI中的基J是例如的次甲基,次乙基,1,2 -或 1,2,次丙基,1,2-,1,3-,2,3-或1,4-次丁基,戊撐基, 己撐基,庚撐基,辛撐基,壬撐基,癸撐基,十一烷撐基 或十二烷撐基。 在化學式VI中的基T2,T3,T4及T5是例如的甲基,乙基 ,丙基,異丙基,丁基,異丁基,第二-丁基•第三-丁 基*戊基,異戊基,新戊基,第三-戊基,2-甲基丁基, 己基,2-甲基戊基,庚基,辛基,2-乙基己基,異辛基, 壬基,異壬基,癸基,十一烷基,十二-烷基,氟化甲基 (請先閱讀背面之注意事項再塡寫本頁) -—裝. 訂. -13- 本紙張尺度適用中國困家標準(CNS)甲4规格(210 X 297公釐) 82.6. 40,000 鳢滴部中次鏢準局Λ工消费含作社印< A6 B6 五、發明説明(12) ,氯化甲基,二氟甲基,三氟甲基,三氛甲基.2-氟化乙 基,2 -氯化乙基,2 -溴化乙基,1,1,卜三氟乙基,七氟丙 基,4 -氣化丁基,5 -氟化戊基,6 -氯化乙基,臃基甲基, 2- 騎基乙基· 3-騁基丙基· 2-騁基丁基,4-臃基丁基· 5- 腈基戊基· 6-腈基己基* 2-胺基乙基,2-胺基丙基* 3- 胺基丙基· 2-胺基丁基,4-胺基丁基· 5-胺基戊基, 6- 胺基己基,2-羥基乙基,2-羥基丙棊· 3-羥基丙基. 2 -羥基丁基,4 -羥基丁基· 5 -羥基戊基,6 -羥基己基· 2- 甲氧基乙基,2-乙氣#乙基,2-丙氧基乙基· 2-異丙氧 基乙基,2-丁氧基乙基,2-甲氧基丙基,2-乙氧基丙基, 3- 乙氧基丙基,4-乙氧基丁基* 4-異丙氧基丁基* 5-乙氧 基戊基,6-甲氧基己基,苄基•卜笨基乙基,2-苯基乙基 ,4 -氛化苄基* 4 -甲氧基苄基* 2-(4 -甲基苯基)乙基,羧 甲基· 2-羧乙基,3-羧丙基,4-羧丁基,5-羧戊基,6-羧 己基,甲氧基羰甲基,乙氧基羰甲基,2-甲氧基羰乙基, 2-乙氧羰乙基,3-甲氧基羰丙基,3-乙氧基羰丙基,4-甲 氧蘂羰丁基,4-艺氧基羰丁基,5-甲氧基羰戊基’ 5-乙氧 基羰戊基,6-甲氧基羰己基,6-乙氧基羰己基。 在化學式VI中的T1是例如的甲氧基羰基’乙氧基欲基’ 丙氧基羧基,異丙氧基羰基* 丁氧基羰基,異丁氧基欲基 ,第二-丁氧基羰基,第三-丁氧基羰基,戊氧基換基, 異戊氧基親基,辛戊氧基羰基,第三-戊氧基激基’己氧 基羰基,庚氧基羰基,辛氧基羰基,異辛氧基教基’壬氧 基羰基,異壬氧基羰基,癸氧基羰基,異癸氧基親基’十 -14- 本紙張尺度適用中理a家標準(CNS〉甲4规格(210 X 297公* > 82.6. 40,000 < 請先W讀背面之注意事項再壜寫本頁) 装· 訂 A6 _B6_ 五、發明説明(13) 一烷氧基羰基,十二烷氧基羰基,甲氧基,乙氧基,丙氧 基,異丙氧基,丁氧基,異丁氧基,戊氧基,己氧基,乙 醣基胺基,胺甲醯基,單-或二甲基胺甲醢基,單-或二 乙基胺甲醯基,單環己基胺甲醸基,笨基胺甲醯基,二甲 基胺甲醯基,二甲基胺甲醯氧基或二乙基胺甲醯氧基。 更偏好於根據本發明始自於不含金臛或金靨萘膂之化合 物的用途。 應該將重點放在根據本發明化學式Ila之莱菁的用途上 (請先《讀背面之注意事項再塡寫本頁) 經濟部中央標準局R工消费合作杜印製
•裝. 訂. 在跟Y1,Y2,Y3,Y*,Y5,Υβ,Y7及Y8彼此分別是g,羥 基,烷基或Ci-Czo-烷氧基,而 Me2是兩個氫原子,兩個鋰原子,鎂,鋅,嗣,鎳,V0* A1C1 或 V20 . I Si (-0—31-—C—γ!9),I Υ21 -15- 本紙張尺度適用中國0家標準(CNS)甲4规格(210 X 297公货) 82.6. 40,000 30^437 A6 B6 五、發明説明) 在此R 1 β是C : - C 1 3 -饶基或C 1。、C 2 〇 -嫌二基,而γ 2 〇及 Υ21彼此分別是(^-(:13-烷基或C2-C4-烯基〇 應該將特殊的重點放在根據本發明化學式IIa之蔡菁的 用途上,在此Y1,Y2,Y3,Y4,YS,γβ , π及丫8彼此分別 是羥基或匕·^2。-烷氧基,特別是Ci-Cio-烷氧基。在此 的烷氧基可能一樣或者不一樣。 更應該將特殊的重黏放在根據本發明化學式Ila之蔡薄 的用途上•在此Me2是氫原子。 而且應該將特殊的重點放在根據本發明化學式M之二磓 環戊烯鎳鹽錯合物的用途上,在此L1· L2,L3及L4彼此分 別是苯基,Ci-Czo-烷基苯基,Ci-Czo-烷氧基苯基或羥 基及取代來基的Ci-Cao-烧基,或者在一'起的L1與L2及 L3與L4在每一僩賁例中是
