TW200408001A - Method of manufacturing semiconductor devices - Google Patents
Method of manufacturing semiconductor devices Download PDFInfo
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- TW200408001A TW200408001A TW091133038A TW91133038A TW200408001A TW 200408001 A TW200408001 A TW 200408001A TW 091133038 A TW091133038 A TW 091133038A TW 91133038 A TW91133038 A TW 91133038A TW 200408001 A TW200408001 A TW 200408001A
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- oxide film
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- teos oxide
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 43
- UPSOBXZLFLJAKK-UHFFFAOYSA-N ozone;tetraethyl silicate Chemical compound [O-][O+]=O.CCO[Si](OCC)(OCC)OCC UPSOBXZLFLJAKK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000002093 peripheral effect Effects 0.000 claims description 16
- 239000000758 substrate Substances 0.000 claims description 12
- 230000008021 deposition Effects 0.000 claims description 9
- 238000000137 annealing Methods 0.000 claims description 6
- 239000003990 capacitor Substances 0.000 claims description 6
- 241001416085 Buteo Species 0.000 claims 1
- 229910052769 Ytterbium Inorganic materials 0.000 claims 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical group [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims 1
- 230000007547 defect Effects 0.000 abstract description 8
- 238000000151 deposition Methods 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 90
- 239000002184 metal Substances 0.000 description 16
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 238000004151 rapid thermal annealing Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000001039 wet etching Methods 0.000 description 2
- 102100033538 Clusterin-associated protein 1 Human genes 0.000 description 1
- 102100040489 DNA damage-regulated autophagy modulator protein 2 Human genes 0.000 description 1
- 101000945057 Danio rerio Clusterin-associated protein 1 homolog Proteins 0.000 description 1
- 101000945060 Homo sapiens Clusterin-associated protein 1 Proteins 0.000 description 1
- 101000968012 Homo sapiens DNA damage-regulated autophagy modulator protein 2 Proteins 0.000 description 1
- 235000015429 Mirabilis expansa Nutrition 0.000 description 1
