BR112017007934A2 - processo de esterificação oxidativa para produzir metacrilato de metila - Google Patents
processo de esterificação oxidativa para produzir metacrilato de metilaInfo
- Publication number
- BR112017007934A2 BR112017007934A2 BR112017007934A BR112017007934A BR112017007934A2 BR 112017007934 A2 BR112017007934 A2 BR 112017007934A2 BR 112017007934 A BR112017007934 A BR 112017007934A BR 112017007934 A BR112017007934 A BR 112017007934A BR 112017007934 A2 BR112017007934 A2 BR 112017007934A2
- Authority
- BR
- Brazil
- Prior art keywords
- methyl methacrylate
- oxidative esterification
- esterification process
- produce methyl
- oxidative
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000006709 oxidative esterification reaction Methods 0.000 title abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 title 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/644—Arsenic, antimony or bismuth
- B01J23/6445—Antimony
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/644—Arsenic, antimony or bismuth
- B01J23/6447—Bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
um processo para a preparação de mma através de esterificação oxidativa na presença de um catalisador compreendendo paládio, bismuto e antimônio.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462073290P | 2014-10-31 | 2014-10-31 | |
US62/073,290 | 2014-10-31 | ||
PCT/US2015/054437 WO2016069225A1 (en) | 2014-10-31 | 2015-10-07 | Oxidative esterification process for making methyl methacrylate |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112017007934A2 true BR112017007934A2 (pt) | 2018-01-23 |
BR112017007934B1 BR112017007934B1 (pt) | 2021-11-30 |
Family
ID=54478203
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112017007934-8A BR112017007934B1 (pt) | 2014-10-31 | 2015-10-07 | Processo de esterificação oxidativa para produzir metacrilato de metila |
Country Status (12)
Country | Link |
---|---|
US (1) | US9969672B2 (pt) |
EP (1) | EP3212608B1 (pt) |
JP (1) | JP6661629B2 (pt) |
KR (1) | KR102455959B1 (pt) |
CN (1) | CN107074727B (pt) |
BR (1) | BR112017007934B1 (pt) |
CA (1) | CA2965481C (pt) |
MX (1) | MX2017004880A (pt) |
SA (1) | SA517381345B1 (pt) |
SG (1) | SG11201703339UA (pt) |
TW (1) | TWI577659B (pt) |
WO (1) | WO2016069225A1 (pt) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020073458A (ja) * | 2017-03-02 | 2020-05-14 | Agc株式会社 | α,β−不飽和酸エステルまたはα−ハロエステルの製造方法 |
CN111051274A (zh) * | 2017-07-28 | 2020-04-21 | 陶氏环球技术有限责任公司 | 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法 |
WO2020005693A1 (en) * | 2018-06-28 | 2020-01-02 | Dow Global Technologies Llc | Heterogeneous catalyst |
KR102417077B1 (ko) * | 2019-01-18 | 2022-07-04 | 주식회사 엘지화학 | 메틸메타크릴레이트의 제조 방법 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51141810A (en) * | 1975-06-02 | 1976-12-07 | Nippon Kayaku Co Ltd | Process for simultaneous preparation of methacrylic acid and methylmet hacrylate or acrylic acid and methylacrylate |
DE2633728C3 (de) * | 1976-07-27 | 1979-07-12 | Boehringer Mannheim Gmbh, 6800 Mannheim | NADH-Peroxidase, ihre Gewinnung und Verwendung |
DE3018071C2 (de) | 1979-05-17 | 1985-06-05 | Asahi Kasei Kogyo K.K., Osaka | Verfahren zur Herstellung von Carbonsäureestern |
JPS5687530A (en) | 1979-12-19 | 1981-07-16 | Asahi Chem Ind Co Ltd | Dehydrating method of gas containing unsaturated aldehyde |
GB2094782A (en) | 1981-03-16 | 1982-09-22 | Johnson Matthey Co Ltd | Production of alkyl methacrylates |