CH3 (請先閱讀背面之注意事項再場寫本頁) 濟部中央標準局R工消费合作杜印製 而且應該將特殊的重點放在根據本發明化學式里之二硫環 戊烯辣鹽錯合物的用途上,在此L1及L4分別是苯基,而 L2及 L4分別是 4-[(C2H5-C(CH3)2]-CefU。 本質上已知在例如的德圃專利申請案第1 073 739號 (DE-B-1 073 739)或歐洲專利申請案第155 780號 (EP-A- 155 780)中說明的化學式la之酞菁,或者可以本霣 -16- 本紙張尺度通用中a國家樣準(CNS)甲4洗格(210 X 297公* ) 82.6. 40,000 經濟部中典襻準场R工消费合作社印* A6 B6 五、發明説明(〗5 ) 上已知的方法獲得,如利用酞菁或萘菁的製備作用及例如 F. H.摩色(Moser) ,A. L.湯瑀斯(Thmoas)的"狀膂”, CRC Press ,波卡羅塔(Boca Rota), (Florida). 1983年 或美國化學協會雜誌(J. Am. Chem. Soc.) 106(1984年) •第7404至7410頁的說明。同樣地在本質上已知在例如的 »專利申講案第155 780號中說明的化學式lb之酞菁,或 者可上先前技《的方法獲得(摩色,美画化學協會雑 誌)。 同樣地在本質上已知在例如的歐洲專利申請案第336 213號,软洲專利申講案第358 080號•英國專利申講第 2,168,372號(GB-A-2,168,372)或英國專利申請案第 2,200,650號中說明的化學式I之萘菁,或者可KM上先 前技蓊的方法獲得(摩色,美國化學協會雜誌)。 同樣地在本質上已知在例如的歐洲專利申請案第192 215號中說明的化學ffl之二硫環戊烯練鹽錯合物。 同樣地在本質上巳知在例如的美國專利申請案第 3,484,467號中論明的化學IV之銨類化合物,或者可以本 文上述之先前技藝的方法獲得。 同樣地在本質上已知在例如的歐洲專利申請茱第464 543號中說明的化學V之次甲基染料,或者可Μ本文說明 之先前技舊的方法獲得。 同樣地在本質上已知在例如的歡洲專利申請案第310 080號或美國專利申謫案第4,990,649號中說明的化學VI 之莫斯夸酸染料,或者可以本文說明之先前技藝的方法獲 -17- 本紙張尺度適用中國國家標準(CNS)甲4现格(210 X 297公釐) 82.6. 40,000 (請先《讀背面之注意事項再塡寫本頁) 丨裝. 訂. 垅濟部中央標準居霣工消費合作社印製 A6 B6 五、發明説明(16 ) 得。 可Μ根據本發明上極詳细說明的化合物檷示的通合 的溶劑特別地是有櫬溶劑,例如如甲酵,乙酵,丙酵,異 丙酵,丁酵,異丁酵,第二-丁酵,戊酵,異戊酵,新戊 酵與己酵等之類的酵類,如1,2 -乙二酵,1.2 -及1,3 -丙二 酵,1,2 -,2 ,3-及1,4-丁二酵,二及三甘酵與二及三丙二 酵等之類的乙二酵,如甲基第三-丁 12-乙二酵單及 二甲醚,1,2-乙二酵單及二乙醚3-甲氧基丙酵,3-異丙氧 基丙酵、四氫呋喃與二嗯烷等之類的_類,如丙鹂,甲乙 酮與二丙酮酵等之類的醑類,如乙酸甲酯,乙酸乙酯,乙 酸丙酯與乙酸丁酯之類的酯類,如戊烷,己烷,庚烷,辛 烷,異辛烷,石油醚,甲笨,二甲苯,乙基笨•四氫化萘 •十氫化萘,二甲基萘與石油溶劑油等之類的脂肪族或芳 族烴類,如汽油,煤油,柴油及加熱油等之類的無櫬油, 如橄檷油,豆油與向日葵油等之類的天然油及天然或合成 的機油,水力油與例如車用機油與鏠紉機油等的潤滑油及 刹事油。 上述的化合物特別方便於用以檷示無櫬油,例如為了税 的理由,故同時須要使彼等分類。為了維持低的分類費用 *慣用的計割是使用可稀釋成非常稀的染料著色。然而也 不可能在無櫬油中全然Μ視覺偵澜到在高度稀釋中即使是 高著色強度的染料。 為了瑄届理由,故特別有利於使用具有最大的吸收範圃 在從600至1,200毫微米及/或最大的螢光範園在從620 -18- {請先閱讀背面之ii意事項再塡寫本頁) -裝- 訂. 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公* ) 82.6. 40,000 經濟部中夬標準局典工消费合作社印製 A6 _B6_ 五、發明説明(彳7 ) 至1,200奄微米的禰示劑,因為.可Μ利用通當的儀器輕易 地偵测到檷示劑。 就分類的液體而言,但是尤指無機油,通常使用Μ溶液 形式的上述化合物。通合的溶劑Μ芳族烴較佳,如甲苯及 二甲苯。為了避免任何所得的溶液遇高的黏度,則通常會 埋擇在IR中吸收及/或發螢光的化合物之濃度以溶液為基 準的重最計從2至50%。 本發明埋提供為偵拥I在液《中的檷示劑之方法*包含從 檷示劑在NIR (近紅外線)光譜範園中的螢光偵澜之。 Μ半導體播射或半導體兩極管可方便地激發存在於液驩 中的棟示劑之螢光。使用具有在光譜範圏從λ ββχ-100毫 微米至λ + 毫微米之内的半導體鐳射或半導«兩極管 特別有利,λ„βχ是檷示劑的最大吸收波長。最大的放射 波長是在從620至1,200毫微米的範圍内。 Μ半導體偵測器•尤指矽光電兩播管或緒光電兩極管可 方便地偵測到Μ該方式產生的螢光。 如果Μ干涉濾波器及/或自動開闢的濾波器(具有在從 λ 至λ 毫微米範園內的短波透射的自動拥翮限 制V及/或餳光器放在偵测器之前*則偵測作用會特別方 便0 上述的化合物會使偵測器非常容易偵澜到檷示的液體, 雖然標示物ΗΜ約百萬分之O.I(ppb) (Κ吸收測得的)至 約十價分之5 (ppb)(以螢光測得的)的濃度存在。 本發明堪提供為進行根據本發明的方法之儀器(=偵测 -19- 本纸張尺度適用中國躕家標準(CNS)甲4规格(210 X 297公* ) 82.6· 40,000 {靖先閲讀背面之注意事項再塡寫本頁) •裝_ 訂· A6 ____B6__ 五、發明説明(18) 器),偵廁器包含NIR光源(半導體捃射或半導Μ兩極管 ),一或數個光學濾波器,一個NIR鴒光器及光霣偵測器 (矽光電兩極管或緒光電兩槿管)與如果須要的光纖或光 嫌束。 企圈ΚΚ下的賁施例更加詳细地例證本發明。 為偵測檷示劑的一般步嫌。
