SA01220540B1 - مكونات حفزيةcatalyst components لبلمرة الأوليفينات polymerization of olefins - Google Patents
مكونات حفزيةcatalyst components لبلمرة الأوليفينات polymerization of olefins Download PDFInfo
- Publication number
- SA01220540B1 SA01220540B1 SA1220540A SA01220540A SA01220540B1 SA 01220540 B1 SA01220540 B1 SA 01220540B1 SA 1220540 A SA1220540 A SA 1220540A SA 01220540 A SA01220540 A SA 01220540A SA 01220540 B1 SA01220540 B1 SA 01220540B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- alkyl
- catalyst
- compounds
- electron
- compound
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 42
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 27
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 77
- 230000003197 catalytic effect Effects 0.000 claims abstract description 28
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 12
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 11
- 150000002367 halogens Chemical class 0.000 claims abstract description 9
- 229920001155 polypropylene Polymers 0.000 claims abstract description 9
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 6
- 150000003444 succinic acids Chemical class 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 40
- 239000011777 magnesium Substances 0.000 claims description 21
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 17
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 15
- 150000004756 silanes Chemical class 0.000 claims description 13
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 150000003609 titanium compounds Chemical class 0.000 claims description 5
- 238000004438 BET method Methods 0.000 claims description 4
- 125000005907 alkyl ester group Chemical group 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 238000006467 substitution reaction Methods 0.000 claims description 3
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 239000000284 extract Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000003386 piperidinyl group Chemical group 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims 2
- 150000003022 phthalic acids Chemical class 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 1
- 150000003890 succinate salts Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 29
- -1 Polypropylene Polymers 0.000 abstract description 25
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 18
- 239000008096 xylene Substances 0.000 abstract description 14
- 238000009826 distribution Methods 0.000 abstract description 9
- 150000002148 esters Chemical class 0.000 abstract description 7
- 239000004743 Polypropylene Substances 0.000 abstract description 5
- 239000011127 biaxially oriented polypropylene Substances 0.000 abstract description 4
- 229920006378 biaxially oriented polypropylene Polymers 0.000 abstract description 4
- 235000011044 succinic acid Nutrition 0.000 abstract description 3
- 230000002457 bidirectional effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 28
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
- 239000007787 solid Substances 0.000 description 18
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 16
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 14
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 13
- 239000012632 extractable Substances 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 11
