TW200744950A - Method of preparing a molecular sieve composition - Google Patents
Method of preparing a molecular sieve compositionInfo
- Publication number
- TW200744950A TW200744950A TW096103755A TW96103755A TW200744950A TW 200744950 A TW200744950 A TW 200744950A TW 096103755 A TW096103755 A TW 096103755A TW 96103755 A TW96103755 A TW 96103755A TW 200744950 A TW200744950 A TW 200744950A
- Authority
- TW
- Taiwan
- Prior art keywords
- molecular sieve
- reaction mixture
- alkali metal
- source
- crystalline molecular
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000002808 molecular sieve Substances 0.000 title abstract 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 2
- 150000002500 ions Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/023—Preparation of physical mixtures or intergrowth products of zeolites chosen from group C01B39/04 or two or more of groups C01B39/14 - C01B39/48
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/62—Synthesis on support in or on other molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/64—Synthesis on support in or on refractory materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/80—Mixtures of different zeolites
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US77301006P | 2006-02-14 | 2006-02-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW200744950A true TW200744950A (en) | 2007-12-16 |
Family
ID=36809023
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW096103755A TW200744950A (en) | 2006-02-14 | 2007-02-01 | Method of preparing a molecular sieve composition |
Country Status (6)
Country | Link |
---|---|
US (2) | US7829062B2 (zh) |
EP (1) | EP1996328B1 (zh) |
CN (2) | CN101384365B (zh) |
TW (1) | TW200744950A (zh) |
WO (1) | WO2007102952A1 (zh) |
ZA (1) | ZA200806442B (zh) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5537813B2 (ja) * | 2006-02-14 | 2014-07-02 | エクソンモービル・ケミカル・パテンツ・インク | Mcm−22型モレキュラーシーブの製造方法 |
EP1996328B1 (en) * | 2006-02-14 | 2016-07-13 | ExxonMobil Chemical Patents Inc. | Method of preparing a molecular sieve composition |
US7846418B2 (en) * | 2006-02-14 | 2010-12-07 | Exxonmobil Chemical Patents Inc. | MCM-22 family molecular sieve composition |
US8859836B2 (en) | 2006-02-14 | 2014-10-14 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process using molecular sieve of MFS framework type |
WO2009055216A2 (en) | 2007-10-26 | 2009-04-30 | Exxonmobil Chemical Patents Inc. | Method of preparing a molecular sieve composition |
US8545796B2 (en) * | 2009-07-31 | 2013-10-01 | Cristal Usa Inc. | Silica-stabilized ultrafine anatase titania, vanadia catalysts, and methods of production thereof |
CN101670296B (zh) * | 2009-10-19 | 2011-05-25 | 浙江大学 | 用于含氧化合物制备低碳烯烃的催化剂及其制备方法 |
BR112012019018B1 (pt) | 2010-02-01 | 2021-01-19 | Johnson Matthey Plc | filtro de fluxo de parede, sistema de escapamento para um veículo, e, processo para a fabricação de um filtro de fluxo de parede |
CN102892731B (zh) * | 2010-05-20 | 2015-12-02 | 埃克森美孚化学专利公司 | 改进的烷基化方法 |
CN101870477B (zh) * | 2010-06-04 | 2012-02-22 | 南京理工大学 | 利用粉煤灰制备成型沸石的工艺 |
CN102372277B (zh) * | 2010-08-23 | 2013-01-09 | 中国石油化工股份有限公司 | 无粘结剂ZSM-5/β共生分子筛的制备方法 |
WO2012050655A2 (en) * | 2010-10-15 | 2012-04-19 | Exxonmobil Chemical Patents Inc. | Selecting an improved catalyst composition and hydrocarbon conversion process using same |
CN102874832B (zh) * | 2011-07-12 | 2014-07-02 | 中国石油化工股份有限公司 | Mfi型沸石择优定向生长方法 |
GB2506776B (en) | 2011-08-03 | 2016-01-06 | Johnson Matthey Plc | Extruded honeycomb catalyst |