I.MIR範園中的吸收偵濟I 實施例1 (請先閱讀背面之注意事項再塡寫本頁) 經濟部中*標丰局R工消费合作社印製
將化學式如上的运夠染料溶在柴油燃料中,得到含有百萬 分之1,000的染料之溶液。 在依序稀釋該溶液,並利用在工業上採用的分光計(1公 分的比色槽)測量在NIR範晒中彼等對純的柴油燃料之吸 收 訂. 本紙張尺度適用中國因家標準(CNS〉甲4規格(210 X 297公釐) 82.6. 40,000 五、發明説明(19 ) A6 B6 在柴油燃料中的染料含量[ΡΡΠ] 吸收 最大的吸收波長[毫微米] 100 » 3 一 50 3.05 844.0 20 2.81 854.0 10 2.10 、 860.4 1 0.27 860.0 使用Μ上化學式的蔡菁(在此R = n-CsHu或或 下列的染料檷示時,則會得到同樣有利的结果。 染料2 十六烷苯基碲代飼萘膂 染料3 十四烷苯基硫代鋦萘菁 染料4 十四烷基十二烷基硫代鋦萘菁 染料5 -------.---'·----ί-------裝------、玎 (請先閱讀背面之注意事項再塡寫本頁) 經 濟 部 中 央 標 準 局 8 X 消 费 合 作 印 %
本紙張尺度適用中國國家標準(CNS>甲4規格(210 X 297公;* ) 82.Γι. 40.000 A6 B6 五、發明説明(20 ) 染料6 十六烷基(4-第三 染料7 丁基苯基硪代)鋦萘菁
NcS i [-0-Si (CH3)2-〇-Ci2H2S]a 染料8 染料9 染料10 ch3 I NcSi(0-Si-0-CH2-CH"I 、 C12H25 CHj NcSi(0-Si-0-CH2-CH*I 、 csHu CHj ^C2h*5 'C4H9 .c2h5 'c4h9 <請先閲讀背面之注意事項再塡寫本頁)
NcSi 染料11至15 -O-Si-O- (CH2) 8-CH=CH-CH2-CH=CH2-C5Hu ch=ch2 經濟部中央標準屬貝工消费合作社印製
Ll、 s
Ni 22-
S 本紙張尺度適用中國國家標準(CNS>甲4规格(210 X 297公釐> 82.6. 40,000 五、發明説明(21 ) A6 B6
染料15至18 (請先閲讀背面之注意事項再塡寫本頁) 丨裝. 訂. 經濟部中喪標準局典工消费合作杜印製 hr
N—— N 23- 本紙張尺度遴用肀國國家標準(CNS)甲4规格(210 X 297公釐) NZ2 0
An θ 82.6. 40,000 A6 B6 五、發明説明(22 ) 染料编號 Z An® 15 C4H5 NOp 17 C2H5 ΝΟβ 13 C4H3 染料19至23
染料 编號 Q1 Q2 Q3 19 CH: Cl Cl 20 CK3 H H I彐 21 0 -丨丨 C2H4CCNHC(CH3i3 0 II C2H4OOiHC(CH3) 3 H H 22 0 II C2H4CNHC5H:3 0 I C2H4CNHC5HU H H C1C4b 23 C3HsS03y C3H5S03H H H 三甲銨乙内醏 (請先《讀背面之注意事項再塡寫本頁) .裝. 訂. 辦24 經濟部中央標準局R工消费合作社印製
-24- 本紙張尺度通用中國國家標準(CNS)甲4規格(210 X 297公货) 82.6. 40,000 A6 B6 五、發明説明(23) I.在近NIR範園中Μ轚光偵測 圖1展示偵測器的立體结構。 利用來自工業上的半導體兩極管鑕射放射激發檷示劑螢 光。使平行的络射光束照射在1公分比色槽中的樣品上。 為了使激發強度成雙倍*以鏑子將透射的光束反射,並再 照射在樣品上。 Μ光學姐件(透鏞系统)蔣螢光映影在砂光電兩槿管偵測 器上。以凹透鏡將在背後放射的光同樣地投射在矽光《兩 槿管上。 為了使不想要的光線(敗射的激發光)與螢光分離*則使 用自動開關及/或干涉濾波器及/或傾光器(NIR極化萡片)。 選擇偏光器的最大作用•所Μ最大的透射方向垂直於激 發光的極化平面。 實施例2 5 {請先閲讀背面之注意事項再填鸾本頁) -装· 訂. 經濟部中央標準屬R工消费合作社印製