- 244000294411 Mirabilis expansa Species 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000005380 borophosphosilicate glass Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 235000013536 miso Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76819—Smoothing of the dielectric
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02551—Group 12/16 materials
- H01L21/02554—Oxides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/31051—Planarisation of the insulating layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/324—Thermal treatment for modifying the properties of semiconductor bodies, e.g. annealing, sintering
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76822—Modification of the material of dielectric layers, e.g. grading, after-treatment to improve the stability of the layers, to increase their density etc.
- H01L21/76828—Modification of the material of dielectric layers, e.g. grading, after-treatment to improve the stability of the layers, to increase their density etc. thermal treatment
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02164—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon oxide, e.g. SiO2
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/314—Inorganic layers
- H01L21/316—Inorganic layers composed of oxides or glassy oxides or oxide based glass
- H01L21/31604—Deposition from a gas or vapour
- H01L21/31608—Deposition of SiO2
- H01L21/31612—Deposition of SiO2 on a silicon body
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Formation Of Insulating Films (AREA)
- Semiconductor Memories (AREA)
Description
0) 0)200408001 玖、發明說明 (發明說日聽敘明:發_狀技術領域、歧麟、岐、實施方式及圖式簡單說明) 背景 發明領域 揭示製造半導體裝置之方法,且更特別地揭示製造具有 氧化物薄膜在其中堆疊之内層絕緣膜的半導體裝置之方 法。 相關技藝之描述 一般地,半導體記憶體裝置包括具有複數個記憶體單元 之記憶體單元陣列和用以在該記憶體單元上儲存資訊或讀 取该儲存貧訊之週邊電路。 在製造該半導體裝置之方法中,該記憶體單元陣列和週 邊電路在不同區域之半導體基材上形成。然而當裝置之整 合度增加,因為在記憶體單元區域和週邊電路區域之間之 地形差異會發生許多瑕疵。 圖1A至1C係為解釋製造011八]^方法之傳統半導體裝置之 剖面檢視圖。 現在參考圖1A,形成堆疊結構之閘極氧化物膜2和閘極電 極3在半導體基材丨上形成。接合區域4在半導體基材1在該 閘極電極3之兩側邊上形成,因此完成一電晶體。在半導體 基材1中在記憶體單元區域c和週邊電路區域p同時執行製 造電晶體之方法。 & 接下來,一第一絕緣膜5在整個結構上形成且圖案化該第 一絕緣膜5使得在一部分之接合區域4可被暴露。之後,一 位元線6在該第一絕緣膜5上形成使得該位元線6可被連接 (2) (2)200408001 至違暴露接合區域4。接菩 稷者一第二絕緣膜7在整個結構上 形成且之後該第二和第一終 弟、吧、味犋7和5循序地圖案化使得在 其他部分之接合區域4 + 飞了破暴路,因此形成一接觸洞。之後 ,一插塞8在該接觸洞中形成。 ”現在參考圖1B,一第三絕緣膜9在該包括該插塞8之第二 :、水膜7上形成。之後’圖案化該第三絕緣膜$以暴露該插 基接者電容器之_下層電極1()在該第三絕緣膜9上形成 使付訂層電極1()可被連接至該插塞8。在此時,該第三絕 緣膜9由PE-TEOS氧化物膜所製造。 >考圖1C,一介電膜丨丨和一上層電極12在包括該下層電 極10之第三絕緣膜9上循序地形成且之後被圖案化以完成 該電容器。在此時,當PE-TE〇S氧化物膜9之濕蝕刻速率緩 k日可,在週邊電路中之該第三絕緣膜9遺留。所以,在單元 區域C和週邊電路區域p之間之地形差異需要被減少。 之後,一第四絕緣膜13在整個結構上形成。之後,該第 四、第一和第一絕緣膜丨3、9、7和5循序地圖案化以形成 一接觸洞1 4使得在週邊電路區域p中之該閘極電極3之給 疋。卩伤可被暴露。接著,一金屬線(未顯示)在該第四絕緣 膜13上形成使得該金屬線可經由接觸洞14被連接至閘極 電極3。此時,該第四絕緣膜13也是由!>卜丁£〇3氧化物膜 所製造。 然而’在上述傳統方法中,因為在電容器中之上層電極 12之高度,在記憶體單元區域c和週邊電路區域p之邊界之 地形角度變成約45度。所以當地形差異在由PE-TEOS氧化 (3) 408001
2所製造之第四絕緣膜13之表面上反應時,在微影方法 j d方法中’其用以形成當形成為與隨後金屬線連接之 插塞之金屬’會遺留導電材料或發生瑕庇。因&,產 接等等,可能導致在金屬線之間之接觸和在線中之瑕庇: 進步地,當在週邊電路區域Ρ中以第三絕緣膜9形成之 上層電極12暴露時,該第三絕緣膜9之表面狀態經過許多方 法(微影方法、姓刻方法等等)變得粗糙時,因此降低盘第四 絕緣膜13之介面特性。所以,在該接觸洞Η形成之後執行 之潔淨方法中,蝕刻代理穿透至第三和第四絕緣膜9和" 之介面,使得形成不想要環狀之蝕刻部分Α。結果,因為顯 不在A之缺陷之結果,在接觸洞14中之障礙金屬層 (Τι/ΤιΝ)之橋接或不良階梯涵蓋率,連接至鄰近接觸洞 困難。 、 同時,在形成該第四絕緣膜13之後,以8〇〇t溫度執行 用以啟動上層電極12之快速熱退火(RTA)或管退火。然而 ,對於在PE-TEOS氧化物膜表面之地形差異之減少或在 PE-TEOS氧化物膜之間之黏附力之增加並沒有實質的效 果。 、' 發明摘要 為了解決上述問題,揭示一種製造半導體裝置之方法, 其中具有類流動性質和黏附力之OrTEOS氧化物膜在由 PE-TEOS氧化物膜所製造之絕緣膜上形成。 一揭示之方法其特徵為該方法包括下列步驟:在半導體 基材上形成一絕緣膜、在該絕緣膜上形成一導電層圖案以 (4) (4)200408001 及在包括該導電層圖案和該絕緣膜之整個結構上形成 o3-teos氧化物膜。 參考圖2A,形成堆疊結構之閘極氧化物膜22和閘極電極 23在半導體基材21上形成。接合區域24在該閘極電極^兩 邊之半導體基材21中形成,因此完成一電晶體。在半導體 基材2 1中在έ己憶體單元區域C和週邊電路區域p同時執行製 造電晶體之方法。 接下來,一第一絕緣膜25在整個結構上形成且圖案化該 第一絕緣膜25使得在一部分之接合區域24可被暴露。之後 ,一位元線26在該第一絕緣膜25上形成使得該位元線26可 被連接至該暴露接合區域24。接著,一第二絕緣膜27在整 個結構上形成且之後該第二和第一絕緣膜27和25循序地圖 案化使得在其他部分之接合區域24可被暴露,因此形成一 接觸洞。之後,一插塞28在該接觸洞中形成。 現在參考圖2Β,一第三絕緣膜29在該包括該插塞28之第 二絕緣膜27上形成。之後,圖案化該第三絕緣膜29以暴露 該插塞28。接著電容器之一下層電極30在該第三絕緣膜29 上形成使得該下層電極30可被連接至該插塞28。在此時, 該第三絕緣膜29由PE-TEOS氧化物膜所製造。 參考圖2C,一介電膜31和一上層電極32在包括該下層電 極30之第三絕緣膜29上循序地形成且之後被圖案化以完成 該電容器。此時,當PE-TEOS氧化物膜之濕蝕刻速率緩慢 時’在週邊電路Ρ中之該第三絕緣膜29遺留。所以,在單元 區域C和週邊電路區域ρ之間之地形差異可被減少。 200408001
之傻,一第四絕緣膜33在整個結構上形成。之後,該第 四、第二和第一絕緣膜33、29、27和25循序地圖案化以形 成一接觸洞34使得在週邊電路區域p中之該閘極電極23之 給定部份可被暴露。接著,一金屬線(未顯示)在該第四絕緣 膜33上形成使得該金屬線可經由接觸洞34被連接至閘極電 極23。此時,該第四絕緣膜33較佳是由〇3-TEOS氧化物膜 所製造。 具有良好特有類流動性質之〇3-TE〇s氧化物膜以大於約 2500埃之厚度,較佳範圍從2500至5000埃,在溫度範圍從 500至約550°C而沉積使得可防止對底下膜之依賴。進一步 地’在沉積上,控制〇3之密度大於約135克/立方公尺,較 佳從約135至約180克/立方公尺。 如上’因為該第四絕緣膜33由03-TE0S氧化物膜所製造 ’所以在記憶體單元區域C和週邊電路區域p之邊界的地形 差異因為良好類流動性質而減少。進一步地,與傳統技術 比較起來該地形角度被減少至約35度。此外,因為〇3-TEOS 氧化物膜之沉積溫度係為高,所以與第三絕緣膜29之介面 接觸變得良好。所以,在該接觸洞34形成之後執行之潔淨 方法中’並沒有產生環狀之蝕刻部份。 並且,在〇3-TEOS形成之後,包含在o3-teos氧化物膜 之不純物可藉由執行用以範圍從約750至約1000 °c之溫度 啟動上層電極32之快速熱退火(RTA)或管退火範圍從約20 秒至約30分鐘而移除。歸因於此,可獲得穩定之膜結構。 表1顯示本發明應用在製造具有0.16埃線寬之半導體裝 200408001
