TW200415704A - Integrated circuits with air gaps and method of making the same - Google Patents

Integrated circuits with air gaps and method of making the same Download PDF

Info

Publication number
TW200415704A
TW200415704A TW092131566A TW92131566A TW200415704A TW 200415704 A TW200415704 A TW 200415704A TW 092131566 A TW092131566 A TW 092131566A TW 92131566 A TW92131566 A TW 92131566A TW 200415704 A TW200415704 A TW 200415704A
Authority
TW
Taiwan
Prior art keywords
layer
metal wire
wire pattern
pattern
dielectric layer
Prior art date
Application number
TW092131566A
Other languages
Chinese (zh)
Other versions
TWI232496B (en
Inventor
Water Lur
David Lee
Kuang-Chih Wang
Ming-Sheng Yang
Original Assignee
United Microelectronics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32719000&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=TW200415704(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US10/295,062 external-priority patent/US6917109B2/en
Priority claimed from US10/295,080 external-priority patent/US7138329B2/en
Priority claimed from US10/295,719 external-priority patent/US7449407B2/en
Application filed by United Microelectronics Corp filed Critical United Microelectronics Corp
Publication of TW200415704A publication Critical patent/TW200415704A/en
Application granted granted Critical
Publication of TWI232496B publication Critical patent/TWI232496B/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/52Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
    • H01L23/522Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
    • H01L23/5222Capacitive arrangements or effects of, or between wiring layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/7682Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing the dielectric comprising air gaps
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/52Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
    • H01L23/522Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
    • H01L23/532Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
    • H01L23/5329Insulating materials
    • H01L23/53295Stacked insulating layers

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

An integrated circuits with air gaps is disclosed. An underlayer is formed on a substrate. A first metal pattern is formed on the underlayer. A dielectric layer is deposited on the underlayer and the first metal pattern. A second metal pattern is formed on the dielectric layer. Utilizing the first metal pattern and the second metal pattern as masks, an isotropic etch process is performed on the dielectric layer and the underlayer. A plurality of holes is formed in the dielectric layer and the remaining dielectric layer serves as supports under the second metal pattern. A chemical vapor deposition process is performed to deposit a cap layer on the second metal pattern and to seal the holes.

Description

200415704 五、發明說明(1) 【技術領域】 本發明係板供一種高效能(high performance )積體電路 (integrated circuit, 1C)結構,尤指一種具有空氣間 隔(air gap)之積體電路結構及其製作方法。本發明尤其 適用於需要高運作效能以及高積集度之邏輯丨(^或整合性 I C(例如系統整合晶片(SyStem-on一chip,S0C))領域。而 本發明形成具有空氣間隔之積體電路結構的方法則提供 半V體製造業者一可達到量產(mass pr〇duction )規模之 完整解決方案。^ ^ ^ ^ ^ ^ ^ ' 【先前技術】 $ $半,體製造技術的進步,製作於一半導體晶圓上的 半V體元件設計尺寸也持績地縮小,並已經演進女 代。然而,積體電路密度不斷地提高的結果,卻 ^成各金屬導線間的時間延遲(RC delay)問題對積雷 路作效能的影響日漸顯著,尤其當製程線寬( Hne ta Ϊ π Γϊ I α Τ ? ^ ^ °· 13^ ^ ^ ^ ^ ^ ^ 顯。寺間、遲對几件運作效能所造成的影響更為明 ί i Ϊ Ϊ線間的時間延遲可以用金屬導線的電阻值(ΙΟ斑 金屬導線間的寄生電容⑹之相乘積來表達。目前值咸(3200415704 V. Description of the invention (1) [Technical Field] The board of the present invention provides a high performance integrated circuit (1C) structure, especially an integrated circuit structure with an air gap. And how to make it. The present invention is particularly suitable for the field of logic that requires high operating performance and high integration degree (or integrated IC (such as a system integrated chip (SyStem-on-chip)). The present invention forms a product with air gaps. The circuit structure method provides a complete solution for semi-V body manufacturers that can reach mass production scale. ^ ^ ^ ^ ^ ^ ^ '[Previous technology] $$ half, the progress of body manufacturing technology, The design size of the half-V component fabricated on a semiconductor wafer has also been shrinking, and has evolved into female generations. However, the continuous increase in the density of integrated circuits has resulted in a time delay (RC between metal wires) The effect of the delay) problem on the performance of the mine road is becoming increasingly significant, especially when the process line width (Hne ta Ϊ π Γϊ I α Τ? ^ ^ ° · 13 ^ ^ ^ ^ ^ ^ ^ The effect of operating efficiency is even clearer. The time delay between i i Ϊ and 用 can be expressed by the product of the resistance of the metal wire (the product of the parasitic capacitance 斑 between the 10 metal wires. The current value is (3

第7頁 200415704Page 7 200415704

導體晶片之金 行:第一是使 第二則是降低 連線的傳輸速 屬内連線時間 用電阻值較低 各金屬導線間 度同時減少電 延遲現象主要 的金屬材料做 的寄生電容, 能消耗。 朝兩値方向進 為金屬導線, 以增加金屬内 在習知的作法中,降低各金屬導線間的寄生 主要是採用如FSG、HSQ、FLAREKt% Siu,低介m 艾)材料。這些低介電常數材料的特性需包 有低介電常數、低表面導電度(surface。丄二括 surfac^ resistivity > 1〇1Ώ )、低應力(c〇 es ’ tensile >30MPa)、優異的機械強度及化學鱼 熱穩疋性、低吸水性以及製程相容性(pr〇cess c^p^ibi 1 ity)。然而許多低介電常數材料都有嚴重的 可罪f (reliability)以及與金屬整合後產生的問題。因 此,在新世代的低介電常數材料尚未問世之前,如何以 製程技術克服時間延遲所造成的運作效能降低問題, 成為一值得探討與改進的課題。 由於空氣的理想介電常數接近於丨,因此使用空氣(Mr ,為金屬連線的絕緣物質,也是降低金屬導線間寄生 容的解決方案之一。雖然許多利甩空氣的低介電常數 锋應用於積體電路的技術已經被公佈出來,但是大部ρ 部都不具有置產價值。例如在美國專利第4 9 2 〇 6 3 9號中, Lan Y. K· Yee即揭露一種製作具有空氣間隔之積體電路的The gold line of the conductor chip: the first is to reduce the transmission speed of the connection. The internal connection time is lower. The resistance value of each metal wire is lower while reducing the electrical delay. The parasitic capacitance of the main metal material, Can consume. The metal wires are moved toward the two sides to increase the internal metal known practice. The parasitics between the metal wires is reduced. Materials such as FSG, HSQ, FLAREKt% Siu, and low-intermediate m Ai) are mainly used. The characteristics of these low dielectric constant materials need to include low dielectric constant, low surface conductivity (surface. 括 surfac ^ resistivity > 1〇1Ώ), low stress (coas' tensile > 30MPa), excellent Mechanical strength and thermal stability of chemical fish, low water absorption and process compatibility (pr〇cess c ^ p ^ ibi 1 ity). However, many low dielectric constant materials have serious reliabilities and problems with integration with metals. Therefore, before the new generation of low-dielectric-constant materials are available, how to overcome the problem of reduced operating efficiency caused by time delay with process technology has become a subject worthy of discussion and improvement. Since the ideal dielectric constant of air is close to 丨, the use of air (Mr), which is an insulating material for metal wiring, is also one of the solutions to reduce the parasitic capacitance between metal wires. Although many low dielectric constant applications that use air The technology of integrated circuits has been announced, but most of the ρ parts have no property value. For example, in US Patent No. 4 922 06 39, Lan Y. K. Yee disclosed a method of making air Spaced product circuit