- 239000007788 liquid Substances 0.000 description 7
- 235000011147 magnesium chloride Nutrition 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- RGMSBDCQLRJNSH-UHFFFAOYSA-N 4-oxo-4-propan-2-yloxybutanoic acid Chemical compound CC(C)OC(=O)CCC(O)=O RGMSBDCQLRJNSH-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 239000006228 supernatant Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 4
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 description 4
- YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical compound CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000012265 solid product Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 150000003900 succinic acid esters Chemical group 0.000 description 3
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229960002380 dibutyl phthalate Drugs 0.000 description 2
- SSQLHHBLAVHVOU-UHFFFAOYSA-N diethyl 2-propan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C(C)C)C(=O)OCC SSQLHHBLAVHVOU-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- GOIPELYWYGMEFQ-UHFFFAOYSA-N dimethoxy-methyl-octylsilane Chemical compound CCCCCCCC[Si](C)(OC)OC GOIPELYWYGMEFQ-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- POXXQVSKWJPZNO-UHFFFAOYSA-N 1-o-ethyl 2-o-(2-methylpropyl) benzene-1,2-dicarboxylate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC(C)C POXXQVSKWJPZNO-UHFFFAOYSA-N 0.000 description 1
- RVHOBHMAPRVOLO-UHFFFAOYSA-N 2-ethylbutanedioic acid Chemical compound CCC(C(O)=O)CC(O)=O RVHOBHMAPRVOLO-UHFFFAOYSA-N 0.000 description 1
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
- ABYCGAKJMGFSPY-UHFFFAOYSA-N 2-hexan-3-yloxycarbonylbenzoic acid Chemical compound CCCC(CC)OC(=O)C1=CC=CC=C1C(O)=O ABYCGAKJMGFSPY-UHFFFAOYSA-N 0.000 description 1
- WXUAQHNMJWJLTG-UHFFFAOYSA-N 2-methylbutanedioic acid Chemical compound OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 description 1
- DUAYDERMVQWIJD-UHFFFAOYSA-N 2-n,2-n,6-trimethyl-1,3,5-triazine-2,4-diamine Chemical compound CN(C)C1=NC(C)=NC(N)=N1 DUAYDERMVQWIJD-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- PDOSDCQRPAABHW-UHFFFAOYSA-N 4-oxo-4-propoxybutanoic acid Chemical compound CCCOC(=O)CCC(O)=O PDOSDCQRPAABHW-UHFFFAOYSA-N 0.000 description 1
- KGYVJUSBRARRBU-UHFFFAOYSA-N 5,5-dimethylcyclohexa-1,3-diene Chemical group CC1(C)CC=CC=C1 KGYVJUSBRARRBU-UHFFFAOYSA-N 0.000 description 1
- QUYFPNWYGLFQQU-UHFFFAOYSA-N 5-methyldecane Chemical compound CCCCCC(C)CCCC QUYFPNWYGLFQQU-UHFFFAOYSA-N 0.000 description 1
- GPVGLDPVEXDUII-UHFFFAOYSA-N CO[SiH](OC)OC.CO[Si](C)(OC)OC Chemical compound CO[SiH](OC)OC.CO[Si](C)(OC)OC GPVGLDPVEXDUII-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- 239000004605 External Lubricant Substances 0.000 description 1
- GMRZGOMTVFBOQJ-UHFFFAOYSA-N FC(CC[Si](OC)(OC)C)(F)F.FC(CC[Si](OC)(OC)C)(F)F Chemical compound FC(CC[Si](OC)(OC)C)(F)F.FC(CC[Si](OC)(OC)C)(F)F GMRZGOMTVFBOQJ-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 102000001708 Protein Isoforms Human genes 0.000 description 1
- 108010029485 Protein Isoforms Proteins 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 125000005418 aryl aryl group Chemical group 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229940090012 bentyl Drugs 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- KYZHGEFMXZOSJN-UHFFFAOYSA-N benzoic acid isobutyl ester Natural products CC(C)COC(=O)C1=CC=CC=C1 KYZHGEFMXZOSJN-UHFFFAOYSA-N 0.000 description 1
