TW200938559A - Thermoplastic aliphatic urethane/urea molding compositions - Google Patents
Thermoplastic aliphatic urethane/urea molding compositions Download PDFInfo
- Publication number
- TW200938559A TW200938559A TW097130554A TW97130554A TW200938559A TW 200938559 A TW200938559 A TW 200938559A TW 097130554 A TW097130554 A TW 097130554A TW 97130554 A TW97130554 A TW 97130554A TW 200938559 A TW200938559 A TW 200938559A
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- Taiwan
- Prior art keywords
- composition
- weight
- patent application
- aliphatic
- thermoplastic
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 156
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 239000004202 carbamide Substances 0.000 title claims abstract description 49
- 125000001931 aliphatic group Chemical group 0.000 title claims abstract description 39
- 229920001169 thermoplastic Polymers 0.000 title claims description 47
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 46
- 238000000465 moulding Methods 0.000 title claims description 16
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 title description 5
- 239000000843 powder Substances 0.000 claims abstract description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004005 microsphere Substances 0.000 claims abstract description 11
- -1 amine ester Chemical class 0.000 claims description 72
- 229920005862 polyol Polymers 0.000 claims description 41
- 239000003607 modifier Substances 0.000 claims description 39
- 150000003077 polyols Chemical class 0.000 claims description 39
- 239000010410 layer Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 30
- 229920001400 block copolymer Polymers 0.000 claims description 28
- 229920000098 polyolefin Polymers 0.000 claims description 25
- 239000000049 pigment Substances 0.000 claims description 22
- 239000003963 antioxidant agent Substances 0.000 claims description 19
- 239000003054 catalyst Substances 0.000 claims description 17
- 150000004985 diamines Chemical class 0.000 claims description 17
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 14
- 229920000570 polyether Polymers 0.000 claims description 14
- 238000005266 casting Methods 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000004970 Chain extender Substances 0.000 claims description 12
- 230000032683 aging Effects 0.000 claims description 12
- 230000003078 antioxidant effect Effects 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 239000012963 UV stabilizer Substances 0.000 claims description 10
- 125000005442 diisocyanate group Chemical group 0.000 claims description 10
- 229920000831 ionic polymer Polymers 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 229920003023 plastic Polymers 0.000 claims description 9
- 239000004033 plastic Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- 239000005977 Ethylene Substances 0.000 claims description 8
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 8
- 239000012141 concentrate Substances 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 150000001993 dienes Chemical class 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 229910052724 xenon Inorganic materials 0.000 claims description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 3
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 2
- 239000005056 polyisocyanate Substances 0.000 claims description 2
- 229920001228 polyisocyanate Polymers 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 229920000428 triblock copolymer Polymers 0.000 claims description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- DGPHMWKZJDYZSN-UHFFFAOYSA-N CCCCCCCCCC(C1=CC=CC=C1)C1=CC=CC=C1.N=C=O.N=C=O Chemical class CCCCCCCCCC(C1=CC=CC=C1)C1=CC=CC=C1.N=C=O.N=C=O DGPHMWKZJDYZSN-UHFFFAOYSA-N 0.000 claims 1
- OARXSHZLFLXCEK-UHFFFAOYSA-N CCCCCCCCCCC(CCO)CCO Chemical compound CCCCCCCCCCC(CCO)CCO OARXSHZLFLXCEK-UHFFFAOYSA-N 0.000 claims 1
- 239000005058 Isophorone diisocyanate Substances 0.000 claims 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims 1
- 238000003801 milling Methods 0.000 claims 1
- 239000002356 single layer Substances 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 38
- 239000000806 elastomer Substances 0.000 abstract description 38
- 229920002803 thermoplastic polyurethane Polymers 0.000 abstract description 30
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 23
- 150000001336 alkenes Chemical class 0.000 abstract description 22
- 229920001577 copolymer Polymers 0.000 abstract description 19
- 239000008188 pellet Substances 0.000 abstract 1
- 235000013877 carbamide Nutrition 0.000 description 47
- 239000000463 material Substances 0.000 description 29
- 239000000956 alloy Substances 0.000 description 28
- 229910045601 alloy Inorganic materials 0.000 description 28
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 26
- 150000001412 amines Chemical group 0.000 description 21
- 229920002725 thermoplastic elastomer Polymers 0.000 description 16
- 238000002156 mixing Methods 0.000 description 15
- 239000000047 product Substances 0.000 description 11
- 239000002245 particle Substances 0.000 description 9
- 235000021419 vinegar Nutrition 0.000 description 8
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- 239000007788 liquid Substances 0.000 description 7
