TW200938558A - Thermoplastic polyurethane copolymer molding compositions - Google Patents
Thermoplastic polyurethane copolymer molding compositions Download PDFInfo
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- TW200938558A TW200938558A TW097130547A TW97130547A TW200938558A TW 200938558 A TW200938558 A TW 200938558A TW 097130547 A TW097130547 A TW 097130547A TW 97130547 A TW97130547 A TW 97130547A TW 200938558 A TW200938558 A TW 200938558A
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- 239000000203 mixture Substances 0.000 title claims abstract description 152
- 229920002803 thermoplastic polyurethane Polymers 0.000 title claims abstract description 59
- 239000004433 Thermoplastic polyurethane Substances 0.000 title claims description 56
- 238000000465 moulding Methods 0.000 title claims description 15
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 37
- 239000000843 powder Substances 0.000 claims abstract description 25
- 229920001400 block copolymer Polymers 0.000 claims abstract description 23
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 22
- 150000001336 alkenes Chemical class 0.000 claims abstract description 21
- 239000004005 microsphere Substances 0.000 claims abstract description 16
- 229920005862 polyol Polymers 0.000 claims description 46
- 150000003077 polyols Chemical class 0.000 claims description 44
- -1 (iv) optionally Substances 0.000 claims description 42
- 239000010410 layer Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 32
- 239000003607 modifier Substances 0.000 claims description 27
- 229920000098 polyolefin Polymers 0.000 claims description 27
- 239000000049 pigment Substances 0.000 claims description 21
- 229920001577 copolymer Polymers 0.000 claims description 18
- 229920001169 thermoplastic Polymers 0.000 claims description 18
- 239000004416 thermosoftening plastic Substances 0.000 claims description 17
- 238000005266 casting Methods 0.000 claims description 16
- 229920000831 ionic polymer Polymers 0.000 claims description 16
- 239000004970 Chain extender Substances 0.000 claims description 14
- 239000003963 antioxidant agent Substances 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- 125000005442 diisocyanate group Chemical group 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 229920000768 polyamine Polymers 0.000 claims description 12
- 229920000570 polyether Polymers 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
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- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 10
- 239000012963 UV stabilizer Substances 0.000 claims description 9
- 230000003078 antioxidant effect Effects 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 8
- 239000012141 concentrate Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 4
- 238000001746 injection moulding Methods 0.000 claims description 4
- 239000000052 vinegar Substances 0.000 claims description 4
- 235000021419 vinegar Nutrition 0.000 claims description 4
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
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- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 2
- 239000005056 polyisocyanate Substances 0.000 claims description 2
- 229920001228 polyisocyanate Polymers 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 claims 1
- MUXHWTZCMZMNDS-UHFFFAOYSA-N C1(=CC=CC=C1)O.C1(=CC=CC=C1)O.[Ar] Chemical compound C1(=CC=CC=C1)O.C1(=CC=CC=C1)O.[Ar] MUXHWTZCMZMNDS-UHFFFAOYSA-N 0.000 claims 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 1
- 238000009646 cryomilling Methods 0.000 claims 1
- 238000005520 cutting process Methods 0.000 claims 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
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- 239000002356 single layer Substances 0.000 claims 1
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- 238000005469 granulation Methods 0.000 description 7
- 230000003179 granulation Effects 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229920003182 Surlyn® Polymers 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
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- 239000005035 Surlyn® Substances 0.000 description 5
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- 150000001875 compounds Chemical class 0.000 description 4
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- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000012768 molten material Substances 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