- 150000001559 benzoic acids Chemical class 0.000 description 1
- WMNULTDOANGXRT-UHFFFAOYSA-N bis(2-ethylhexyl) butanedioate Chemical compound CCCCC(CC)COC(=O)CCC(=O)OCC(CC)CCCC WMNULTDOANGXRT-UHFFFAOYSA-N 0.000 description 1
- FPGRDBPTRVSBLF-UHFFFAOYSA-N bis(2-methylpropyl) 2,2-dimethylbutanedioate Chemical compound CC(C)COC(=O)CC(C)(C)C(=O)OCC(C)C FPGRDBPTRVSBLF-UHFFFAOYSA-N 0.000 description 1
- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- OVYQSRKFHNKIBM-UHFFFAOYSA-N butanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)CCC(O)=O OVYQSRKFHNKIBM-UHFFFAOYSA-N 0.000 description 1
- GCCFZWLZABMEJV-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1.CCCCOC(=O)C1=CC=CC=C1 GCCFZWLZABMEJV-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OOSZILWKTQCRSZ-UHFFFAOYSA-N butyl-dimethoxy-methylsilane Chemical compound CCCC[Si](C)(OC)OC OOSZILWKTQCRSZ-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- GYMBTLRVABDEHT-UHFFFAOYSA-N chlorobenzene;dichloromethane Chemical compound ClCCl.ClC1=CC=CC=C1 GYMBTLRVABDEHT-UHFFFAOYSA-N 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- GWUJPMKBSYJFCK-UHFFFAOYSA-N decyl-dimethoxy-methylsilane Chemical compound CCCCCCCCCC[Si](C)(OC)OC GWUJPMKBSYJFCK-UHFFFAOYSA-N 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- CURUTKGFNZGFSE-UHFFFAOYSA-N dicyclomine Chemical group C1CCCCC1C1(C(=O)OCCN(CC)CC)CCCCC1 CURUTKGFNZGFSE-UHFFFAOYSA-N 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- DODIKAULZAKDIN-UHFFFAOYSA-N diethyl 2,2-dimethylbutanedioate Chemical compound CCOC(=O)CC(C)(C)C(=O)OCC DODIKAULZAKDIN-UHFFFAOYSA-N 0.000 description 1
- YCYHZGIPKZHEEL-UHFFFAOYSA-N diethyl 2,3-bis(2,2-dimethylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)(C)C)C(CC(C)(C)C)C(=O)OCC YCYHZGIPKZHEEL-UHFFFAOYSA-N 0.000 description 1
- AVLHXEDOBYYTGV-UHFFFAOYSA-N diethyl 2,3-bis(2-methylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)C)C(CC(C)C)C(=O)OCC AVLHXEDOBYYTGV-UHFFFAOYSA-N 0.000 description 1
- FITPXUCDWCINLG-UHFFFAOYSA-N diethyl 2,3-bis(cyclohexylmethyl)butanedioate Chemical compound C1CCCCC1CC(C(=O)OCC)C(C(=O)OCC)CC1CCCCC1 FITPXUCDWCINLG-UHFFFAOYSA-N 0.000 description 1
- OTUNNRWESSPIBH-UHFFFAOYSA-N diethyl 2,3-bis(trimethylsilyl)butanedioate Chemical compound CCOC(=O)C([Si](C)(C)C)C([Si](C)(C)C)C(=O)OCC OTUNNRWESSPIBH-UHFFFAOYSA-N 0.000 description 1
- ISOWAXIPBFLPIC-UHFFFAOYSA-N diethyl 2,3-dicyclopentylbutanedioate Chemical compound C1CCCC1C(C(=O)OCC)C(C(=O)OCC)C1CCCC1 ISOWAXIPBFLPIC-UHFFFAOYSA-N 0.000 description 1
- JHAJGFZBBOGWCQ-UHFFFAOYSA-N diethyl 2-(2,2-dimethylpropyl)butanedioate Chemical compound CCOC(=O)CC(CC(C)(C)C)C(=O)OCC JHAJGFZBBOGWCQ-UHFFFAOYSA-N 0.000 description 1
- JGGZCPROKCVDLL-UHFFFAOYSA-N diethyl 2-(2,3-dimethylbutan-2-yl)butanedioate Chemical compound CCOC(=O)CC(C(C)(C)C(C)C)C(=O)OCC JGGZCPROKCVDLL-UHFFFAOYSA-N 0.000 description 1
- QILIJPUOBXQLLC-UHFFFAOYSA-N diethyl 2-(2-methylpropyl)butanedioate Chemical compound CCOC(=O)CC(CC(C)C)C(=O)OCC QILIJPUOBXQLLC-UHFFFAOYSA-N 0.000 description 1
- YKNVJKQSCZQURF-UHFFFAOYSA-N diethyl 2-(3-methylbutyl)-2-(2-methylpropyl)butanedioate Chemical compound CCOC(=O)CC(CCC(C)C)(CC(C)C)C(=O)OCC YKNVJKQSCZQURF-UHFFFAOYSA-N 0.000 description 1