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- 239000000052 vinegar Substances 0.000 description 7
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 238000010112 shell-mould casting Methods 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 239000011324 bead Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
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- 229910052751 metal Inorganic materials 0.000 description 5
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- 229920006342 thermoplastic vulcanizate Polymers 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 229920002633 Kraton (polymer) Polymers 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 229920003182 Surlyn® Polymers 0.000 description 4
- 239000005035 Surlyn® Substances 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
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- 238000009472 formulation Methods 0.000 description 4
- 239000004611 light stabiliser Substances 0.000 description 4
- 239000012768 molten material Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229920006132 styrene block copolymer Polymers 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000013467 fragmentation Methods 0.000 description 3
- 238000006062 fragmentation reaction Methods 0.000 description 3
- 210000004907 gland Anatomy 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920001281 polyalkylene Polymers 0.000 description 3
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 3
- 229920003225 polyurethane elastomer Polymers 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 150000003672 ureas Chemical class 0.000 description 3
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229920006311 Urethane elastomer Polymers 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 150000002009 diols Chemical group 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
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- 125000002524 organometallic group Chemical group 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
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- 150000003141 primary amines Chemical class 0.000 description 2
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- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
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- 229910052725 zinc Inorganic materials 0.000 description 2
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 description 1
- XNRULZQPCJXTMC-UHFFFAOYSA-N 2-[1-[6-[2-hydroxyethyl(methyl)amino]naphthalen-2-yl]ethylidene]propanedinitrile Chemical compound C1=C(C(C)=C(C#N)C#N)C=CC2=CC(N(CCO)C)=CC=C21 XNRULZQPCJXTMC-UHFFFAOYSA-N 0.000 description 1
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 1
- CDBAMNGURPMUTG-UHFFFAOYSA-N 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol Chemical compound C1CC(O)CCC1C(C)(C)C1CCC(O)CC1 CDBAMNGURPMUTG-UHFFFAOYSA-N 0.000 description 1
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- YSKOFAYGTBLQTL-UHFFFAOYSA-N 4-phenyl-1,2,3-benzotriazine Chemical class C1=CC=CC=C1C1=NN=NC2=CC=CC=C12 YSKOFAYGTBLQTL-UHFFFAOYSA-N 0.000 description 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
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- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 235000003385 Diospyros ebenum Nutrition 0.000 description 1
- 241000792913 Ebenaceae Species 0.000 description 1
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- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
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- 238000003723 Smelting Methods 0.000 description 1
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- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- CQQXCSFSYHAZOO-UHFFFAOYSA-L [acetyloxy(dioctyl)stannyl] acetate Chemical compound CCCCCCCC[Sn](OC(C)=O)(OC(C)=O)CCCCCCCC CQQXCSFSYHAZOO-UHFFFAOYSA-L 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
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- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
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- 229910052783 alkali metal Inorganic materials 0.000 description 1
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- 125000002947 alkylene group Chemical group 0.000 description 1
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- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
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- C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
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- C08L33/064—Copolymers with monomers not covered by C08L33/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
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Landscapes
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Moulding By Coating Moulds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Inorganic Chemistry (AREA)
- Instrument Panels (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US95515907P | 2007-08-10 | 2007-08-10 | |
| US95737607P | 2007-08-22 | 2007-08-22 | |
| US95792207P | 2007-08-24 | 2007-08-24 | |
| US98650507P | 2007-11-08 | 2007-11-08 | |
