SU1022657A3 - Способ получени фенилизотиоцианата - Google Patents
Способ получени фенилизотиоцианата Download PDFInfo
- Publication number
- SU1022657A3 SU1022657A3 SU782672305A SU2672305A SU1022657A3 SU 1022657 A3 SU1022657 A3 SU 1022657A3 SU 782672305 A SU782672305 A SU 782672305A SU 2672305 A SU2672305 A SU 2672305A SU 1022657 A3 SU1022657 A3 SU 1022657A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- alkoxy
- dialkylamino
- producing
- morpholino
- amino
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
- C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
- C07D295/182—Radicals derived from carboxylic acids
- C07D295/192—Radicals derived from carboxylic acids from aromatic carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/46—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=C=S groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C331/00—Derivatives of thiocyanic acid or of isothiocyanic acid
- C07C331/16—Isothiocyanates
- C07C331/28—Isothiocyanates having isothiocyanate groups bound to carbon atoms of six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
Description
Me х-хх-х- б 55,68/55,66 4,67/«,63 5,90 (lH5 .ОМе 53,80/53,96 4,06/4,09 6,27 СН- хЧйООМе 52,17 $(IR y iOOMe 52,35 .OjNS ,0,NS C,H,, /5,89 13,51/13,55 -80,3 14,36/14,26 - 59,2 /6,25 - 78,3 . оме (iH s; 100Me «iOOEV ,OE JOI SCK СООМб - $CH - -SX COOCH 55,12/55,22 Me 59,07/59,27 OMe . 57,59/57,46 5,64/5,63 11,20/11,04 Ме Me 54,13/54,08 5,30/5,21 10,52/10,54 OMe56,82/56,92 5,64/5,62 11,04/11,30 : OMe 54,13/54,04 5,30/5,38 10,52/10,22
Продолжение таблицы
- 84,3
- 64,3 ,0,N,S «1/10 H,0 . 55,68/56,16 4,67/4,78 5,90/5,87 13,51/13,55 - 58,7 52,17/52,28 4,38/4,40 5,53/5,48 12,66/11,98 57 ,35/57,27 5,21/5,23 5,58/5,62 12,76/12,55 - 67,6 57,37/57,27 5,22/5,21 5,58/5,49 12,76/12,77 С,, С, H. ,o,NS C,,NS 1 H 7 6,00/5,854,95/4,14 11,31/12,70 .S 6,10/6,10 10,60/10,48 12,13/12,31 12,81/12,78 - 75,9 12,04/12,10 - 57,2 12,64/12,76 - 91,1 12,04/12,03 -42,8 Элементный анализ JR анализ Соединение . ..
Продолжение. таОлицы/
« - - 4 ( вычислено/найдено }j % ( вычислено/найдено/7 « дцтг --т1 --рг , г- i..J.i.... .. (iooMe .x.,OMe АЫй 25К )... JK3i El $( 51,24/50,77 3,94/3,98 4,98/4,73 11,40/11,94 -57,0 59,07/59,27 6,10/6,10 10,60/10,48 12,13/12,31 -64,3 C,,NS ,N,S 26 27 30 31 33
Продолжение таблицы Me 4x;2s.OM€ ТОТ/bit i(iH ,79/59,82 7,21/7,20 13,08/12,97 9,98/10,12 -64,7 МСч с H. S ,-. we TOT j54,13/54,065,30/5,3010,52/10,5212.04/11,88- 51,4 IfiU С OOMe 11,5 O N2SCI (iONH-Ю 58,87/58,91 4,36/4,28 8,08/8,02 9,24/9Д4 10,22/46,0 ( ilv OMe iOOM«46,61/46,753,13/3,06 5,44/5,. i-lVSY bC HnOiNzSCl/13,62 1C Jl . 48,80/,8,69 ,9910,35/10,3411,84/11,9513,09/ 58,1 We/13,29 Hl.WfiC,,N4SCl 1ГИ. ., Лй« :: ttSWHC 46,79/46,773,53/3,43 10,91/10,9112,49/12,5913,81/56,2 16Г п ull ОШчЛо- - 51, ,46/51,42 4,63/4,68 8,57/8,62 10,65/10,83-9,81/5, Me it« y oow 53,80/53,924,06/4,11 6,27/6,3514,36/14,06 - 6,0 C gligO NSCl , 46 12,44/12,58 13,76/41,0 /13,so . (:„ 1Ц5П.,С15 /10,12 Сед i ХХ Me ffiT (i-N 0 37 tS . 38 O6uiHft выход из соответ 55,68/55,83 5,75/5,78 9,99/9,9022,87/22,60 - 58,8 54,52/54,645,23/5,18 9,08/9,1020,79/20,88- 59,9 49,25/49,54 4,51/4,56 10,45/10,3423,91/24,16,- 64,8 твукхцего нитросоединени . To же, что и в примере 34 ,,ON,S2 СиЧб 2 2 2 I .
