TR201802600T4 - Polimerlerin ve bunlara ilişkin bileşimlerin molekül ağırlığı dağılımını düzenlemek için usuller. - Google Patents
Polimerlerin ve bunlara ilişkin bileşimlerin molekül ağırlığı dağılımını düzenlemek için usuller. Download PDFInfo
- Publication number
- TR201802600T4 TR201802600T4 TR2018/02600T TR201802600T TR201802600T4 TR 201802600 T4 TR201802600 T4 TR 201802600T4 TR 2018/02600 T TR2018/02600 T TR 2018/02600T TR 201802600 T TR201802600 T TR 201802600T TR 201802600 T4 TR201802600 T4 TR 201802600T4
- Authority
- TR
- Turkey
- Prior art keywords
- reaction
- catalyst
- molecular weight
- time
- polymerization
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 238000009826 distribution Methods 0.000 title claims description 42
- 230000001105 regulatory effect Effects 0.000 title abstract description 3
- 229920000642 polymer Polymers 0.000 title description 35
- 239000000203 mixture Substances 0.000 title description 5
- 238000012644 addition polymerization Methods 0.000 claims abstract description 26
- 238000006243 chemical reaction Methods 0.000 claims description 124
- 239000003054 catalyst Substances 0.000 claims description 80
- 239000003426 co-catalyst Substances 0.000 claims description 40
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 34
- 230000002441 reversible effect Effects 0.000 claims description 33
- 239000012986 chain transfer agent Substances 0.000 claims description 27
- 239000000047 product Substances 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 238000007334 copolymerization reaction Methods 0.000 claims description 18
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 17
- 239000001569 carbon dioxide Substances 0.000 claims description 17
- 150000002924 oxiranes Chemical class 0.000 claims description 9
- 230000000977 initiatory effect Effects 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004417 polycarbonate Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 239000002954 polymerization reaction product Substances 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 abstract description 38
- 238000010348 incorporation Methods 0.000 abstract description 6
- -1 polyethylene Polymers 0.000 description 31
- 239000000178 monomer Substances 0.000 description 25
- 239000007795 chemical reaction product Substances 0.000 description 22
- 229920002689 polyvinyl acetate Polymers 0.000 description 8
- 239000011118 polyvinyl acetate Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000002902 bimodal effect Effects 0.000 description 7
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 229910017052 cobalt Inorganic materials 0.000 description 6
- 239000010941 cobalt Substances 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229920000379 polypropylene carbonate Polymers 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- GRFNBEZIAWKNCO-UHFFFAOYSA-N 3-pyridinol Chemical compound OC1=CC=CN=C1 GRFNBEZIAWKNCO-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- PSHKMPUSSFXUIA-UHFFFAOYSA-N n,n-dimethylpyridin-2-amine Chemical compound CN(C)C1=CC=CC=N1 PSHKMPUSSFXUIA-UHFFFAOYSA-N 0.000 description 2
- NEDHXUZHZBDWPK-UHFFFAOYSA-N n,n-dimethylquinolin-2-amine Chemical compound C1=CC=CC2=NC(N(C)C)=CC=C21 NEDHXUZHZBDWPK-UHFFFAOYSA-N 0.000 description 2
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 description 2