| US98649507P | 2007-11-08 | 2007-11-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200938559A true TW200938559A (en) | 2009-09-16 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097130545A TWI445763B (zh) | 2007-08-10 | 2008-08-11 | 熱塑性聚胺酯共聚物模製組成物（一） |
| TW097130547A TW200938558A (en) | 2007-08-10 | 2008-08-11 | Thermoplastic polyurethane copolymer molding compositions |
| TW097130554A TW200938559A (en) | 2007-08-10 | 2008-08-11 | Thermoplastic aliphatic urethane/urea molding compositions |
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| TW097130545A TWI445763B (zh) | 2007-08-10 | 2008-08-11 | 熱塑性聚胺酯共聚物模製組成物（一） |
| TW097130547A TW200938558A (en) | 2007-08-10 | 2008-08-11 | Thermoplastic polyurethane copolymer molding compositions |
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| TW (3) | TWI445763B (enExample) |
| WO (3) | WO2009023131A2 (enExample) |
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| WO2009023131A2 (en) * | 2007-08-10 | 2009-02-19 | Bayer Materialscience Llc | Thermoplastic polyurethane copolymer molding compositions |
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| EP2464686B1 (en) * | 2009-08-10 | 2019-05-08 | Union Carbide Chemicals & Plastics Technology LLC | Thermoplastic elastomer compositions comprising intumescent flame retardants and non-phosphorous-based flame retardant synergists |
| TWI394767B (zh) * | 2009-12-14 | 2013-05-01 | Chung Shan Inst Of Science | 樹枝狀高分子、含有側鏈規則樹枝狀高分子之聚胺酯及其製備方法 |
| DE102009060065C5 (de) | 2009-12-22 | 2024-09-05 | Veritas Ag | Fluidleitung |
| JP5881615B2 (ja) * | 2010-01-08 | 2016-03-09 | ハンツマン ペトロケミカル エルエルシーＨｕｎｔｓｍａｎ Ｐｅｔｒｏｃｈｅｍｉｃａｌ ＬＬＣ | アミン酸化の抑制 |
| EP2365012A1 (en) * | 2010-03-05 | 2011-09-14 | RECTICEL Automobilsysteme GmbH | Method for producing a skin layer of a flexible, elastomeric, thermoset, phase-separated polyurethane material |
| US9120896B2 (en) | 2012-09-28 | 2015-09-01 | Elevance Renewable Sciences, Inc. | Polymers containing metathesized natural oil derivatives |
| FR3008918B1 (fr) * | 2013-07-29 | 2015-12-25 | Visteon Global Tech Inc | Procede de fabrication d'une piece d'habillage interieur et piece correspondante |
| CN104559130A (zh) * | 2014-11-26 | 2015-04-29 | 江苏绿艳高分子材料有限公司 | 一种tpu手机保护套及其制备方法 |
| CN104530683A (zh) * | 2014-12-08 | 2015-04-22 | 江苏绿艳高分子材料有限公司 | 一种新型tpu专用料的制备方法 |
| CN104530740A (zh) * | 2014-12-08 | 2015-04-22 | 江苏绿艳高分子材料有限公司 | 一种新型tpu专用料 |
| EP3371234B1 (de) * | 2015-11-04 | 2023-03-29 | Basf Se | Verfahren zur herstellung thermoplastischer polyurethane |
| WO2017202782A1 (de) * | 2016-05-25 | 2017-11-30 | Basf Se | Hohlpartikel aus thermoplastischen elastomeren und poröse formkörper |
| EP3867105A1 (en) | 2018-10-17 | 2021-08-25 | Dow Global Technologies, LLC | A coating composition, a coated fabric, a method of making a coated fabric, and an article made from the coated fabric |
| CN110144112B (zh) * | 2019-05-13 | 2021-11-23 | 浙江万马聚力新材料科技有限公司 | 无卤电缆料及其制备方法和包含该无卤电缆料的电缆 |
| JP7567759B2 (ja) | 2021-11-26 | 2024-10-16 | 豊田合成株式会社 | ステアリングホイール |
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-
2008
- 2008-08-08 WO PCT/US2008/009519 patent/WO2009023131A2/en not_active Ceased
- 2008-08-08 US US12/672,174 patent/US9708438B2/en not_active Expired - Fee Related
- 2008-08-08 EP EP08795154A patent/EP2188338A4/en not_active Withdrawn
- 2008-08-08 EP EP08795136A patent/EP2178979A4/en not_active Withdrawn
- 2008-08-08 KR KR1020107002901A patent/KR101516450B1/ko not_active Expired - Fee Related
- 2008-08-08 CN CN2008801020626A patent/CN101784609B/zh not_active Expired - Fee Related
- 2008-08-08 MX MX2010001389A patent/MX2010001389A/es active IP Right Grant
- 2008-08-08 MX MX2010001386A patent/MX2010001386A/es active IP Right Grant
- 2008-08-08 CA CA2695534A patent/CA2695534C/en not_active Expired - Fee Related
- 2008-08-08 CN CN200880102080A patent/CN101772549A/zh active Pending
- 2008-08-08 KR KR1020107002954A patent/KR101556025B1/ko not_active Expired - Fee Related
- 2008-08-08 KR KR1020107002902A patent/KR101519679B1/ko not_active Expired - Fee Related
- 2008-08-08 JP JP2010520994A patent/JP5366949B2/ja not_active Expired - Fee Related
- 2008-08-08 US US12/672,148 patent/US9796807B2/en not_active Expired - Fee Related
- 2008-08-08 MX MX2010001391A patent/MX2010001391A/es active IP Right Grant
- 2008-08-08 CN CN2008801020490A patent/CN102216389A/zh active Pending
- 2008-08-08 WO PCT/US2008/009541 patent/WO2009023138A2/en not_active Ceased
- 2008-08-08 US US12/733,059 patent/US20110105673A1/en not_active Abandoned
- 2008-08-08 CA CA2695537A patent/CA2695537C/en not_active Expired - Fee Related
- 2008-08-08 CN CN201410225557.5A patent/CN103980696A/zh active Pending
- 2008-08-08 JP JP2010520993A patent/JP5281087B2/ja not_active Expired - Fee Related
- 2008-08-08 WO PCT/US2008/009518 patent/WO2009023130A2/en not_active Ceased
- 2008-08-08 JP JP2010520996A patent/JP5325218B2/ja not_active Expired - Fee Related
- 2008-08-08 EP EP08795137A patent/EP2178980A4/en not_active Withdrawn
- 2008-08-08 CA CA2695567A patent/CA2695567C/en not_active Expired - Fee Related
- 2008-08-11 TW TW097130545A patent/TWI445763B/zh not_active IP Right Cessation
- 2008-08-11 TW TW097130547A patent/TW200938558A/zh unknown
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2017
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