TWI232496B - Integrated circuits with air gaps and method of making same - Google Patents
Integrated circuits with air gaps and method of making same Download PDFInfo
- Publication number
- TWI232496B TWI232496B TW092131566A TW92131566A TWI232496B TW I232496 B TWI232496 B TW I232496B TW 092131566 A TW092131566 A TW 092131566A TW 92131566 A TW92131566 A TW 92131566A TW I232496 B TWI232496 B TW I232496B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- metal wire
- wire pattern
- patent application
- dielectric layer
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- 229910052751 metal Inorganic materials 0.000 claims abstract description 143
- 239000002184 metal Substances 0.000 claims abstract description 143
- 238000000034 method Methods 0.000 claims abstract description 60
- 230000008569 process Effects 0.000 claims abstract description 29
- 238000005229 chemical vapour deposition Methods 0.000 claims abstract description 17
- 239000000758 substrate Substances 0.000 claims abstract description 17
- 238000005530 etching Methods 0.000 claims description 27
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 25
- 239000010931 gold Substances 0.000 claims description 24
- 229910052737 gold Inorganic materials 0.000 claims description 24
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- QUCZBHXJAUTYHE-UHFFFAOYSA-N gold Chemical group [Au].[Au] QUCZBHXJAUTYHE-UHFFFAOYSA-N 0.000 claims 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 154
- 229920002120 photoresistant polymer Polymers 0.000 description 13
- 238000010586 diagram Methods 0.000 description 10
- 230000005611 electricity Effects 0.000 description 10
- 239000004065 semiconductor Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000001459 lithography Methods 0.000 description 3
- 230000003071 parasitic effect Effects 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241001327708 Coriaria sarmentosa Species 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- CCAZWUJBLXKBAY-ULZPOIKGSA-N Tutin Chemical compound C([C@]12[C@@H]3O[C@@H]3[C@@]3(O)[C@H]4C(=O)O[C@@H]([C@H]([C@]32C)O)[C@H]4C(=C)C)O1 CCAZWUJBLXKBAY-ULZPOIKGSA-N 0.000 description 1
- UMVBXBACMIOFDO-UHFFFAOYSA-N [N].[Si] Chemical compound [N].[Si] UMVBXBACMIOFDO-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000007775 late Effects 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/5222—Capacitive arrangements or effects of, or between wiring layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/7682—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing the dielectric comprising air gaps
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/5329—Insulating materials
- H01L23/53295—Stacked insulating layers
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Abstract
Description
1232496 案號92131566 年月日 修正 五、發明說明(1) 【技術領域】 本發明係提供一種高效能(high performance)積體電路 (integrated circuit, 1C)結構,尤指一種具有空氣間 隔(air gap)之積體電路結構及其製作方法。本發明尤其 適用於需要高運作效能以及高積集度之邏輯I C或整合性 I C (例如系統整合晶片(s y s t e in - ο η - c h i p, S 0 C ))領域。而 本發明形成具有空氣間隔之積體電路結構的方法則提供 半導體製造業者一可達到量產(mass production)規模之 完整解決方案。 【先前技術1232496 Case No. 92131566 Amended on May 5, V. Description of the Invention (1) [Technical Field] The present invention provides a high-performance integrated circuit (1C) structure, especially an air gap ) Integrated circuit structure and manufacturing method thereof. The invention is particularly applicable to the field of logic IC or integrated IC (such as system integrated chip (s y s t e in-ο η-c h i p, S 0 C)) which requires high operation performance and high accumulation degree. The method for forming an integrated circuit structure with an air gap provided by the present invention provides a complete solution for a semiconductor manufacturer to reach a mass production scale. [Prior art
I 隨著半導體製造技術的進步,製作於一半導體晶圓上的 半導體元件設計尺寸也持續地縮小,並已經演進到深次 微米世代。然而,積體電路密度不斷地提高的結果,卻 造成各金屬導線間的時間延遲(RC delay )問題對積體電 路的運作效能的影響曰漸顯著,尤其當製程線寬(1 i n e w i d t h )降到0 . 1 5微米以下,甚至0 · 1 3微米以下的半導體 製程時,時間延遲對元件運作效能所造成的影響更為明 顯0 達 導,主 來、 屬»象金J現 用目遲 以U延 可}間 遲(C時 延容線 間電連 時生内 的寄屬 間的金 線間之 連線片 内導晶 屬屬體 金金導 的 兩 朝 與半進 R)少 R C向 1(減 1 值 方 阻r個With the advancement of semiconductor manufacturing technology, the design size of semiconductor elements fabricated on a semiconductor wafer has continued to shrink, and has evolved to the deep sub-micron generation. However, as a result of the increasing density of integrated circuits, the problem of the RC delay between the metal wires has a significant impact on the operating performance of integrated circuits, especially when the process line width (1 inewidth) drops to When the semiconductor process is below 0.1 micron, and even below 0.1 micron, the effect of time delay on the operation performance of the element is more obvious. OK} Time delay (C time delay capacity line is electrically connected to the time between the host and the gold wire in the connection between the on-chip crystal genus of the metal gold and the two directions and semi-advance R) less RC to 1 ( Minus 1 square resistance r
1232496 _案號92131566 年月 a 修正_ 五、發明說明(2) 行··第一是使用電阻值較低的金屬材料做為金屬導線, 第二則是降低各金屬導線間的寄生電容,以增加金屬内 連線的傳輸速度同時減少電能消耗。 在習知的作法中,降低:各金屬導線間的寄生電容的方法 主要是採用如FSG、HSQ、FLAREKi或SiLKTM等低介電常數 (k < 3)材料。這些低介電常數材料的特性基本上需包括 有巧介電常數、低.表面導電度(surface conductance, rSiStlVity> 1〇15Ω)、低應力(compressive 埶獐—哇ei)Slle > 3〇MPa)、優異的機械強度及化學鱼1232496 _Case No. 92131566a Amendment _ V. Description of the invention (2) OK. The first is to use a metal material with a lower resistance value as the metal wire, and the second is to reduce the parasitic capacitance between the metal wires. Increasing the transmission speed of metal interconnects while reducing power consumption. In the conventional practice, the method of reducing the parasitic capacitance between metal wires is mainly to use low dielectric constant (k < 3) materials such as FSG, HSQ, FLAREKi, or SiLKTM. The characteristics of these low dielectric constant materials basically need to include smart dielectric constant, low surface conductivity (rSiStlVity > 1015Ω), and low stress (compressive 埶 獐 —wowei) Slle > 3〇MPa ), Excellent mechanical strength and chemical fish
^ ; 7Κ α A ^ ^ ^ ,i( f A compatibUuy)。然而許多 process 可靠度(reliability)以及斑屬*數材料都有嚴重的 此,在新世代的低介電常數/材屬正合後產生的問題。因 製程技術克服時間延遲所造成的ί f問世之前,如何以 成為一值得探討與改進的課題、運作效能降低問題,便 由於空氣的理想介電常數^; 7Κ α A ^ ^ ^, i (f A compatibUuy). However, many process reliability and speckle number materials have serious problems, which are caused by the new generation of low dielectric constant / material type. Before the advent of process technology to overcome the time delay, how to become a subject worthy of discussion and improvement and a decrease in operating efficiency was due to the ideal dielectric constant of air.
