SA515360885B1 - استخدام استرات ميركابتو ميثيل كعوامل نقل سلسلة - Google Patents

استخدام استرات ميركابتو ميثيل كعوامل نقل سلسلة

Info

Publication number
SA515360885B1
SA515360885B1 SA515360885A SA515360885A SA515360885B1 SA 515360885 B1 SA515360885 B1 SA 515360885B1 SA 515360885 A SA515360885 A SA 515360885A SA 515360885 A SA515360885 A SA 515360885A SA 515360885 B1 SA515360885 B1 SA 515360885B1
Authority
SA
Saudi Arabia
Prior art keywords
chain transfer
methyl mercapto
esters
transfer agents
relates
Prior art date
Application number
SA515360885A
Other languages
English (en)
Inventor
لويس اوجوستين باسكال سينت
جورجيس فريمى
جين بينوت كازوكس
Original Assignee
اركيما فرنسا
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by اركيما فرنسا filed Critical اركيما فرنسا
Publication of SA515360885B1 publication Critical patent/SA515360885B1/ar

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/52Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/126Acids containing more than four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D321/00Heterocyclic compounds containing rings having two oxygen atoms as the only ring hetero atoms, not provided for by groups C07D317/00 - C07D319/00
    • C07D321/12Eight-membered rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

يتعلق الاختراع الحالي باستخدام استر ميركابتو ميثيل ‏mercapto-methyl ester‏ واحد على ‏الأقل كعامل نقل سلسلة ‏chain transfer agent‏ في طريقة لبلمرة مستحلب شقي ‏radical ‎emulsion polymerisation‏. يتعلق الاختراع أيضا بطريقة لبلمرة متعددة(مشتركة) لمستحلب شقي ‏تشتمل على استر ميركابتو واحدة على الأقل ميثيل المذكور. يتعلق الاختراع أيضا بداي استرات ‏ميركابتو ميثيل ‏methyl mercapto-diesters‏ على النحو الموصوف في الوصف
SA515360885A 2013-02-15 2015-08-12 استخدام استرات ميركابتو ميثيل كعوامل نقل سلسلة SA515360885B1 (ar)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361765058P 2013-02-15 2013-02-15
FR1351312A FR3002230B1 (fr) 2013-02-15 2013-02-15 Utilisation de mercapto-esters methyliques en tant qu'agents de transfert de chaine
PCT/FR2014/050296 WO2014125223A1 (fr) 2013-02-15 2014-02-14 Utilisation de mercapto-esters methyliques en tant qu'agents de transfert de chaine

Publications (1)

Publication Number Publication Date
SA515360885B1 true SA515360885B1 (ar) 2016-04-20

Family

ID=48468520

Family Applications (1)

Application Number Title Priority Date Filing Date
SA515360885A SA515360885B1 (ar) 2013-02-15 2015-08-12 استخدام استرات ميركابتو ميثيل كعوامل نقل سلسلة

Country Status (16)

