SE522822C2 - Hydroxifenyltriaziner - Google Patents

Info

Publication number

SE522822C2

SE522822C2 SE9703288A SE9703288A SE522822C2 SE 522822 C2 SE522822 C2 SE 522822C2 SE 9703288 A SE9703288 A SE 9703288A SE 9703288 A SE9703288 A SE 9703288A SE 522822 C2 SE522822 C2 SE 522822C2

Authority

SE

Sweden

Prior art keywords

alkyl

alkoxy

substituted

halogen

tert

Prior art date

1996-09-13

Links

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• Global Dossier
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• VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical class OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 title 1
• 150000001875 compounds Chemical class 0.000 claims abstract description 74
• 150000002367 halogens Chemical class 0.000 claims abstract description 48
• 229910052736 halogen Inorganic materials 0.000 claims abstract description 47
• 125000001424 substituent group Chemical group 0.000 claims abstract description 27
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
• 239000001301 oxygen Substances 0.000 claims abstract description 13
• 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
• 239000011368 organic material Substances 0.000 claims abstract description 10
• 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims abstract description 9
• 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims abstract description 8
• 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 3
• 150000001340 alkali metals Chemical class 0.000 claims abstract description 3
• 229910006069 SO3H Inorganic materials 0.000 claims abstract 3
• -1 C4-C12-cycloalkyl Chemical group 0.000 claims description 161
• 239000000203 mixture Substances 0.000 claims description 54
• 125000000217 alkyl group Chemical group 0.000 claims description 40
• 229910052739 hydrogen Inorganic materials 0.000 claims description 35
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 33
• 229920000642 polymer Polymers 0.000 claims description 26
• 239000003381 stabilizer Substances 0.000 claims description 25
• 229920005989 resin Polymers 0.000 claims description 22
• 239000011347 resin Substances 0.000 claims description 22
• 125000003118 aryl group Chemical group 0.000 claims description 21
• 229910052751 metal Inorganic materials 0.000 claims description 20
• 239000002184 metal Substances 0.000 claims description 20
• 125000003545 alkoxy group Chemical group 0.000 claims description 18
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 18
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 18
• 238000002360 preparation method Methods 0.000 claims description 17
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
• 239000011230 binding agent Substances 0.000 claims description 16
• 239000000463 material Substances 0.000 claims description 16
• 238000000034 method Methods 0.000 claims description 16
• 239000002253 acid Substances 0.000 claims description 14
• 239000002537 cosmetic Substances 0.000 claims description 14
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 14
• 239000004814 polyurethane Substances 0.000 claims description 13
• 229910052799 carbon Inorganic materials 0.000 claims description 12
• 125000001072 heteroaryl group Chemical group 0.000 claims description 12
• 239000001257 hydrogen Substances 0.000 claims description 12
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 12
• 229910052727 yttrium Inorganic materials 0.000 claims description 12
• 125000002947 alkylene group Chemical group 0.000 claims description 10
• 125000001624 naphthyl group Chemical group 0.000 claims description 10
• 239000004305 biphenyl Substances 0.000 claims description 9
• 235000010290 biphenyl Nutrition 0.000 claims description 9
• 239000004922 lacquer Substances 0.000 claims description 9
• 150000003839 salts Chemical class 0.000 claims description 9
• 230000000087 stabilizing effect Effects 0.000 claims description 9
• 239000000654 additive Substances 0.000 claims description 8
• 125000004429 atom Chemical group 0.000 claims description 7
• 229920000180 alkyd Polymers 0.000 claims description 6
• 230000000475 sunscreen effect Effects 0.000 claims description 6
• 239000000516 sunscreening agent Substances 0.000 claims description 6
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 5
• 239000002966 varnish Substances 0.000 claims description 5
• 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 4
• 125000001188 haloalkyl group Chemical group 0.000 claims description 4
• 229920001225 polyester resin Polymers 0.000 claims description 4
• 229920000178 Acrylic resin Polymers 0.000 claims description 3
• 125000003302 alkenyloxy group Chemical group 0.000 claims description 3
• 150000001602 bicycloalkyls Chemical group 0.000 claims description 3
• 125000000392 cycloalkenyl group Chemical group 0.000 claims description 3
• 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
• XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 2
• 150000001616 biphenylenes Chemical class 0.000 claims description 2
• 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 claims description 2
• 229920000620 organic polymer Polymers 0.000 claims description 2
• 229920006122 polyamide resin Polymers 0.000 claims description 2
• 229920005749 polyurethane resin Polymers 0.000 claims description 2
• 229920001059 synthetic polymer Polymers 0.000 claims description 2
• 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 3
• 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims 1