做為金屬連線的絕緣物質, j ’因此使用空氣(a i r 容的解決方案之一、。雖然斗,是降低金屬導線間寄生’ 性應用於積體電路的技^ α夕利用空氣的低介電常數j 卻都不具有量產價值。例 $,公佈出來,但是大部1 1^11丫.1(.丫66即揭露一種黎^國專利第4 9 2 0 6 3 9號中 方法,其作法是先利用光1且…有空氣間隔之積體電鲜 電層,待完成金屬内連線 1 =金屬内連線間的暫時: 衣作後,再利用溶劑去除^As an insulating material for metal wiring, j 'so use air (one of the solutions of air capacity. Although the bucket is to reduce the parasitics between metal wires' technology applied to integrated circuits ^ α Xi's low dielectric The electric constant j does not have the value of mass production. For example, $, published, but most of the 1 1 ^ 11 y.1 (. Y 66 is a method disclosed in Li ^ Patent No. 4 9 2 0 6 39 The method is to first use the integrated electric fresh layer of light 1 and ... with air separation, to complete the metal interconnect 1 = temporary between the metal interconnect: after the clothes are made, then use the solvent to remove ^
1232496 修正1232496 fix
_案號92131566 年 月 五、發明說明(3) 份、甚至所有的光阻,而於金屬内連線間开i成大量的空 氣間隔。這種作法會使得金屬内連線幾乎完全被架空t 而無法獲得足夠的支撐,容易造成積體電路受到機械力 而損壞。 此外,美國專利第6 1 3 0 1 5 1號揭露一種形成空氣間隔於金 屬内連線間的矽氧層内的方法,其作法是先形成矽氧層 以及一氮石夕層於金屬層上,然後經由一微影(p h 〇 t 〇 lithography)製程於氮石夕層上定義出複數個開口,再進 行一蝕刻製程沿著前述之開口依序蝕刻矽氧層及氮矽層 或僅蝕刻矽氧層,以形成空氣間隔於矽氧層内。 - 美國專利第5 9 4 9 1 4 3號則揭露一種形成空氣間隔於金屬内 連線間的方法,其作法是先形成一雙鑲嵌金屬連線於介 電層中,然後再沈積一餘刻終止層(e t c h s t ο p 1 a y e r )於 金屬連線及介電層之上,但裸露出部份的介電層,最後 進行一姓刻製程完全地去除未被钱刻終止層覆蓋之介電 層,以於各該金屬連線以及蝕刻終止層之間形成空氣間 隔。其它諸如美國專利案號5 324683、6077767、6083821 與5 4 0 7 8 6 0等,也都分別揭露各式於金屬内連線間形成空 氣間隔的方法’在此不多資述。 然而,上述這些習知技術除了製程過於複雜,難以整合 之外,同時也面臨一些可靠摩問題,例如金屬内連線無 法獲得足夠的支撐。本發明則可以提供一完整的解決方_Case No. 92131566 V. Description of the invention (3), or even all photoresistors, and a large amount of air space is formed between the metal interconnects. This method will cause the metal interconnects to be almost completely suspended without sufficient support, which may easily cause the integrated circuit to be damaged by mechanical forces. In addition, U.S. Patent No. 6 1 3 0 1 51 discloses a method for forming a silicon oxide layer with air spaced between metal interconnects. The method is to first form a silicon oxide layer and a nitrogen oxide layer on the metal layer. Then, a plurality of openings are defined on the nitrogen stone layer through a lithography process, and then an etching process is performed to sequentially etch the silicon oxide layer and the nitrogen silicon layer or the silicon only along the foregoing openings. An oxygen layer to form air spaced inside the silicon-oxygen layer. -U.S. Patent No. 5 9 4 9 1 4 3 discloses a method for forming air space between metal interconnects. The method is to first form a double damascene metal connection in the dielectric layer and then deposit it for a while. The termination layer (etchst ο p 1 ayer) is on the metal connection and the dielectric layer, but the exposed part of the dielectric layer is finally etched to remove the dielectric layer that is not covered by the termination layer. To form an air gap between each of the metal lines and the etch stop layer. Others, such as U.S. Patent Nos. 5 324683, 6077767, 6083821, and 5 4 0 7 8 60, etc., also disclose various methods for forming an air gap between metal interconnects', which are not described here. However, in addition to the above-mentioned conventional technologies, which are too complex and difficult to integrate, they also face some problems with reliable friction, such as the metal interconnects cannot obtain sufficient support. The present invention can provide a complete solution
第8頁 1232496 _案號 92131566_•年 月 曰_i±i-_ · 五、發明說明(4) 案,以解決習知技術無法突破之瓶頸,可達到一量產規 、 模。 【内容】 本發明之主要,目的在提供一種高操作效能之積體電路結 構及其製作方法。 本發明之另一目的在提供一種具有空氣間隔以及足夠支 撐之積體電路結構及其製作方法,以於金屬内連線間製 作大量的空氣間隔,進而達到減少金屬内連線的時間延- 4 遲之功效。 使首導 及構屬 以結金 隔路層 間電一 氣體第 空積一 量能有 大性含 有高包 具之構 時撐結 、同支路 種夠電 一足體 ,備積 的具該 目路。 之線來 明屬出 發金露 本線揭 據連被 依内先 形於 ,成 案形 [S11 , 線構 導結 屬撐 金支 層一 二; 第方 一上 •,案 上圖 層線 底導 一屬 於金 成層 形一 ,第 案該 圖於 線成 構 之結 案撐 圖支 線該 導中 屬其 金, 層案 二圖 第線 該導 及屬 以金 案層 圖二 線第 導該 屬# 金支 層來 一用 第, 該間 所案 層圖 蓋線 一導 由屬 及金 以層 •,二 層第 電該 介於 之成 刻形 #, 性隔 向間 等氣 非空 過個 經數 一複 有之。 含成間 包形之. 法 方 之 路 體 積 能 性 高 述 上 作 製 Mitsui 種 1 露 揭 時 同 明 發 本 1Page 8 1232496 _ Case No. 92131566_ • Year Month _i ± i-_ · V. Description of Invention (4) The case is to solve the bottleneck that the conventional technology cannot break through, and can reach a mass production specification and model. [Content] The main purpose of the present invention is to provide a high-efficiency integrated circuit structure and a manufacturing method thereof. Another object of the present invention is to provide an integrated circuit structure having an air gap and sufficient support, and a manufacturing method thereof, so as to make a large amount of air gaps between metal interconnects, thereby reducing the time delay of the metal interconnects. Late effect. Make the leader and the structure to be gold-separated, and the space between electricity and gas can be large enough to contain the structure when the structure is high, and the same branch can be charged with enough electricity. . The line of the line belongs to the starting line of the gold dew. The original line of the line was first formed in the form of the case [S11, the line structure is a branch of the gold branch 1 or 2; The gold is in layer one, the case is the figure in the line formation structure, the branch line is the gold in the guide, the layer is the second line in the line, and the guide is the gold line in the second line, the line is the guide # 金 支 层Let ’s use the first layer. The guide line of the floor plan of the room is covered by a guide and a layer of gold. • The second floor of the electricity should be between the engraved shapes. There are. Included in the form of a package. The method of the French method is highly productive. It is made on the Mitsui species 1 when it is exposed.
