TW200529920A - Multiphase alloy and metal membrane for hydrogen separation-purification and methods for preparing the alloy and the metal membrane - Google Patents
Multiphase alloy and metal membrane for hydrogen separation-purification and methods for preparing the alloy and the metal membrane Download PDFInfo
- Publication number
- TW200529920A TW200529920A TW094103235A TW94103235A TW200529920A TW 200529920 A TW200529920 A TW 200529920A TW 094103235 A TW094103235 A TW 094103235A TW 94103235 A TW94103235 A TW 94103235A TW 200529920 A TW200529920 A TW 200529920A
- Authority
- TW
- Taiwan
- Prior art keywords
- hydrogen
- alloy
- phase
- purification
- film
- Prior art date
Links
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 181
- 239000001257 hydrogen Substances 0.000 title claims abstract description 181
- 239000000956 alloy Substances 0.000 title claims abstract description 84
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 65
- 239000002184 metal Substances 0.000 title claims abstract description 65
- 238000000746 purification Methods 0.000 title claims abstract description 62
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 48
- 239000012528 membrane Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 18
- 125000004435 hydrogen atom Chemical class [H]* 0.000 title description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 131
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 229910001000 nickel titanium Inorganic materials 0.000 claims abstract description 20
- 230000005496 eutectics Effects 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 229910001252 Pd alloy Inorganic materials 0.000 claims abstract description 14
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 7
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 7
- 239000013078 crystal Substances 0.000 claims abstract description 5
- 238000000926 separation method Methods 0.000 claims description 45
- 230000035515 penetration Effects 0.000 claims description 18
- 238000011978 dissolution method Methods 0.000 claims description 16
- 239000002131 composite material Substances 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 6
- RZJQYRCNDBMIAG-UHFFFAOYSA-N [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] Chemical class [Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Zn].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn].[Sn] RZJQYRCNDBMIAG-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 230000006698 induction Effects 0.000 claims description 5
- 239000006104 solid solution Substances 0.000 claims description 5
- 238000010894 electron beam technology Methods 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 238000005191 phase separation Methods 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 3
- 238000007733 ion plating Methods 0.000 claims description 3
- 238000004093 laser heating Methods 0.000 claims description 3
- 238000004544 sputter deposition Methods 0.000 claims description 3
- 238000001771 vacuum deposition Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000009826 distribution Methods 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 20
- 239000007787 solid Substances 0.000 abstract description 3
- 238000002844 melting Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract description 2
- 238000010314 arc-melting process Methods 0.000 abstract 1
- 229910052756 noble gas Inorganic materials 0.000 abstract 1