將化學式如上的足夠染料溶在柴油燃料中,得到含有十 -25- 本紙張尺度逯用中困國家標準(CNS)甲4规格(210 X 297公货〉 82.6. 40,000 經濟部中央櫟準局貝工消费合作社印製 A6 _B6__ 五、發明説明(2缽) 億分之219的染料之儲備溶液。K柴油燃料稀釋得W自此 製備進一步的溶液。 根據一般的步驟Π ,利用Μ下設定的設備测悬逭些溶液 。激發作用:具有波長為813奄微米之GaAl As半導體兩極 管钃射:CW输出為7毫瓦特。 濾波器:Long-pass干涉濾波器850蠹嫌米(科瑞爾 (Cor i on)) ° V . 光霣偵測器:具有面積為1平方公分的矽光《兩棰管 (UDT)。利用霣流/¾ «轉換器測量光霣流(UDT, 35053 )° 將结果展示在以下的表中。 (請先《讀背面之注意事項再埔寫本頁) -裝· 在柴油燃料中的染料含量[ppb] 在λ «下的吸收 螢光信號 (以刻度軍位計) 219 0.05 2366 43.7 0.01 451 8.75 0.002 106 1.75 0.0004 40 0 0.0 20 這樣會為螢光約十僚分之5的檷示_提供較低的偵測極 限。 铯用以上化學式的萘膂(在此Rm-CbHu Sn-C12H2B) 或下列的染料標示時,則會得到同樣有利的结果。 -26- 本紙張尺度適用中a國家標準(CNS)甲4规格(210 X 297公釐) 82.6. 40,000 訂. A6 B6 五、發明説明(25 )
R
R R
R (R=C-C1H9) - — ------l·——:----{ (請先W讀背面之注意事項再塡寫衣頁) 装
染料26 Me = 2H 訂 染料27 Me = Zn 染料28 Me = A1C1 染料29
NcSi[-0-Si(CH3)2-0-C,2H25]2 染料30 CH3 經濟部中央樣準局S工消费合作社印製
NcSi(0-Si-0-CH2-CH- C12H25 27 .C2H5 'C4Hg 本紙張尺度適用中國國家標準(CNS〉甲4规格(210 X 297公釐) 82.6. 40,000 3ϋ£437 Α6 Β6 五、發明説明(26) 染料31 CH3
NcSi(0-Si-0-CH2-CH' ,c2h5 'C^Hg 染料32 染料33
NcSi OC2H5 I . NcSi(0-Si-0C2HS) 2、 I OC2H5 CK3 0-Si-0(CH2) 3-CH(CH3)2LI I — CH3 (請先閲讀背面之注意事項再塡寫本頁)‘ 丨裝· 染料34
NcSi 染料35至37 ch3 _ -O-ii-C- (CH2 ) 3-CH=CH-CH2-CH=CH2-C5Hn I '一 CH=CK2 經濟部中央搮準居8工消费合作社印製
28 Θ
An Θ 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公 82.6. 40,000 A6 B6 五、發明説明(27) 染料38至42 CHi 染料43 CH3 ch3 • Θ 經濟部中央標準局S工消费合作社印製
(請先«讀背面之注意寧噌满踔衮+項'- ------装! 'π,, • ' .___ I_-» > I*1 I 〆 · .紙張尺度適用中國國家標準(tNS)甲4规格(210 X 297 ;货〉 82.Γι. 40.000 染料鑷號 Ζ Αηβ 35 C.H, νο3· 36 c2h5 NO/ 3 7 c4h, bf49 ch3
H=CH·
染料 编號 Q2 Q3 Q4 Ar*^ 33 ch3 ch3 Cl Cl 39 CH] ch3 H H 40 0 II C2K4CCNHC(CH3)3 0 II C2K4OCNHC(CH 山 H H 41 Q II C2H^CN'KC5Hu 0 II C2H4CNHC5H13 H H C104® 42 CjKsSO-/^ C3H55〇3H H H 三甲銨乙内丨
ClI CH—CH:
Claims (1)
- 第82105852¾¾利由請案 中文由謫專利範圍修正本(8 5年12月) A8 B8 C8 D8 申請專利範同2 . 3 . 5 . 經濟部中央標準局貝工消費合作社印製 6 . 7 一種使吊化合物作為碟物 來自不含金羅或含有金屬 之萘菁,二碕環戊烯鎳鹽 ,次甲基染料或Μ斯夸酸 收範圍在從600至1 ,200毫 從 620至 1,200 〇 根據申請專利範圍第1項 含金屬或含有金屬之萘菁 根撺由請專利範圍第1項 含金屬或含有金屬之萘菁 一種為偵測在液髑中的標 NIR光譜範圍内自其螢光 金暍或含有金鼷之酞菁, 二碕環戊烯§$鹽錯合物, 染料或萆斯夸酸染料等分 從<500至1 , 200毫微米及 至 1,200 ° 根撺申請專利範圍第4項 半導體兩極管潲發螢光。 根捸申請專利範圍第4項 偵測螢光。 根撺由請專利範圍第4項 放射波長在光譜範圍從λ 微米之内半導體鐳射或半 油類標示劑之方法*該化合物 之酞菁,不含金屬或含有金屬 錯合物,芳族胺的銨鹽化合物 染料等分類,並具有最大的吸 微米及/或最大的螢光範圍在 之方法,其中化合物來自於不 或二碲環戊烯_鹽錯合物。 之方法,其中化合物來自於不 Ο 示劑之方法*其中標示劑在 偵測得*且標示劑係選自不含 不含金鼷或含有金屬之萘菁, 芳族胺的铵鹽化合物,次甲基 類•並具有最大的吸收範圍在 /或最大的螢光範圍在從620 之方法*其中Κ半導體鐳射或 之方法,其中Κ半導體偵測器 之方法,其中使用具有最大的 η^-100輋微米至λ mex + 20毫 導體兩極管,是櫟示劑 (請先Η讀背面之注意事項再填寫本頁) 本紙張尺度遑用中國國家揉準(CNS ) Α4規格(210X297公釐),的最大吸收波長。 