WO2013039673A1 (en) * | 2011-09-16 | 2013-03-21 | Exxonmobil Chemical Patents Inc. | Improved liquid phase alkylation process |
CN103058210B (zh) * | 2011-10-21 | 2015-04-01 | 中国石油化工股份有限公司 | 一种mcm-22分子筛的制备方法 |
CN103121690B (zh) * | 2011-11-18 | 2015-01-07 | 中国石油化工股份有限公司 | 气相法合成丝光沸石的方法 |
PL2888042T3 (pl) | 2012-08-24 | 2020-11-02 | Tronox Llc | Materiały nośnika katalizatora, katalizatory, sposoby ich wytwarzania i ich zastosowanie |
CN103274427A (zh) * | 2013-06-18 | 2013-09-04 | 北京北大先锋科技有限公司 | 一种p型分子筛的制备方法 |
ITMI20131704A1 (it) | 2013-10-15 | 2015-04-16 | Versalis Spa | Composizione catalitica e processo che la utilizza per l'alchilazione di idrocarburi aromatici con alcoli, o miscele di alcoli e olefine |
CN109422282A (zh) * | 2017-08-31 | 2019-03-05 | 中国科学院大连化学物理研究所 | 一种合成烷烃临氢异构化催化剂载体的方法 |
CN108298552B (zh) * | 2018-02-06 | 2021-06-22 | 润和催化剂股份有限公司 | 一种大粒径Beta分子筛的合成方法 |
CA3110677A1 (en) * | 2018-08-27 | 2020-03-05 | Exxonmobil Research And Engineering Company | Molecular sieves and a process for making molecular sieves |
EP3844248A1 (en) | 2018-08-27 | 2021-07-07 | ExxonMobil Research and Engineering Company | Dewaxing using a molecular sieve catalyst |
EP4180396A2 (en) * | 2018-08-27 | 2023-05-17 | ExxonMobil Technology and Engineering Company | Molecular sieves and a process for making molecular sieves |
WO2020046622A1 (en) * | 2018-08-27 | 2020-03-05 | Exxonmobil Research And Engineering Company | A process for making molecular sieves |
CN111392745B (zh) * | 2020-04-24 | 2021-11-16 | 中国石油大学(北京) | 一种高硅铝比镁碱沸石及其制备方法和应用 |
KR20230039716A (ko) * | 2020-07-16 | 2023-03-21 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Mww 골격 유형의 분자체를 합성하는 방법 |
CN115231586B (zh) * | 2022-07-06 | 2023-10-20 | 安阳工学院 | 晶面可调节Coffin形貌ZSM-5分子筛及其合成方法 |
Family Cites Families (75)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4100262A (en) | 1977-08-15 | 1978-07-11 | Mobil Oil Corporation | Synthesis of zeolite ZSM-5 |
DE3117135A1 (de) | 1981-04-30 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe |
US4973781A (en) | 1982-11-17 | 1990-11-27 | Mobil Oil Corporation | Zeolite ZSM-57 and catalysis therewith |
US4873067A (en) | 1984-08-21 | 1989-10-10 | Mobil Oil Corporation | Zeolite ZSM-57 |
BR8504010A (pt) | 1984-08-21 | 1986-06-10 | Mobil Oil Corp | Processo para preparacao de zeolito cristalino poroso sintetico e processo para efetuar conversao catalitica de carga organica |
US4826667A (en) | 1986-01-29 | 1989-05-02 | Chevron Research Company | Zeolite SSZ-25 |
US4954325A (en) | 1986-07-29 | 1990-09-04 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis and use |
US5019664A (en) | 1988-10-06 | 1991-05-28 | Mobil Oil Corp. | Process for the conversion of paraffins to olefins and/or aromatics and low acidity zeolite catalyst therefor |
US4956514A (en) | 1988-10-06 | 1990-09-11 | Mobil Oil Corp. | Process for converting olefins to higher hydrocarbons |
US4983276A (en) | 1988-10-06 | 1991-01-08 | Mobil Oil Corp. | Octane improvement in catalytic cracking and cracking catalyst composition therefor |
US5019670A (en) | 1986-07-29 | 1991-05-28 | Mobil Oil Corporation | Process for producing alkylaromatic lubricant fluids |
US4962256A (en) | 1988-10-06 | 1990-10-09 | Mobil Oil Corp. | Process for preparing long chain alkyl aromatic compounds |
US4954663A (en) | 1988-10-06 | 1990-09-04 | Mobil Oil Corp. | Process for preparing long chain alkyl phenols |
US5013422A (en) | 1986-07-29 | 1991-05-07 | Mobil Oil Corp. | Catalytic hydrocracking process |