⑹ 置之方法之情況下,良好與缺陷比例。確認使用PE-TEOS 氧化物膜和03-TE0S氧化物膜本方法可獲得比傳統方法還 好之結果,因為分析瑕疵項目之結果可由因為橋接產生在 金屬線之間之接觸而產生。 表1 絕緣膜 可修護之 漏電流 操作電流 靜待電流 瑕庇比例 晶圓(REP) (LKG) (ICC) (ICC2) ea/wf %/wf ea/wf %/wf ea/wf %/wf ea/wf %/wf ea/wf %/wf PE-TEOS 1 1.2 1.4 1.7 34.2 41.7 32.9 40.1 4.1 5.0 (15 張) OrTE〇S 6 7.3 1.5 1.8 27.5 33.5 26.5 32.3 3.3 4.0 (4張) 在表1中,該可修護晶片(REP)指示雖然該晶片因為錯誤 方法而不能操作但是經由電路之改變而可操作。此時,漏 電流(LKG)指示流向基材之電流,操作電流(ICC)指示當電 路被驅動時流入金屬線之電流,而靜待電流(ICC2)指示在 · 電路被驅動之前流入金屬線之電流。 雖然流入基材和金屬線之電流被限制,但是不想要之電 流可能因為例如線之橋接之製程問題流入金屬線。雖然可 能有許多製程問題,但是對於本揭示方法提供在03-TE0S 氧化物膜形成之後之金屬線方法係為明顯的。 假如03-TE0S氧化物膜沒有特有類流動性質或其之表面 不平坦,在隨後之金屬線蝕刻方法中可能產生短路,使得 過度操作電流或靜待電流流動。所以,當測量有多少瑕疵 -11- 408001
⑺ 曰曰圓之結果’已經決定本揭示之方法具有改進之效果,如 可從表1所看到。換句話說,當因為〇^丁£〇3使用而減少地 $角度時’可有效地防止在金屬線之間之微小短路。 如上所述’本揭示方法包括使用具有良好類流動性質和 黏附力之O^TEOS氧化物膜在由pE-TE〇s氧化物膜所製造 之絕緣膜上形成一絕緣膜。所以,本揭示之方法可獲得下 列優點: 首先’當在記憶體單元區域和週邊電路區域邊界之地形 差異被減少時’可容易地執行隨後方法且可防止瑕疵。 第二’當〇3_TEOS氧化物膜在對底下膜之依賴為低之情 況下沉積以增加黏附力時,與PE_TE0S氧化物膜之介面接 觸,该膜之表面係為不良。因此,當潔淨接觸洞時蝕刻物 之穿入該介面可被防止。 第三,當包含在〇3_TEOS氧化物膜之不純物藉由隨後方 法移除時,可獲得一穩定膜結構以改進該膜之電氣特性。 第四,因為〇3_TEOS氧化物膜之沉積速度比使用之 PE-TEOS氧化物膜之沉積速度還快,所以可改進良率。 第五,需要專屬之沉積設備以沉積PE_TE〇s氧化物膜。 然而,當〇3-TEOS氧化物膜可藉由既存〇3-BPSG沉積設備 所沉積,可減少額外成本。 該揭不方法和其之許多變異已經參考特別具體實施例一 起與特別應用而描述。普通熟悉此技藝的人士和接觸到本 發明之教詢:將承認在其範圍内之額外修改和應用。所以, 本增附申請專利範圍的企圖係為涵蓋在本發明範圍内之任 -12- (8) 200408001 何及全部這樣之應用、修改、和具體實施例。 圖式簡述 在 本揭示方法之4述觀點和其他特點一起與隨附圖式 以上描述中解釋,其中: 圖1A至1C係為用以解釋製造半導體裝置之傳統方法 傳統半導體裝置之剖面檢視圖;以及 之 圖2 A至2 C係為用以解釋製造該半導體裝置之揭 之半導體裝置之剖面檢視圖。 法 季父佳具體實施例之詳細描述 圖2A至2C传炎03 半導體裝置 解釋包括製造DRAM2方法之製造該 旦、之揭示方法之半導體裝置之剖面檢視圖。 3、23 5、25 4、24 7、27 8、28 9、29 10 、 30 、 2〇 13、33 12、32 14、34 1、21 圖式代表符號說明 閘極氧化物膜 閘極電極 第一絕緣膜 接合區域 第二絕緣膜 插塞 第三絕緣膜 較低電極 第四絕緣膜 較上電極 接觸洞 半導體基材 -13- 200408001 (9) 6 ^ 26 位元線 31 介電膜
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Claims (1)
- 拾、申請專利範圍 1. 一種製造半導體裝置之方法,其包括: 在半導體基材上形成一絕緣膜; 在該絕緣膜上形成一導電層圖案;以及 在該導電層圖案和該絕緣膜上形成〇3-TE〇s氧化物 膜。 2 ·如申請專利範圍第1項之方法,其中該絕緣膜係為 PE-TEOS氧化物膜。 3·如申請專利範圍第1項之方法,其中該〇3-TE〇s在範圍從 2500至5000埃之厚度,在範圍從5〇〇至約55〇。〇之溫度而 沉積。 4.如申请專利範圍第3項之方法,其中在該〇3_TE〇s氧化物 膜沉積期間,該〇3之密度範圍從約i 3 5至約1 8〇克/立方公 尺。 5·如申凊專利範圍第}項之方法,尚包括在形成該〇3_te〇s 氧化物膜之步驟之後執行一退火方法。 6. 如申請專利範圍第5項之方法,其中該退火方法在範圍從 750至約l〇〇〇°C之溫度執行。 7. 一種製造半導體裝置之方法,其包括: 在電晶體和位元線形成其中之半導體基材上形成一 PE-TEOS氧化物膜,在單元區域中和周邊電路區域中形 成電晶體; 在單疋區域之PE-TEOS氧化物膜上形成電容器;以及 在包括該電容器和PE-TE〇s氧化物膜之整個結構上 200408001形成〇3-TE〇S氧化物膜。 8_如申請專利範圍第7項之方法,其中該〇3•丁E〇s在範圍從 2500至5000埃之厚度,在範圍從5〇〇至約55〇。〇之溫度而 沉積。 9.如申凊專利範圍第8項之方法,其中在該丁E〇s氧化物 膜沉積期間,該〇3之密度範圍從約135至約1 80克/立方公 10·如申請專利範圍第7項之方法,尚包括在形成該〇3-TEOS 氧化物膜之步驟之後執行一退火方法。 11 ·如申請專利範圍第1 〇項之方法,其中該退火方法在範圍 從7 50至約i〇〇〇°c之溫度執行。