- BRKFQVAOMSWFDU-UHFFFAOYSA-M tetraphenylphosphanium;bromide Chemical compound [Br-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 BRKFQVAOMSWFDU-UHFFFAOYSA-M 0.000 description 2
- WAGFXJQAIZNSEQ-UHFFFAOYSA-M tetraphenylphosphonium chloride Chemical compound [Cl-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 WAGFXJQAIZNSEQ-UHFFFAOYSA-M 0.000 description 2
- IONYGGJUUJFXJK-UHFFFAOYSA-N 2,3,4,5,6-pentachlorobenzoic acid Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IONYGGJUUJFXJK-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- MEXUTNIFSHFQRG-UHFFFAOYSA-N 6,7,12,13-tetrahydro-5h-indolo[2,3-a]pyrrolo[3,4-c]carbazol-5-one Chemical compound C12=C3C=CC=C[C]3NC2=C2NC3=CC=C[CH]C3=C2C2=C1C(=O)NC2 MEXUTNIFSHFQRG-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- VUEDNLCYHKSELL-UHFFFAOYSA-N arsonium Chemical class [AsH4+] VUEDNLCYHKSELL-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- LVRCYPYRKNAAMX-UHFFFAOYSA-M bis(triphenylphosphine)iminium chloride Chemical compound [Cl-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)N=P(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 LVRCYPYRKNAAMX-UHFFFAOYSA-M 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000007156 chain growth polymerization reaction Methods 0.000 description 1
- 238000012711 chain transfer polymerization Methods 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 230000033001 locomotion Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000903 polyhydroxyalkanoate Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- TYLVUOJLQDVPMQ-UHFFFAOYSA-M sodium;2,3,4,5,6-pentafluorobenzoate Chemical compound [Na+].[O-]C(=O)C1=C(F)C(F)=C(F)C(F)=C1F TYLVUOJLQDVPMQ-UHFFFAOYSA-M 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polymerisation Methods In General (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/129,106 US7858729B2 (en) | 2008-05-29 | 2008-05-29 | Methods of controlling molecular weight distribution of polymers and compositions thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR201802600T4 true TR201802600T4 (tr) | 2018-03-21 |
Family
ID=41380619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR2018/02600T TR201802600T4 (tr) | 2008-05-29 | 2009-05-27 | Polimerlerin ve bunlara ilişkin bileşimlerin molekül ağırlığı dağılımını düzenlemek için usuller. |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US7858729B2 (enExample) |
| EP (1) | EP2281013B1 (enExample) |
| JP (1) | JP5552116B2 (enExample) |
| KR (2) | KR101825340B1 (enExample) |
| CN (2) | CN103626983B (enExample) |
| DK (1) | DK2281013T3 (enExample) |
| ES (1) | ES2663704T3 (enExample) |
| HU (1) | HUE038560T2 (enExample) |
| NO (1) | NO2281013T3 (enExample) |
| PL (1) | PL2281013T3 (enExample) |
| PT (1) | PT2281013T (enExample) |
| TR (1) | TR201802600T4 (enExample) |
| WO (1) | WO2009148889A2 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7858729B2 (en) * | 2008-05-29 | 2010-12-28 | Novomer, Inc. | Methods of controlling molecular weight distribution of polymers and compositions thereof |
| KR101823440B1 (ko) | 2008-08-22 | 2018-03-14 | 사우디 아람코 테크놀로지스 컴퍼니 | 촉매 및 중합체 합성방법 |
| CN111848940B (zh) | 2008-09-08 | 2024-09-06 | 沙特阿美技术公司 | 聚碳酸酯多元醇组合物和方法 |
| US8252891B2 (en) * | 2008-09-17 | 2012-08-28 | Novomer, Inc. | Purification of polycarbonates |
| KR101486483B1 (ko) * | 2010-04-13 | 2015-01-27 | 에스케이이노베이션 주식회사 | 폴리(알킬렌 카보네이트)와 다양한 고분자와의 블록 또는 그라프트 공중합체 |