DE3625693A1 (de) | 1986-07-30 | 1988-02-11 | Bayer Ag | Verfahren zur umsetzung von aminen mit heterocyclischen reaktivkomponenten |
US4721807A (en) | 1986-10-06 | 1988-01-26 | Uop Inc. | Process for separating 2,6-toluene diisocyanate from isomers of toluene diisocyanate |
US4721806A (en) | 1986-10-06 | 1988-01-26 | Uop Inc. | Process for separating 2,4-toluene diisocyanate from isomers of toluene diisocyanate |
GB8704365D0 (en) | 1987-02-25 | 1987-04-01 | Exxon Chemical Patents Inc | Zeolite l preparation |
IT1205681B (it) | 1987-05-26 | 1989-03-31 | Eniricerche Spa | Materiale sintetico cristallino poroso contenente ossidi di silicio e boro |
US5240892A (en) | 1987-09-02 | 1993-08-31 | Mobil Oil Corporation | Small crystal ZSM-5, as a catalyst |
US4962257A (en) | 1988-10-06 | 1990-10-09 | Mobil Oil Corp. | Process for the catalytic disproportionation of toluene |
US5001283A (en) | 1988-10-06 | 1991-03-19 | Mobil Oil Corp. | Process for preparing aromatic alkanols |
US4992606A (en) | 1988-10-06 | 1991-02-12 | Mobil Oil Corp. | Process for preparing short chain alkyl aromatic compounds |
US5012033A (en) | 1988-10-06 | 1991-04-30 | Mobil Oil Corp. | Isoparaffin-olefin alkylation process and catalyst composition thereof |
US5001295A (en) | 1988-10-06 | 1991-03-19 | Mobil Oil Corp. | Process for preparing dialkylnaphthalene |
US4962239A (en) | 1988-10-06 | 1990-10-09 | Mobil Oil Corp. | Process for preparing ethers |
US4973784A (en) | 1988-10-06 | 1990-11-27 | Mobil Oil Corp. | Process for reducing the durene content of effluent resulting from the catalytic conversion of C1 -C4 oxygenates to gasoline |
US4982040A (en) | 1988-10-06 | 1991-01-01 | Mobil Oil Corp. | Process for the catalytic disproportionation of methylnaphthalenes |
US4986894A (en) | 1988-10-06 | 1991-01-22 | Mobil Oil Corp. | Catalytic hydroisomerization process |
US4982033A (en) | 1988-10-06 | 1991-01-01 | Mobil Oil Corp. | Process for converting light aliphatics to aromatics |
US4992611A (en) | 1989-12-13 | 1991-02-12 | Mobil Oil Corp. | Direct conversion of C1 -C4 oxygenates to low aromatic distillate range hydrocarbons |
US4962250A (en) | 1990-01-24 | 1990-10-09 | Mobile Oil Corp. | Process for the conversion of paraffins to olefins and/or aromatics and non-acidic zeolite catalyst therefor |
US4992615A (en) | 1990-01-25 | 1991-02-12 | Mobil Oil Corp. | Isoparaffin-olefin alkylation process |
US5000839A (en) | 1990-02-14 | 1991-03-19 | Mobil Oil Corp. | Hydrocracking process for producing a high density jet fuel |
US4968402A (en) | 1990-02-14 | 1990-11-06 | Mobil Oil Corp. | Process for upgrading hydrocarbons |
US5001296A (en) | 1990-03-07 | 1991-03-19 | Mobil Oil Corp. | Catalytic hydrodealkylation of aromatics |
US5019665A (en) | 1990-04-18 | 1991-05-28 | Mobil Oil Corp. | Shape-selective process for concentrating diamondoid-containing hydrocarbon solvents |
US5250277A (en) | 1991-01-11 | 1993-10-05 | Mobil Oil Corp. | Crystalline oxide material |
GB9101456D0 (en) | 1991-01-23 | 1991-03-06 | Exxon Chemical Patents Inc | Process for producing substantially binder-free zeolite |
US5164170A (en) | 1991-06-14 | 1992-11-17 | Mobil Oil Corporation | Synthesis of zeolite Beta |
US5236575A (en) | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
US5143879A (en) | 1991-07-18 | 1992-09-01 | Mobil Oil Corporation | Method to recover organic templates from freshly synthesized molecular sieves |
CA2151592A1 (en) * | 1992-12-16 | 1994-06-23 | Stephen J. Miller | Preparation of aluminosilicate zeolites |