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US5851867A (en) | 1996-08-27 | 1998-12-22 | Mosel Vitellic Incorporated | Rugged stacked oxide layer structure and method of fabricating same |
KR100230738B1 (ko) * | 1996-12-28 | 1999-11-15 | 김영환 | 반도체 소자의 캐패시터 형성방법 |
US5766994A (en) | 1997-04-11 | 1998-06-16 | Vanguard International Semiconductor Corporation | Dynamic random access memory fabrication method having stacked capacitors with increased capacitance |
US5728618A (en) | 1997-06-04 | 1998-03-17 | Vanguard International Semiconductor Corporation | Method to fabricate large capacitance capacitor in a semiconductor circuit |
US6184551B1 (en) | 1997-10-24 | 2001-02-06 | Samsung Electronics Co., Ltd | Method of forming integrated circuit capacitors having electrodes therein that comprise conductive plugs |
US6084261A (en) | 1998-01-26 | 2000-07-04 | Wu; Shye-Lin | DRAM cell with a fork-shaped capacitor |
US6162681A (en) | 1998-01-26 | 2000-12-19 | Texas Instruments - Acer Incorporated | DRAM cell with a fork-shaped capacitor |
KR100299594B1 (ko) * | 1998-07-13 | 2001-09-22 | 윤종용 | 디램 장치의 제조 방법 |
KR100267106B1 (ko) | 1998-09-03 | 2000-10-02 | 윤종용 | 반도체 소자의 다층 배선 형성방법 |
US6071789A (en) | 1998-11-10 | 2000-06-06 | Vanguard International Semiconductor Corporation | Method for simultaneously fabricating a DRAM capacitor and metal interconnections |
US6140178A (en) | 1999-04-06 | 2000-10-31 | Vanguard International Semiconductor Corporation | Method to manufacture a capacitor with crown-shape using edge contact exposure |
KR100350811B1 (ko) * | 2000-08-19 | 2002-09-05 | 삼성전자 주식회사 | 반도체 장치의 금속 비아 콘택 및 그 형성방법 |
-
2001
- 2001-12-20 KR KR10-2001-0081929A patent/KR100432785B1/ko not_active IP Right Cessation
-
2002
- 2002-09-24 JP JP2002277261A patent/JP2003197619A/ja active Pending
- 2002-11-11 TW TW091133038A patent/TW200408001A/zh unknown
- 2002-11-27 US US10/306,335 patent/US7022599B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR20030051031A (ko) | 2003-06-25 |
KR100432785B1 (ko) | 2004-05-24 |
JP2003197619A (ja) | 2003-07-11 |
US7022599B2 (en) | 2006-04-04 |
US20030119302A1 (en) | 2003-06-26 |
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