SE523938C2 - Stabiliserad gummiberedning, metod för stabilisering av gummi samt användning av stabilisator för stabilisering av gummi - Google Patents
Stabiliserad gummiberedning, metod för stabilisering av gummi samt användning av stabilisator för stabilisering av gummiInfo
- Publication number
- SE523938C2 SE523938C2 SE0003700A SE0003700A SE523938C2 SE 523938 C2 SE523938 C2 SE 523938C2 SE 0003700 A SE0003700 A SE 0003700A SE 0003700 A SE0003700 A SE 0003700A SE 523938 C2 SE523938 C2 SE 523938C2
- Authority
- SE
- Sweden
- Prior art keywords
- tert
- butyl
- rubber
- latex
- formula
- Prior art date
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 52
- 239000005060 rubber Substances 0.000 title claims abstract description 50
- 239000003381 stabilizer Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims description 8
- 230000000087 stabilizing effect Effects 0.000 title claims description 6
- 238000002360 preparation method Methods 0.000 title description 4
- -1 C1-C12alkyl Chemical group 0.000 claims abstract description 87
- 239000000203 mixture Substances 0.000 claims abstract description 48
- 239000000839 emulsion Substances 0.000 claims abstract description 44
- 229920000126 latex Polymers 0.000 claims abstract description 41
- 239000004816 latex Substances 0.000 claims abstract description 40
- 150000001875 compounds Chemical class 0.000 claims abstract description 36
- 229920006173 natural rubber latex Polymers 0.000 claims abstract description 23
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 10
- 230000015556 catabolic process Effects 0.000 claims abstract description 9
- 238000006731 degradation reaction Methods 0.000 claims abstract description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 9
- 239000001257 hydrogen Substances 0.000 claims abstract description 9
- 230000001590 oxidative effect Effects 0.000 claims abstract description 9
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims abstract 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 22
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 239000002174 Styrene-butadiene Substances 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 14
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
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- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
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- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
- C08L21/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/375—Thiols containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
- Paper (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH190099 | 1999-10-18 | ||
| CH189999 | 1999-10-18 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE0003700D0 SE0003700D0 (sv) | 2000-10-13 |
| SE0003700L SE0003700L (sv) | 2001-04-19 |
| SE523938C2 true SE523938C2 (sv) | 2004-06-01 |
Family
ID=25688952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE0003700A SE523938C2 (sv) | 1999-10-18 | 2000-10-13 | Stabiliserad gummiberedning, metod för stabilisering av gummi samt användning av stabilisator för stabilisering av gummi |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6596796B1 (fr) |
| JP (1) | JP2001158839A (fr) |
| KR (1) | KR100642673B1 (fr) |
| BE (1) | BE1013756A3 (fr) |
| CA (1) | CA2323319C (fr) |