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- 229910052724 xenon Inorganic materials 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- PZWQOGNTADJZGH-UHFFFAOYSA-N 2-methylpenta-2,4-dienoic acid Chemical compound OC(=O)C(C)=CC=C PZWQOGNTADJZGH-UHFFFAOYSA-N 0.000 description 2
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- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
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- 238000003723 Smelting Methods 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
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- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
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- C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
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- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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Landscapes
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- Chemical Kinetics & Catalysis (AREA)
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- Engineering & Computer Science (AREA)
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- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Moulding By Coating Moulds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Instrument Panels (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US95515907P | 2007-08-10 | 2007-08-10 | |
| US95737607P | 2007-08-22 | 2007-08-22 | |
| US95792207P | 2007-08-24 | 2007-08-24 | |
| US98649507P | 2007-11-08 | 2007-11-08 | |
| US98650507P | 2007-11-08 | 2007-11-08 |
Publications (1)
| Publication Number | Publication Date |
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| TW200938558A true TW200938558A (en) | 2009-09-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| TW097130547A TW200938558A (en) | 2007-08-10 | 2008-08-11 | Thermoplastic polyurethane copolymer molding compositions |
| TW097130545A TWI445763B (zh) | 2007-08-10 | 2008-08-11 | 熱塑性聚胺酯共聚物模製組成物(一) |
| TW097130554A TW200938559A (en) | 2007-08-10 | 2008-08-11 | Thermoplastic aliphatic urethane/urea molding compositions |
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| Application Number | Title | Priority Date | Filing Date |
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| TW097130545A TWI445763B (zh) | 2007-08-10 | 2008-08-11 | 熱塑性聚胺酯共聚物模製組成物(一) |
| TW097130554A TW200938559A (en) | 2007-08-10 | 2008-08-11 | Thermoplastic aliphatic urethane/urea molding compositions |
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| EP (3) | EP2188338A4 (enExample) |
| JP (3) | JP5325218B2 (enExample) |
| KR (3) | KR101556025B1 (enExample) |
| CN (4) | CN101772549A (enExample) |
| CA (3) | CA2695534C (enExample) |
| MX (3) | MX2010001391A (enExample) |
| TW (3) | TW200938558A (enExample) |
| WO (3) | WO2009023138A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI394767B (zh) * | 2009-12-14 | 2013-05-01 | Chung Shan Inst Of Science | 樹枝狀高分子、含有側鏈規則樹枝狀高分子之聚胺酯及其製備方法 |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101772549A (zh) * | 2007-08-10 | 2010-07-07 | 拜尔材料科学有限公司 | 热塑性聚氨酯共聚物模塑组合物 |
| US8129015B2 (en) * | 2009-05-14 | 2012-03-06 | International Automotive Components North America, Inc. | Modified moldable urethane with tunable haptics |
| US8691897B2 (en) * | 2009-08-10 | 2014-04-08 | Union Carbide Chemicals & Plastics Technology Llc | Thermoplastic elastomer compositions comprising intumescent flame retardants and non-phosphorous-based flame retardant synergists |
| DE202009019165U1 (de) | 2009-12-22 | 2017-05-15 | Veritas Ag | Fluidleitung |
| PL2521746T3 (pl) | 2010-01-08 | 2019-09-30 | Huntsman Petrochemical Llc | Hamowanie utleniania amin |
| EP2365012A1 (en) * | 2010-03-05 | 2011-09-14 | RECTICEL Automobilsysteme GmbH | Method for producing a skin layer of a flexible, elastomeric, thermoset, phase-separated polyurethane material |
| US9120896B2 (en) | 2012-09-28 | 2015-09-01 | Elevance Renewable Sciences, Inc. | Polymers containing metathesized natural oil derivatives |
| FR3008918B1 (fr) * | 2013-07-29 | 2015-12-25 | Visteon Global Tech Inc | Procede de fabrication d'une piece d'habillage interieur et piece correspondante |
| CN104559130A (zh) * | 2014-11-26 | 2015-04-29 | 江苏绿艳高分子材料有限公司 | 一种tpu手机保护套及其制备方法 |
| CN104530683A (zh) * | 2014-12-08 | 2015-04-22 | 江苏绿艳高分子材料有限公司 | 一种新型tpu专用料的制备方法 |
| CN104530740A (zh) * | 2014-12-08 | 2015-04-22 | 江苏绿艳高分子材料有限公司 | 一种新型tpu专用料 |
| EP3371234B1 (de) * | 2015-11-04 | 2023-03-29 | Basf Se | Verfahren zur herstellung thermoplastischer polyurethane |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI394767B (zh) * | 2009-12-14 | 2013-05-01 | Chung Shan Inst Of Science | 樹枝狀高分子、含有側鏈規則樹枝狀高分子之聚胺酯及其製備方法 |
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