200415704 五、發明說明(3) 方法,其作法是先利用光阻作為金屬内連線間的暫時介 電層,待完成金屬内連線之製作後,再利用溶劑去除部 份、甚至所有的光阻,而於金屬内連線間形成大量的空 氣間隔。這種作法會使得金屬内連線幾乎完全被架空, 而無法獲得足夠的支撐’容易造成積體電路受到機械力 而損壞。 此外,美國專利第6 1 3 0 1 5 1號揭露一種形成空氣間隔於金 屬内連線間的矽氧層内的方法,其作法是先形成矽氧層 以及一氮矽層於金屬層上,然後經由一微影(photo 1 i thogr aphy )製程於氮石夕層上定義出複數個開口,再進 行一蝕刻製程沿著前述之開口依序蝕刻砍氧層及氮矽層 或僅蝕刻矽氧層,以形成空氣間隔於矽氧層内。 美國專利第5949 1 43號則揭露一種形成空氣間隔於金屬内 連線間的方法,其作法是先形成一雙鑲嵌金屬連線於介 電層中’然後再沈積一姓刻終止層(e t c h s t ο p 1 a y e r )於 金展連線及介電層之上,伹裸露出部份的介電層,最後 進行一蝕刻製程完全地去除未被蝕刻終止層覆蓋之介電 層,以於各該金屬連線以及蝕刻終止層之間形成空氣間 隔。其它諸如美國專利案號5 3 24683、6 077767、6 08 382 1 與54 0 786 0等,也都分別揭露各式於金屬内連線間形成空 氣間隔的方法,在此不多贅述。200415704 V. Description of the invention (3) The method is to use photoresist as a temporary dielectric layer between the metal interconnects. After the metal interconnects are completed, some or even all of the light is removed by using a solvent. Resistance, and a large amount of air space is formed between the metal interconnects. This method will cause the metal interconnects to be almost completely overhead, and failing to obtain sufficient support ’will easily cause the integrated circuit to be damaged by mechanical forces. In addition, U.S. Patent No. 6 1 3 0 1 51 discloses a method of forming a silicon oxide layer with air spaced between metal interconnects. The method is to first form a silicon oxide layer and a silicon nitrogen layer on the metal layer. Then, a plurality of openings are defined on the nitrogen stone layer through a photolithography (photo 1 thogr aphy) process, and then an etching process is performed to sequentially etch the oxygen cutting layer and the nitrogen silicon layer or the silicon oxide only along the foregoing openings. Layer to form an air space within the silicon oxide layer. U.S. Patent No. 5,949,43 discloses a method for forming an air gap between metal interconnects. The method is to first form a double damascene metal link in a dielectric layer, and then deposit an etch stop layer (etchst ο p 1 ayer) on the Jinzhan connection and the dielectric layer, exposing a part of the dielectric layer, and finally performing an etching process to completely remove the dielectric layer not covered by the etching stopper layer for each metal connection An air gap is formed between the etch stop layers. Other methods, such as U.S. Patent Nos. 5 3 24683, 6 077767, 6 08 382 1 and 54 0 786 0, also disclose various methods for forming an air gap between metal interconnects, which are not described in detail here.

第9頁 200415704 五、發明說明(4) 然而,上述這些習知技術除了製程過於複雜,難以整合 之外,同時也面臨一些可靠度問題,例如金屬内連線無 法獲得足夠的支撐。本發明則可以提供一完整的解決方 案,以解決習知技術無法突破之瓶頸,可達到一量產規 模。 【内容】 本發明之主要目的在提供一種高操作效能之積體電路結 構及其製作方法。 本發明之另一目的在提供一種具有空氣間隔以及足夠支 撐之積體電路結構及其製作方法,以於金屬内連線間製 作大量的空氣間隔,進而達到減少金屬内連線的時間延 遲之功效。 依據本發明之目的,一種同時具有大量空氣間隔以及使 内連線金屬線路具備足夠支撐之高性能積體電路結構首 先被揭露出來。該積體電路結構包含有一第一層金屬導 線圖案,形成於一底層上;一第二層金屬導線圖案,形 成於該第一層金屬導線圖案上方;一支撐結構,形成於 該第一層金屬導線圖案以及談第二層金屬導線圖案之 間,用來支撐該第二層金屬導線圖案,其中該支撐結構 包含有一經過非等向性餘刻之介電層;以及由一蓋層所Page 9 200415704 V. Description of the invention (4) However, in addition to the above-mentioned conventional technologies, which are too complicated and difficult to integrate, they also face some reliability issues, such as the inability of metal interconnects to obtain sufficient support. The present invention can provide a complete solution to solve the bottleneck that the conventional technology cannot break through and reach a mass production scale. [Content] The main object of the present invention is to provide a high-efficiency integrated circuit structure and a manufacturing method thereof. Another object of the present invention is to provide an integrated circuit structure having an air gap and sufficient support and a manufacturing method thereof, so as to produce a large amount of air gaps between metal interconnects, thereby achieving the effect of reducing the time delay of the metal interconnects. . In accordance with the purpose of the present invention, a high-performance integrated circuit structure having both a large amount of air separation and sufficient support for the interconnected metal lines is first exposed. The integrated circuit structure includes a first layer of metal wire pattern formed on a bottom layer; a second layer of metal wire pattern formed on the first layer of metal wire pattern; a support structure formed on the first layer of metal Between the wire pattern and the second layer of metal wire pattern is used to support the second layer of metal wire pattern, wherein the supporting structure includes a dielectric layer subjected to anisotropic etching; and a cover layer

第10頁 200415704Page 10 200415704

形成於該第二層金屬導線圖案 形成之複數個空氣間隔 之間。 本發明同時揭露一種製作上 在本發明的最佳實施例中, 一底層,並於該底層上形成 著於第一層金屬導線圖案以 於4介電層上形成一第二層 一層金屬導線圖案以及第二 遮罩’非等向性姓刻部份之 成複數個凹槽,同時使剩餘 線圖案的支撐結構。最後進 程’以於各該凹槽表面以及 一蓋層,並封蓋各該凹槽, 述高性能積體電路之方法。 該方法首先於一基底上形成 一第一層金屬導線圖案。接 及底層上形成一介電層,並 金屬導線圖案。隨後利用第 層金屬導線圖案作為一钱刻 該介電層以及該底層,以开< 的介電層構成第二層金屬‘ 行一化學氣相沈積(Cvd)製 第二層金屬導線圖案上沈产 形成複數個空氣間隔。 貝 _ 由於本發明利用金屬層圖案、或用於定義金屬層圖案 光阻層作為蝕刻遮旱,來對金屬層圖案下方之介電層' 逸 行一等向性钱刻及一非等向性钕刻,以於金屬内連綠間 形成複數値空氣間隔,進而達到減少金屬内連線的時間 延遲之功效。此外,利用本發明方法所形成的積體電路 結構具有使金屬内連線或的足夠支撐之介電層架構,可 以提高積體電路的可靠度。 【實施方法】Formed between the plurality of air spaces formed by the second layer of metal wire pattern. The invention also discloses a manufacturing method. In the preferred embodiment of the present invention, a bottom layer is formed on the bottom layer, and a first layer of metal wire pattern is formed on the bottom layer to form a second layer of metal wire pattern on the 4 dielectric layer. And a plurality of grooves of the second mask 'non-isotropic engraved part, while supporting the remaining line pattern support structure. The final process is to describe the method of a high-performance integrated circuit by covering each groove surface and a cover layer and covering each groove. The method first forms a first layer of metal wire patterns on a substrate. A dielectric layer is formed on the bottom layer, and a metal wire pattern is formed. The second metal wire pattern is then used to engrav the dielectric layer and the bottom layer, and a second metal layer is formed with a dielectric layer of < and a second metal wire pattern made of chemical vapor deposition (Cvd) is formed. Shen Chen formed a number of air gaps. _ As the present invention uses the metal layer pattern or the photoresist layer used to define the metal layer pattern as an etch mask, the dielectric layer under the metal layer pattern can be escaped by an isotropic coin and an anisotropy Neodymium engraving, in order to form a plurality of radon air spaces between the metal interconnected with the green, thereby achieving the effect of reducing the time delay of the metal interconnect. In addition, the integrated circuit structure formed by using the method of the present invention has a dielectric layer structure with sufficient support for metal interconnects or the like, which can improve the reliability of the integrated circuit. 【method of execution】