i 1 ii 1 i
1232496 _案號92131566 年月日 修正 五、發明說明(5) 在本發明的最佳實施例中,該方法首先於一基底上形成 一底層,並於該底層上形成一第一層金屬導線圖案。接 著於第一層金屬導線圖案以及底層上形成一介電層,並 於該介電層上形成一第二層金屬導線圖案。隨後利用第 一層金屬導線圖案以及第二層金屬導線圖案作為一蝕刻 遮罩,非等向性蝕刻部份之該介電層以及該底層,以形 成複數個凹槽,同時使剩餘的介電層構成第二層金屬導 線圖案的支撐結構。最後進行一化學氣相沈積(CVD)製 ' . 程,以於各該凹槽表面以及第二層·金屬導線圖案上沈積 一蓋層,並封蓋各該凹槽,形成複數個空氣間隔。 之·進間間路可 案層線時電, 圖電連的體構 層介内線積架 属之屬連的層 金方金内成電 義下於屬形介 定案以金所之 於圖,少法撑 用層刻減方支 或屬#到明夠 、金性達發足 案對向而本的。 圖來等進用或度 層,非,利線靠 屬罩一隔,連可 金遮及間外内的 用刻刻氣此屬路 利#餘空。金電 明為性個效使體 發作向數功有積 本層等複之具高 於阻一成遲構提 由光行形延結以 【實施方法】 » 本發明之結構 請參考圖一,圖一為本發明較佺實施例中具有空氣間隔 (a i r gap )或空氣懸隔(a i r br i dge )之積體電路結構之剖 面示意圖。如圖一所示,半導體晶片10包含有一基底1232496 _ Case No. 92131566 Amendment V. Description of the invention (5) In the preferred embodiment of the present invention, the method first forms a bottom layer on a substrate and forms a first layer of metal wire pattern on the bottom layer. . A dielectric layer is formed next to the first metal wire pattern and the bottom layer, and a second metal wire pattern is formed on the dielectric layer. Subsequently, the first layer of metal wire pattern and the second layer of metal wire pattern are used as an etch mask, and the dielectric layer and the bottom layer are anisotropically etched to form a plurality of grooves, and at the same time, the remaining dielectric The layers constitute a support structure for the second layer of metal wire patterns. Finally, a chemical vapor deposition (CVD) process is performed to deposit a capping layer on the surface of each groove and the second layer of metal wire pattern, and cover each groove to form a plurality of air spaces. Zhi · Jianjian Road can be layered when the electricity is drawn, the structure of the electric connection layer is connected to the layered layer of gold, which belongs to the layer of gold, which is in the sense of electricity. Shaofa supports the use of layers to cut the square branch or belong to ########################################################### Figure to wait for the use of the degree or not, non-profit lines are separated by a metal cover, and can be covered with gold and inside and outside with a moment of engraving this belongs to Lu Li # 余 空. Jin Dianming has a physical effect on the body and the number of layers has a higher level. The structure is higher than the resistance. The structure is delayed by light. [Implementation method] »Please refer to Figure 1 for the structure of the present invention. FIG. 1 is a schematic cross-sectional view of an integrated circuit structure having an air gap or an air gap in a comparative embodiment of the present invention. As shown in FIG. 1, the semiconductor wafer 10 includes a substrate
第10頁Page 10
1232496 ___案號 92131566_年 月 日 修正__ 五、發明說明(6) π ’可以為一單晶矽基底或其它半導體基底。在基411 的表面上可以包含有已經製作完成之半導體元件,例如 記憶體單元(m e m 〇 r y c e 1 1 )、Μ 0 S電晶體、電阻或電容等 等。由於這些元件並非本發明之重點,因此並未顯示在 圖示之中。底層1 2形成於基底1 1之上,其中底層1 2可以 為單一介電層所構成,或由多層介電層所構成。三層金 屬圖案層(ΜΙ、M2及M3)、各金屬插塞24a以及26a以及介 電層24、26以及28形成於底層12之上,構成一層疊堆積 之金屬内連線架構。此處,金屬圖案層(Ml、M2及M3)係 指定義於同一層的金屬導線圖案。定義金屬導線圖案 (Ml、M2及M3)以及金屬插塞24a以及26a可以利用傳統的 金脣濺鍍以及蝕刻技術·,介電層2 4、2 6以及2 8則可以利 用一般的化學氣相沈積或旋轉塗佈方式形成。 ' 在圖一中,空氣間隔22a以及22b形成於金屬圖案層M2之 間’並向下延伸至介電層24,甚至更向下延伸至底層12 中。空氣間隔2 3a以及2 3b則形成於金屬圖案層M3之間, 並向下延伸至介電層2 6。其中空氣間隔2 2 a以及2 2 b係由 介電層2 6所包覆形成,並且在空氣間隔2 2 b頂部具有一突 懸(overhang)封閉結構。空氣間隔23a以及23b係由介電 層28所包覆形成。空氣間隔2 2a與空氣間隔2 3a呈現連通 狀態,這是由於形成空氣間隔2 3 a的過程中,非等向性餘 刻挖穿原先由介電層2 6所包覆的空氣間隔2 2 a。在本發明 之其它實施例中,被挖穿的空氣間隔2 2a可以利用介電層 2 8再次被封閉起來,而形成獨立的兩個空氣間隔2 2 a以及1232496 ___ Case No. 92131566_Year Month Day Amendment __ V. Description of the invention (6) π ′ may be a single crystal silicon substrate or other semiconductor substrate. The surface of the substrate 411 may include a semiconductor device that has been fabricated, such as a memory unit (m e m 0 r y c e 1 1), an M 0S transistor, a resistor, or a capacitor. Since these elements are not the focus of the invention, they are not shown in the illustration. The bottom layer 12 is formed on the substrate 11, wherein the bottom layer 12 may be composed of a single dielectric layer or a plurality of dielectric layers. Three metal pattern layers (MI, M2, and M3), metal plugs 24a and 26a, and dielectric layers 24, 26, and 28 are formed on the bottom layer 12 to form a stacked metal interconnect structure. Here, the metal pattern layers (M1, M2, and M3) are metal wire patterns defined in the same layer. Define metal wire patterns (Ml, M2, and M3) and metal plugs 24a and 26a can use traditional gold lip sputtering and etching techniques. Dielectric layers 2 4, 2 6 and 28 can use general chemical vapor phase Formed by deposition or spin coating. 