Q •根據申請專利範圍第4項之方法,其中使用具有最大的 牧射波長在光譜範圍從(5 20至1,200毫微米之内半導體 鍵射或半導賴兩極管。 9 · ~種偵測在液體中的標示劑之裝置,包含N I R (1 >光源( 半導髑鐳射或半導體兩極管),一或數個光學濾波器 ~画NIR偏光器(3)及光電偵測器(4)(矽光電兩極 管或结光電兩極管)與如果須要的光纖或光纖束,其中 標示劑係選自不含金靨或含有金羼之酞菁,不含金羼或 含有金賜之萘菁,二硫環戊烯鎳鹽錯合物,芳族胺的鞍 鹽化合物,次甲基染料或莫斯夸酸染料等分類。 --------ί _裝------訂 (請先閲讀背面之注意事項再填寫本頁) 【線 經濟部中央標準局另工消费合作社印製 2 本紙張尺度逍用中國國家揉準(CNS)Α4規格(210x297公釐)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4224301A DE4224301A1 (de) | 1992-07-23 | 1992-07-23 | Verwendung von im IR-Bereich absorbierenden Verbindungen als Markierungsmittel für Flüssigkeiten |
DE19924243776 DE4243776A1 (de) | 1992-12-23 | 1992-12-23 | Verwendung von im IR-Bereich fluoreszierenden Verbindungen als Markierungsmittel für Flüssigkeiten |
DE19924243774 DE4243774A1 (de) | 1992-12-23 | 1992-12-23 | Verfahren zur Detektion von Markierstoffen in Flüssigkeiten |
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TW302437B true TW302437B (zh) | 1997-04-11 |
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TW082105852A TW302437B (zh) | 1992-07-23 | 1993-07-22 |
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EP (1) | EP0656929B1 (zh) |
JP (1) | JP3561739B2 (zh) |
KR (1) | KR100254571B1 (zh) |
CN (1) | CN1045984C (zh) |
AT (1) | ATE148736T1 (zh) |
AU (1) | AU673530B2 (zh) |
BR (1) | BR9306754A (zh) |
CA (1) | CA2140667C (zh) |
CO (1) | CO4230033A1 (zh) |
CZ (1) | CZ294548B6 (zh) |
DE (1) | DE59305414D1 (zh) |
DK (1) | DK0656929T3 (zh) |
ES (1) | ES2097525T3 (zh) |
FI (1) | FI118086B (zh) |
GR (1) | GR3022613T3 (zh) |
HU (1) | HU214637B (zh) |
IL (1) | IL106322A (zh) |
MX (1) | MX9304188A (zh) |
MY (1) | MY117562A (zh) |
NO (2) | NO317928B1 (zh) |
PL (1) | PL175152B1 (zh) |
TR (1) | TR28190A (zh) |
TW (1) | TW302437B (zh) |
UA (1) | UA39942C2 (zh) |
WO (1) | WO1994002570A1 (zh) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19818176A1 (de) * | 1998-04-23 | 1999-10-28 | Basf Ag | Verfahren zur Markierung von Flüssigkeiten mit mindestens zwei Markierstoffen und Verfahren zu deren Detektion |
