SU1168095A3 - Способ получени полипропилена - Google Patents
Способ получени полипропилена Download PDFInfo
- Publication number
- SU1168095A3 SU1168095A3 SU752163117A SU2163117A SU1168095A3 SU 1168095 A3 SU1168095 A3 SU 1168095A3 SU 752163117 A SU752163117 A SU 752163117A SU 2163117 A SU2163117 A SU 2163117A SU 1168095 A3 SU1168095 A3 SU 1168095A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- titanium
- polymerization
- propylene
- component
- catalyst
- Prior art date
Links
- -1 polypropylene Polymers 0.000 title claims abstract description 18
- 229920001155 polypropylene Polymers 0.000 title claims description 12
- 239000004743 Polypropylene Substances 0.000 title claims description 11
- 238000000034 method Methods 0.000 title description 4
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 5
- 239000011777 magnesium Substances 0.000 claims abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims abstract description 3
- 150000003609 titanium compounds Chemical class 0.000 claims abstract 3
- 238000006116 polymerization reaction Methods 0.000 claims description 24
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 22
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 22
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- IIHIJFJSXPDTNO-UHFFFAOYSA-N methyl cyclopentanecarboxylate Chemical compound COC(=O)C1CCCC1 IIHIJFJSXPDTNO-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 2
- ZQWPRMPSCMSAJU-UHFFFAOYSA-N methyl cyclohexanecarboxylate Chemical compound COC(=O)C1CCCCC1 ZQWPRMPSCMSAJU-UHFFFAOYSA-N 0.000 claims 2
- 229920006395 saturated elastomer Polymers 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- HBJZBPQYTLKQBY-UHFFFAOYSA-N ethyl 2-methylcyclohexane-1-carboxylate Chemical compound CCOC(=O)C1CCCCC1C HBJZBPQYTLKQBY-UHFFFAOYSA-N 0.000 claims 1
- JJOYCHKVKWDMEA-UHFFFAOYSA-N ethyl cyclohexanecarboxylate Chemical compound CCOC(=O)C1CCCCC1 JJOYCHKVKWDMEA-UHFFFAOYSA-N 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 239000010936 titanium Substances 0.000 abstract description 22
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 20
- 229910052719 titanium Inorganic materials 0.000 abstract description 20
- 239000011949 solid catalyst Substances 0.000 abstract description 3
- 125000003262 carboxylic acid ester group Chemical class [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 18
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
- 239000007787 solid Substances 0.000 description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 230000003197 catalytic effect Effects 0.000 description 11
- 239000000843 powder Substances 0.000 description 10
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- 239000003350 kerosene Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- VSIKJPJINIDELZ-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octakis-phenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VSIKJPJINIDELZ-UHFFFAOYSA-N 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- VLQZJOLYNOGECD-UHFFFAOYSA-N 2,4,6-trimethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound C[SiH]1O[SiH](C)O[SiH](C)O1 VLQZJOLYNOGECD-UHFFFAOYSA-N 0.000 description 1