'In FIG. 1, the air gaps 22 a and 22 b are formed between the metal pattern layer M2 ′ and extend downward to the dielectric layer 24 and even further downward into the bottom layer 12. The air gaps 2 3a and 2 3b are formed between the metal pattern layers M3 and extend downward to the dielectric layer 26. The air gaps 2 2 a and 2 2 b are covered by a dielectric layer 26 and have an overhang closed structure on top of the air gaps 2 2 b. The air gaps 23a and 23b are formed by being covered with a dielectric layer 28. The air gap 2 2a is in a connected state with the air gap 2 3a. This is because during the formation of the air gap 2 3 a, the anisotropy cuts through the air gap 2 2 a originally covered by the dielectric layer 2 6. . In other embodiments of the present invention, the excavated air gap 2 2a can be closed again by the dielectric layer 28 to form two independent air gaps 2 2 a and
第11頁 1232496 案號 92131566_ 年 月 曰 修」 五、發明說明(7) 2 3 a。這可以藉由調整沈積介電層2 8時的階梯覆蓋(s t e p coverage )程度來達到° 實施例 請參考 間隔之 半導體 上。第 序形成 12上沈 學機械 塞1 3a 之上, 光阻層 圖二至圖六,圖二至圖六為依據本發明具有空氣 積體電路結構的製作方法示意圖。如圖二所示, 晶片10包含有一基底11及一底層12位於基底11之 一層金屬圖案1 3可以經由濺鍍、微影及蝕刻等程 於底層12之上。接著於第一層金屬圖案13與底層 積一介電層1 4,然後經由微影、蝕刻、沈積及化 研磨(CMP)等製程,再於介電層14之内製作金屬插 。隨後形成一金屬層1 5於介電層1 4及金屬插塞1 3 a 並於金屬層15表面形成一經過定義之光阻層ΐβ。-16於金屬層15上定義出一第二層金屬圖案。 接著如圖三所示’利用光阻層1 6為触刻遮罩對金屬層1 5 進行蝕刻,以於介電層14及金屬插塞i3a上方形成一第二 層金屬圖案1 7,並藉由金屬插塞1 3 a作為接觸插塞(v i a Plug)與第一層金屬圖案13電連接。隨後去除光阻層16。 第一金屬層圖案13與第二層金屬圖案17可以由鋁金屬、 紹銅合金或銅金屬所構成。金屬插塞1 3 a可以由嫣(W)、 鈦/氮化鈦(Ti/TiN)所構成。介電層14的組成可以是二氧 化石夕、氟石夕玻璃(fluorinated silicate glass,FSG)、 或其他利用電聚加強化.學氣相沈積法(plasma-enhanced chemical vapor deposition, PECVD)或高密度電漿化學Page 11 1232496 Case No. 92131566_ Year Month Revision "V. Description of the invention (7) 2 3 a. This can be achieved by adjusting the degree of step coverage when the dielectric layer 28 is deposited. For example, please refer to the spaced semiconductor. The photoresist layer is formed on the top of the mechanical plug 13a in the first order. Figs. 2 to 6 and Figs. 2 to 6 are schematic diagrams of a method for manufacturing an air circuit structure according to the present invention. As shown in FIG. 2, the wafer 10 includes a substrate 11 and a bottom layer 12. A metal pattern 13 located on the substrate 11 can be formed on the bottom layer 12 by sputtering, lithography, and etching. A dielectric layer 14 is then deposited on the first layer of metal pattern 13 and the bottom layer, and then through the processes of lithography, etching, deposition, and chemical polishing (CMP), metal inserts are formed in the dielectric layer 14. Subsequently, a metal layer 15 is formed on the dielectric layer 14 and the metal plug 1 3 a, and a defined photoresist layer ΐβ is formed on the surface of the metal layer 15. -16 defines a second metal pattern on the metal layer 15. Next, as shown in FIG. 3, the photoresist layer 16 is used as an etching mask to etch the metal layer 15 to form a second metal pattern 17 over the dielectric layer 14 and the metal plug i3a. The metal plug 1 3 a is electrically connected to the first layer metal pattern 13 as a via plug. The photoresist layer 16 is subsequently removed. The first metal layer pattern 13 and the second metal pattern 17 may be made of aluminum metal, copper alloy or copper metal. The metal plug 1 3 a may be composed of W (W) and titanium / titanium nitride (Ti / TiN). The composition of the dielectric layer 14 may be SiO 2, fluorinated silicate glass (FSG), or other enhancement using electropolymerization. Plasma-enhanced chemical vapor deposition (PECVD) or high Density plasma chemistry
第12頁 1232496 案號92131566 年月日 修正 五、發明說明(8) 氣相沈積法(high-density plasma chemical vapor deposition, HDPCVD)戶斤形成之介電層。 亦金 構層 結一 路第 電之 體述 積上 之’ 隔時 間此 氣 。 空中 有構 具結 之線 ‘明連 發内 本屬 ,金 是銅 的於 調用 強應 需可 案d為 圖嵌程 屬鑲製Page 12 1232496 Case No. 92131566 Date of Amendment V. Description of the Invention (8) A dielectric layer formed by high-density plasma chemical vapor deposition (HDPCVD). The structure of Yijin's structure has been built up in time, and it ’s time. There is a structured line in the sky. ‘Ming Lian Fa ’s internal genus, gold is copper. It ’s called on demand. Case d.
