TW200540864A - Method for producing a multilayer storage media - Google Patents
Method for producing a multilayer storage media Download PDFInfo
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- TW200540864A TW200540864A TW094115913A TW94115913A TW200540864A TW 200540864 A TW200540864 A TW 200540864A TW 094115913 A TW094115913 A TW 094115913A TW 94115913 A TW94115913 A TW 94115913A TW 200540864 A TW200540864 A TW 200540864A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 41
- 239000000853 adhesive Substances 0.000 claims abstract description 30
- 230000001070 adhesive effect Effects 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims description 23
- 238000000576 coating method Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 5
- 238000005452 bending Methods 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000010076 replication Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
Classifications
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/26—Apparatus or processes specially adapted for the manufacture of record carriers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
- B29C65/483—Reactive adhesives, e.g. chemically curing adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
- B29C65/483—Reactive adhesives, e.g. chemically curing adhesives
- B29C65/4845—Radiation curing adhesives, e.g. UV light curing adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/112—Single lapped joints
- B29C66/1122—Single lap to lap joints, i.e. overlap joints
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
- B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
- B29C66/45—Joining of substantially the whole surface of the articles
- B29C66/452—Joining of substantially the whole surface of the articles the article having a disc form, e.g. making CDs or DVDs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/1403—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the type of electromagnetic or particle radiation
- B29C65/1406—Ultraviolet [UV] radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/52—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive
- B29C65/521—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive by spin coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
- B29C66/712—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined the composition of one of the parts to be joined being different from the composition of the other part
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
- B29C66/832—Reciprocating joining or pressing tools
- B29C66/8322—Joining or pressing tools reciprocating along one axis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
- B29K2033/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2017/00—Carriers for sound or information
- B29L2017/001—Carriers of records containing fine grooves or impressions, e.g. disc records for needle playback, cylinder records