- 238000007738 vacuum evaporation Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000446 fuel Substances 0.000 description 10
- 229910001257 Nb alloy Inorganic materials 0.000 description 9
- 230000005540 biological transmission Effects 0.000 description 9
- 230000000149 penetrating effect Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
- 238000010494 dissociation reaction Methods 0.000 description 4
- 230000005593 dissociations Effects 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 230000006798 recombination Effects 0.000 description 4
- 238000005215 recombination Methods 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- 229910001868 water Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 229910001316 Ag alloy Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- -1 for example Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000008261 resistance mechanism Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 238000000550 scanning electron microscopy energy dispersive X-ray spectroscopy Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
- C22C27/02—Alloys based on vanadium, niobium, or tantalum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14008—Inserting articles into the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0049—Inorganic membrane manufacture by evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0074—Inorganic membrane manufacture from melts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0221—Group 4 or 5 metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02231—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02232—Nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
- C01B3/505—Membranes containing palladium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/20—Specific permeability or cut-off range
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
- B65G47/00—Article or material-handling devices associated with conveyors; Methods employing such devices
- B65G47/22—Devices influencing the relative position or the attitude of articles during transit by conveyors
- B65G47/26—Devices influencing the relative position or the attitude of articles during transit by conveyors arranging the articles, e.g. varying spacing between individual articles
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0687—Reactant purification by the use of membranes or filters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/05—Methods of making filter
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Combustion & Propulsion (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004039994A JP4363633B2 (ja) | 2004-02-17 | 2004-02-17 | 水素分離・精製用複相合金及びその作製方法、並びに水素分離・精製用金属膜及びその作製方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200529920A true TW200529920A (en) | 2005-09-16 |
| TWI351308B TWI351308B (de) | 2011-11-01 |
Family
ID=34709081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW094103235A TW200529920A (en) | 2004-02-17 | 2005-02-02 | Multiphase alloy and metal membrane for hydrogen separation-purification and methods for preparing the alloy and the metal membrane |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7468093B2 (de) |
| EP (1) | EP1566457B9 (de) |
| JP (1) | JP4363633B2 (de) |
| KR (1) | KR101290942B1 (de) |
| CN (1) | CN100420624C (de) |
| DE (1) | DE602005009586D1 (de) |
| TW (1) | TW200529920A (de) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4953337B2 (ja) * | 2005-03-28 | 2012-06-13 | 日立金属株式会社 | 水素分離・精製用複相合金 |