塞 *丄 frt 捅屬 金 > 3 1A 第 及丄 * 丄 frt 捅 金 > 3 1A cap and
a W 藝 技 項 該 知 習 喝, Μ介術 金於技 -之 形知 程熟 製所 e)者 雙 用 利 可 亦 7 11 案 圖 嵌。 鑲述 雙贅 。再 中不 之此層因 用 應 地 易 輕 明 發 本 將 而 明 發 本 考 參 可 應 者 藝。 技上 項程 該製 知銅 習在 ,預 槽 行一成的凹 進除形刻的原 ,去以餘中為 罩下,制2現 遮向14控^1曰表 刻直層由底性 蝕垂電藉至電 為,介,伸的 作程之中i件 7製蓋其整元 案刻覆。調響 圖蝕+::内地影 屬}案之當不 金1C圖14適以 層OP屬層X度 二tr金電可深 第so層介P槽 以ni二於de凹 ,(B第18S 一 示性被#le*-此 所向未凹im但 四等度個(t, 圖非深數間度。 如一定複時深則 接著如圖五所示,對凹槽1 8内的介電層1 4進行一等向性 (i s 〇 t r 〇 p i c )乾餘刻或濕餘刻製程,以進一步地擴大凹槽 18之面積,形成一底切輪靡(undercut profile)於第二 層金屬圖案1 7之下。需注意的是,前述之該等向性蝕刻 製程係為一選擇性的步驟,亦即該等向性蝕刻製程亦可 省略不進行,另一方面,進行該等向性蝕刻製程的主要a W Arts and technology items The knowledge of drinking, ML introduces the technique of gold in technology-Zhizhi Chengshu Institute e) The dual-use Ricoh 7 11 plan is embedded. Mosaic double redundant. This layer is not easy to use because it is easy to lightly publish the text, and to publish the text for the applicants. In the technical process, the system knows the copper habit. The pre-groove line is recessed and removed, and the rest is used as the cover. The system 2 is now hidden to 14 controls. In the process of eroding electricity to electricity, i-piece 7 covers the whole case and engraved it. Reverberation etch + :: Mainland film belongs to the case of gold 1C Figure 14 is suitable for the layer OP layer X degree two tr gold electricity can be deep so layer interlayer P groove with ni two to de concave, (B section 18S A display is # le * -this direction is not concave im but four equal degrees (t, the figure is not deep. If it is a certain time depth, then as shown in Figure 5, the media in the groove 18 The electrical layer 14 is subjected to an isotropic dry or wet etch process to further expand the area of the groove 18 to form an undercut profile on the second layer of metal. Under the pattern 17. It should be noted that the aforementioned isotropic etching process is an optional step, that is, the isotropic etching process may be omitted and not performed, and on the other hand, the isotropic process is performed. The main process of etching
第13頁 1232496 案號92131566 年月日 修正 五、發明說明(9) 目的乃是選擇性地擴大凹槽1 8之面積,因此只部份移除 位於第二層金屬圖案17下之介電層14。用於支撐第二層 金屬圖案17的支撐結構包含有介電層14及金屬插塞13a。Page 13 1232496 Case No. 92131566 Amendment Date V. Invention Description (9) The purpose is to selectively expand the area of the groove 18, so that only the dielectric layer under the second metal pattern 17 is partially removed. 14. The supporting structure for supporting the second metal pattern 17 includes a dielectric layer 14 and a metal plug 13a.
及)1 8 Γ 1 e 曹 y a 凹1 #a ,C XC 第 層 9 封, 並是 製 間 >声氣 VD一空 (C積-個 積沈數 沈面 相表 氣之 學17 化案 一 圖 行線 進導 槽 凹 住 屬蓋 金 複 成 形 而 同 由 經 量 盡 須 士V 日 9 11 層 蓋 積 沈 在 導 屬 金 層 二 第 於 9 11 層 蓋 讓 而‘ 數 參 程 的製 意的得t值" 氣 a學 8 匕 隔整 將 地情 速的 快内 以8 11 , 槽 g)凹 an入 rh積 e沈 V V 0 9 κίν 1 懸層 突蓋 成少 形減 份而. 部進 落, 角住 的蓋 7封' 11 案18 1111 槽。 線凹形 實施例二 請參閱圖七與圖八,圖七與圖八為本發明之另一實施例 的製程方法示意圖。其中,圖七係延續圖二的製程步 驟,經過曝光、顯影及蝕刻等製程,於介電層1 4及金屬 插塞13a上形成一第二層金屬圖案17,並且不移除用於定 義第二層金屬圖案1 7的光阻層1 6。如圖八所示,本發明 方法可以光阻層1 6作為蝕刻遮罩,依序進行圖四與圖五 所示之非等向性钱刻及等向性#刻製程,在#刻金屬層 1 5之後隨即於介電層1 4内蝕刻形成複數個凹槽1 8,並凹 槽18形成一底切輪廓(undercut profile)於第二層金屬 圖案17之下。也就是說,在完成第二層金屬圖案17之 後,隨即調整蝕刻氣體的成份,以同時(i η - s i t u )蝕刻介And) 1 8 Γ 1 e Caoya Concave 1 #a, C XC The first layer 9 seals, and is a system of sound &sound; VD is empty The line guide groove is recessed and covered with gold. The same amount of power is required. V Day 9 11 layer cover is deposited in the metal layer. The second layer is on the 9 11 layer cover. Get the value of "Teaching Qi" 8 daggers will quickly reduce the speed of the ground to 8 11, groove g) recessed into the rh product eVV 0 9 κίν 1 Suspension projection into a small shape reduction. Into and out of the corner, cover the cover with 7 seals, 11 cases, 18 1111 slots. Concave line Embodiment 2 Please refer to FIG. 7 and FIG. 8. FIG. 7 and FIG. 8 are schematic diagrams of a manufacturing method according to another embodiment of the present invention. Among them, FIG. 7 continues the process steps of FIG. 2. After exposure, development, and etching processes, a second layer of metal pattern 17 is formed on the dielectric layer 14 and the metal plug 13 a. Photoresist layer 16 of two-layer metal pattern 17. As shown in FIG. 8, the method of the present invention can use the photoresist layer 16 as an etching mask, and sequentially perform the anisotropic money engraving and isotropic #etching process shown in FIG. 4 and FIG. Subsequent to 15, a plurality of grooves 18 are formed in the dielectric layer 14 by etching, and the groove 18 forms an undercut profile under the second layer metal pattern 17. That is, after the second layer of metal pattern 17 is completed, the composition of the etching gas is adjusted at the same time to simultaneously (i η-s i t u)