| US11644471B2 (en) | 2010-09-30 | 2023-05-09 | Ablynx N.V. | Techniques for predicting, detecting and reducing aspecific protein interference in assays involving immunoglobulin single variable domains |
| WO2012071505A1 (en) | 2010-11-23 | 2012-05-31 | Novomer, Inc. | Polycarbonate polyol compositions |
| AU2011333792A1 (en) | 2010-11-23 | 2013-05-30 | Dsm Ip Assets B.V. | Polycarbonate polyol compositions |
| KR101406989B1 (ko) * | 2011-01-18 | 2014-06-13 | 에스케이이노베이션 주식회사 | 다층필름 |
| EP2707353B1 (en) | 2011-05-13 | 2021-03-31 | Novomer, Inc. | Carbonylation catalysts and method |
| JP6258199B2 (ja) | 2011-06-23 | 2018-01-10 | アブリンクス エン.ヴェー. | 免疫グロブリン単一可変ドメインを伴うアッセイにおける非特異的タンパク質干渉を予測、検出及び低減するための技術 |
| CN114774053A (zh) | 2012-04-16 | 2022-07-22 | 沙特阿美技术公司 | 粘合剂组合物和方法 |
| KR102159100B1 (ko) | 2012-05-24 | 2020-09-23 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리카보네이트 폴리올 조성물 및 방법 |
| KR20150036034A (ko) * | 2012-06-27 | 2015-04-07 | 노보머, 인코포레이티드 | 폴리에스터 제조를 위한 촉매 및 방법 |
| KR102096761B1 (ko) | 2012-08-24 | 2020-04-03 | 사우디 아람코 테크놀로지스 컴퍼니 | 금속 착물 |
| WO2014178972A2 (en) | 2013-05-01 | 2014-11-06 | Novomer, Inc. | Aliphatic polycarbonate compositions and methods |
| US10308759B2 (en) | 2014-04-03 | 2019-06-04 | Saudi Aramco Technologies Company | Aliphatic polycarbonate polyol compositions |
| US10858329B2 (en) | 2014-05-05 | 2020-12-08 | Novomer, Inc. | Catalyst recycle methods |
| EP3148959B1 (en) | 2014-05-30 | 2023-11-22 | Novomer Inc. | Integrated methods for chemical synthesis |
| AU2015292361B2 (en) | 2014-07-25 | 2019-07-18 | Novomer, Inc. | Synthesis of metal complexes and uses thereof |
| MA41513A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de distillation pour la production d'acide acrylique |
| MA41510A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de production d'acide acrylique |
| EP3696161A1 (en) | 2015-02-13 | 2020-08-19 | Novomer, Inc. | Continuous carbonylation processes |
| MA41514A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédés intégrés de synthèse chimique |
| WO2019126221A1 (en) | 2017-12-22 | 2019-06-27 | Saudi Aramco Technologies Company | Catalysts for polycarbonate production |
| EP3781609A1 (en) | 2018-04-18 | 2021-02-24 | Saudi Aramco Technologies Company | End-group isomerization of poly(alkylene carbonate) polymers |
| US11180609B2 (en) | 2018-08-02 | 2021-11-23 | Saudi Aramco Technologies Company | Sustainable polymer compositions and methods |
| US11634539B2 (en) | 2018-09-24 | 2023-04-25 | Saudi Aramco Technologies Company | Polycarbonate block copolymers and methods thereof |
| CN114466870B (zh) * | 2019-08-06 | 2025-01-07 | 艾利丹尼森公司 | 分散于含乙烯基的聚合物中的纳米晶材料及其方法 |
| CN113265018B (zh) * | 2021-06-04 | 2022-03-29 | 大连理工大学 | 一种基于锁定-解锁机理的聚合物分子量分布调控方法 |
| KR20240034195A (ko) | 2021-06-23 | 2024-03-13 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리올 조성물 및 방법 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3248415A (en) * | 1963-01-16 | 1966-04-26 | Pittsburgh Plate Glass Co | Method of preparing high molecular weight polycarbonates |
| US3585168A (en) * | 1968-09-21 | 1971-06-15 | Shohei Inoue | Process for producing copolymer of epoxide and carbon dioxide |
| US3900424A (en) * | 1972-07-21 | 1975-08-19 | Nippon Oil Seal Ind Co Ltd | Catalyst for copolymerizing epoxy compounds with carbon dioxide |
| US3953383A (en) * | 1972-07-21 | 1976-04-27 | Nippon Oil Seal Industry Co., Ltd. | Catalytic process for copolymerizing epoxy compounds with carbon dioxide |