200415704200415704

本發明之結構 請參考圖一,圖一為本發明較佳實施例中具有空氣間隔 (a i r g a ρ )或空氣懸隔(a i r b r i d g e )之積體電路結構之剖 面示意圖。如圖一所示,半導體晶片1〇包含有一基底 1 1,可以為一單晶矽基底或其它半導體基底。在基底i丄 的表面上可以包含有已經製作完成之半導體元件,例如 記憶體單元(memory cell)、M0S電晶體、電阻或電容等 等。由於這些元件並非本發明之重點,因此並未顯示在 圖示之中。底層1 2形成於基底丨丨之上,其中底層丨2可以 為單一介電層所構成,或由多層介電層所構成。三層金 屬圖案層(Ml、M2及M3)、各金屬插塞24a以及26a以及介 電層2 4、2 6以及2 8形成於底層1 2之上,構成一層疊堆積 之金屬内速線架構。此處’金屬圖案層(Μ1、μ 2及Μ 3 )係 指定義於同一層的金蜃導線圖案。定義金屬導線圖案 (Μ1、Μ 2及Μ 3 )以及金屬插塞2 4 a以及2 6 a可以利用傳統的 金屬濺鍍以及蝕刻技術,介電層2 4、2 6以及2 8則可以利 用 < 般.的化學氣相沈積或旋轉塗佈方式形成。 在圖一中,空氣間隔22a以及22b形成於金屬圖案層M2之 間,並向下延伸至介電層24,甚至更向下延伸至底層12 中。空氣間隔23a以及23b則形成於金屬圖案層M3之間, 並向下延伸至介電層26。其中空氣間隔22a以及2 2b係由 介電層2 6所包覆形成,並且在空氣間隔2 2 b頂部具有一突Structure of the present invention Please refer to FIG. 1. FIG. 1 is a schematic cross-sectional view of a integrated circuit structure having an air gap (a i r g a ρ) or an air suspension (a i r b r d g e) in a preferred embodiment of the present invention. As shown in FIG. 1, the semiconductor wafer 10 includes a substrate 11, which may be a single crystal silicon substrate or other semiconductor substrates. The surface of the substrate i 丄 may include semiconductor devices that have been fabricated, such as memory cells, MOS transistors, resistors, or capacitors. Since these elements are not the focus of the invention, they are not shown in the illustration. The bottom layer 12 is formed on the substrate, and the bottom layer 2 may be formed of a single dielectric layer, or may be formed of a plurality of dielectric layers. Three metal pattern layers (Ml, M2, and M3), metal plugs 24a and 26a, and dielectric layers 24, 26, and 28 are formed on the bottom layer 12 to form a stacked metal inner speed line structure. . Here, the 'metal pattern layer (M1, µ2, and M3) is a gold-alloy wire pattern defined in the same layer. The metal wire patterns (M1, M2, and M3) and metal plugs 2 4 a and 2 6 a can be defined by traditional metal sputtering and etching techniques, and the dielectric layers 2 4, 2 6, and 2 8 can be obtained by using < Normally formed by chemical vapor deposition or spin coating. In FIG. 1, air gaps 22a and 22b are formed between the metal pattern layer M2, and extend downward to the dielectric layer 24, and even extend downward to the bottom layer 12. The air gaps 23 a and 23 b are formed between the metal pattern layers M3 and extend downward to the dielectric layer 26. The air gaps 22a and 2 2b are formed by covering the dielectric layer 26, and a protrusion is formed on the top of the air gap 2 2b.

第12頁 200415704 五、發明說明(7) ---- 懸(overhang)# p曰,· _ 声28所勺罗5 閉結構。空氣間隔23a以及23b係由介電 二能,^彳f >成。空氣間隔22a與空氣間隔23a呈現連通 列y 杏由於形成空氣間隔2 3 a的過程中’非等向性名虫 ^ ^ > 由介電層2 6所包覆的空氣間隔2 2 a。在本發明 之八^貝&例中’被挖穿的空氣間隔2 2 a可以利用介電層 28再^^封閉~起來,而形成獨立的兩個空氣間隔22a以及 2 3a。這可以藉由調整沈積介電層28時的階梯覆蓋(step coverage)程度來達到。 實施例一 請參考圖二至圖六,圖二至圖六為依據本發明具有空氣 間隔之積體電路結構的製作方法示意圖。如圖二所示, 丰導^晶片1 0包含有一基底丨丨及一底層j 2位於基底j k 上。第一層金羼圖案1 3可以經由濺鍍、微影及蝕刻等程 序形成於底層1 2之上。接著於第一層金屬圖案丨3與底層 12上沈積一介電層14,然後經由微影、蝕刻、沈積及化 學機械研磨(CMP)等製程,再於介電層14之内製作金屬插 塞13a。隨後形成一金屬層15於介電層.14及金屬插塞13a 之上,並於金属層1 5表面形成一經過定義之光阻層1 6。 光阻層1 6於金屬層1 5上定義出一第二層金屬圖案。 接著如圖三所示,利用光阻層1 6為蝕刻遮罩對金屬層丄5 進行餘刻,以於介電層1 4及金屬插塞1 3 a上方形成一第二 層金屬圖案1 7,並藉由金屬插塞1 3 a作為接觸插塞(v i aPage 12 200415704 V. Description of the invention (7) ---- Overhang # p Yue, · _ Acoustic 28 Solu 5 closed structure. The air gaps 23a and 23b are made of a dielectric dual energy, ^ 彳 f >. The air gap 22a is in communication with the air gap 23a. In the process of forming the air gap 2 3 a, the anisotropic name ^ ^ > The air gap 2 2 a covered with the dielectric layer 2 6. In the eighth example of the present invention, the air gap 2 2 a which has been cut through can be closed again with the dielectric layer 28 to form two independent air gaps 22 a and 2 3 a. This can be achieved by adjusting the degree of step coverage when the dielectric layer 28 is deposited. Embodiment 1 Please refer to FIGS. 2 to 6. FIGS. 2 to 6 are schematic diagrams of a method for fabricating an integrated circuit structure with an air gap according to the present invention. As shown in FIG. 2, the wafer 100 includes a substrate and a bottom layer j 2 on the substrate j k. The first layer of gold pattern 13 may be formed on the bottom layer 12 by sputtering, lithography, and etching processes. Next, a dielectric layer 14 is deposited on the first layer of metal pattern 3 and the bottom layer 12, and then a metal plug is formed in the dielectric layer 14 through processes such as photolithography, etching, deposition, and chemical mechanical polishing (CMP). 13a. Subsequently, a metal layer 15 is formed on the dielectric layer 14 and the metal plug 13a, and a defined photoresist layer 16 is formed on the surface of the metal layer 15. The photoresist layer 16 defines a second metal pattern on the metal layer 15. Next, as shown in FIG. 3, the photoresist layer 16 is used as an etching mask to etch the metal layer 丄 5 to form a second metal pattern 17 on the dielectric layer 14 and the metal plug 1 3a. , And use the metal plug 1 3 a as the contact plug (via