- FESDHLLVLYZNFY-UHFFFAOYSA-M 2-benzylbenzoate Chemical compound [O-]C(=O)C1=CC=CC=C1CC1=CC=CC=C1 FESDHLLVLYZNFY-UHFFFAOYSA-M 0.000 description 1
- ZMNJWSHRBLQOSM-UHFFFAOYSA-N 2-methylpropyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCC(C)C)=CC=CC2=C1 ZMNJWSHRBLQOSM-UHFFFAOYSA-N 0.000 description 1
- HVXGXUAVMOCVHB-UHFFFAOYSA-M 3-octylbenzoate Chemical compound CCCCCCCCC1=CC=CC(C([O-])=O)=C1 HVXGXUAVMOCVHB-UHFFFAOYSA-M 0.000 description 1
- QCIWHVKGVVQHIY-UHFFFAOYSA-M 4-cyclohexylbenzoate Chemical compound C1=CC(C(=O)[O-])=CC=C1C1CCCCC1 QCIWHVKGVVQHIY-UHFFFAOYSA-M 0.000 description 1
- ZQVKTHRQIXSMGY-UHFFFAOYSA-M 4-ethylbenzoate Chemical compound CCC1=CC=C(C([O-])=O)C=C1 ZQVKTHRQIXSMGY-UHFFFAOYSA-M 0.000 description 1
- SGYAMNNIKRWVKZ-UHFFFAOYSA-N 6-(furan-2-yl)hexa-3,5-dien-2-one Chemical compound CC(=O)C=CC=CC1=CC=CO1 SGYAMNNIKRWVKZ-UHFFFAOYSA-N 0.000 description 1
- LYJHVEDILOKZCG-UHFFFAOYSA-N Allyl benzoate Chemical compound C=CCOC(=O)C1=CC=CC=C1 LYJHVEDILOKZCG-UHFFFAOYSA-N 0.000 description 1
- YYLLIJHXUHJATK-UHFFFAOYSA-N Cyclohexyl acetate Chemical compound CC(=O)OC1CCCCC1 YYLLIJHXUHJATK-UHFFFAOYSA-N 0.000 description 1
- VONGZNXBKCOUHB-UHFFFAOYSA-N Phenylmethyl butanoate Chemical compound CCCC(=O)OCC1=CC=CC=C1 VONGZNXBKCOUHB-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- XSBSXJAYEPDGSF-UHFFFAOYSA-N diethyl 3,5-dimethyl-1h-pyrrole-2,4-dicarboxylate Chemical compound CCOC(=O)C=1NC(C)=C(C(=O)OCC)C=1C XSBSXJAYEPDGSF-UHFFFAOYSA-N 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- WSJNYOVBJSOQST-UHFFFAOYSA-N ethyl 3-methylbenzoate Chemical compound CCOC(=O)C1=CC=CC(C)=C1 WSJNYOVBJSOQST-UHFFFAOYSA-N 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- PSXNDMJWRZYVTM-UHFFFAOYSA-N octanoic acid butyl ester Natural products CCCCCCCC(=O)OCCCC PSXNDMJWRZYVTM-UHFFFAOYSA-N 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP49091181A JPS5120297A (en) | 1974-08-10 | 1974-08-10 | Arufua orefuinno koritsutaikisokuseijugohoho |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1168095A3 true SU1168095A3 (ru) | 1985-07-15 |
Family
ID=14019272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752163117A SU1168095A3 (ru) | 1974-08-10 | 1975-08-08 | Способ получени полипропилена |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5120297A (enExample) |
| AT (1) | AT338512B (enExample) |
| BR (1) | BR7505050A (enExample) |
| CA (1) | CA1046492A (enExample) |
| DK (1) | DK152760C (enExample) |
| FI (1) | FI59107C (enExample) |
| NO (1) | NO148292C (enExample) |
| PH (1) | PH13975A (enExample) |
| PL (1) | PL106505B1 (enExample) |
| SE (1) | SE430787B (enExample) |
| SU (1) | SU1168095A3 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1054410B (it) * | 1975-11-21 | 1981-11-10 | Mitsui Petrochemical Ind | Catalizzatori per la polimerizzazione delle alfa olefine |
| JPS52100596A (en) * | 1976-02-19 | 1977-08-23 | Mitsui Petrochem Ind Ltd | Production of olefin |
