SK202001A3 - A catalyst composition and methods for its preparation and use in a polymerization process - Google Patents
A catalyst composition and methods for its preparation and use in a polymerization process Download PDFInfo
- Publication number
- SK202001A3 SK202001A3 SK20-2001A SK202001A SK202001A3 SK 202001 A3 SK202001 A3 SK 202001A3 SK 202001 A SK202001 A SK 202001A SK 202001 A3 SK202001 A3 SK 202001A3
- Authority
- SK
- Slovakia
- Prior art keywords
- catalyst
- polymerization
- reactor
- metal salt
- polymerization catalyst
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 341
- 238000000034 method Methods 0.000 title claims abstract description 187
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 101
- 239000000203 mixture Substances 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 178
- 239000002184 metal Substances 0.000 claims abstract description 178
- 239000003446 ligand Substances 0.000 claims abstract description 154
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 142
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 140
- 150000003839 salts Chemical class 0.000 claims abstract description 140
- 150000001336 alkenes Chemical class 0.000 claims abstract description 38
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 230000008569 process Effects 0.000 claims description 139
- 229920000642 polymer Polymers 0.000 claims description 110
- 150000001875 compounds Chemical class 0.000 claims description 107
- -1 stearate compound Chemical class 0.000 claims description 57
- 125000004432 carbon atom Chemical group C* 0.000 claims description 45
- 150000003624 transition metals Chemical class 0.000 claims description 45
- 229910052723 transition metal Inorganic materials 0.000 claims description 44
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 37
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 35
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- 239000005977 Ethylene Substances 0.000 claims description 31
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- 239000000463 material Substances 0.000 claims description 21
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- 230000015572 biosynthetic process Effects 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 20
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- 125000005843 halogen group Chemical group 0.000 claims description 9
- 230000000379 polymerizing effect Effects 0.000 claims description 9
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- 230000008018 melting Effects 0.000 claims description 8
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- 238000012685 gas phase polymerization Methods 0.000 claims description 5
- 229940083916 aluminum distearate Drugs 0.000 claims description 4
- RDIVANOKKPKCTO-UHFFFAOYSA-K aluminum;octadecanoate;hydroxide Chemical compound [OH-].[Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O RDIVANOKKPKCTO-UHFFFAOYSA-K 0.000 claims description 4
- 125000004104 aryloxy group Chemical group 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 3
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- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 6
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- 229910000077 silane Inorganic materials 0.000 claims 2
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- 230000000694 effects Effects 0.000 description 14
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 14
- 239000012968 metallocene catalyst Substances 0.000 description 14
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 13
- 239000000377 silicon dioxide Substances 0.000 description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 12
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- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 9
- 150000002367 halogens Chemical group 0.000 description 9
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- 239000010703 silicon Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 229910052720 vanadium Inorganic materials 0.000 description 9
- 239000007983 Tris buffer Substances 0.000 description 8
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- 238000002474 experimental method Methods 0.000 description 7
- 125000005842 heteroatom Chemical group 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
- 239000001282 iso-butane Substances 0.000 description 7
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- 230000003068 static effect Effects 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
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- 238000000151 deposition Methods 0.000 description 6
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- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- IUGYQRQAERSCNH-UHFFFAOYSA-M pivalate Chemical compound CC(C)(C)C([O-])=O IUGYQRQAERSCNH-UHFFFAOYSA-M 0.000 description 6
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Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/02—Anti-static agent incorporated into the catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/113,216 US7354880B2 (en) | 1998-07-10 | 1998-07-10 | Catalyst composition and methods for its preparation and use in a polymerization process |
| PCT/US1999/014214 WO2000002931A1 (en) | 1998-07-10 | 1999-06-23 | A catalyst composition and methods for its preparation and use in a polymerization process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK202001A3 true SK202001A3 (en) | 2001-10-08 |
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| SK20-2001A SK202001A3 (en) | 1998-07-10 | 1999-06-23 | A catalyst composition and methods for its preparation and use in a polymerization process |
| SK19-2001A SK192001A3 (en) | 1998-07-10 | 1999-06-23 | A CATALYST COMPOSITION AND METHODS FOR ITS PREPARATION AND USE INì (54) A POLYMERIZATION PROCESS |
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| SK19-2001A SK192001A3 (en) | 1998-07-10 | 1999-06-23 | A CATALYST COMPOSITION AND METHODS FOR ITS PREPARATION AND USE INì (54) A POLYMERIZATION PROCESS |
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-
1998
- 1998-07-10 US US09/113,216 patent/US7354880B2/en not_active Expired - Fee Related
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1999
- 1999-06-23 CN CNB998081019A patent/CN1166700C/zh not_active Expired - Lifetime
- 1999-06-23 IL IL13955399A patent/IL139553A0/xx unknown
- 1999-06-23 IL IL13955499A patent/IL139554A0/xx unknown
- 1999-06-23 BR BR9911988-9A patent/BR9911988A/pt not_active IP Right Cessation
- 1999-06-23 SK SK20-2001A patent/SK202001A3/sk unknown
- 1999-06-23 EP EP99930603A patent/EP1102798B1/en not_active Expired - Lifetime
- 1999-06-23 AU AU47100/99A patent/AU762896B2/en not_active Ceased
- 1999-06-23 CA CA002333239A patent/CA2333239C/en not_active Expired - Lifetime
- 1999-06-23 CN CNB998080969A patent/CN1133661C/zh not_active Expired - Fee Related
- 1999-06-23 TR TR2001/00006T patent/TR200100006T2/xx unknown
- 1999-06-23 KR KR1020017000083A patent/KR20010083089A/ko not_active Ceased
- 1999-06-23 PL PL99345417A patent/PL345417A1/xx not_active Application Discontinuation
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- 1999-06-23 CA CA002332324A patent/CA2332324A1/en not_active Abandoned
- 1999-06-23 ID IDW20010025A patent/ID26870A/id unknown
- 1999-06-23 WO PCT/US1999/014214 patent/WO2000002931A1/en not_active Ceased
- 1999-06-23 TR TR2001/00010T patent/TR200100010T2/xx unknown
- 1999-06-23 RU RU2000132194/04A patent/RU2233291C2/ru active
- 1999-06-23 JP JP2000559159A patent/JP2002520427A/ja not_active Withdrawn
- 1999-06-23 KR KR10-2001-7000081A patent/KR100470577B1/ko not_active Expired - Lifetime
- 1999-06-23 SK SK19-2001A patent/SK192001A3/sk unknown
- 1999-06-23 JP JP2000559160A patent/JP2002520428A/ja active Pending
- 1999-06-23 WO PCT/US1999/014192 patent/WO2000002930A1/en not_active Ceased
- 1999-06-23 AU AU47107/99A patent/AU752470B2/en not_active Ceased
- 1999-06-23 ES ES99930603T patent/ES2331341T3/es not_active Expired - Lifetime
- 1999-06-23 BR BR9912025-9A patent/BR9912025A/pt not_active IP Right Cessation
- 1999-06-23 DE DE69941191T patent/DE69941191D1/de not_active Expired - Lifetime
- 1999-06-23 EP EP99930593A patent/EP1123322A1/en not_active Withdrawn
- 1999-07-01 TW TW088111209A patent/TWI239962B/zh not_active IP Right Cessation
- 1999-07-07 EG EG82499A patent/EG22259A/xx active
- 1999-07-07 EG EG82599A patent/EG22216A/xx active
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- 2001-08-20 US US09/932,912 patent/US6472342B2/en not_active Expired - Lifetime
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