• 125000000081 (C5-C8) cycloalkenyl group Chemical group 0.000 claims 1
• 150000001412 amines Chemical class 0.000 abstract description 15
• 230000006641 stabilisation Effects 0.000 abstract description 6
• 125000003860 C1-C20 alkoxy group Chemical group 0.000 abstract description 4
• 230000000254 damaging effect Effects 0.000 abstract 1
• 229910052757 nitrogen Inorganic materials 0.000 description 38
• 229920001577 copolymer Polymers 0.000 description 35
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 31
• 239000003054 catalyst Substances 0.000 description 18
• 239000003973 paint Substances 0.000 description 18
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 16
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
• 239000004743 Polypropylene Substances 0.000 description 15
• 229920001155 polypropylene Polymers 0.000 description 15
• 238000000576 coating method Methods 0.000 description 14
• 239000011248 coating agent Substances 0.000 description 13
• 239000008199 coating composition Substances 0.000 description 13
• 150000002148 esters Chemical class 0.000 description 13
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 11
• 239000004952 Polyamide Substances 0.000 description 11
• 239000006096 absorbing agent Substances 0.000 description 11
• 229920002647 polyamide Polymers 0.000 description 11
• 239000000047 product Substances 0.000 description 11
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 10
• 239000012964 benzotriazole Substances 0.000 description 10
• 238000005336 cracking Methods 0.000 description 10
• 239000002904 solvent Substances 0.000 description 10
• 229920000877 Melamine resin Polymers 0.000 description 9
• 239000004721 Polyphenylene oxide Substances 0.000 description 9
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
• 239000003795 chemical substances by application Substances 0.000 description 9
• 229920001684 low density polyethylene Polymers 0.000 description 9
• 239000004702 low-density polyethylene Substances 0.000 description 9
• 239000003921 oil Substances 0.000 description 9
• 229920002857 polybutadiene Polymers 0.000 description 9
• 229920002635 polyurethane Polymers 0.000 description 9
• 239000005062 Polybutadiene Substances 0.000 description 8
• 239000007983 Tris buffer Substances 0.000 description 8
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
• 238000001723 curing Methods 0.000 description 8
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
• 229920000728 polyester Polymers 0.000 description 8
• 239000000843 powder Substances 0.000 description 8
• 239000007787 solid Substances 0.000 description 8
• 239000004698 Polyethylene Substances 0.000 description 7
• 239000007859 condensation product Substances 0.000 description 7
• 229920000570 polyether Polymers 0.000 description 7
• 229920000573 polyethylene Polymers 0.000 description 7
• 229920006324 polyoxymethylene Polymers 0.000 description 7
• 239000000243 solution Substances 0.000 description 7
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 6
• 239000000839 emulsion Substances 0.000 description 6
• 150000002739 metals Chemical class 0.000 description 6
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
• 229920000647 polyepoxide Polymers 0.000 description 6
• 239000005056 polyisocyanate Substances 0.000 description 6
• 229920001228 polyisocyanate Polymers 0.000 description 6
• 229920000915 polyvinyl chloride Polymers 0.000 description 6
• 239000004800 polyvinyl chloride Substances 0.000 description 6
• 229920001169 thermoplastic Polymers 0.000 description 6
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
• 238000005160 1H NMR spectroscopy Methods 0.000 description 5
• 239000004925 Acrylic resin Substances 0.000 description 5
• 229920002943 EPDM rubber Polymers 0.000 description 5
• 150000001298 alcohols Chemical class 0.000 description 5
• 125000001931 aliphatic group Chemical group 0.000 description 5
• 125000003277 amino group Chemical group 0.000 description 5
• 238000006243 chemical reaction Methods 0.000 description 5
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 5
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 5
• 238000001035 drying Methods 0.000 description 5
• 150000002118 epoxides Chemical class 0.000 description 5
• 229920001903 high density polyethylene Polymers 0.000 description 5
• 239000004700 high-density polyethylene Substances 0.000 description 5
• 150000002431 hydrogen Chemical class 0.000 description 5
• 239000012948 isocyanate Substances 0.000 description 5
• TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
• 239000000049 pigment Substances 0.000 description 5
• 229920000058 polyacrylate Polymers 0.000 description 5
• 239000004417 polycarbonate Substances 0.000 description 5
• 238000011105 stabilization Methods 0.000 description 5
• 239000000758 substrate Substances 0.000 description 5
• 239000004416 thermosoftening plastic Substances 0.000 description 5
• ZQMPWXFHAUDENN-UHFFFAOYSA-N 1,2-bis[(2-methylphenyl)amino]ethane Natural products CC1=CC=CC=C1NCCNC1=CC=CC=C1C ZQMPWXFHAUDENN-UHFFFAOYSA-N 0.000 description 4
• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
• BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 4
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
• XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
• 229910052782 aluminium Inorganic materials 0.000 description 4
• 239000007864 aqueous solution Substances 0.000 description 4
• 239000002585 base Substances 0.000 description 4