| JP4577775B2 (ja) * | 2005-03-28 | 2010-11-10 | 日立金属株式会社 | 水素分離・精製用複相合金の製造方法 |
| JP4860969B2 (ja) * | 2005-09-14 | 2012-01-25 | 株式会社日本製鋼所 | 水素透過合金およびその製造方法 |
| JP5000115B2 (ja) * | 2005-09-26 | 2012-08-15 | 株式会社日本製鋼所 | 水素透過合金 |
| JP4953279B2 (ja) * | 2006-03-08 | 2012-06-13 | 三菱マテリアル株式会社 | すぐれた水素透過分離性能を発揮する水素透過分離薄膜 |
| WO2007105594A1 (ja) | 2006-03-08 | 2007-09-20 | Mitsubishi Materials Corporation | 水素透過分離薄膜 |
| JP4953278B2 (ja) * | 2006-03-08 | 2012-06-13 | 三菱マテリアル株式会社 | すぐれた水素透過分離性能を発揮する水素透過分離薄膜 |
| JP5463557B2 (ja) * | 2006-09-08 | 2014-04-09 | 国立大学法人北見工業大学 | 複相型水素透過合金およびその製造方法 |
| JP4742269B2 (ja) * | 2006-09-08 | 2011-08-10 | 国立大学法人北見工業大学 | 複相水素透過合金の製造方法および複相水素透過合金 |
| JP2008068231A (ja) * | 2006-09-15 | 2008-03-27 | Kitami Institute Of Technology | 水素透過膜およびその製造方法 |
| JP5039968B2 (ja) * | 2006-09-19 | 2012-10-03 | 国立大学法人北見工業大学 | 結晶質複相水素透過合金および水素透過合金膜 |
| WO2008111516A1 (ja) | 2007-03-09 | 2008-09-18 | Hitachi Metals, Ltd. | 水素透過合金、並びに水素透過膜及びその製造方法 |
| JP5549205B2 (ja) * | 2008-12-04 | 2014-07-16 | 日立金属株式会社 | 水素分離合金、水素分離合金圧延形成用素材、水素分離合金の製造方法、および水素分離装置 |
| CN101805843B (zh) * | 2010-04-16 | 2011-11-16 | 中国石油大学(北京) | 一种NbTi/TiNi记忆合金复合材料及其制备方法 |
| EP2578710A4 (de) | 2010-05-31 | 2016-10-05 | Hitachi Metals Ltd | Wasserstofftrennungslegierung und herstellungsverfahren dafür |
| WO2013039092A1 (ja) * | 2011-09-13 | 2013-03-21 | 日立金属株式会社 | 水素分離装置及びその運転方法 |
| US9073007B2 (en) | 2012-02-15 | 2015-07-07 | Samsung Electronics Co., Ltd. | Separation membrane, hydrogen separation membrane including the separation membrane, and hydrogen purifier including the hydrogen separation membrane |
| US8900345B2 (en) | 2012-03-19 | 2014-12-02 | Samsung Electronics Co., Ltd. | Separation membrane, hydrogen separation membrane including the separation membrane, and device including the hydrogen separation membrane |
| RU2521382C1 (ru) * | 2012-11-13 | 2014-06-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный университет телекоммуникаций им. проф. М.А. Бонч-Бруевича" | Способ изготовления мембраны для выделения водорода из газовых смесей |
| CN105132749A (zh) * | 2015-09-11 | 2015-12-09 | 中国工程物理研究院机械制造工艺研究所 | 一种NiTiNb形状记忆合金及其制备方法 |
| KR102535227B1 (ko) | 2021-08-24 | 2023-05-26 | 주식회사 더이엔 | 수소 정제용 산소 제거 촉매제 및 이를 포함하는 수소 정제 장치 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3211193C1 (de) * | 1982-03-26 | 1983-10-13 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Nicht poroese Wasserstoffdiffusionsmembran |
| US4728580A (en) * | 1985-03-29 | 1988-03-01 | The Standard Oil Company | Amorphous metal alloy compositions for reversible hydrogen storage |
| CN1022097C (zh) * | 1989-06-16 | 1993-09-15 | 北京有色金属研究总院 | 一种纯化氢气用锆基合金 |
| KR950011630A (ko) | 1993-10-27 | 1995-05-15 | 전성원 | 전지용 타이타늄-니오븀-니켈계 수소저장합금 |
| JPH07252553A (ja) * | 1994-03-16 | 1995-10-03 | Furukawa Electric Co Ltd:The | Ｎｉ−Ｔｉ−Ｎｂ系形状記憶合金の溶解鋳造方法 |
| WO1995027092A1 (en) * | 1994-03-31 | 1995-10-12 | Besselink Petrus A | Ni-Ti-Nb ALLOY PROCESSING METHOD AND ARTICLES FORMED FROM THE ALLOY |
| JP3377640B2 (ja) | 1995-02-13 | 2003-02-17 | 三菱重工業株式会社 | 水素分離膜及びその製造方法 |
| US6461408B2 (en) * | 1995-11-06 | 2002-10-08 | Robert E. Buxbaum | Hydrogen generator |
| US6312455B2 (en) | 1997-04-25 | 2001-11-06 | Nitinol Devices & Components | Stent |
| JP2000159503A (ja) * | 1998-11-20 | 2000-06-13 | Mitsubishi Heavy Ind Ltd | Ｎｂ合金水素分離膜 |
| DE10039596C2 (de) * | 2000-08-12 | 2003-03-27 | Omg Ag & Co Kg | Geträgerte Metallmembran, Verfahren zu ihrer Herstellung und Verwendung |