| CZ (1) | CZ301379B6 (fr) |
| DE (1) | DE10051198A1 (fr) |
| ES (1) | ES2178568B1 (fr) |
| FR (1) | FR2799764B1 (fr) |
| GB (1) | GB2355463B (fr) |
| IT (1) | IT1319212B1 (fr) |
| NL (1) | NL1016412C2 (fr) |
| RU (1) | RU2255946C2 (fr) |
| SE (1) | SE523938C2 (fr) |
| TW (1) | TWI275617B (fr) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101104780B1 (ko) * | 2003-11-03 | 2012-01-13 | 시바 홀딩 인코포레이티드 | 할로겐 함유 중합체용 안정화제 조성물 |
| GB0418312D0 (en) * | 2004-08-17 | 2004-09-15 | Great Lakes Chemical Europ | Self-emulsifying liquid stabilisers |
| JP2007270057A (ja) * | 2006-03-31 | 2007-10-18 | Nippon Zeon Co Ltd | ラテックス組成物 |
| WO2008117620A1 (fr) * | 2007-03-27 | 2008-10-02 | Zeon Corporation | Latex de caoutchouc, latex de caoutchouc pour moulage par immersion et article moulé par immersion. |
| CN102027056B (zh) * | 2008-05-15 | 2013-09-18 | 巴斯夫欧洲公司 | 用于乳液聚合的橡胶的基本稳定体系 |
| DE102011003425B4 (de) * | 2011-02-01 | 2015-01-08 | Henkel Ag & Co. Kgaa | Verwendung einer härtbaren Zusammensetzung mit kombinierten Stabilisatoren |
| CN102942718A (zh) * | 2012-11-29 | 2013-02-27 | 利安隆（天津）化工有限公司 | 用于丁二烯类合成橡胶生产中的复配抗氧化剂及应用 |
| CN103030843A (zh) * | 2012-12-27 | 2013-04-10 | 利安隆（天津）化工有限公司 | 用于丁二烯合成橡胶生产用复配抗氧化剂及应用 |
| CN103435956B (zh) * | 2013-08-28 | 2016-03-02 | 天津利安隆新材料股份有限公司 | 用于热塑性丁苯嵌段共聚物的抗氧化剂 |
| CN103497376B (zh) * | 2013-09-13 | 2015-05-20 | 天津利安隆新材料股份有限公司 | 应用于丁腈胶乳和羧基丁腈胶乳的抗氧化剂及制备方法 |
| CN103881172B (zh) * | 2014-04-09 | 2015-12-30 | 天津利安隆新材料股份有限公司 | 乳液聚合丁苯橡胶生产用复配抗氧化剂 |
| KR101964278B1 (ko) * | 2015-11-24 | 2019-04-01 | 주식회사 엘지화학 | 딥 성형용 라텍스 조성물 및 이로부터 제조된 딥 성형품 |
| RU2687970C1 (ru) * | 2018-07-27 | 2019-05-17 | Публичное акционерное общество "СИБУР Холдинг" | Антиоксидантная композиция, применяемая для стабилизации бутадиен-стирольных блок-сополимеров |
| WO2021133188A1 (fr) * | 2019-12-25 | 2021-07-01 | Публичное Акционерное Общество "Сибур Холдинг" (Пао "Сибур Холдинг") | Composition de stabilisation de latex et procédé de production |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL284832A (fr) * | 1961-10-30 | |||
| US4228297A (en) | 1972-12-27 | 1980-10-14 | Ciba-Geigy Corporation | Process for the production of hydroxyalkylphenyl derivatives |
| US3962123A (en) * | 1974-05-20 | 1976-06-08 | Ciba-Geigy Corporation | Phenolic antioxidant aqueous dispersions |
| EP0165209B1 (fr) * | 1984-06-12 | 1989-07-19 | Ciba-Geigy Ag | Phénols o'-substitués, o,p-bifonctionnalisés |
| DE3531497A1 (de) | 1985-09-04 | 1987-03-05 | Bayer Ag | Schwefelhaltige aliphatische polyester und ihre verwendung als stabilisatoren fuer polymere |
| ES2014433B3 (es) * | 1985-11-13 | 1990-07-16 | Ciba-Geigy Ag | Fenoles sustituidos, como estabilizadores. |
| US4713475A (en) | 1986-06-12 | 1987-12-15 | Ciba-Geigy Corporation | Long chain (4-hydroxyphenyl) propanoate stabilizers |
| JPS63122750A (ja) * | 1986-11-12 | 1988-05-26 | Adeka Argus Chem Co Ltd | 安定化されたゴム強化スチレン系樹脂組成物 |
| EP0273013B2 (fr) * | 1986-12-24 | 1996-07-24 | Ciba-Geigy Ag | Phénols substitués utilisables comme des stabilisateurs |
| JP2952387B2 (ja) * | 1989-08-31 | 1999-09-27 | 住友化学工業株式会社 | 耐γ線変着色性スチレンブタジェンブロック共重合体組成物 |
| CA2029708C (fr) | 1989-11-14 | 2003-07-29 | Paul Dubs | Melanges stabilisants pour des elastomeres |
| GB2252324A (en) | 1990-12-20 | 1992-08-05 | Bp Chem Int Ltd | Stabilizer composition |