第13頁 200415704 五、發明說明(8) plug)與第一層金屬圖案13電連接。隨後去除光阻層16。 第一金屬層圖案13與第二層金屬圖案17可以由鋁金屬、 鋁銅合金或銅金屬所構成。金屬插塞13a可以由鎢(W)、 鈦/氮化鈦(T i / T i N )所構成。介電層1 4的組成可以是二氧 化矽、氟矽玻璃(f luorinated silicate glass, FSG)、 或其他利用電漿加強化學氣相沈積法(plasma-enhanced chemical vapor deposition, PECVD)或高密度電漿化學 氣相沈積法(high-density plasma chemical vapor deposition,HDPCVD)所形成之介電層。 需強調的是,本發明之具有空氣間隔之積體電路結構亦 可應用於銅金屬内連線結構中。此時,上述之第一層金 屬圖案1 3、金屬插塞1 3 a及第二層金屬圖案1 7亦可利用雙 鑲喪(d u a 1 d a m a s c e n e )製程形成於介電層之中。雙鑲喪 製程為習知該項技藝者所熟知之技術,因此不再贅述。 習知該項技藝者應可參考本發明而將本發明輕易地應用 在銅製程上。 如圖四所示’以第二層金屬圖案1 7作為钱刻遮罩,進行 一非等向性(an isotropic)蝕刻製程,垂直向下去除一預 疋珠度未被第二層金屬圖案1 7覆蓋之介電層1 4,以形成 複數個凹槽1 8於介電層1 4之内。其中,藉由控制蝕刻的 時間(time-mode)可以適當地調整延伸至底層丨2中的凹槽 深度,但此一凹槽深度以不影響元件的電性表現為原 曰Page 13 200415704 V. Description of the invention (8) plug) is electrically connected to the first layer of metal pattern 13. The photoresist layer 16 is subsequently removed. The first metal layer pattern 13 and the second metal pattern 17 may be made of aluminum metal, aluminum copper alloy, or copper metal. The metal plug 13a may be composed of tungsten (W), titanium / titanium nitride (T i / T i N). The composition of the dielectric layer 14 can be silicon dioxide, fluorinated silicate glass (FSG), or other plasma-enhanced chemical vapor deposition (PECVD) or high-density A dielectric layer formed by high-density plasma chemical vapor deposition (HDPCVD). It should be emphasized that the integrated circuit structure with air separation of the present invention can also be applied to copper metal interconnect structure. At this time, the above-mentioned first layer metal pattern 1 3, metal plug 13a and second layer metal pattern 17 may also be formed in the dielectric layer by a dual damascene (d u a 1 d a m a s c ene) process. The double inlay funeral process is a technique well known to those skilled in the art, so it will not be repeated here. Those skilled in the art should refer to the present invention and easily apply the present invention to the copper process. As shown in FIG. 4 ', the second layer of metal pattern 17 is used as a mask for money engraving, and an isotropic etching process is performed, and a pre-sphericity is not removed. The dielectric layer 14 covered by 7 forms a plurality of grooves 18 within the dielectric layer 14. Among them, by controlling the time-mode of etching, the depth of the groove extending into the bottom layer 2 can be appropriately adjusted, but the depth of this groove is not to affect the electrical performance of the device.

200415704200415704

則0 接著如圖五所示,對凹槽丨8内的介電層丨4進行一等向性 (i sotropi c)乾蝕刻或濕蝕刻製程,以進一步地擴大凹样 1 8之面積’形成一底切輪廓(undercut profile )於第一 層金屬圖案1 7之下。需注意的是,前述之該等向性敍刻 製程係為一選擇性的步驟,亦即該等向性蝕刻製程亦可 省略不進行,另一方面,進行該等向性蝕刻製程的主要 目的乃是選擇性地擴大凹槽1 8之面積,因此只部份移除 位於第二層鲞屬圖案1 7下之介電層1 4。用於支撐第二層 金屬圖案1 7的支撐結構包含有介電層1 4及金屬插塞1 3 a。 如圖五以及圖六所示,接著進行一化學氣相沈積(CVD)製 程,於凹槽1 8及第二層金屬導線圖案1 7之表面沈積一蓋 層(cap layer)19,並封蓋住凹槽18而形成複數個空氣間 隔18a。值得注意的是,在沈積蓋層19時,須盡量經由調 整化學氣相沈積的製程參數而讓蓋層19於第.二層金屬導 線圖案1 7的角落部份形成突懸(overhang),以快速地將 凹槽1 8封蓋住,進而減少蓋層1 9沈積入凹槽1 8内的情 實施例二 請參閱圖七與圖八,圖七與圖八為本發明之另〆實施例 的製程方法示意圖。其中,圖七係延續圖二的製释步Then, as shown in FIG. 5, the dielectric layer 丨 4 in the groove 丨 8 is subjected to an isotropic dry etching or wet etching process to further expand the area of the concave sample 18. An undercut profile is under the first metal pattern 17. It should be noted that the aforementioned isotropic etching process is an optional step, that is, the isotropic etching process may be omitted and not performed. On the other hand, the main purpose of performing the isotropic etching process is However, the area of the grooves 18 is selectively enlarged, so the dielectric layer 14 under the second metal pattern 17 is only partially removed. The supporting structure for supporting the second metal pattern 17 includes a dielectric layer 14 and a metal plug 13a. As shown in FIG. 5 and FIG. 6, a chemical vapor deposition (CVD) process is then performed, and a cap layer 19 is deposited on the surface of the groove 18 and the second metal wire pattern 17, and then capped. The grooves 18 are held to form a plurality of air gaps 18a. It is worth noting that, when the cover layer 19 is deposited, it is necessary to make the cover layer 19 overhang at the corner portion of the second layer metal wire pattern 17 by adjusting the process parameters of chemical vapor deposition as much as possible. Quickly cover the groove 18, thereby reducing the deposition of the cover layer 19 into the groove 18. Embodiment 2 Please refer to FIG. 7 and FIG. 8. FIG. 7 and FIG. 8 show another embodiment of the present invention. Schematic of the process method. Among them, Figure 7 is a continuation of the steps shown in Figure 2.

200415704 五、發明說明(10) 驟,經過曝光、顯影及蝕刻等製程,於介電層1 4及金屬 插塞13a上形成一第二層金屬圖案17,並且不移除用於定 義第二層金屬圖案1 7的光阻層1 6。如圖八所示,本發明 方法可以光阻層16作為姓刻遮罩’依序進行圖四與圖五 所示之非等向性蝕刻及等向性蝕刻製程,在蝕刻金屬層 1 5之後隨即於介電層1 4内姓刻形成複數個凹槽1 g,並凹 槽18形成一底切輪廓(undercut profile)於第二層金屬 圖案1 7之下。也就是說,在完成第二層金屬圖案丨7之 後,隨即調整蝕刻氣體的成份,以同時(in —situ)餘刻介 電層1 4。最後才去除光阻層1 6,並進行圖六所示之化學 氣相沈積(CVD)製程,於凹槽18及第二層金屬導線圖案17 之表面沈積一蓋層( cap 1 ay e r ) 19,封蓋住凹槽1 8而开多成 複數個空氣間隔18a。 實施例三 依據本發明所揭露於圖四、圖五與圖八所示之製作空氣 間隔ISa的製程方法,亦可實施於多重金屬内連線製程的 任二層^屬圖案層或每一層金屬圖案層。請參閱圖九, 連續做完三層金屬圖案層(MV、M2及M3)以及各金屬插塞 13a之後,再利用最上面的金屬圖案層M3作為蝕刻遮罩, 氕利ϋ屬f案層M2、金屬圖案層Ml作為餘刻停止層, 以進行 非專向性|虫刻,而於多重金屬内連線間製作大 1的二氣凹槽18。此外,如圖十所示,本發明可在底層 1 2中加入阻絕層(s t op 1 ay er ) 1 2a,如此一來便可避免200415704 V. Description of the invention (10) Step: After exposure, development, and etching processes, a second metal pattern 17 is formed on the dielectric layer 14 and the metal plug 13a, and the second layer is not removed to define the second layer. Photoresist layer 16 of metal pattern 17. As shown in FIG. 8, the method of the present invention can sequentially perform the anisotropic etching and isotropic etching processes shown in FIG. 4 and FIG. 5 using the photoresist layer 16 as a mask of the last name. After the metal layer 15 is etched, Then, a plurality of grooves 1 g are formed in the dielectric layer 14, and the groove 18 forms an undercut profile under the second layer metal pattern 17. That is, after the second metal pattern 7 is completed, the composition of the etching gas is then adjusted to etch the dielectric layer 14 in-situ at the same time. Finally, the photoresist layer 16 is removed, and a chemical vapor deposition (CVD) process shown in FIG. 6 is performed, and a cap layer (cap 1 ay er) 19 is deposited on the surface of the groove 18 and the second metal wire pattern 17 , Cover the groove 18 and open a plurality of air intervals 18a. Embodiment 3 According to the present invention, the manufacturing method of the air gap ISa shown in FIGS. 4, 5 and 8 can be implemented in any two layers of the multi-metal interconnection process. It is a pattern layer or each layer of metal. Pattern layer. Please refer to FIG. 9, after three consecutive metal pattern layers (MV, M2, and M3) and each metal plug 13a are successively made, the uppermost metal pattern layer M3 is used as an etching mask, which belongs to the f-case layer M2. And the metal pattern layer M1 is used as a stop layer for non-specificity to carry out non-specificity | insect engraving, and a large 1 two-air groove 18 is made between the multiple metal interconnects. In addition, as shown in FIG. 10, in the present invention, a barrier layer (s t op 1 ay er) 1 2a can be added to the bottom layer 12 so that it can be avoided.