US5362697A (en) | 1993-04-26 | 1994-11-08 | Mobil Oil Corp. | Synthetic layered MCM-56, its synthesis and use |
US5763347A (en) | 1994-07-08 | 1998-06-09 | Exxon Research And Engineering Company | In-situ crystallized zeolite containing composition (LAI-ISC) |
EP0775015B1 (en) | 1994-07-08 | 2004-09-15 | ExxonMobil Research and Engineering Company | Zeolite layers with controlled crystal width and preferred orientation grown on a growth enhancing layer |
US5871650A (en) | 1994-07-08 | 1999-02-16 | Exxon Research And Engineering Company | Supported zeolite membranes with controlled crystal width and preferred orientation grown on a growth enhancing layer |
ES2124154B1 (es) | 1995-11-08 | 1999-12-01 | Univ Politecnica De Valencia C | Metodo de preparaciion y propiedades cataliticas de un solido microporoso con alta superficie externa. |
ES2105982B1 (es) | 1995-11-23 | 1998-07-01 | Consejo Superior Investigacion | Zeolita itq-1 |
KR100455817B1 (ko) | 1996-08-14 | 2005-04-06 | 니혼 엔바이로 케미카루즈 가부시키가이샤 | 이온흡착제 |
US5925330A (en) | 1998-02-13 | 1999-07-20 | Mobil Oil Corporation | Method of m41s functionalization of potentially catalytic heteroatom centers into as-synthesized m41s with concomitant surfactant extraction |
KR100624246B1 (ko) | 1998-07-29 | 2006-09-13 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 결정질 분자체 |
EP0999182B1 (fr) | 1998-11-02 | 2003-05-14 | Institut Francais Du Petrole | Procédé de préparation d'une zéolithe de type structural EUO à l'aide de germes de matériaux zéolitiques et son utilisation comme catalyseur d'isomérisation des aromatiques à huit atomes de carbone |
DE60036508T2 (de) | 1999-06-18 | 2008-06-26 | Nippon Shokubai Co., Ltd. | Formling aus binderfreien Zeolith , Verfahren zu seiner Herstellung und seine Verwendung |
US6099820A (en) | 1999-08-17 | 2000-08-08 | Chevron U.S.A. Inc. | Method for making MTT zeolites without an organic template |
CN1107644C (zh) | 1999-11-17 | 2003-05-07 | 中国石油化工集团公司 | 一种mcm-22分子筛的制备方法 |
ES2204409T5 (es) | 2000-06-26 | 2008-04-16 | Saudi Basic Industries Corporation | Dimerizacion de isobuteno. |
US6936744B1 (en) | 2000-07-19 | 2005-08-30 | Exxonmobil Chemical Patents, Inc. | Alkylaromatics production |
US6632415B2 (en) * | 2001-04-09 | 2003-10-14 | Chevron U.S.A. Inc. | Methods for making molecular sieves |
US20020042548A1 (en) | 2001-07-11 | 2002-04-11 | Dandekar Ajit B. | Process for producing cumene |
US6781025B2 (en) | 2001-07-11 | 2004-08-24 | Exxonmobil Chemical Patents Inc. | Reactivation of aromatics alkylation catalysts |
US7011810B2 (en) | 2001-09-28 | 2006-03-14 | Exxonmobil Chemical Patents Inc. | Crystalline molecular sieves |
US20030204121A1 (en) * | 2002-04-30 | 2003-10-30 | Miller Stephen J. | Process for aromatics alkylation employing zeolite beta prepared by the in-extrudate method |
CN1207199C (zh) * | 2002-11-13 | 2005-06-22 | 中国石油化工股份有限公司 | Mcm-22分子筛的制备方法 |
ES2246704B1 (es) | 2004-05-28 | 2007-06-16 | Universidad Politecnica De Valencia | Zeolita itq-30. |
TWI376361B (en) | 2004-08-13 | 2012-11-11 | Exxonmobil Chem Patents Inc | Process for producing phenol and methyl ethyl ketone |
TW200616939A (en) | 2004-08-13 | 2006-06-01 | Exxonmobil Chemical Patents Inc | Production of bisphenol-a |
ATE455741T1 (de) | 2004-08-13 | 2010-02-15 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von sek.-butylbenzol |
EP1996328B1 (en) * | 2006-02-14 | 2016-07-13 | ExxonMobil Chemical Patents Inc. | Method of preparing a molecular sieve composition |