Country Link
US (1) US9126919B2 (ar)
EP (1) EP2956487B1 (ar)
JP (2) JP6280930B2 (ar)
KR (1) KR101745231B1 (ar)
CN (1) CN105026437B (ar)
AU (1) AU2014217661B2 (ar)
BR (1) BR112015017652A2 (ar)
CA (1) CA2897517C (ar)
ES (1) ES2730650T3 (ar)
FR (1) FR3002230B1 (ar)
MX (1) MX2015009442A (ar)
PH (1) PH12015501281B1 (ar)
RU (1) RU2625314C2 (ar)
SA (1) SA515360885B1 (ar)
SG (1) SG11201505471WA (ar)
WO (1) WO2014125223A1 (ar)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10189779B2 (en) 2016-09-12 2019-01-29 Chevron Phillips Chemical Company, Lp Methods for producing thiol compounds and sulfide compounds using diphenylamine or a phenol compound
CN106748931B (zh) * 2016-11-14 2018-08-14 重庆石博士新材料有限公司 一种星形聚羧酸减水剂成核剂三乙醇胺三(3-巯基丙酸)酯及其制备方法
FR3062852B1 (fr) * 2017-02-13 2021-05-07 Arkema France Procede de preparation de polythiols
CN109354653A (zh) * 2018-10-29 2019-02-19 北方华锦化学工业股份有限公司 一种低voc低气味本体abs树脂的制备方法
WO2023084805A1 (ja) * 2021-11-11 2023-05-19 星光Pmc株式会社 エマルション組成物、水性コート剤及びエマルション組成物の製造方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB519730A (en) 1937-09-29 1940-04-04 Ig Farbenindustrie Ag The manufacture of synthetic rubber-like materials
US2497107A (en) 1944-03-10 1950-02-14 Armstrong Cork Co Process of polymerizing conjugated dienes in the presence of selected alkyl esters of mercaptyl undecanoic acids as polymerization regulators
US2568648A (en) * 1946-12-26 1951-09-18 Goodrich Co B F Method of polymerizing butadiene-1, 3 hydrocarbons in aqueous emulsion in the presence of mercaptosubstituted monocarboxylic acid esters
US3682804A (en) * 1969-11-13 1972-08-08 Dow Chemical Co Method of preparing mercaptans using high energy radiation
US4102931A (en) 1977-05-17 1978-07-25 Pennwalt Corporation Manufacture of tertiary mercaptans using zeolite catalysts
FR2424907A1 (fr) * 1978-05-05 1979-11-30 Elf Aquitaine Perfectionnement a la synthese de mercaptans
FR2571721B1 (fr) 1984-10-12 1988-04-08 Rhone Poulenc Chim Base Compositions notamment dans le but d'ameliorer les proprietes des vulcanisats et le renforcement des caoutchoucs naturels et synthetiques
US4593081A (en) 1985-04-25 1986-06-03 Phillips Petroleum Company Chain-transfer agents for emulsion polymerization and polymer products produced therewith
FR2603889B1 (fr) 1986-09-11 1989-05-05 Elf Aquitaine Procede catalytique de production de mercaptans a partir de thioethers
CA2022190C (en) * 1989-08-11 2002-06-04 Andrew W. Gross Thiol-terminated hydroxyamides
JP2965611B2 (ja) * 1990-03-23 1999-10-18 旭化成工業株式会社 共重合体ラテックスの製造法
JP3238455B2 (ja) * 1992-03-11 2001-12-17 武田薬品工業株式会社 共重合体ラテックスの製造方法、共重合体ラテックスおよびそれを用いた紙塗工用組成物
DE4236316A1 (en) * 1991-10-31 1993-05-06 Takeda Chemical Industries Ltd Copolymer lattices, useful as binders in paper coating compsns. - by two=stage emulsion polymerisation of monomer mixt., with hydrophilic chain transfer agent and hydrophobic agent in second stage
AT397510B (de) 1991-11-06 1994-04-25 Wimmer Theodor Verfahren zur herstellung von fettsäureestern kurzkettiger alkohole
JP2857013B2 (ja) * 1993-04-19 1999-02-10 株式会社日本触媒 硫黄化合物の製造方法
JP3083485B2 (ja) * 1996-11-25 2000-09-04 株式会社日本触媒 スルフィド基含有メルカプトカルボン酸およびそのエステルの製造方法
JP5014148B2 (ja) * 2005-10-25 2012-08-29 独立行政法人理化学研究所 ペプチドチオエステルの製造方法
FR2921363B1 (fr) 2007-09-20 2009-11-06 Arkema France Procedes de synthese de diacides gras par metathese de diacides insatures obtenus par fermentation d'acides gras naturels
CN101544712A (zh) * 2009-04-02 2009-09-30 浙江大学 相转变胶囊分散液的细乳液聚合制备方法
JP5825819B2 (ja) * 2011-04-13 2015-12-02 住友ゴム工業株式会社 ジエン系重合体及びその製造方法

Also Published As

Publication number Publication date
KR101745231B1 (ko) 2017-06-08
BR112015017652A2 (pt) 2017-07-11
ES2730650T3 (es) 2019-11-12
FR3002230A1 (fr) 2014-08-22
RU2625314C2 (ru) 2017-07-13
JP2018076490A (ja) 2018-05-17
SG11201505471WA (en) 2015-09-29
EP2956487A1 (fr) 2015-12-23
KR20150119173A (ko) 2015-10-23
CN105026437B (zh) 2017-09-05
CN105026437A (zh) 2015-11-04
US20140235807A1 (en) 2014-08-21
FR3002230B1 (fr) 2016-02-05
MX2015009442A (es) 2015-10-05
AU2014217661A1 (en) 2015-08-20
CA2897517C (fr) 2017-05-30
EP2956487B1 (fr) 2019-04-24
RU2015139085A (ru) 2017-03-21
WO2014125223A1 (fr) 2014-08-21
JP2016505698A (ja) 2016-02-25
PH12015501281A1 (en) 2015-08-24
CA2897517A1 (fr) 2014-08-21
PH12015501281B1 (en) 2015-08-24
US9126919B2 (en) 2015-09-08
JP6280930B2 (ja) 2018-02-14
AU2014217661B2 (en) 2016-04-21

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