200415704 五、發明說明(π) 過度蝕刻,而破壞底層1 2下的元件。 實施例四 為了避免發生當如圖十中第二層金屬圖案17的導線間空 隙過大,以至於不論如何調整化學氣相沈積製程的製程 參數,蓋層1 9皆會沈積入凹槽1 8之内,因而發生空氣間 隔1 8a之體積減少的情況,可以在金屬導線間空隙較大之 區域上形成虛設圖案(dummy pattern)。請參閱圖十一至 圖十四,圖十一至圖十四為於導線間空隙過大的金屬内 連線製作空氣間隔的示意圖。首先如圖十一所示,當第 二層金屬圖案1 7的導線間空隙過大,本發明可適當地加 入虛設圖案(dummy pattern)l 7澈過大的導線間空隙中 的介電層1 4之上。其中,虛設圖案1 7 a的形成方法可在第 二層金屬圖案17之光罩的佈局(layout)中加入複數個虛 設圖案,使第二層金屠圖案17與虛設圖案17a同時形成^ 介電層1 4之上,藉此縮小第二層金屬圖案17的導線間空、 隙。接著再依序進行圖四至圖六所示之非等向性鍅刻、 等向性钱刻及北學氣相沈積製程,以於介電層]4内形成 複數個空氣間隔1 8a,如圖十二所示。 如圖十三所示,當第二層金屬圖案丨7的導線間空隙較大 時,本發明之方法也可在形成第二層金屬圖案17之後, 先沈積一薄膜層(未顯示)於第二層金屬圖案丨7之上,再 利用一蝕刻製程以於第二層金屬圖案丨7的側邊形成侧壁200415704 V. Description of the invention (π) Excessive etching will damage the components under the bottom layer 12. Embodiment 4 In order to prevent the gap between the wires in the second layer metal pattern 17 shown in FIG. In this case, the volume of the air gap 18a decreases, and a dummy pattern can be formed in a region with a large gap between the metal wires. Please refer to Fig. 11 to Fig. 14. Fig. 11 to Fig. 14 are schematic diagrams for making air gaps on metal inner wires with excessively large gaps between the wires. Firstly, as shown in FIG. 11, when the space between the wires of the second metal pattern 17 is too large, the present invention can appropriately add a dummy pattern 14 to the dielectric layer 14 in the space between the wires that is too large. on. Wherein, the method of forming the dummy pattern 17 a can add a plurality of dummy patterns to the layout of the mask of the second layer of the metal pattern 17, so that the second layer of the gold pattern 17 and the dummy pattern 17 a form a dielectric at the same time ^ Dielectric Above the layer 14, the space and gap between the wires of the second metal pattern 17 are reduced. Then sequentially perform the anisotropic engraving, isotropic coin engraving, and Beixue vapor deposition processes shown in Figs. 4 to 6 in order to form a plurality of air spaces 1 8a in the dielectric layer] 4 as shown in the figure. Twelve. As shown in FIG. 13, when the space between the wires of the second metal pattern 7 is large, the method of the present invention can also deposit a thin film layer (not shown) on the first layer after forming the second metal pattern 17. On top of the two-layer metal pattern 丨 7, an etching process is used to form a sidewall on the side of the second-layer metal pattern 丨 7

第17頁 200415704 五、發明說明(12) 子(spacer) 17b。其中,形成側壁子i7b的方法為習知該 項技藝者所熟知’因此不再贅述。由於側壁子1 7 b的形 成,因而縮小了導線間空隙。接著再依序進行圖三至^圖 五所示之非等向性姓刻、等向性蝕刻及化學氣相沈積製 程,以於介電層14内形成複數個空氣間隔i8a。 、 如圖 大, 後, 金屬 金屬 二層 進行 於未 然後 程, 十四 本發 再利 圖案 圖案 金屬 圖四 被光 移除 以於 所示 明之 用一 17之 17, 圖案 與圖 阻層 光阻 介電 ,當第 方法亦 光阻層 上,而 或利用 17間形 五所示 2 0覆蓋 層20, 層14内 二層金屬圖案 可於形成完第 2 0覆蓋於導線 僅裸露出導線 光阻層2 0而於 成至少一個虛 之非專向性钱 之介電層1 4内 並進行圖六所 形成複數個空 1 7的導線間空隙過 二層金屬圖案1 7之 間空隙較大的第二層 間空隙較小的第二^ 導線間空隙過大的第 設圖案。接著再依序 刻、專向性姓刻,以 形成複數偭凹槽18。 示之化學氣相沈積製 氣間隔18a。 相較於習知的方法,本發明的特點乃是直接利用金屬導 線圖案、或用於定義金屬導線圖案之光阻層作為蝕刻遮 罩,來對金屬導線圖案下方之介電層進行一等向性蝕刻 及一非等向性蝕刻,以於金屬内連線間形成複數個空氣 間隔,進而達到減少金屬内連線的時間延遲之功效。在 每一金屬導線的正下方皆有一層間介電層(i nt er 1 ay er dielectric)使金屬内連線獲得足夠的支撐。本發明方法Page 17 200415704 V. Description of the invention (12) Spacer 17b. Among them, the method of forming the side wall i7b is well-known to those skilled in the art ', so it will not be described again. Due to the formation of the side walls 17b, the space between the leads is reduced. Then, the anisotropic last name engraving, isotropic etching, and chemical vapor deposition processes shown in FIGS. 3 to 5 are sequentially performed to form a plurality of air gaps i8a in the dielectric layer 14. As shown in the figure, the second layer of metal and metal is carried forward. Fourteen copies of the pattern metal pattern are removed by light. As shown in the figure, 17-17 are used. Electricity, when the first method is also on the photoresist layer, or using the 20 cover layer 20 shown in the shape of the 17 space, two metal patterns in the layer 14 can be formed after the 20th cover is formed on the wire, and only the photoresist layer of the wire is exposed. 2 0 in the dielectric layer 14 forming at least one virtual non-specific money and performing a plurality of voids 17 between the wires formed in FIG. 6 through the two-layer metal pattern 17 The second pattern with a small gap between the two layers of the second ^ leads is too large. Then, the engraved and specific surnames are engraved in order to form a plurality of troughs 18. The CVD gas-making interval 18a is shown. Compared with the conventional method, the present invention is characterized by directly using the metal wire pattern or the photoresist layer for defining the metal wire pattern as an etching mask to perform an isotropic treatment of the dielectric layer under the metal wire pattern. Anisotropic etching and an anisotropic etching are used to form a plurality of air spaces between the metal interconnects, thereby achieving the effect of reducing the time delay of the metal interconnects. There is an interlayer dielectric (i nt 1 ay er dielectric) directly underneath each metal wire, so that the metal interconnects have sufficient support. Method of the invention