KR100259743B1 (ko) * | 1995-07-18 | 2000-07-01 | 야마모토 카즈모토 | 카르복실산 에스테르 제조용 촉매 |
JPH09216850A (ja) * | 1996-02-09 | 1997-08-19 | Mitsubishi Rayon Co Ltd | カルボン酸エステルの製造方法 |
TW385304B (en) | 1996-09-10 | 2000-03-21 | Asahi Chemical Ind | Process for producing methacrylic acid ester or acrylic acid ester |
JP3313993B2 (ja) | 1996-11-29 | 2002-08-12 | 三菱レイヨン株式会社 | カルボン酸エステルの製造法 |
TW377306B (en) | 1996-12-16 | 1999-12-21 | Asahi Chemical Ind | Noble metal support |
JP3297342B2 (ja) | 1997-03-24 | 2002-07-02 | 三菱レイヨン株式会社 | カルボン酸エステルの製造法 |
JP3511350B2 (ja) * | 1997-03-25 | 2004-03-29 | 旭化成ケミカルズ株式会社 | カルボン酸エステル製造用触媒 |
SG71815A1 (en) | 1997-07-08 | 2000-04-18 | Asahi Chemical Ind | Method of producing methyl methacrylate |
CN1122569C (zh) * | 1997-08-07 | 2003-10-01 | 三菱丽阳株式会社 | 用于制造羧酸酯的催化剂和羧酸酯的制造方法 |
US7326806B2 (en) * | 2001-06-04 | 2008-02-05 | Nippon Shokubai Co., Ltd. | Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters |
CN1214865C (zh) * | 2003-01-22 | 2005-08-17 | 中国科学院过程工程研究所 | 一种用于甲基丙烯醛一步氧化酯化生产甲基丙烯酸甲酯的新型催化剂 |
CN101815579A (zh) | 2007-08-13 | 2010-08-25 | 旭化成化学株式会社 | 羧酸酯制造用催化剂、其制造方法、以及羧酸酯的制造方法 |
WO2012035637A1 (ja) | 2010-09-16 | 2012-03-22 | 旭化成ケミカルズ株式会社 | シリカ系材料及びその製造方法、並びに貴金属担持物及びそれを触媒として用いるカルボン酸類の製造方法 |
CN103772171B (zh) * | 2012-10-17 | 2016-08-17 | 中国石油化工股份有限公司 | 异丁烯或叔丁醇氧化制甲基丙烯醛方法 |
US20140206897A1 (en) | 2013-01-22 | 2014-07-24 | Saudi Basic Industries Corporation | Method for making methyl methacrylate from propionaldehyde and formaldehyde via oxidative esterification |
WO2014170223A1 (de) * | 2013-04-19 | 2014-10-23 | Evonik Industries Ag | Verfahren zur herstellung von methylmethacrylat |
CN103721744A (zh) * | 2013-12-27 | 2014-04-16 | 天津大学 | 用于一步氧化酯化生产甲基丙烯酸甲酯的疏水催化剂及制备方法 |
-
2015
- 2015-10-07 BR BR112017007934-8A patent/BR112017007934B1/pt active IP Right Grant
- 2015-10-07 EP EP15791386.4A patent/EP3212608B1/en active Active
- 2015-10-07 US US15/521,750 patent/US9969672B2/en active Active
- 2015-10-07 MX MX2017004880A patent/MX2017004880A/es unknown
- 2015-10-07 SG SG11201703339UA patent/SG11201703339UA/en unknown
- 2015-10-07 CA CA2965481A patent/CA2965481C/en active Active
- 2015-10-07 KR KR1020177012818A patent/KR102455959B1/ko active IP Right Grant
- 2015-10-07 WO PCT/US2015/054437 patent/WO2016069225A1/en active Application Filing
- 2015-10-07 CN CN201580056112.1A patent/CN107074727B/zh active Active
- 2015-10-07 JP JP2017522600A patent/JP6661629B2/ja active Active
- 2015-10-27 TW TW104135278A patent/TWI577659B/zh not_active IP Right Cessation
-
2017
- 2017-04-17 SA SA517381345A patent/SA517381345B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
CN107074727A (zh) | 2017-08-18 |
KR20170076708A (ko) | 2017-07-04 |
CN107074727B (zh) | 2021-02-09 |
WO2016069225A1 (en) | 2016-05-06 |
TW201615612A (zh) | 2016-05-01 |
CA2965481C (en) | 2023-03-21 |
SG11201703339UA (en) | 2017-05-30 |
SA517381345B1 (ar) | 2021-01-17 |
US9969672B2 (en) | 2018-05-15 |
JP2017534622A (ja) | 2017-11-24 |
EP3212608B1 (en) | 2020-12-30 |
US20170226043A1 (en) | 2017-08-10 |
CA2965481A1 (en) | 2016-05-06 |
TWI577659B (zh) | 2017-04-11 |
EP3212608A1 (en) | 2017-09-06 |
MX2017004880A (es) | 2017-07-05 |
KR102455959B1 (ko) | 2022-10-18 |
JP6661629B2 (ja) | 2020-03-11 |
BR112017007934B1 (pt) | 2021-11-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 07/10/2015, OBSERVADAS AS CONDICOES LEGAIS. |