第14頁 1232496 案號 92131566 _η 曰 修正 五、發明說明(10) 電層14。最後才去除光阻層16,並進行圖六所示之化學 氣相沈積(C V D )製程,於凹槽1 8及第二層金屬導線圖案1 7 之表面沈積一蓋層(cap layer)19,封蓋住凹槽18而形成 複數個空氣間隔1 8 a。 實施例三 依據本發明所揭露於圖四、圖五與圖八所示之製作空氣 間隔1 8 a的製程方法,亦可實施於多重金屬内連線製程的 任一層金屬圖案層或每一層金屬圖案層。請參閱圖九, 連續做完三層金屬圖案層(Ml、M2及M3)以及各金屬插塞 1 3 a之後,再利用最上面的金屬圖案層Μ 3作為蝕刻遮罩, 並利用金屬圖案層Μ 2、金屬圖案層Μ 1作為蝕刻停止層, 以進行一非等向性蝕刻,而於多重金屬内連線間製作大_ 量的空氣凹槽1 8。此外,如圖十所示,本發明可在底層 1 2中加入一阻絕層(s t ο ρ 1 a y e r ) 1 2 a,如此一來便可避免 過度蝕刻,而破壞底層1 2下的元件。 實施例四 為了避免發生當如圖十中第二層金屬圖案17的導線間空 隙過大,以至於不論如何調整化學氣相沈積製程的製程 參數,蓋層1 9皆會沈積入凹槽1 8之内,因而發生空氣間 隔1 8 a之體積減少的情況,可以在金屬導線間空隙較大之 區域上形成虛設圖案(d u mmy pattern)。請參閱圖十一至 圖十四,圖十一至圖十四為於導線間空隙過大的金屬内 連線製作空氣間隔的示意圖。首先如圖十一所示,當第Page 14 1232496 Case No. 92131566 _η Revision V. Description of the invention (10) Electrical layer 14. Finally, the photoresist layer 16 is removed, and a chemical vapor deposition (CVD) process shown in FIG. 6 is performed, and a cap layer 19 is deposited on the surface of the groove 18 and the second metal wire pattern 17. The grooves 18 are covered to form a plurality of air intervals 1 8 a. Embodiment 3 According to the present invention, the manufacturing method for manufacturing the air interval 18 a shown in FIG. 4, FIG. 5, and FIG. 8 can also be implemented in any metal pattern layer or each metal layer in the multi-metal interconnection process. Pattern layer. Referring to FIG. 9, after three consecutive metal pattern layers (M1, M2, and M3) and each metal plug 1 3 a are made, the uppermost metal pattern layer M 3 is used as an etching mask, and the metal pattern layer is used. M2, the metal pattern layer M1 is used as an etch stop layer to perform anisotropic etching, and a large number of air grooves 18 are made between the multiple metal interconnects. In addition, as shown in FIG. 10, in the present invention, a barrier layer (s t ο ρ 1 a y e r) 1 2 a can be added to the bottom layer 12, so that over-etching can be avoided and the components under the bottom layer 12 can be destroyed. Embodiment 4 In order to prevent the gap between the wires in the second layer metal pattern 17 shown in FIG. 10 from being too large, so that no matter how to adjust the process parameters of the chemical vapor deposition process, the cover layer 19 will be deposited into the groove 18 In this case, the volume of the air gap is reduced by 18 a, and a du mmy pattern can be formed on a region with a large gap between the metal wires. Please refer to Fig. 11 to Fig. 14. Fig. 11 to Fig. 14 are schematic diagrams for making air gaps on metal inner wires with excessively large gaps between the wires. First, as shown in Figure 11, when the first
_111 1 II III 111 1 11 III 画1_1_ 1 ill ill II ill ill 第15頁 1232496 _案號92131566 年 月 五、發明說明(11) 曰 修正 二層金屬圖案1 7的導線·間空隙過大,本發明可適當地加 入虛設圖案(d u m m y . p a 11 e r η ) 1 7 a於過大的導線間空隙中 的介電層14之上。其中,虛設圖案17a的形成方法可在第 二層金屬圖案17之光罩的佈局(layout)中加入複數個虛 設圖案,使第二層金屬圖案17與虛設圖案i7a同時形成於 介電層14之上,藉此縮小第二層金·屬圖案17的導線間空 隙。接著再依序進行圖四至圖六所示之非等向性餘刻、 專向性钱刻及化學氣相沈積製程’以於介電層内形成 複數個空氣間隔1 8 a,如圖十二所示。 如圖十三所示,當第二層金屬圖案1 7的導線間空隙較大. 時’本發明之方法也可在形成第二層金屬周案1 了之後, 先沈積一薄膜層(未顯示)於第二層金屬圖案1 了之上,再 利用一蝕刻製程以於第二層金屬圖案丨7的側邊形成側壁 子(spacer ) 17b。其中,形成側壁子17b的方法為習知該 項技藝者所熟知’因此不再贅述。由於側壁子1 7 b的形 成’因而細小了導線間空隙。接著再依序進行圖三至圖 五所示之非等向性蝕刻、等向性叙刻及化學氣相沈積製 程,以於介電層1 4内形成複數個空氣間隔丨。 如圖十四所示’當第一層金屬圖案1 7的導線間空隙過 大,本發明之方法亦可於形成完第二層金屬圖案17之 後,再利用一光阻層2 0覆蓋於導線間空隙較大的第二層 金屬圖案1 7之上,而僅裸露出導線間空隙較小的第二層 金屬圖案1 7 ’或利用光阻層2 〇而於導線間空隙過大的第_111 1 II III 111 1 11 III Draw 1_1_ 1 ill ill II ill ill Page 15 1232496 _ Case No. 92131566 Fifth, the description of the invention (11) Means to modify the two-layer metal pattern 17 The wires and interspaces are too large, the present invention A dummy pattern (dummy. Pa 11 er η) 1 7 a may be appropriately added on the dielectric layer 14 in the gap between the excessively large wires. Wherein, the method for forming the dummy pattern 17 a may include a plurality of dummy patterns in the layout of the mask of the second metal pattern 17, so that the second metal pattern 17 and the dummy pattern i7 a are simultaneously formed on the dielectric layer 14. As a result, the space between the wires of the second-layer metal / metal pattern 17 is reduced. Then, sequentially perform the anisotropic relief, the specific money engraving, and the chemical vapor deposition process shown in FIGS. 4 to 6 in order to form a plurality of air spaces 1 8 a in the dielectric layer, as shown in FIG. 12 As shown. As shown in FIG. 13, when the space between the wires of the second metal pattern 17 is large. The method of the present invention can also deposit a thin film layer after the second metal pattern 1 is formed (not shown) ) On the second layer of metal pattern 1, an etching process is used to form a side wall 17b on the side of the second layer of metal pattern 7. Among them, the method of forming the side wall 17b is well known to those skilled in the art ', and therefore will not be described again. Due to the formation of the side wall member 17b, the space between the wires is narrowed. Then, the anisotropic etching, isotropic engraving, and chemical vapor deposition processes shown in FIGS. 3 to 5 are sequentially performed to form a plurality of air spaces in the dielectric layer 14. As shown in FIG. 14 'When the gap between the wires of the first metal pattern 17 is too large, the method of the present invention can also cover the wires with a photoresist layer 20 after forming the second metal pattern 17 The second layer metal pattern 17 with a large gap is only exposed, and only the second layer metal pattern 17 'with a small gap between the wires is exposed or the photoresist layer 20 uses the second layer with a large gap between the wires.