| JPS57126809A (en) * | 1981-01-30 | 1982-08-06 | Sumitomo Chem Co Ltd | Ethylene/alpha-olefin copolymer |
| US4686276A (en) * | 1985-12-30 | 1987-08-11 | The Dow Chemical Company | Process for preparing poly (alkylene carbonates) |
| US4665136A (en) * | 1986-04-07 | 1987-05-12 | Air Products And Chemicals, Inc. | Process for producing novel block alkylene polycarbonate copolymers |
| JPH04106104A (ja) * | 1990-08-27 | 1992-04-08 | Nippon Zeon Co Ltd | 重合工程における反応制御方法及び反応制御装置 |
| FI924730L (fi) | 1992-03-20 | 1993-09-21 | Rohm & Haas | Foerfarande foer reglering av molekylviktsfoerdelningen i polymerer |
| US6133402A (en) * | 1998-08-04 | 2000-10-17 | Cornell Research Foundation, Inc. | Polycarbonates made using high activity catalysts |
| US6486271B1 (en) | 2001-03-09 | 2002-11-26 | Fina Technology, Inc. | Method of controlling molecular weight distributions during a polymerization process |
| JP3943382B2 (ja) * | 2001-12-10 | 2007-07-11 | 日本合成化学工業株式会社 | ポリビニルアルコール系樹脂およびその用途 |
| US7304172B2 (en) * | 2004-10-08 | 2007-12-04 | Cornell Research Foundation, Inc. | Polycarbonates made using highly selective catalysts |
| JP4590284B2 (ja) * | 2005-03-01 | 2010-12-01 | 学校法人東京理科大学 | ポリカーボネートの製造方法 |
| KR100789236B1 (ko) | 2005-12-07 | 2008-01-02 | 주식회사 엘지화학 | 마그네슘 담지 지글러 나타 촉매를 이용한 폴리올레핀의제조방법 |
| CN103788276B (zh) | 2005-12-09 | 2017-10-17 | 陶氏环球技术有限责任公司 | 乙烯/α‑烯烃组合物中控制分子量分布的方法 |
| JP2008045069A (ja) * | 2006-08-18 | 2008-02-28 | Jsr Corp | 環状オレフィン系付加共重合体およびその製造方法ならびに用途 |
| EP2112187A1 (en) | 2008-04-21 | 2009-10-28 | Stichting Dutch Polymer Institute | Process for the preparation of polycarbonates |
| GB0807607D0 (en) * | 2008-04-25 | 2008-06-04 | Imp Innovations Ltd | Catalyst |
| US7858729B2 (en) * | 2008-05-29 | 2010-12-28 | Novomer, Inc. | Methods of controlling molecular weight distribution of polymers and compositions thereof |
-
2008
- 2008-05-29 US US12/129,106 patent/US7858729B2/en active Active
-
2009
- 2009-05-27 WO PCT/US2009/045216 patent/WO2009148889A2/en not_active Ceased
- 2009-05-27 PT PT97590509T patent/PT2281013T/pt unknown
- 2009-05-27 ES ES09759050.9T patent/ES2663704T3/es active Active
- 2009-05-27 KR KR1020107028573A patent/KR101825340B1/ko active Active
- 2009-05-27 HU HUE09759050A patent/HUE038560T2/hu unknown
- 2009-05-27 DK DK09759050.9T patent/DK2281013T3/en active
- 2009-05-27 CN CN201310308300.1A patent/CN103626983B/zh active Active
- 2009-05-27 TR TR2018/02600T patent/TR201802600T4/tr unknown
- 2009-05-27 KR KR1020187002770A patent/KR101979576B1/ko active Active
- 2009-05-27 EP EP09759050.9A patent/EP2281013B1/en active Active
- 2009-05-27 PL PL09759050T patent/PL2281013T3/pl unknown
- 2009-05-27 CN CN200980119858.7A patent/CN102046695B/zh active Active
- 2009-05-27 NO NO09759050A patent/NO2281013T3/no unknown
- 2009-05-27 JP JP2011511762A patent/JP5552116B2/ja active Active
-
2010
- 2010-11-17 US US12/948,191 patent/US8324337B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN102046695A (zh) | 2011-05-04 |
| PL2281013T3 (pl) | 2018-06-29 |
| US20090299032A1 (en) | 2009-12-03 |
| CN103626983B (zh) | 2016-12-28 |
| CN102046695B (zh) | 2013-08-21 |
| KR101825340B1 (ko) | 2018-02-05 |
| HUE038560T2 (hu) | 2018-10-29 |
| DK2281013T3 (en) | 2018-03-05 |
| EP2281013A2 (en) | 2011-02-09 |
| PT2281013T (pt) | 2018-03-28 |
| EP2281013B1 (en) | 2017-12-27 |
| JP5552116B2 (ja) | 2014-07-16 |
| WO2009148889A2 (en) | 2009-12-10 |