| DE4041320A1 (de) | 1990-12-21 | 1992-06-25 | Hoechst Ag | Verfahren zur herstellung von ethylen-alkencarbonsaeureester-mischpolymerisaten |
| JP3059499B2 (ja) * | 1991-01-29 | 2000-07-04 | 日本エラストマー株式会社 | 共役ジエン系ゴム組成物 |
| JP3151461B2 (ja) * | 1991-01-29 | 2001-04-03 | 日本エラストマー株式会社 | ジエン系重合体組成物 |
| TW254955B (fr) * | 1992-09-25 | 1995-08-21 | Ciba Geigy | |
| TW406127B (en) | 1992-12-21 | 2000-09-21 | Ciba Sc Holding Ag | Novel liquid phenolic antioxidants |
| DE4244609C2 (de) | 1992-12-31 | 1996-07-11 | Thueringisches Inst Textil | Stabile Form- und Spinnmasse |
| DE4331083A1 (de) | 1993-09-13 | 1995-03-16 | Basf Ag | Lagerstabile, nach phosgenfreien Verfahren erhältliche Polyisocyanatzusammensetzungen, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP3401349B2 (ja) * | 1994-12-07 | 2003-04-28 | 新日本石油株式会社 | 潤滑油組成物 |
| JP3401348B2 (ja) * | 1994-12-07 | 2003-04-28 | 新日本石油株式会社 | 潤滑油組成物 |
| DE19701869A1 (de) | 1997-01-21 | 1997-09-18 | Agfa Gevaert Ag | Farbfotografisches Aufzeichnungsmaterial |
| WO1998044034A1 (fr) * | 1997-03-31 | 1998-10-08 | Asahi Kasei Kogyo Kabushiki Kaisha | Composition polymere de diene conjugue et resine de styrene a renfort de caoutchouc |
-
2000
- 2000-10-11 GB GB0024855A patent/GB2355463B/en not_active Expired - Fee Related
- 2000-10-12 RU RU2000125657/04A patent/RU2255946C2/ru not_active IP Right Cessation
- 2000-10-13 SE SE0003700A patent/SE523938C2/sv unknown
- 2000-10-13 IT IT2000MI002218A patent/IT1319212B1/it active
- 2000-10-16 DE DE10051198A patent/DE10051198A1/de not_active Withdrawn
- 2000-10-16 BE BE2000/0657A patent/BE1013756A3/fr not_active IP Right Cessation
- 2000-10-16 CZ CZ20003826A patent/CZ301379B6/cs not_active IP Right Cessation
- 2000-10-16 CA CA002323319A patent/CA2323319C/fr not_active Expired - Fee Related
- 2000-10-16 TW TW089121550A patent/TWI275617B/zh not_active IP Right Cessation
- 2000-10-16 US US09/688,417 patent/US6596796B1/en not_active Expired - Fee Related
- 2000-10-16 NL NL1016412A patent/NL1016412C2/nl not_active IP Right Cessation
- 2000-10-17 ES ES200002483A patent/ES2178568B1/es not_active Expired - Fee Related
- 2000-10-17 KR KR1020000060969A patent/KR100642673B1/ko not_active IP Right Cessation
- 2000-10-17 FR FR0013271A patent/FR2799764B1/fr not_active Expired - Fee Related
- 2000-10-18 JP JP2000317922A patent/JP2001158839A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2001158839A (ja) | 2001-06-12 |
| SE0003700D0 (sv) | 2000-10-13 |
| FR2799764B1 (fr) | 2006-07-21 |
| CA2323319A1 (fr) | 2001-04-18 |
| NL1016412C2 (nl) | 2001-06-28 |
| FR2799764A1 (fr) | 2001-04-20 |
| GB2355463B (en) | 2001-12-05 |
| ES2178568B1 (es) | 2003-11-01 |
| GB2355463A (en) | 2001-04-25 |
| ES2178568A1 (es) | 2002-12-16 |
| KR20010051070A (ko) | 2001-06-25 |
| CZ20003826A3 (en) | 2001-06-13 |
| SE0003700L (sv) | 2001-04-19 |
| CZ301379B6 (cs) | 2010-02-03 |
| CA2323319C (fr) | 2008-11-25 |
| ITMI20002218A1 (it) | 2002-04-13 |
| IT1319212B1 (it) | 2003-09-26 |
| DE10051198A1 (de) | 2001-05-23 |
| US6596796B1 (en) | 2003-07-22 |
| BE1013756A3 (fr) | 2002-07-02 |
| RU2255946C2 (ru) | 2005-07-10 |
| NL1016412A1 (nl) | 2001-04-19 |
| KR100642673B1 (ko) | 2006-11-10 |
| TWI275617B (en) | 2007-03-11 |
| GB0024855D0 (en) | 2000-11-22 |
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