US5525516B1 (en) * | 1994-09-30 | 1999-11-09 | Eastman Chem Co | Method for tagging petroleum products |
US5723338A (en) * | 1994-11-04 | 1998-03-03 | Amoco Corporation | Tagging hydrocarbons for subsequent identification |
US5843783A (en) * | 1994-11-04 | 1998-12-01 | Amoco Corporation | Tagging hydrocarbons for subsequent identification |
US5710046A (en) * | 1994-11-04 | 1998-01-20 | Amoco Corporation | Tagging hydrocarbons for subsequent identification |
DE19721399A1 (de) | 1997-05-22 | 1998-11-26 | Basf Ag | Phthalocyanine und ihre Verwendung als Markierungsmittel |
US5958780A (en) * | 1997-06-30 | 1999-09-28 | Boston Advanced Technologies, Inc. | Method for marking and identifying liquids |
DE19818177A1 (de) * | 1998-04-23 | 1999-10-28 | Basf Ag | Verfahren zur Markierung von Flüssigkeiten mit mindestens zwei Markierstoffen und Verfahren zu deren Detektion |
US6274381B1 (en) | 1998-11-09 | 2001-08-14 | Rohm And Haas Company | Method for invisibly tagging petroleum products using visible dyes |
US5984983A (en) * | 1998-12-04 | 1999-11-16 | Morton International, Inc. | Use of carbonyl compounds as markers |
US7157611B2 (en) * | 2002-07-11 | 2007-01-02 | Rohm And Haas Company | Pyrazinoporphyrazines as markers for liquid hydrocarbons |
EP1494000A1 (en) * | 2003-07-02 | 2005-01-05 | Sicpa Holding S.A. | Method of marking a material with ions already comprised in said material and method of verifying the authenticity of said material |
US20050019939A1 (en) * | 2003-07-25 | 2005-01-27 | Dale Spall | Combination marker for liquids and method identification thereof |
DE102004003791A1 (de) * | 2004-01-23 | 2005-08-11 | Basf Ag | Verwendung von Phthalocyaninen als Markierungsstoffe für Flüssigkeiten |
US7919325B2 (en) | 2004-05-24 | 2011-04-05 | Authentix, Inc. | Method and apparatus for monitoring liquid for the presence of an additive |
US7278727B2 (en) * | 2004-08-09 | 2007-10-09 | Silverbrook Research Pty Ltd | Method of minimizing absorption of visible light in infrared dyes |
US8486711B2 (en) | 2004-10-22 | 2013-07-16 | Bayer Materialscience Llc | Highly fluorescent markers for fluids or articles |