第16頁 1232496 案號.92131566 __年月 修正 _ 五、發明說明(12) 二層金屬圖案1 7間形成至少一個虛設圖案。接著再依序 進行圖四與圖五所示之非等向性钱到、等向性姓刻,以 於未被光阻層20覆蓋之介電層14内形成複數個凹槽18。 然後移除光阻層2 0,並進行圖六所示之化學氣相沈積製 程,以於介電層1 4内形成複數個空氣間隔1 8 a。 -法 導遮刻氣在Γ方義金路線 屬刻蝕空。ye明定的電導 金蝕性個效la發的層體屬 用為向數功er以案各積金 利作等複之nt。圖以在層 接層一成遲(i#線後以各 直阻行形延層支導之,使 是光進間間電的屬案刻夠。 乃之層線時介夠金圖蝕能撐 點案電連的間足層線的時支 特圖介内線層得一導次同的 的線之屬連一獲每屬一又夠 明導方金内·有W著金行而足 發屬下於屬皆連隨層進,層 本金案以金方Θ以數罩隔電 ,義圖,少下屬可成遮間介 法定線刻減正金隔完刻氣得 方於導蝕到的殳間在蝕空獲 的用屬性達線h氣或為的可 知或金向而導1C空,案量皆 習、對等進屬tr之作圖大下 於案來非,金ec成製線成底 較圖,一隔一el形時導形案 相線罩及間每dl所同屬中圖Page 16 1232496 Case No. 92131566 __Year Month Amendment _ V. Description of the invention (12) At least one dummy pattern is formed between 17 two-layer metal patterns. Then, the anisotropic money arrival and the isotropic surname shown in FIG. 4 and FIG. 5 are sequentially performed, so that a plurality of grooves 18 are formed in the dielectric layer 14 not covered by the photoresist layer 20. Then, the photoresist layer 20 is removed, and a chemical vapor deposition process shown in FIG. 6 is performed to form a plurality of air spaces 18 a in the dielectric layer 14. -The method guides the obscuration gas in the Γ Fang Yijin route, which belongs to the etching space. The well-defined conductivity of the layer of the metal erosive effect la is used to calculate the power of each case, and the nt is the same. The diagram is made after the layers are connected one by one (i # line is supported by various straight resistance line extension layers to guide it, so that the belonging case of light into the electricity is enough. When the layer is lined, the gold pattern is enough to etch energy. The time line of the mesopod line of the electric company was recorded. The inner line layer got a lead of the same line. The line of the line was obtained. Each line was clear enough. There is a gold line and a foot line. The subordinates follow each layer continuously. The layered capital case is separated by gold and Θ with several masks. The meaning map, less subordinates can be used to cover the legal line and reduce the positive gold. In the eclipse, the space obtained by using the attribute reaching the line h or the known or golden direction leads to 1C space. The case size is familiar, and the equivalent mapping of tr belongs to the case. The gold ec becomes the line. The bottom is compared with the figure, and the elliptical shape of the guide wire cover and each dl are the same middle diagram.
專涵 1232496 案號92131566 年月日 修正 圖式簡單說明 圖式之簡單說明 積 作的 隔之 製大 懸隔 。。的過 氣間 圖圖路隙 空。氣 意意電空 或圖空 示示體間 隔意有 法法積線 間示具 方方之導 氣面中 程程隔於 空剖例 製製.間成 有之施 的的氣形 具構實 二三空係 中結佳。例例有隔 例路較圖施施具間 施電之意實實作氣 實體明示明明製空 佳積發法發發為此 較之本方本本四而 明e)為作為為十, 發dg六製八十圖圖 本ri圖的圖圖至意。 為b至路與與一示内 一ir二電七九十法域 圖(a圖體圖圖圖方區 圖式之符號說明 10 半 導 體 晶 片 11 基 底 12 底 層 13 第 一 層 金屬圖案 13a 金 屬 插 塞 14 介 電 層 15 第 二 層 金 屬 16 光 阻 層 17 第 二 層 金 屬圖案 17a 虛 設 圖 案 17b 側 壁 子 18 孔 隙 18a 空 氣 間 隔、 19 蓋 層 20 光 阻 層 22a 空 氣 間 隔 22b 空 氣 間 隔 23a 空 氣 間 隔 23b 空 氣 間 隔 24 介 電 層Dedicated to 1232496 Case No. 92131566 Month and Day Amendment Simple illustration of the drawing Simple illustration of the drawing Large gaps in the production system. . The air gap in Tutu is empty. The air-to-air, air-to-air, or air-to-air display of the display body interval means the method of showing the square of the air-conducting surface between the product lines. The result is good in the air department. For example, there are two examples: the road is compared with the plan, the intention is to implement electricity, the entity is expressly stated that the air quality accumulation method is issued for this purpose. Six-to-eight diagrams The diagrams of the ri diagrams are perfect. It is a map of b to lu and yi yi yi two electric seventy or ninety domains (a picture of the body of the diagram, the diagram of the square area of the symbol description 10 semiconductor wafer 11 substrate 12 bottom layer 13 first layer metal pattern 13a metal plug 14 Dielectric layer 15 Second metal 16 Photoresist layer 17 Second metal pattern 17a Dummy pattern 17b Side wall 18 Pore 18a Air gap, 19 Cover layer 20 Photoresist layer 22a Air gap 22b Air gap 23a Air gap 23b Air gap 24 Dielectric layer
第18頁 1232496 案號 92131566 年 月 曰 修正 圖式簡單說明 24a 插塞 26 介 電 層 26a 插塞 28 介 電 層 Ml 金屬 圖 案 層 M2 金 屬 圖案層 M3 金屬 圖 案 層 m· 第19頁Page 18 1232496 Case No. 92131566 Modification of the drawing Brief description of 24a plug 26 dielectric layer 26a plug 28 dielectric layer Ml metal pattern layer M2 metal pattern layer M3 metal pattern layer m · page 19
Claims (1)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/295,080 US7138329B2 (en) | 2002-11-15 | 2002-11-15 | Air gap for tungsten/aluminum plug applications |
US10/295,719 US7449407B2 (en) | 2002-11-15 | 2002-11-15 | Air gap for dual damascene applications |
US10/295,062 US6917109B2 (en) | 2002-11-15 | 2002-11-15 | Air gap structure and formation method for reducing undesired capacitive coupling between interconnects in an integrated circuit device |
Publications (2)
Publication Number | Publication Date |
---|---|
TW200415704A TW200415704A (en) | 2004-08-16 |
TWI232496B true TWI232496B (en) | 2005-05-11 |
Family
ID=32719000
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW092131566A TWI232496B (en) | 2002-11-15 | 2003-11-11 | Integrated circuits with air gaps and method of making same |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP2004172620A (en) |
CN (1) | CN100372113C (en) |
TW (1) | TWI232496B (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6838354B2 (en) * | 2002-12-20 | 2005-01-04 | Freescale Semiconductor, Inc. | Method for forming a passivation layer for air gap formation |
DE102005039323B4 (en) * | 2005-08-19 | 2009-09-03 | Infineon Technologies Ag | Guideway arrangement and associated production method |
US20080265377A1 (en) * | 2007-04-30 | 2008-10-30 | International Business Machines Corporation | Air gap with selective pinchoff using an anti-nucleation layer |