| JPS53143684A (en) * | 1977-05-20 | 1978-12-14 | Mitsui Petrochem Ind Ltd | Polymerization of olefin |
| JPS5436409U (enExample) * | 1977-08-17 | 1979-03-09 | ||
| IT1209255B (it) | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| US6777508B1 (en) | 1980-08-13 | 2004-08-17 | Basell Poliolefine Italia S.P.A. | Catalysts for the polymerization of olefins |
| JPS58113209A (ja) * | 1981-12-28 | 1983-07-06 | Nippon Oil Co Ltd | ポリオレフインの製造方法 |
| JPS58113210A (ja) * | 1981-12-28 | 1983-07-06 | Nippon Oil Co Ltd | ポリオレフインの製造方法 |
| KR100341040B1 (ko) | 1994-08-18 | 2002-11-23 | 칫소가부시키가이샤 | 고강성프로필렌-에틸렌블록공중합체조성물및이의제조방법 |
| JP3355864B2 (ja) * | 1995-04-24 | 2002-12-09 | チッソ株式会社 | 高剛性プロピレン・エチレンブロック共重合体の連続製造法 |
| JP3765278B2 (ja) * | 2002-03-11 | 2006-04-12 | 東邦キャタリスト株式会社 | オレフィン類重合用固体触媒成分及び触媒 |
| JP2007039529A (ja) * | 2005-08-02 | 2007-02-15 | Toho Catalyst Co Ltd | オレフィン類重合用固体触媒成分及び触媒並びにこれを用いたオレフィン類重合体の重合方法 |
| WO2018124070A1 (ja) | 2016-12-27 | 2018-07-05 | 三井化学株式会社 | 潤滑油組成物、潤滑油用粘度調整剤、および潤滑油用添加剤組成物 |
| US11873462B2 (en) | 2019-08-29 | 2024-01-16 | Mitsui Chemicals, Inc. | Lubricating oil composition |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7114641A (enExample) * | 1970-10-29 | 1972-05-03 | ||
| GB1452314A (en) * | 1972-11-10 | 1976-10-13 | Mitsui Petrochemical Ind Ld | Catalyst compositions for use in the polymerziation of olefins |
-
1974
- 1974-08-10 JP JP49091181A patent/JPS5120297A/ja active Granted
-
1975
- 1975-01-31 CA CA219,139A patent/CA1046492A/en not_active Expired
- 1975-02-03 AT AT77275A patent/AT338512B/de not_active IP Right Cessation
- 1975-02-20 PL PL1975178214A patent/PL106505B1/pl unknown
- 1975-07-30 FI FI752175A patent/FI59107C/fi not_active IP Right Cessation
- 1975-08-04 PH PH17446A patent/PH13975A/en unknown
- 1975-08-07 BR BR7505050*A patent/BR7505050A/pt unknown
- 1975-08-08 DK DK361475A patent/DK152760C/da not_active IP Right Cessation
- 1975-08-08 SU SU752163117A patent/SU1168095A3/ru active
- 1975-08-08 NO NO752784A patent/NO148292C/no unknown
- 1975-08-08 SE SE7508961A patent/SE430787B/xx not_active IP Right Cessation
Non-Patent Citations (1)
| Title |
|---|
| Патент FR № 2113313, кл. С 08 f 1/00, опублик. 1972. Патент GB № 1299962, кл. С 3 Р, опублик. 1972. * |
Also Published As
| Publication number | Publication date |
|---|---|
| FI59107B (fi) | 1981-02-27 |
| SE7508961L (sv) | 1976-02-11 |
| JPS5236913B2 (enExample) | 1977-09-19 |
| ATA77275A (de) | 1976-12-15 |
| JPS5120297A (en) | 1976-02-18 |
| PL106505B1 (pl) | 1979-12-31 |
| NO148292B (no) | 1983-06-06 |
| SE430787B (sv) | 1983-12-12 |
| NO148292C (no) | 1983-09-14 |
| NO752784L (enExample) | 1976-02-11 |
| DK152760B (da) | 1988-05-09 |
| PH13975A (en) | 1980-11-20 |
| FI59107C (fi) | 1981-06-10 |
| DK152760C (da) | 1988-10-24 |
| BR7505050A (pt) | 1976-08-03 |
| FI752175A7 (enExample) | 1976-02-11 |
| CA1046492A (en) | 1979-01-16 |
| DK361475A (da) | 1976-02-11 |
| AT338512B (de) | 1977-08-25 |
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