CN101384361A (zh) | 2006-02-14 | 2009-03-11 | 埃克森美孚化学专利公司 | 用于制备mfs结构型分子筛的方法及其应用 |
US7846418B2 (en) * | 2006-02-14 | 2010-12-07 | Exxonmobil Chemical Patents Inc. | MCM-22 family molecular sieve composition |
EP1996327A1 (en) * | 2006-02-14 | 2008-12-03 | ExxonMobil Chemical Patents Inc. | A molecular sieve composition |
JP5537813B2 (ja) * | 2006-02-14 | 2014-07-02 | エクソンモービル・ケミカル・パテンツ・インク | Mcm−22型モレキュラーシーブの製造方法 |
ES2722629T3 (es) * | 2006-07-28 | 2019-08-14 | Exxonmobil Chemical Patents Inc | Una composición de tamiz molecular novedosa, un método de elaboración y un proceso de uso de la misma |
US8500991B2 (en) | 2008-12-16 | 2013-08-06 | Exxonmobil Research And Engineering Company | High activity MTT framework type molecular sieves |
-
2007
- 2007-01-26 EP EP07749289.0A patent/EP1996328B1/en active Active
- 2007-01-26 CN CN2007800053064A patent/CN101384365B/zh active Active
- 2007-01-26 WO PCT/US2007/002170 patent/WO2007102952A1/en active Application Filing
- 2007-01-26 CN CN201210004889.1A patent/CN102527428B/zh active Active
- 2007-01-26 US US11/698,500 patent/US7829062B2/en active Active
- 2007-02-01 TW TW096103755A patent/TW200744950A/zh unknown
-
2008
- 2008-07-24 ZA ZA200806442A patent/ZA200806442B/xx unknown
-
2010
- 2010-10-01 US US12/896,065 patent/US8017540B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
ZA200806442B (en) | 2009-08-26 |
CN101384365A (zh) | 2009-03-11 |
US8017540B2 (en) | 2011-09-13 |
EP1996328A1 (en) | 2008-12-03 |
CN102527428A (zh) | 2012-07-04 |
CN102527428B (zh) | 2014-11-26 |
US20110021856A1 (en) | 2011-01-27 |
EP1996328B1 (en) | 2016-07-13 |
US20070191658A1 (en) | 2007-08-16 |
US7829062B2 (en) | 2010-11-09 |
WO2007102952A1 (en) | 2007-09-13 |
CN101384365B (zh) | 2012-02-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TW200744950A (en) | Method of preparing a molecular sieve composition | |
WO2009055216A3 (en) | Method of preparing a molecular sieve composition | |
TW200740524A (en) | A molecular sieve composition | |
CN105692647B (zh) | 一种ssz‑13分子筛的制备方法 | |
TW200744753A (en) | An MCM-22 family molecular sieve composition | |
RU2011127679A (ru) | Высокоактивные молекулярные сита со структурой типа мтт | |
WO2007089527B1 (en) | Method of forming a dianhydrosugar alcohol | |
GEP20094576B (en) | New cyrstalline form iii of agomelatine, a process for its preparation and pharmaceutical compositions containing it | |
PL1935877T3 (pl) | Sposób wytwarzania toluilenodiizocyjanianu | |
KR20080078835A (ko) | 글리세릴 카르보네이트의 제조 방법 | |
WO2009154783A3 (en) | Synthesis and use of mse-framework type molecular sieves | |
WO2008146741A1 (ja) | トリクロロシランの製造方法と製造装置および多結晶シリコンの製造方法 | |
SG153629A1 (en) | Process for preparing isobutene from tert-butanol | |
YU79600A (sh) | Katalizator za reakcije krekovanja sa vodenom parom i odgovarajući postupak proizvodnje | |
TW200617224A (en) | Production process of periodic table group 13 metal nitride crystal and production method of semiconductor device using the same | |
MY143324A (en) | Process for preparing phosphorus compounds having phosphate-phosphonate bond | |
WO2009044803A1 (ja) | 不斉触媒マイケル反応生成物の製造方法 | |
RU2005129112A (ru) | Способ получения параксилола | |
CN101391774A (zh) | 硅烷气体的生产方法 | |
CN103272528A (zh) | 用碱金属叠氮化物合成立方氮化硼的方法 | |
CN107720767B (zh) | 一种钙长石水热合成高岭石的方法 | |
CA2725412A1 (en) | Method for manufacturing dialkylzinc and dialkylaluminum monohalide | |
CN114572997B (zh) | 丝光沸石分子筛以及制备方法、应用 | |
CN108084045B (zh) | 一种混旋的拉科酰胺的高效制备方法 | |
CN108114741A (zh) | 一种制碳酸二甲酯的催化剂及其制备方法和应用 |