US7879683B2 (en) * | 2007-10-09 | 2011-02-01 | Applied Materials, Inc. | Methods and apparatus of creating airgap in dielectric layers for the reduction of RC delay |
US8436473B2 (en) * | 2009-05-06 | 2013-05-07 | Taiwan Semiconductor Manufacturing Company, Ltd. | Integrated circuits including air gaps around interconnect structures, and fabrication methods thereof |
US8587121B2 (en) * | 2010-03-24 | 2013-11-19 | International Business Machines Corporation | Backside dummy plugs for 3D integration |
CN102891100B (en) * | 2011-07-22 | 2015-04-29 | 中芯国际集成电路制造(上海)有限公司 | Shallow-trench isolation structure and formation method thereof |
CN102376684B (en) * | 2011-11-25 | 2016-04-06 | 上海集成电路研发中心有限公司 | Copper interconnection structure and preparation method thereof |
JP5696679B2 (en) * | 2012-03-23 | 2015-04-08 | 富士通株式会社 | Semiconductor device |
CN104425230A (en) * | 2013-09-09 | 2015-03-18 | 中芯国际集成电路制造(上海)有限公司 | Side wall structure and formation method thereof |
CN104362172B (en) * | 2014-10-15 | 2018-09-11 | 杰华特微电子(杭州)有限公司 | Semiconductor chip structure with end ring and its manufacturing method |
US9653348B1 (en) * | 2015-12-30 | 2017-05-16 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and manufacturing method thereof |
US10896888B2 (en) * | 2018-03-15 | 2021-01-19 | Microchip Technology Incorporated | Integrated circuit (IC) device including a force mitigation system for reducing under-pad damage caused by wire bond |
US10818541B2 (en) | 2018-12-27 | 2020-10-27 | Nanya Technology Corporation | Semiconductor structure |
US11309263B2 (en) * | 2020-05-11 | 2022-04-19 | Nanya Technology Corporation | Semiconductor device structure with air gap structure and method for preparing the same |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0393635B1 (en) * | 1989-04-21 | 1997-09-03 | Nec Corporation | Semiconductor device having multi-level wirings |
GB2247986A (en) * | 1990-09-12 | 1992-03-18 | Marconi Gec Ltd | Reducing interconnection capacitance in integrated circuits |
JP2555940B2 (en) * | 1993-07-27 | 1996-11-20 | 日本電気株式会社 | Semiconductor device and manufacturing method thereof |
JPH07326670A (en) * | 1994-05-31 | 1995-12-12 | Texas Instr Inc <Ti> | Semiconductor integrated circuit device |
JPH08148556A (en) * | 1994-11-16 | 1996-06-07 | Sony Corp | Semiconductor device and its manufacture |
CN1204867A (en) * | 1997-06-20 | 1999-01-13 | 日本电气株式会社 | Semiconductor device, and method of manufacturing same |
US6184121B1 (en) * | 1997-07-10 | 2001-02-06 | International Business Machines Corporation | Chip interconnect wiring structure with low dielectric constant insulator and methods for fabricating the same |
JP2000058549A (en) * | 1998-08-04 | 2000-02-25 | Nec Corp | Formation of integrated circuit wiring |
JP2000269327A (en) * | 1999-03-15 | 2000-09-29 | Toshiba Corp | Semiconductor device and manufacture thereof |
US6413852B1 (en) * | 2000-08-31 | 2002-07-02 | International Business Machines Corporation | Method of forming multilevel interconnect structure containing air gaps including utilizing both sacrificial and placeholder material |
-
2003
- 2003-11-07 CN CNB2003101034859A patent/CN100372113C/en not_active Expired - Lifetime
- 2003-11-11 TW TW092131566A patent/TWI232496B/en not_active IP Right Cessation
- 2003-11-14 JP JP2003385281A patent/JP2004172620A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
CN100372113C (en) | 2008-02-27 |
TW200415704A (en) | 2004-08-16 |
JP2004172620A (en) | 2004-06-17 |
CN1501492A (en) | 2004-06-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI232496B (en) | Integrated circuits with air gaps and method of making same | |
JP5299703B2 (en) | Method of manufacturing a transistor including a fin and a gate | |
JP7192121B2 (en) | Formation of staircase structures in three-dimensional memory devices | |
CN104054171A (en) | Flattened substrate surface for substrate bonding | |
JPH1074905A (en) | Manufacturing method of semiconductor device | |
US11646223B2 (en) | Metal lead, semiconductor device and methods of fabricating the same | |
TW200539281A (en) | Wiring structure for integrated circuit with reduced intralevel capacitance | |
CN109427651A (en) | Semiconductor structure and forming method thereof | |
TW202324662A (en) | Semiconductor device with alignment marks and method for fabricating the same | |
JP2001210645A (en) | Semiconductor device and its manufacturing method | |
CN109273456A (en) | The manufacturing method of three-dimensional storage | |
TWI722510B (en) | Semiconductor structure and method for forming the same | |
JPH10308498A (en) | Semiconductor device and manufacture thereof | |
TW202147576A (en) | Contact pad structure of three-dimensional memory device and method of forming the same | |
US7678661B2 (en) | Method of forming an insulating layer in a semiconductor device | |
CN207409478U (en) | The interconnection structure and semiconductor devices of metal interconnecting | |
CN209029384U (en) | Three-dimensional storage | |
TW202218130A (en) | Coaxially stepped structure in three-dimensional memory device and forming method thereof | |
CN105336676B (en) | The forming method of contact plunger | |
CN102339791A (en) | Manufacture method of semiconductor device | |
CN102361019A (en) | Method for manufacturing semiconductor device | |
CN102592993B (en) | Method for improving uniformity of chemical and mechanical planarization process for metal plug in post-gate engineering | |
JP2000124419A (en) | Semiconductor device and manufacture thereof | |
JP2003273246A (en) | Semiconductor memory device and method of manufacturing the same | |
JP2024523978A (en) | Floating metal backside for increased capacitance |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK4A | Expiration of patent term of an invention patent |