DE102005062910A1 (de) * | 2005-12-29 | 2007-07-05 | Basf Ag | Verfahren zur Bestimmung der Identität oder Nicht-Identität und Konzentration einer chemischen Verbindung in einem Medium |
US7858373B2 (en) * | 2006-02-03 | 2010-12-28 | Rohm And Haas Company | Chemical markers |
AU2007220528A1 (en) * | 2006-03-01 | 2007-09-07 | Basf Se | Use of rylenes as markers for liquids |
AU2007224512A1 (en) * | 2006-03-15 | 2007-09-20 | Basf Se | Use of aryl- or alkyloxy-substituted phthalocyanines as marking substances for liquids |
US7553673B2 (en) * | 2006-11-13 | 2009-06-30 | Rohmax Additives Gmbh | Quality control of a functional fluid |
US8129190B2 (en) * | 2006-11-17 | 2012-03-06 | Applied Nanotech Holdings, Inc. | Tagged petroleum products and methods of detecting same |
CN101668818A (zh) * | 2007-04-05 | 2010-03-10 | 巴斯夫欧洲公司 | 硅酞菁和锗酞菁的制备及相关物质 |
KR101073375B1 (ko) * | 2008-12-23 | 2011-10-17 | 한국조폐공사 | 기기감지요소를 포함하는 보안인쇄용 평판잉크 |
US9995681B2 (en) * | 2010-09-28 | 2018-06-12 | Authentix, Inc. | Determining the quantity of a taggant in a liquid sample |
US9244017B2 (en) | 2011-05-26 | 2016-01-26 | Altria Client Services Llc | Oil detection process and apparatus |
US9080987B2 (en) | 2011-05-26 | 2015-07-14 | Altria Client Services, Inc. | Oil soluble taggants |
US10900897B2 (en) | 2012-05-29 | 2021-01-26 | Altria Client Services Llc | Oil detection process |
KR101520607B1 (ko) * | 2012-09-28 | 2015-05-15 | 한국화학연구원 | 나프탈로시아닌 화합물을 표지물질로 포함하는 비수용성 유체류 및 이를 이용한 비수용성 유체류의 식별방법 |
WO2014051393A1 (en) * | 2012-09-28 | 2014-04-03 | Korea Research Institute Of Chemical Technology | Nonaqueous fluid containing naphthalocyanine compound as marker and method for marking nonaqueous fluid using the same |
US20140154813A1 (en) | 2012-11-30 | 2014-06-05 | Sicpa Holding Sa | Marking of material, marked material and process of authentication or dilution determination |
US9097668B2 (en) | 2013-03-15 | 2015-08-04 | Altria Client Services Inc. | Menthol detection on tobacco |
EP2821940A1 (en) | 2013-07-03 | 2015-01-07 | Lumiprobe GmbH | Binary labeling |
KR102023710B1 (ko) * | 2014-02-20 | 2019-09-20 | 동우 화인켐 주식회사 | 염료 및 착색 경화성 수지 조성물 |