| US8324337B2 (en) | 2012-12-04 |
| KR20110013493A (ko) | 2011-02-09 |
| CN103626983A (zh) | 2014-03-12 |
| JP2011522091A (ja) | 2011-07-28 |
| ES2663704T3 (es) | 2018-04-16 |
| KR20180014844A (ko) | 2018-02-09 |
| WO2009148889A3 (en) | 2010-02-25 |
| EP2281013A4 (en) | 2015-04-29 |
| US7858729B2 (en) | 2010-12-28 |
| US20110065894A1 (en) | 2011-03-17 |
| NO2281013T3 (enExample) | 2018-05-26 |
| KR101979576B1 (ko) | 2019-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TR201802600T4 (tr) | Polimerlerin ve bunlara ilişkin bileşimlerin molekül ağırlığı dağılımını düzenlemek için usuller. | |
| Coates et al. | Discrete metal‐based catalysts for the copolymerization of CO2 and epoxides: discovery, reactivity, optimization, and mechanism | |
| Wu et al. | Recent developments in main group metal complexes catalyzed/initiated polymerization of lactides and related cyclic esters | |
| Qin et al. | Carbon dioxide‐based copolymers: Environmental benefits of PPC, an industrially viable catalyst | |
| CN111072945B (zh) | 制备聚碳酸酯的方法 | |
| Hu et al. | Self-switchable polymerization: a smart approach to sequence-controlled degradable copolymers | |
| Garden et al. | Greater than the sum of its parts: a heterodinuclear polymerization catalyst | |
| CN100384907C (zh) | 通过晚加入弗利斯-诱导催化剂生产支化熔融聚碳酸酯的方法 | |
| Wu et al. | Perfectly alternating copolymerization of CO2 and epichlorohydrin using cobalt (III)-based catalyst systems | |
| US20150267001A1 (en) | Isocyantate-free Method for Preparing Poly(carbonate-urethane) or Poly(ester-urethane) | |
| Rosetto et al. | High molar mass polycarbonates as closed-loop recyclable thermoplastics | |
| Sugimoto et al. | Recent progress in the synthesis of polymers based on carbon dioxide | |
| CN101379091A (zh) | 在催化剂再生下的聚合方法 | |
| Reiter et al. | In situ generated ABA block copolymers from CO2, cyclohexene oxide, and poly (dimethylsiloxane) s | |
| Zhang et al. | Lithium-assisted copolymerization of CO2/cyclohexene oxide: A novel and straightforward route to polycarbonates and related block copolymers | |
| Wei et al. | Aluminum complexes bearing bidentate amido–phosphine ligands for ring-opening polymerization of ε-caprolactone: steric effect on coordination chemistry and reactivity | |
| Scholten et al. | Merging CO2-based building blocks with cobalt-mediated radical polymerization for the synthesis of functional poly (vinyl alcohol) s | |
| Qin et al. | Conversion of CO2 into Polymers | |
| Yang et al. | Precise Synthesis of Sequence-Controlled Oxygen-Rich Multiblock Copolymers via Reversible Carboxylation of a Commercial Salen-Mn (III) Catalyst | |
| Palenzuela et al. | 5-methylene-1, 3-dioxane-2-one: a first-choice comonomer for trimethylene carbonate | |
| Bruckmoser et al. | Simple and Rapid Access toward AB, BAB and ABAB Block Copolyesters from One-Pot Monomer Mixtures Using an Indium Catalyst | |
| Hsu et al. | Kinetics of transesterification of dimethyl terephthalate with 1, 4‐butanediol catalyzed by tetrabutyl titanate | |
| Chen et al. | Relative reactivities of epoxide monomers during copolymerization with carbon dioxide | |
| Patil et al. | Low molar mass polycarbonate diols from degradation of terpolymers obtained by epoxide/o-phthalaldehyde/CO2 copolymerization | |
| Dong et al. | Architecting CO2-Based Tri-Segmented Polyols via the Cerium-Modified Double Metal Cyanide Catalyst for Sustainable Polyurethane Elastomers |