9102265710
Фенилизотиоцианаты формулы (I) NTO-мучниста роса тыквенна , ложна мучгут быть использованы в качестве роса тыквенна , антракноз
сельскохоз йственных фунгицидов втыквенный, вредители рисо.вых расгеборьВе с различными фиуопатогеннымнний и заболевани ми,вызываюсцимиув дагрибками , в частности с такими,каккие-различных культур растений .
Claims (1)
- (541 СПОСОБ ПОЛУЧЕНИЯ ФЕНИЛИЗОТИО ЦИАНАТА общей формулы где - С4 -Cg-алкокси, гидроксил, амино, метиламино, С^-С^диалкиламино, фенокси, матил пиперазино, морфолино, тетрагидрофурфуриламино, диметиланилин, диэтиламиноэтиламино ;R2 - С4-С?-алкокси, этоксикарбонил/R-j - водород, метил, метокси, хлор, диметиламино, о т л и ч а ю ш и.й ся тем, что соединение общей формулы где R<- Rj имеют указанные значения, подвергают взаимодействию с сероуглеродом в органическом растворителе в присутствии триэтиламина с последующей обработкой полученного продукта реакции алкилгалоидкарбонатом.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP52119789A JPS6034542B2 (ja) | 1977-10-04 | 1977-10-04 | 新規イソチオシアン酸フエニルエステル類 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1022657A3 true SU1022657A3 (ru) | 1983-06-07 |
Family
ID=14770251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU782672305A SU1022657A3 (ru) | 1977-10-04 | 1978-10-04 | Способ получени фенилизотиоцианата |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US4248869A (ru) |
| JP (1) | JPS6034542B2 (ru) |
| AU (1) | AU518311B2 (ru) |
| BE (1) | BE870991A (ru) |
| BR (1) | BR7806553A (ru) |
| CA (1) | CA1091669A (ru) |
| CH (1) | CH637636A5 (ru) |
| DE (1) | DE2843291A1 (ru) |
| DK (1) | DK435978A (ru) |
| ES (1) | ES473896A1 (ru) |
| FR (1) | FR2405244A1 (ru) |
| GB (1) | GB2005268B (ru) |
| IE (1) | IE47663B1 (ru) |
| IL (1) | IL55675A (ru) |
| IT (1) | IT1108121B (ru) |
| NL (1) | NL7810026A (ru) |
| NO (1) | NO146059C (ru) |
| SE (1) | SE7810312L (ru) |
| SU (1) | SU1022657A3 (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2490256C2 (ru) * | 2008-02-29 | 2013-08-20 | Ниссан Кемикал Индастриз, Лтд. | Способ получения изотиоцианатного соединения, содержащего карбоксильную группу |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2485526A1 (fr) * | 1980-06-24 | 1981-12-31 | Shionogi & Co | Procede de preparation de derives de n-(diethylaminoethyl)-2 - alcoxybenzamide, nouveaux produits ainsi obtenus et leurs utilisations comme produits pharmaceutiques antiemetiques ou pour guerir les troubles gastriques |
| US4680338A (en) * | 1985-10-17 | 1987-07-14 | Immunomedics, Inc. | Bifunctional linker |
| JPH0752055Y2 (ja) * | 1989-06-14 | 1995-11-29 | 株式会社ミドリ十字 | 抗菌性容器 |
| US5436268A (en) * | 1989-11-09 | 1995-07-25 | The Green Cross Corporation | Processes including germ-destroying step, germicidal products and their preparation method, fumigant and fumigation method, as well as germicidal gas compositions, their preparation method and apparatus therefor |
| KR0153246B1 (ko) * | 1989-11-09 | 1998-10-15 | 가와노 다께히꼬 | 이소티오시안산 에스테르를 이용한 살균처리를 수반하는 식품의 가공방법 |
| SK44894A3 (en) | 1991-10-18 | 1995-04-12 | Monsanto Co | Trisubstituted aromatic compounds, method of their preparation and fungicidal agents |
| HRP921338B1 (en) * | 1992-10-02 | 2002-04-30 | Monsanto Co | Fungicides for the control of take-all disease of plants |
| CA2124137A1 (en) * | 1993-05-25 | 1994-11-26 | Mitsuhiro Matsumoto | Process for producing aromatic isothiocyanate derivatives |
| US5482974A (en) * | 1994-03-08 | 1996-01-09 | Monsanto Company | Selected fungicides for the control of take-all disease of plants |
| US5486621A (en) * | 1994-12-15 | 1996-01-23 | Monsanto Company | Fungicides for the control of take-all disease of plants |