第18頁 200415704 五、發明說明(13) 所形成之空氣間隔可以隨著每一層金屬導線圖案的定義 同時製作,或在完成數層金屬導線圖案之後以各層的金 屬導線圖案為蝕刻遮罩進行一次的蝕刻,以在積體電路 中形成大量的空氣間隔,而又同時能夠使各層金屬導線 圖案底下皆可獲得介電層足夠的支撐。 以上所述僅為本發明之較佳實施例,凡依本發明申請專 利範圍所做之均等變化與修飾,皆應屬本發明專利之涵 蓋範圍。 章節結束Page 18 200415704 V. Description of the invention (13) The air gap formed can be made at the same time as the definition of each layer of metal wire pattern, or after several layers of metal wire pattern are completed, the metal wire pattern of each layer is used as an etching mask once. Etching to form a large number of air gaps in the integrated circuit, and at the same time, sufficient support of the dielectric layer can be obtained under each layer of metal wire pattern. The above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications made in accordance with the scope of the patent application for the present invention shall fall within the scope of the patent of the present invention. End of chapter

第19頁 200415704 圖式簡單說明 圖式之簡單說明 積 作的 隔 之 製大 懸隔 。。的過 氣 間 圖圖路隙 空。氣 意意電空 或圖空 示示體間 隔意有 法法積線 間示具 方方之導 氣面中 程程隔於 空剖例 製製間成 有之施 的的氣形 具構實 二三空係 中結佳。例例有隔 例路較圖施施具間 施電之意實實作氣 實體明示明明製空 佳積發法發發為此 較之本方本本四而 明 e為作為為十, 發d六製八十圖圖 •1 本 Γ圖的圖圖至意。 為至路與與一示内 一ir二電七九十法域 a 圖圖體圖圖圖方區 圖式之符號說明 10 半 導 體 晶 片 11 基 底 12 底 層 13 第 一 層 金 13a 金 屬 插 塞 14 介 電 層 15 第 二 層 金 屬 16 光 阻 層 17 第 二 層 金 屬圖案 17a 虛 設 圖 案 17b 侧 壁 子 18 孔 隙 18a 空 氣 間 隔 19 蓋 層 20 光 阻 層 22a 空 氣 間 隔 2 2 b 空 氣 間 隔 23a 空 氣 間 隔 23b 空 氣 間 隔 24 介 電 層 第20頁 200415704Page 19 200415704 Simple illustration of the drawing Simple illustration of the drawing Large gap of the product. . The air gap in the graph is empty. The air of mind, mind, and air, or the space of the figure, shows the space between the lines of the law, the square, and the air plane. The medium-range distance is separated from the air shape by the air-conditioning system. The knot is good. For example, there are two examples: the road is compared with the plan, the intention is to implement electricity, the entity is expressly stated that the system of air quality and accumulation is issued for this purpose. Make eighty graphs • 1 This graph of Γ is perfect. For the road to the road, the first and second tiers are shown in the diagram. Figures, diagrams, diagrams, diagrams, and symbols in the diagrams. 10 semiconductor wafers 11 substrates 12 bottom layers 13 first layers of gold 13a metal plugs 14 dielectric layers 15 Second layer of metal 16 Photoresist layer 17 Second layer of metal pattern 17a Dummy pattern 17b Side wall 18 Pore 18a Air gap 19 Cover layer 20 Photoresist layer 22a Air gap 2 2 b Air gap 23a Air gap 23b Air gap 24 Electrical layer

第21頁Page 21

Claims (1)