- B29L2017/003—Records or discs
- B29L2017/005—CD''s, DVD''s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2429/00—Carriers for sound or information
- B32B2429/02—Records or discs
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Manufacturing Optical Record Carriers (AREA)
- Prostheses (AREA)
- Chair Legs, Seat Parts, And Backrests (AREA)
Description
200540864 九、發明說明: 【發明所屬之技術領域】 本發明係關於光學資料儲存媒體,特別關於如 DVD-14/18、DVD R DL與其他多層媒體之光碟的製造。 【先前技術】 一般用來製造雙層單面DVD (如DVD-9)的方法爲黏 結2片0.6mm基板在一起,其中每一片係載有一資訊層。用 來製作雙層碟片之其他方法爲所謂”2P製程”。該2P製程將 ® 雙層單面(單層於每一片基板)提升爲具有雙層內部資訊層 之單一基板構造。其對於DVD-9之製造並不需要,但對於 其他如DVD 14/1 8或DVDR9的多層格式則爲必要的。 相關技術
美國專利第6,1 17,284號與6,309,496號說明關於該2P 製程之一般資訊。 在2P製程之第一步驟中,藉由射出成形製造具有資訊 層之第一基板並以適用之層形材料來塗布。然後製造具有第 ®二資訊層之第二基板,通常使用一種紫外線硬化黏著劑來黏 結該第二基板與第一基板。於下一步驟中,分離該2片(已 黏結)之基板,因而第二基板之資訊層影像必定會完全留存 在第一基板上。隨施作之不同,亦可能以相似方法將第二層 金屬層移轉至第一層基板。 爲了良好之壓印結果與容易之分離目的,UV硬化黏著 劑與第二基板之材料選擇爲重要的。然而通常使用聚碳酸酯 於第一基板,而使用PMMA或其他非極性材料於第二基板。 200540864 然而,於第一與第二基板間所使用二 須滿足許多要求。一方面該材料應提供$ 一方面該材料應於分離程序後使第一基 械應力,以避免該基板之彎曲。由於通常 縮程序而無法避免某些應力之發生。 爲克服使用單一硬化黏著劑來達成 最小化的困難,該黏結層可使用2種不同 布一種具有最佳化之彈力性質黏著劑於養 β 塗布第二種已對於複製性質最佳化之i 上。其中應以第一與第二黏著劑之厚度比 須藉最大化第一黏著劑厚度來避免第二 增加厚度而增加之基板彎曲之所導致的景 用於DVD R DL媒體之黏結層所需之厚J! 由提供40μπι之第一黏著劑於第一基板上 著劑於第二基板上並使其黏結在一起來· 圖)。 ^ 在本工藝之說明的實驗中,如 6,1 3 6,1 33號公報中所述,同時使用該2 板上,然後藉由一硬化步驟將其黏結在一 些許的製程步驟,但是具有某些缺點。當 厚度之第一與第二黏著劑時,則難以達成 度與碟片外緣清潔度之要求。 【發明內容】 爲了避免使用兩種不同黏著劑之2Ρ :UV硬化黏著劑必 :好之壓印結果,另 板上受到最小的機 在硬化期間發生收 良好之複製與彎曲 丨黏著劑來製造。塗 I 一基板之上,並且 注著劑於第二基板 ;例不對等爲佳。必 黏著劑對於其隨著 >響。提出一範例: 変爲50μιη,其可藉 .及1 Ομπι之第二黏 ί造(本例參照第1 例如美國專利第 種黏著劑於該等基 起。該方法雖僅需 使用具有顯著不同 黏結程序中高信賴 製程技術的缺點, 200540864 提出以下之方法。旋轉塗布一種以具有良好複製性質爲佳之 第一黏著劑於適當基板之上並於第一硬化步驟中以UV光線 硬化之。於下一步驟中,使用第二黏著劑將該已塗布之基板 與其他基板黏結在一起。該步驟係以一種第二硬化步驟結束 之標準黏結步驟。 【實施方式】 藉助於第2圖來詳細地顯示一個較佳實施例。一種用於 製造碟形工作部件之發明方法包含製造第一與第二碟形基 g板、塗布第一黏著劑1於該第一基板2之至少部份平面側 上、硬化該第一黏著劑、塗布第二黏著劑3於該第一基板2 或第二基板4之至少之一平面側之至少部份上、與黏結該等 基板而形成該碟形工作部件5的步驟。然後碟形工作部件可 再次進行硬化。 本發明將製備複合黏結層之製程分爲塗布程序與黏結 程序之二個可被良好控制之步驟。該製程不但將解決與現行 方法相關製程之問題,同時亦將提高黏結程序之信賴度與所 完成之碟片的外緣清潔度。 •【圖式簡單說明】 第1圖係顯示一種黏結程序之先前技術的狀況。 第2圖係顯示本發明製程之一實施例。 【元件符號說明】 1 第一黏著劑 2 第一基板 3 第二黏著劑 4 第二基板 5 已黏結狀態之碟形工作部件
Claims (1)
- 200540864 十、申請專利範圍: 1 · 一種用於製造碟形工作部件之方法,包含如下步驟: a) 製造第一與第二碟形基板; b) 將第一黏著劑至少部分地塗布於該第一基板之平面側 中之一者; c) 硬化該第一黏著劑; d) 將第二黏著劑至少部分地塗布於該第一或第二基板之 平面側至少一者;以及 e) 黏結該等基板而形成該碟形工作部件。 2·如申請專利範圍第1項之製造碟形工作部件之方法,其中 尙包含之步驟: f) 硬化該碟形工作部件。 3 ·如申請專利範圍第1或2項之製造碟形工作部件之方丨去, 其中該第一黏著劑係適於提供良好之複製性質。 4·如申請專利範圍第1〜3項中任一項之製作碟形工作部# 之方法,其中第二黏著劑係適於提供良好之彈力性質。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US57219404P | 2004-05-18 | 2004-05-18 |
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TW200540864A true TW200540864A (en) | 2005-12-16 |
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TW094115913A TW200540864A (en) | 2004-05-18 | 2005-05-17 | Method for producing a multilayer storage media |
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US (1) | US20050266656A1 (zh) |