WO2016077471A1 (en) | 2014-11-11 | 2016-05-19 | Altria Client Services Inc. | Method for detecting oil on tobacco products and packaging |
CN104964935A (zh) * | 2015-05-25 | 2015-10-07 | 天津悦泰石化科技有限公司 | 一种油溶性标识剂及其在燃油和燃油添加剂中的应用 |
FR3046611B1 (fr) * | 2016-01-12 | 2019-10-25 | Inoventeam | Utilisation de complexes de terres rares comme marqueurs de produits petroliers, de petroles bruts, de biocarburants ou de lubrifiants |
US11262298B2 (en) * | 2018-08-30 | 2022-03-01 | Caterpillar Inc. | System and method for determining fluid origin |
EP4327073A1 (en) | 2021-04-20 | 2024-02-28 | Basf Se | A method of detecting one or more markers in a petroleum fuel using a photoacoustic detector |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3484467A (en) * | 1967-01-05 | 1969-12-16 | American Cyanamid Co | Diaryl - (n,n - diarylaminoaryl)-aminium hexafluoroantimonates and hexafluoroarsenates |
US4009008A (en) * | 1972-12-08 | 1977-02-22 | Morton-Norwich Products, Inc. | Colored water immiscible organic liquid |
US4209302A (en) * | 1979-05-10 | 1980-06-24 | Morton-Norwich Products, Inc. | Marker for petroleum fuels |
US4735631A (en) * | 1983-12-16 | 1988-04-05 | Morton Thiokol, Inc. | Colored petroleum markers |
ATE51402T1 (de) * | 1984-03-21 | 1990-04-15 | Ici Plc | Infrarot-absorber. |
DE3505751A1 (de) * | 1985-02-20 | 1986-08-21 | Basf Ag, 6700 Ludwigshafen | Neue tetraphenyldithiolen-komplexe und diese komplexe enthaltende optische aufzeichnungsmedien |
EP0310080A3 (en) * | 1987-10-01 | 1990-05-16 | Basf Aktiengesellschaft | Azulene-squarillic dyes, azulenes as their intermediary products, and optical recording medium |
DE3830041A1 (de) * | 1988-09-03 | 1990-03-08 | Basf Ag | Siliciumnaphthalocyanine mit ungesaettigten liganden sowie duenne strahlungsempfindliche beschichtungsfilme |
DE4021078A1 (de) * | 1990-07-03 | 1992-01-09 | Basf Ag | Polymethinfarbstoffe |
WO1994012874A1 (en) * | 1992-11-27 | 1994-06-09 | Bp Oil International Limited | Method of identifying liquid petroleum products |
US5525516B1 (en) * | 1994-09-30 | 1999-11-09 | Eastman Chem Co | Method for tagging petroleum products |
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