200415704 六、申請專利範圍 1. 一種具有空氣間隔之積體電路結構,包含有: 一基底,其上具有一底層; 一第一層金屬導線圖案,形成於該底層上; 一第二層金屬導線圖案,形成於該第一層金屬導線圖案 上方; 一支撐結構,形成於該第一層金屬導線圖案以及該第二 層金屬導線圖案之間,用來支撐該第二層金屬導線圖 案,其中該支撐結構包含有一經過等向性蝕刻之介電 層;以及 由一蓋層所形成之複數個空氣間隔,形成於該第二層金 屬導線圖案之間。 2. 如申請專利範圍第1項之積體電路結構,其中該基底為 一石夕基底。 3. 如申請專利範圍第1項之積體電路結構,其中該第一層 金屬導線圖案以及該第二層金屬導線圖案係皆由銅所構 成。 4. 如申請專利範圍第1項之積體電路結構,其中該第一層 金屬導線圖案以及該第二層金屬導線圖案皆包含有铭金 屬。 5. 如申請專利範圍第1項之積體電路結構,其中該支撐結200415704 VI. Scope of patent application 1. An integrated circuit structure with an air gap, comprising: a substrate having a bottom layer thereon; a first layer of metal wire pattern formed on the bottom layer; a second layer of metal wire A pattern formed on the first layer of metal wire pattern; a support structure formed between the first layer of metal wire pattern and the second layer of metal wire pattern to support the second layer of metal wire pattern, wherein the The support structure includes a dielectric layer subjected to isotropic etching; and a plurality of air gaps formed by a capping layer, formed between the second metal wire patterns. 2. For the integrated circuit structure of item 1 in the scope of patent application, wherein the substrate is a shixi substrate. 3. For the integrated circuit structure of item 1 of the patent application scope, wherein the first layer of metal wire pattern and the second layer of metal wire pattern are made of copper. 4. For example, the integrated circuit structure of the first scope of the patent application, wherein the first layer of metal wire pattern and the second layer of metal wire pattern both include metal. 5. If the integrated circuit structure of item 1 of the patent application scope, wherein the supporting junction 第22頁 200415704 六、申請專利範圍 構另包含有至少一電連接該第一層金屬導線圖案以及該 第二層金屬導線圖案之接觸插塞(v i a p 1 ug )。 6 ·如申請專利範圍第1項之積體電路結構,其中該蓋層係 利用電聚加強化學氣相沈積法(plasma-enhanced CVD, PECVD)或高密度電漿化學氣相沈積法(h igh dens i ty p 1 a s m a C V D,H D P C V D )形成。 7.如申請專利範圍第1項之積體電路結構,其中該第二層 金屬導線圖案之支撐結構具有一底切輪廓。 8·-種具有空氣間隔之積體電t結^ 一第一層金屬導線圖案,形成於一底層上; 一第二層金屬導線圖案,形成於該第一層金屬導線圖案 上:方 一支撐結構,形成於該第, 層金屬導線圖案之間,用來支撐該第二層金屬導^ 案;以及 V 由一蓋層所形成之複數個空氣間隔’形成於該第二A 屬導線圖案之間。 9 ·如申請專利範圍第8項之積體電路結構,其中該支撐結 構包含有至少一電連接該第一層金展 二層金屬導線圖案之接觸插塞(V i a p l ug)。Page 22 200415704 6. Scope of patent application The structure further includes at least one contact plug (v i a p 1 ug) electrically connecting the first layer of metal wire pattern and the second layer of metal wire pattern. 6 · The integrated circuit structure according to item 1 of the patent application scope, wherein the capping layer is formed by plasma-enhanced CVD (PECVD) or high-density plasma chemical vapor deposition (h igh) dens i ty p 1 asma CVD (HDPCVD). 7. The integrated circuit structure according to item 1 of the patent application scope, wherein the support structure of the second layer of metal wire pattern has an undercut profile. 8 · -Integrated electric junction with air gap ^ A first layer of metal wire pattern is formed on a bottom layer; a second layer of metal wire pattern is formed on the first layer of metal wire pattern: a square support A structure formed between the first and second metal wire patterns to support the second metal wire pattern; and V is formed by a plurality of air gaps formed by a cover layer on the second A metal wire pattern between. 9. The integrated circuit structure according to item 8 of the scope of patent application, wherein the support structure includes at least one contact plug (V i a p ug) electrically connected to the first layer of gold metal layer and the second layer of metal wire pattern. 第23頁 200415704 六、申請專利範圍 1 0 .如申請專利範圍第8項之積體電路結構,其中該支撐 結構包含有一經過等向性#刻之介電層。 1 1.如申請專利範圍第8項之積體電路結構,其中該第二 層金屬導線圖案包含有一虛設圖案(dummy pattern),使 縮小該第二層金屬導線圖案之金屬導線間空隙。 1 2 .如申請專利範圍第8項之積體電路結構,其中該第二 層金屬導線圖案包含有一側壁子形成於該第二層金屬導 線圖案之各側壁上。 1 3.如申請專利範圍第8項之積體電路結構,其中該蓋層 係利用電漿加強化學氣相沈積法(PECVD)或高密度電漿化 學氣相沈積法(HDPCVD)形成。 14.一種具有空氣間隔之積體電路的製作方法,該製作方 法包含有: 提供一基底,其上具有一底層; 於該底層上形成一第一層金屬導線圖案; 於該第一層金屬導線圖案以及該底層上形成一介電層; 於該介電層上形成一第二層金屬導線圖案; 利用該第二層金屬導線圖案以及讓第二層金屬導線圖案 作為一蝕刻遮罩,非等向性蝕刻該介電層,以形成複數Page 23 200415704 VI. Scope of patent application 10. For example, the integrated circuit structure of item 8 of the scope of patent application, wherein the support structure includes a dielectric layer that has been subjected to isotropic #etching. 1 1. The integrated circuit structure according to item 8 of the scope of patent application, wherein the second layer of metal wire patterns includes a dummy pattern to reduce the gap between the metal wires of the second layer of metal wire patterns. 12. The integrated circuit structure according to item 8 of the scope of patent application, wherein the second-layer metal wire pattern includes a sidewall formed on each side wall of the second-layer metal wire pattern. 1 3. The integrated circuit structure according to item 8 of the patent application scope, wherein the cap layer is formed by plasma enhanced chemical vapor deposition (PECVD) or high density plasma chemical vapor deposition (HDPCVD). 14. A manufacturing method of an integrated circuit with air gaps, the manufacturing method comprising: providing a substrate having a bottom layer thereon; forming a first layer of metal wire pattern on the bottom layer; and forming the first layer of metal wire on the bottom layer Forming a dielectric layer on the pattern and the bottom layer; forming a second metal wire pattern on the dielectric layer; using the second metal wire pattern and using the second metal wire pattern as an etch mask, etc. The dielectric layer is etched to form a plurality 第24頁 200415704 六、申請專利範圍 個凹槽,同時使剩餘的該介電層構成該第二層金屬導線 圖案之支撐結構;以及 進行一化學氣相沈積(CVD)製程,以於該凹槽表面以及該 第二層金屬導線圖案上沈積一蓋層,以封蓋該凹槽,形 成複數個空氣間隔。 為 底 基 亥 =° 中 其 法 方 作 製 之 項 4 IX 第 圍 範 利 專 請 申 如 底 基 矽 第 圍 範 利 專 請 申 如 於 嵌 鑲 係 案 圖 線 導 金 層 一 第 該 中 其 法 方 作 製L-o之Γ ®曰 項 4 底 I該 第 圍 範 利 專 請 申 如 於 嵌 鑲 係 案 圖 線 導 屬 金 層 二 第 該 中 其 法 方 ο 作 上 製 的層 5介 I該 第 圍 範 利 專 請 申 如 第 該 及 以 案 圖 線 導ο· 8 IX 0^^ 成 金- 層 I 第 該 中 其 法 方 作 製 .的 項 4 構 所 銅 由 皆 係 案 圖 線 導 金 層 第 圍 範 利 專 請 申 如 第 該 及 以 案 圖 線 導。 9 1 屬屬 法 方 作 製 的 項 4 金 層 一 第 該 中 其 金 鋁 有 含 包 比白 係 案 圖 線 導 屬 金 層 法 方 作 製 該 中 其 法 方 作 製 的 項 4 11 第 圍 範 利 專 請 申 如· ο 2Page 24 200415704 6. Apply for a patent for a groove, and at the same time make the remaining dielectric layer constitute the supporting structure of the second metal wire pattern; and perform a chemical vapor deposition (CVD) process for the groove A cover layer is deposited on the surface and the second metal wire pattern to cover the groove and form a plurality of air spaces. For the base method of the base method = °, the method made by the French party 4 IX Fan Fan special application, such as the foundation silicon Fan Fan special application, such as in the inlay system diagram line gold guide layer The system of Lo Γ ® of item 4 is called the bottom 4 and the first fan is requested to apply for the gold layer in the inlay system. The second method is to make the upper layer. Please refer to the application and guideline of the plan drawing. 8 IX 0 ^^ Gold-Layer I Item 4 of its legal system. The copper structure of the structure is the guideline of the plan guideline gold layer. Li is requested to apply as directed and guide to the plan. 9 1 Items that are made by the French party 4 Items that are made of gold and aluminum, including gold and aluminum, which are included in the case series, are drawn by the gold layer, and items that are made by the French party 4 11 Please apply as ο 2 第25頁 200415704 六、申請專利範圍 於非等向性蝕刻該介電層以及該底層之後,另包含有等 向性蝕刻該第二層金屬導線圖案之支撐結構,以形成一 底切輪靡,擴大該凹槽之面積。 2 1. —種具有空氣間隔之積體電路的製作方法,包含有: 提供一基底,其上具有一底層; 於該底層上形成一介電層; 於該介電層上形成一金屬導線圖案;以及 利用該金屬導線圖案作為一蝕刻遮罩,蝕刻該介電層至 一預定深度,以於該介電層中形成複數個凹槽,同時使 剩餘的該介電層構成該金屬導線圖案之支撐結構。 2 2.如申請專利範圍第2 1項之製作方法,其中該金屬導線 圖案於該介電層上構成複數個導線間空隙(interl ine spac i ng),且該複數個凹槽係形成於該複數個導線間空 隙内之該介電層中。 2 3.如申請專利範圍第21項的製作方法,其中蝕刻該介電 層的方法係利用一非等向性姓刻技術。 24.如申請專利範圍第21項的製作方法,其中該金屬導線 圖案係鑲嵌於該介電層上。 2 5 .如申請專利範圍第2 1項的製作方法,其中該製作方法Page 25 200415704 6. The scope of the patent application includes anisotropic etching of the second layer of metal wire pattern after the dielectric layer and the bottom layer to form an undercut pattern. Enlarge the area of the groove. 2 1. A method for manufacturing an integrated circuit with an air gap, comprising: providing a substrate having a bottom layer thereon; forming a dielectric layer on the bottom layer; forming a metal wire pattern on the dielectric layer And using the metal wire pattern as an etching mask to etch the dielectric layer to a predetermined depth so as to form a plurality of grooves in the dielectric layer, while making the remaining dielectric layer constitute the metal wire pattern. supporting structure. 2 2. The production method according to item 21 of the scope of patent application, wherein the metal wire pattern forms a plurality of interl ine space gaps on the dielectric layer, and the plurality of grooves are formed in the dielectric layer. In the dielectric layer in the space between the plurality of wires. 2 3. The manufacturing method according to item 21 of the patent application scope, wherein the method of etching the dielectric layer uses an anisotropic lasting technique. 24. The method of claim 21, wherein the metal wire pattern is embedded on the dielectric layer. 25. The manufacturing method according to item 21 of the scope of patent application, wherein the manufacturing method 第26頁 200415704 六、申請專利範圍 於蝕刻該介電層之後,另包含有下列步驟: 等向性(i s 〇 t r ο p i c )钱刻該金屬導線圖案之支#結構,以 形成一底切輪靡(undercut profile),擴大該凹槽之面 積;以及 進行一化學氣相沈積(chemical vapor deposition, CVD)製程,以於該凹槽表面以及該金屬導線圖案上沈積 一蓋層(c a p 1 a y e r ),同時封蓋該凹槽,形成複數個空氣 間隔。Page 26 200415704 6. The scope of applying for a patent after etching the dielectric layer further includes the following steps: Isotropic (is 〇tr ο pic) money engraving the support #structure of the metal wire pattern to form an undercut wheel Undercut profile, expanding the area of the groove; and performing a chemical vapor deposition (CVD) process to deposit a cap layer (cap 1 ayer) on the groove surface and the metal wire pattern At the same time, the groove is covered to form a plurality of air gaps. 第27頁Page 27
TW092131566A 2002-11-15 2003-11-11 Integrated circuits with air gaps and method of making same TWI232496B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/295,062 US6917109B2 (en) 2002-11-15 2002-11-15 Air gap structure and formation method for reducing undesired capacitive coupling between interconnects in an integrated circuit device
US10/295,080 US7138329B2 (en) 2002-11-15 2002-11-15 Air gap for tungsten/aluminum plug applications
US10/295,719 US7449407B2 (en) 2002-11-15 2002-11-15 Air gap for dual damascene applications