| ES2211577T3 (es) | 1999-08-13 | 2004-07-16 | Monsanto Technology Llc | Amidas oxima y amidas hidrazona con actividad fungicida. |
| CN103221389B (zh) * | 2010-11-29 | 2016-01-20 | 日产化学工业株式会社 | 异硫氰酸酯化合物的制造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL290565A (ru) * | 1962-03-23 | |||
| US3781360A (en) * | 1966-01-14 | 1973-12-25 | Schering Corp | 2-polyfluoroloweralkylamino benzophenones |
| US3755358A (en) * | 1966-01-14 | 1973-08-28 | Schering Corp | 2-(n-(phthalimidoacetyl)-n-(polyfluoroloweralkyl))aminobenzophenones |
| US3449112A (en) * | 1966-02-04 | 1969-06-10 | Upjohn Co | P-isothiocyanatobenzoates as herbicides |
| US3480424A (en) * | 1966-02-04 | 1969-11-25 | Upjohn Co | Phenylisothiocyanates as herbicides |
| DE1793480A1 (de) * | 1968-09-24 | 1972-02-24 | Basf Ag | Fungizid |
| DE2013788A1 (en) * | 1970-03-23 | 1971-10-21 | Farbenfabriken Bayer Ag, 5090 Lever Kusen | Aryl isothiocyanate miticides |
| GB1318681A (en) * | 1971-01-01 | 1973-05-31 | Shell Int Research | Phenyl ketoxime derivatives |
-
1977
- 1977-10-04 JP JP52119789A patent/JPS6034542B2/ja not_active Expired
-
1978
- 1978-09-25 US US05/946,422 patent/US4248869A/en not_active Expired - Lifetime
- 1978-09-28 GB GB7838560A patent/GB2005268B/en not_active Expired
- 1978-09-29 CA CA312,384A patent/CA1091669A/en not_active Expired
- 1978-10-02 NO NO783323A patent/NO146059C/no unknown
- 1978-10-02 SE SE7810312A patent/SE7810312L/xx unknown
- 1978-10-02 DK DK435978A patent/DK435978A/da not_active Application Discontinuation
- 1978-10-02 IE IE1962/78A patent/IE47663B1/en unknown
- 1978-10-03 BR BR7806553A patent/BR7806553A/pt unknown
- 1978-10-03 FR FR7828275A patent/FR2405244A1/fr active Granted
- 1978-10-03 BE BE78190892A patent/BE870991A/xx not_active IP Right Cessation
- 1978-10-03 ES ES473896A patent/ES473896A1/es not_active Expired
- 1978-10-03 AU AU40376/78A patent/AU518311B2/en not_active Expired
- 1978-10-04 IL IL55675A patent/IL55675A/xx unknown
- 1978-10-04 IT IT69295/78A patent/IT1108121B/it active
- 1978-10-04 CH CH1032878A patent/CH637636A5/de not_active IP Right Cessation
- 1978-10-04 SU SU782672305A patent/SU1022657A3/ru active
- 1978-10-04 DE DE19782843291 patent/DE2843291A1/de not_active Ceased
- 1978-10-04 NL NL7810026A patent/NL7810026A/xx not_active Application Discontinuation
-
1979
- 1979-06-11 US US06/047,803 patent/US4228165A/en not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| ) 1. Патент Вельгии 1545679, кл. С 07 С, опублик. . * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2490256C2 (ru) * | 2008-02-29 | 2013-08-20 | Ниссан Кемикал Индастриз, Лтд. | Способ получения изотиоцианатного соединения, содержащего карбоксильную группу |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1108121B (it) | 1985-12-02 |
| IL55675A (en) | 1982-11-30 |
| FR2405244A1 (fr) | 1979-05-04 |
| US4228165A (en) | 1980-10-14 |
| IE781962L (en) | 1979-04-04 |
| AU518311B2 (en) | 1981-09-24 |
| JPS6034542B2 (ja) | 1985-08-09 |
| SE7810312L (sv) | 1979-04-05 |
| AU4037678A (en) | 1980-04-17 |
| ES473896A1 (es) | 1979-10-16 |
| FR2405244B1 (ru) | 1981-12-11 |
| GB2005268B (en) | 1982-06-23 |
| BE870991A (fr) | 1979-02-01 |
| NO783323L (no) | 1979-04-05 |
| CA1091669A (en) | 1980-12-16 |
| NO146059C (no) | 1982-07-21 |
| DK435978A (da) | 1979-04-05 |
| GB2005268A (en) | 1979-04-19 |
| IT7869295A0 (it) | 1978-10-04 |
| NL7810026A (nl) | 1979-04-06 |
| CH637636A5 (de) | 1983-08-15 |
| JPS5455550A (en) | 1979-05-02 |
| NO146059B (no) | 1982-04-13 |
| IE47663B1 (en) | 1984-05-16 |
| DE2843291A1 (de) | 1979-04-12 |
| US4248869A (en) | 1981-02-03 |
| IL55675A0 (en) | 1978-12-17 |
| BR7806553A (pt) | 1979-05-02 |
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