| JP3837481B2 (ja) * | 2001-09-19 | 2006-10-25 | 独立行政法人物質・材料研究機構 | Ｖ−Ｎｉ合金の薄板化方法 |
| JP3801061B2 (ja) * | 2002-02-04 | 2006-07-26 | トヨタ自動車株式会社 | 水素透過膜 |
| US7001446B2 (en) * | 2002-03-05 | 2006-02-21 | Eltron Research, Inc. | Dense, layered membranes for hydrogen separation |
| JP3935851B2 (ja) * | 2002-05-20 | 2007-06-27 | 福田金属箔粉工業株式会社 | 水素分離膜及びその製造方法 |
| JP5000115B2 (ja) * | 2005-09-26 | 2012-08-15 | 株式会社日本製鋼所 | 水素透過合金 |
-
2004
- 2004-02-17 JP JP2004039994A patent/JP4363633B2/ja not_active Expired - Lifetime
-
2005
- 2005-02-02 TW TW094103235A patent/TW200529920A/zh unknown
- 2005-02-16 KR KR1020050012787A patent/KR101290942B1/ko active IP Right Grant
- 2005-02-17 CN CNB2005100083359A patent/CN100420624C/zh active Active
- 2005-02-17 DE DE602005009586T patent/DE602005009586D1/de active Active
- 2005-02-17 EP EP05405199A patent/EP1566457B9/de active Active
- 2005-02-17 US US11/059,641 patent/US7468093B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20060041998A (ko) | 2006-05-12 |
| EP1566457A1 (de) | 2005-08-24 |
| TWI351308B (de) | 2011-11-01 |
| CN1661124A (zh) | 2005-08-31 |
| EP1566457B9 (de) | 2009-08-12 |
| JP4363633B2 (ja) | 2009-11-11 |
| CN100420624C (zh) | 2008-09-24 |
| JP2005232491A (ja) | 2005-09-02 |
| US20050217480A1 (en) | 2005-10-06 |
| KR101290942B1 (ko) | 2013-07-29 |
| DE602005009586D1 (de) | 2008-10-23 |
| EP1566457B1 (de) | 2008-09-10 |
| US7468093B2 (en) | 2008-12-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW200529920A (en) | Multiphase alloy and metal membrane for hydrogen separation-purification and methods for preparing the alloy and the metal membrane | |
| Dolan et al. | Hydrogen transport through V85Ni10M5 alloy membranes | |
| JP5998022B2 (ja) | 分離膜、これを備える水素分離膜、および該水素分離膜を備える水素分離装置 | |
| Hashi et al. | Microstructure and hydrogen permeability in Nb–Ti–Co multiphase alloys | |
| JP4756450B2 (ja) | 水素分離・精製用複相合金 | |
| JP3749952B1 (ja) | 結晶質複相水素透過合金および結晶質複相水素透過合金膜 | |
| Yan et al. | Development of Nb-Ti-Co alloy for high-performance hydrogen separating membrane | |
| Endo et al. | Characterization of mechanical strength and hydrogen permeability of a PdCu alloy film prepared by one-step electroplating for hydrogen separation and membrane reactors | |
| US8900345B2 (en) | Separation membrane, hydrogen separation membrane including the separation membrane, and device including the hydrogen separation membrane | |
| JP3749953B1 (ja) | 複相水素透過合金および水素透過合金膜 | |
| Ishikawa et al. | Effects of rolling and annealing on hydrogen permeability and crystal orientation in Nb-TiNi two-phase alloys | |
| JP2007083198A (ja) | 水素透過合金およびその製造方法 | |
| JP2007077445A (ja) | 水素透過合金およびその製造方法 | |
| JP4953337B2 (ja) | 水素分離・精製用複相合金 | |
| JP4577775B2 (ja) | 水素分離・精製用複相合金の製造方法 | |
| AU2007225886A1 (en) | Hydrogen-permeable separation thin membranes | |
| JP3882089B1 (ja) | 結晶質複相水素透過合金および水素透過合金膜 | |
| JP5039968B2 (ja) | 結晶質複相水素透過合金および水素透過合金膜 | |
| Yan et al. | Microstructure and hydrogen transport behaviour of Nb5Ti58Fe35M2 alloy membranes | |
| Chin et al. | Hydrogen permeability of glass-forming Ni-Nb-Zr-Ta crystalline membranes | |
| JP4860961B2 (ja) | 水素透過合金 | |
| KR20140123218A (ko) | 수소 분리막 및 상기 수소 분리막을 포함하는 수소 분리 장치 | |
| Mazzolai et al. | Elastic energy dissipation in the palladium-silver-hydrogen (deuterium) system. II. Zener effects | |
| KR20130094259A (ko) | 분리막, 이를 포함하는 수소 분리막 및 상기 수소 분리막을 포함하는 수소 분리 장치 | |
| Pişkin | Nanoporous surface modification of 316L support materials by electrochemical dealloying |