Publications (2)

Publication Number Publication Date
TW200415704A true TW200415704A (en) 2004-08-16
TWI232496B TWI232496B (en) 2005-05-11

Family

ID=32719000

Family Applications (1)

Application Number Title Priority Date Filing Date
TW092131566A TWI232496B (en) 2002-11-15 2003-11-11 Integrated circuits with air gaps and method of making same

Country Status (3)

Country Link
JP (1) JP2004172620A (en)
CN (1) CN100372113C (en)
TW (1) TWI232496B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI786612B (en) * 2020-05-11 2022-12-11 南亞科技股份有限公司 Semiconductor device structure with air gap structure and method for preparing the same

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6838354B2 (en) * 2002-12-20 2005-01-04 Freescale Semiconductor, Inc. Method for forming a passivation layer for air gap formation
DE102005039323B4 (en) * 2005-08-19 2009-09-03 Infineon Technologies Ag Guideway arrangement and associated production method
US20080265377A1 (en) * 2007-04-30 2008-10-30 International Business Machines Corporation Air gap with selective pinchoff using an anti-nucleation layer
US7879683B2 (en) * 2007-10-09 2011-02-01 Applied Materials, Inc. Methods and apparatus of creating airgap in dielectric layers for the reduction of RC delay
US8436473B2 (en) * 2009-05-06 2013-05-07 Taiwan Semiconductor Manufacturing Company, Ltd. Integrated circuits including air gaps around interconnect structures, and fabrication methods thereof
US8587121B2 (en) * 2010-03-24 2013-11-19 International Business Machines Corporation Backside dummy plugs for 3D integration
CN102891100B (en) * 2011-07-22 2015-04-29 中芯国际集成电路制造(上海)有限公司 Shallow-trench isolation structure and formation method thereof
CN102376684B (en) * 2011-11-25 2016-04-06 上海集成电路研发中心有限公司 Copper interconnection structure and preparation method thereof
JP5696679B2 (en) * 2012-03-23 2015-04-08 富士通株式会社 Semiconductor device
CN104425230A (en) * 2013-09-09 2015-03-18 中芯国际集成电路制造(上海)有限公司 Side wall structure and formation method thereof
CN104362172B (en) * 2014-10-15 2018-09-11 杰华特微电子(杭州)有限公司 Semiconductor chip structure with end ring and its manufacturing method
US9653348B1 (en) * 2015-12-30 2017-05-16 Taiwan Semiconductor Manufacturing Co., Ltd. Semiconductor device and manufacturing method thereof
US10896888B2 (en) * 2018-03-15 2021-01-19 Microchip Technology Incorporated Integrated circuit (IC) device including a force mitigation system for reducing under-pad damage caused by wire bond
US10818541B2 (en) * 2018-12-27 2020-10-27 Nanya Technology Corporation Semiconductor structure

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0393635B1 (en) * 1989-04-21 1997-09-03 Nec Corporation Semiconductor device having multi-level wirings
GB2247986A (en) * 1990-09-12 1992-03-18 Marconi Gec Ltd Reducing interconnection capacitance in integrated circuits
JP2555940B2 (en) * 1993-07-27 1996-11-20 日本電気株式会社 Semiconductor device and manufacturing method thereof
JPH07326670A (en) * 1994-05-31 1995-12-12 Texas Instr Inc <Ti> Semiconductor integrated circuit device
JPH08148556A (en) * 1994-11-16 1996-06-07 Sony Corp Semiconductor device and its manufacture
CN1204867A (en) * 1997-06-20 1999-01-13 日本电气株式会社 Semiconductor device, and method of manufacturing same
US6184121B1 (en) * 1997-07-10 2001-02-06 International Business Machines Corporation Chip interconnect wiring structure with low dielectric constant insulator and methods for fabricating the same
JP2000058549A (en) * 1998-08-04 2000-02-25 Nec Corp Formation of integrated circuit wiring
JP2000269327A (en) * 1999-03-15 2000-09-29 Toshiba Corp Semiconductor device and manufacture thereof
US6413852B1 (en) * 2000-08-31 2002-07-02 International Business Machines Corporation Method of forming multilevel interconnect structure containing air gaps including utilizing both sacrificial and placeholder material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI786612B (en) * 2020-05-11 2022-12-11 南亞科技股份有限公司 Semiconductor device structure with air gap structure and method for preparing the same

Also Published As

Publication number Publication date
CN100372113C (en) 2008-02-27
JP2004172620A (en) 2004-06-17
TWI232496B (en) 2005-05-11
CN1501492A (en) 2004-06-02

Similar Documents

Publication Publication Date Title
TW201011861A (en) Method for fabricating integrated circuit
TW200415704A (en) Integrated circuits with air gaps and method of making the same
JPH09246242A (en) Semiconductor device and manufacture of the same
JP2003282573A (en) Bonding pad structure for semiconductor device and manufacturing method therefor
US7781892B2 (en) Interconnect structure and method of fabricating same
TW200807684A (en) Mim capacitor and method of making same
JP2011009581A (en) Process of producing semiconductor device and the semiconductor device
EP1743366A2 (en) Wiring structure for integrated circuit with reduced intralevel capacitance
US6278147B1 (en) On-chip decoupling capacitor with bottom hardmask
KR20000026588A (en) Semiconductor device having contact holes and method for manufacturing the same
TW200910520A (en) Method for forming contact in semiconductor device
TWI276184B (en) Methods for producing electrode and semiconductor device
TWI690003B (en) Method for forming a dual damascene interconnect structure
JP3526289B2 (en) Method for manufacturing semiconductor device
TWI223393B (en) Method of filling bit line contact via
US8563432B2 (en) Method for forming through silicon via structure
JP4587604B2 (en) Manufacturing method of semiconductor device
TW468223B (en) Method for improving the planarization of inter layer dielectric layer
WO2023093676A1 (en) Beol top via wirings with dual damascene via and super via redundancy
US8664743B1 (en) Air-gap formation in interconnect structures
JP2004235586A (en) Semiconductor device
JPH11186274A (en) Dual damascene technique
US20230099965A1 (en) Airgap isolation for back-end-of-the-line semiconductor interconnect structure with top via
KR100696774B1 (en) A method for forming a capacitor of a semiconductor device
JP2003273246A (en) Semiconductor memory device and method of manufacturing the same

Legal Events

Date Code Title Description
MK4A Expiration of patent term of an invention patent