EP (1) | EP1756817B1 (zh) |
JP (1) | JP4616341B2 (zh) |
AT (1) | ATE452405T1 (zh) |
DE (1) | DE602005018351D1 (zh) |
TW (1) | TW200540864A (zh) |
WO (1) | WO2005112020A1 (zh) |
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DE102007007323A1 (de) | 2007-02-14 | 2008-08-21 | Singulus Technologies Ag | Verfahren zur Herstellung optischer Datenträger mit mehreren Informationsschichten |
WO2009154156A1 (ja) * | 2008-06-16 | 2009-12-23 | 東レ株式会社 | パターニング方法およびこれを用いたデバイスの製造方法ならびにデバイス |
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US4892606A (en) * | 1986-08-28 | 1990-01-09 | Canon Kabushiki Kaisha | Optical recording medium having space therein and method of manufacturing the same |
JPH08306085A (ja) * | 1995-04-28 | 1996-11-22 | Sony Corp | 多層構造光学記録媒体の製造方法 |
JP3840566B2 (ja) * | 1995-04-28 | 2006-11-01 | ソニー株式会社 | 多層構造光学記録媒体とその製造方法 |
JPH09231621A (ja) * | 1996-02-27 | 1997-09-05 | Nikka Eng Kk | ディスクの製造方法 |
WO1998008220A1 (en) * | 1996-08-21 | 1998-02-26 | Imation Corp. | Process for bonding optical media |
JP3581246B2 (ja) * | 1997-12-17 | 2004-10-27 | パイオニア株式会社 | 貼り合わせ型光ディスクの製造方法 |
US6117284A (en) * | 1998-09-28 | 2000-09-12 | Wea Manufacturing, Inc. | Dual-layer DVD disc, and method and apparatus for making same |
US6309496B1 (en) * | 1999-03-04 | 2001-10-30 | Wea Manfacturing Inc. | Method and apparatus for making dual layer DVD discs |
JP2000345073A (ja) * | 1999-06-09 | 2000-12-12 | Dainippon Ink & Chem Inc | 紫外線硬化型組成物及びこれを用いた光ディスク |
JP2002241711A (ja) * | 2001-02-15 | 2002-08-28 | Hitachi Chem Co Ltd | 光記録媒体用フィルム状接着剤及び光記録媒体の製造方法 |
JP2002251803A (ja) * | 2001-02-26 | 2002-09-06 | Origin Electric Co Ltd | 光ディスク基板の貼り合わせ装置および光ディスク基板の貼り合わせ方法 |
JP2003296978A (ja) * | 2002-01-30 | 2003-10-17 | Sony Disc Technology Inc | 光学記録媒体の製造方法および光学記録媒体 |
EP1518899A3 (en) * | 2003-09-18 | 2005-08-03 | Fuji Photo Film Co., Ltd. | Photocurable adhesive and bonding process employing same |
-
2005
- 2005-05-13 AT AT05737466T patent/ATE452405T1/de not_active IP Right Cessation
- 2005-05-13 DE DE602005018351T patent/DE602005018351D1/de active Active
- 2005-05-13 JP JP2007516929A patent/JP4616341B2/ja not_active Expired - Fee Related
- 2005-05-13 EP EP05737466A patent/EP1756817B1/en not_active Not-in-force
- 2005-05-13 WO PCT/CH2005/000272 patent/WO2005112020A1/en not_active Application Discontinuation
- 2005-05-16 US US11/129,896 patent/US20050266656A1/en not_active Abandoned
- 2005-05-17 TW TW094115913A patent/TW200540864A/zh unknown
Also Published As
Publication number | Publication date |
---|---|
EP1756817B1 (en) | 2009-12-16 |
ATE452405T1 (de) | 2010-01-15 |
EP1756817A1 (en) | 2007-02-28 |
JP2007538348A (ja) | 2007-12-27 |
DE602005018351D1 (de) | 2010-01-28 |
JP4616341B2 (ja) | 2011-01-19 |
US20050266656A1 (en) | 2005-12-01 |
WO2005112020A1 (en) | 2005-11-24 |
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