SU525420A3 - Катализатор дл синтеза метанола - Google Patents
Катализатор дл синтеза метанолаInfo
- Publication number
- SU525420A3 SU525420A3 SU2076869A SU2076869A SU525420A3 SU 525420 A3 SU525420 A3 SU 525420A3 SU 2076869 A SU2076869 A SU 2076869A SU 2076869 A SU2076869 A SU 2076869A SU 525420 A3 SU525420 A3 SU 525420A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- catalyst
- mol
- hours
- solution
- methanol
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title description 36
- 239000003054 catalyst Substances 0.000 title description 32
- 230000015572 biosynthetic process Effects 0.000 title description 6
- 238000003786 synthesis reaction Methods 0.000 title description 6
- 239000000203 mixture Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000007789 gas Substances 0.000 description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000003456 ion exchange resin Substances 0.000 description 6
- 229920003303 ion-exchange polymer Polymers 0.000 description 6
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 238000006073 displacement reaction Methods 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000011363 dried mixture Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- -1 copper - zinc - boron - aluminum Chemical compound 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP48119764A JPS5144715B2 (enExample) | 1973-10-24 | 1973-10-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU525420A3 true SU525420A3 (ru) | 1976-08-15 |
Family
ID=14769589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU2076869A SU525420A3 (ru) | 1973-10-24 | 1974-10-24 | Катализатор дл синтеза метанола |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3971735A (enExample) |
| JP (1) | JPS5144715B2 (enExample) |
| CA (1) | CA1032523A (enExample) |
| DE (1) | DE2449493C3 (enExample) |
| GB (1) | GB1488042A (enExample) |
| SU (1) | SU525420A3 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4199479A (en) * | 1978-02-24 | 1980-04-22 | Chevron Research Company | Hydrogenation catalyst |
| JPS55106543A (en) * | 1979-02-10 | 1980-08-15 | Mitsubishi Gas Chem Co Inc | Preparation of catalyst for synthesizing methanol |
| JPS5910256B2 (ja) * | 1979-11-12 | 1984-03-07 | 三菱瓦斯化学株式会社 | メタノ−ル合成触媒の製造法 |
| US5004845A (en) * | 1981-08-20 | 1991-04-02 | Davy Mckee (London) Limited | Hydrogenation of aldehydes |
| JPS5933420B2 (ja) * | 1982-07-21 | 1984-08-15 | 三菱瓦斯化学株式会社 | メタノ−ル合成用触媒 |
| DE3318855A1 (de) * | 1983-05-25 | 1984-11-29 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von methanol |
| US4729979A (en) * | 1985-03-11 | 1988-03-08 | Amoco Corporation | Copper aluminum borate |
| US4645753A (en) * | 1985-03-13 | 1987-02-24 | Standard Oil Company | Doped aluminum borate |
| US4724226A (en) * | 1986-09-23 | 1988-02-09 | W. R. Grace & Co. | Boria-promoted HP catalyst |
| US4755497A (en) * | 1986-10-28 | 1988-07-05 | Amoco Corporation | Preparaton of copper aluminum borate catalyst and optional improvement of the catalyst by incorporation with active metals |
| USH1311H (en) | 1989-02-09 | 1994-05-03 | Mitsubishi Gas Chemical Company | Methanol synthesis process |
| JP2773183B2 (ja) * | 1989-02-09 | 1998-07-09 | 三菱瓦斯化学株式会社 | メタノール合成触媒前駆体の製造法 |
| FR2647367B1 (fr) * | 1989-04-24 | 1991-08-30 | Inst Francais Du Petrole | Procede de preparation de precurseurs de catalyseurs contenant du cuivre, de l'aluminium et du zinc, utilisables pour la synthese et la decomposition du methanol |
| US5155086A (en) * | 1989-09-12 | 1992-10-13 | Engelhard Corporation | Hydrogenation catalyst, process for preparing and process of using said catalyst |
| US5345005A (en) * | 1989-09-12 | 1994-09-06 | Engelhard Corporation | Hydrogenation catalyst, process for preparing and process of using said catalyst |
| US5134108A (en) * | 1991-05-22 | 1992-07-28 | Engelhard Corporation | Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof |
| JPH08299796A (ja) * | 1995-05-11 | 1996-11-19 | Mitsubishi Gas Chem Co Inc | メタノール合成触媒の製造法 |
| US6114279A (en) * | 1997-03-31 | 2000-09-05 | Director-General Of Agency Of Industrial Science And Technology | Catalyst for methanol synthesis and reforming |
| EP3210961B1 (en) | 2014-10-20 | 2021-03-24 | Mitsubishi Gas Chemical Company, Inc. | Methanol production method and methanol production apparatus |
| US10010875B2 (en) * | 2014-10-30 | 2018-07-03 | China Petroleum & Chemical Corporation | Method for preparing copper-zinc-based catalyst used in synthesis of methanol through CO2 hydrogenation |
| WO2016145023A1 (en) * | 2015-03-10 | 2016-09-15 | Ph Matter, Llc | Chromium-free water-gas shift catalyst and process for making the same |
| WO2024143182A1 (ja) | 2022-12-26 | 2024-07-04 | 三菱瓦斯化学株式会社 | メタノール製造方法及びメタノール製造装置 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3703386A (en) * | 1970-10-27 | 1972-11-21 | Owens Illinois Inc | Nonflow solder-stop glasses comprising lead-zinc borate and ceramic |
| US3790505A (en) * | 1971-05-04 | 1974-02-05 | Catalysts & Chem Inc | Low temperature methanol synthesis catalyst |
-
1973
- 1973-10-24 JP JP48119764A patent/JPS5144715B2/ja not_active Expired
-
1974
- 1974-10-18 GB GB45268/74A patent/GB1488042A/en not_active Expired
- 1974-10-19 DE DE2449493A patent/DE2449493C3/de not_active Expired
- 1974-10-21 US US05/516,872 patent/US3971735A/en not_active Expired - Lifetime
- 1974-10-23 CA CA212,140A patent/CA1032523A/en not_active Expired
- 1974-10-24 SU SU2076869A patent/SU525420A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5144715B2 (enExample) | 1976-11-30 |
| GB1488042A (en) | 1977-10-05 |
| JPS5068983A (enExample) | 1975-06-09 |
| DE2449493A1 (de) | 1975-04-30 |
| DE2449493B2 (de) | 1980-04-10 |
| DE2449493C3 (de) | 1980-12-11 |
| CA1032523A (en) | 1978-06-06 |
| US3971735A (en) | 1976-07-27 |
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