• 230000015556 catabolic process Effects 0.000 description 4
• 125000000000 cycloalkoxy group Chemical group 0.000 description 4
• 238000006731 degradation reaction Methods 0.000 description 4
• 235000014113 dietary fatty acids Nutrition 0.000 description 4
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
• 239000006185 dispersion Substances 0.000 description 4
• 229920001971 elastomer Polymers 0.000 description 4
• 238000000921 elemental analysis Methods 0.000 description 4
• 239000003995 emulsifying agent Substances 0.000 description 4
• 239000000194 fatty acid Substances 0.000 description 4
• 229930195729 fatty acid Natural products 0.000 description 4
• 238000010348 incorporation Methods 0.000 description 4
• ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
• 229910052748 manganese Inorganic materials 0.000 description 4
• 239000011572 manganese Substances 0.000 description 4
• JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
• 238000002156 mixing Methods 0.000 description 4
• 239000000178 monomer Substances 0.000 description 4
• SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
• 230000001590 oxidative effect Effects 0.000 description 4
• NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 4
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
• QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
• 238000006116 polymerization reaction Methods 0.000 description 4
• 229920006380 polyphenylene oxide Polymers 0.000 description 4
• 235000013772 propylene glycol Nutrition 0.000 description 4
• 230000004224 protection Effects 0.000 description 4
• 239000011541 reaction mixture Substances 0.000 description 4
• 239000004332 silver Substances 0.000 description 4
• 229910052709 silver Inorganic materials 0.000 description 4
• 239000011734 sodium Substances 0.000 description 4
• 238000001228 spectrum Methods 0.000 description 4
• YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
• WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 4
• DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 3
• HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical class OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 description 3
• ONTODYXHFBKCDK-UHFFFAOYSA-N 2-(2,4-dimethylphenyl)-1,3,5-triazine Chemical compound CC1=CC(C)=CC=C1C1=NC=NC=N1 ONTODYXHFBKCDK-UHFFFAOYSA-N 0.000 description 3
• KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 3
• FJGQBLRYBUAASW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)phenol Chemical class OC1=CC=CC=C1N1N=C2C=CC=CC2=N1 FJGQBLRYBUAASW-UHFFFAOYSA-N 0.000 description 3
• ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 3
• 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 3
• SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
• 239000003490 Thiodipropionic acid Substances 0.000 description 3
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
• 239000001361 adipic acid Substances 0.000 description 3
• 150000001408 amides Chemical class 0.000 description 3
• 150000008064 anhydrides Chemical group 0.000 description 3
• FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 3
• 238000009835 boiling Methods 0.000 description 3
• 239000001273 butane Substances 0.000 description 3
• CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
• 238000007796 conventional method Methods 0.000 description 3
• 239000010949 copper Substances 0.000 description 3
• 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 3
• 150000001991 dicarboxylic acids Chemical class 0.000 description 3
• 150000001993 dienes Chemical class 0.000 description 3
• 230000000694 effects Effects 0.000 description 3
• 239000000806 elastomer Substances 0.000 description 3
• 150000002170 ethers Chemical class 0.000 description 3
• JHYNXXDQQHTCHJ-UHFFFAOYSA-M ethyl(triphenyl)phosphanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CC)C1=CC=CC=C1 JHYNXXDQQHTCHJ-UHFFFAOYSA-M 0.000 description 3
• 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
• 238000001704 evaporation Methods 0.000 description 3
• 230000008020 evaporation Effects 0.000 description 3
• 150000004665 fatty acids Chemical class 0.000 description 3
• 239000000835 fiber Substances 0.000 description 3
• 238000000227 grinding Methods 0.000 description 3
• 230000009931 harmful effect Effects 0.000 description 3
• XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
• 229920000554 ionomer Polymers 0.000 description 3
• 239000003446 ligand Substances 0.000 description 3
• UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 3
• 150000002815 nickel Chemical class 0.000 description 3
• 239000000546 pharmaceutical excipient Substances 0.000 description 3
• 239000004014 plasticizer Substances 0.000 description 3
• 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
• 230000005855 radiation Effects 0.000 description 3
• 229940116351 sebacate Drugs 0.000 description 3
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
• 229920001187 thermosetting polymer Polymers 0.000 description 3
• AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 description 3
• 229920002554 vinyl polymer Polymers 0.000 description 3
• 229910052725 zinc Inorganic materials 0.000 description 3
• 239000011701 zinc Substances 0.000 description 3
• 229910052726 zirconium Inorganic materials 0.000 description 3
• GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
• YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
• 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
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