- GBEDNFHCEKAPAV-UHFFFAOYSA-N diethyl 2-(4-methoxyphenyl)butanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=C(OC)C=C1 GBEDNFHCEKAPAV-UHFFFAOYSA-N 0.000 description 1
- GRVYPVYGTIWYIC-UHFFFAOYSA-N diethyl 2-(cyclohexylmethyl)butanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)CC1CCCCC1 GRVYPVYGTIWYIC-UHFFFAOYSA-N 0.000 description 1
- UKZUISCHPZZJME-UHFFFAOYSA-N diethyl 2-butan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C(C)CC)C(=O)OCC UKZUISCHPZZJME-UHFFFAOYSA-N 0.000 description 1
- GKCJIKJXEOGKJU-UHFFFAOYSA-N diethyl 2-butyl-2-phenylbutanedioate Chemical compound CCOC(=O)CC(CCCC)(C(=O)OCC)C1=CC=CC=C1 GKCJIKJXEOGKJU-UHFFFAOYSA-N 0.000 description 1
- DJHQJVJMROPIHP-UHFFFAOYSA-N diethyl 2-ethyl-2-methylbutanedioate Chemical compound CCOC(=O)CC(C)(CC)C(=O)OCC DJHQJVJMROPIHP-UHFFFAOYSA-N 0.000 description 1
- 229940105984 diethylhexyl succinate Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- DIJRHOZMLZRNLM-UHFFFAOYSA-N dimethoxy-methyl-(3,3,3-trifluoropropyl)silane Chemical compound CO[Si](C)(OC)CCC(F)(F)F DIJRHOZMLZRNLM-UHFFFAOYSA-N 0.000 description 1
- XKRPWHZLROBLDI-UHFFFAOYSA-N dimethoxy-methyl-propylsilane Chemical compound CCC[Si](C)(OC)OC XKRPWHZLROBLDI-UHFFFAOYSA-N 0.000 description 1
- IPKKHRVROFYTEK-UHFFFAOYSA-N dipentyl phthalate Chemical compound CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCC IPKKHRVROFYTEK-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- NWPWRAWAUYIELB-UHFFFAOYSA-N ethyl 4-methylbenzoate Chemical compound CCOC(=O)C1=CC=C(C)C=C1 NWPWRAWAUYIELB-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- ZVBWPVOCTORPLM-UHFFFAOYSA-N formylsilicon Chemical compound [Si]C=O ZVBWPVOCTORPLM-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000004 low energy electron diffraction Methods 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00203535 | 2000-10-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SA01220540B1 true SA01220540B1 (ar) | 2008-03-23 |
Family
ID=8172130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SA1220540A SA01220540B1 (ar) | 2000-10-13 | 2001-11-24 | مكونات حفزيةcatalyst components لبلمرة الأوليفينات polymerization of olefins |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US6825309B2 (enExample) |
| EP (1) | EP1272533B1 (enExample) |
| JP (1) | JP4964396B2 (enExample) |
| KR (1) | KR100899958B1 (enExample) |
| CN (2) | CN1721455A (enExample) |
| AR (1) | AR030989A1 (enExample) |
| AT (1) | ATE407153T1 (enExample) |
| AU (1) | AU781278B2 (enExample) |
| BR (1) | BR0107335B1 (enExample) |
| CA (1) | CA2396232C (enExample) |
| DE (1) | DE60135643D1 (enExample) |
| ES (1) | ES2312484T3 (enExample) |
| HU (1) | HUP0204041A3 (enExample) |
| MX (1) | MXPA02005825A (enExample) |
| MY (1) | MY128622A (enExample) |
| PL (1) | PL355609A1 (enExample) |
| RU (1) | RU2279442C2 (enExample) |
| SA (1) | SA01220540B1 (enExample) |
| TW (1) | TWI289144B (enExample) |
| WO (1) | WO2002030998A1 (enExample) |
| ZA (1) | ZA200204396B (enExample) |
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| KR100700957B1 (ko) * | 1999-04-15 | 2007-03-28 | 바셀 테크놀로지 컴퍼니 비.브이. | 올레핀 중합반응을 위한 성분 및 촉매 |
| PL374508A1 (en) | 2002-08-01 | 2005-10-31 | Basell Poliolefine Italia S.P.A. | Highly stereoregular polypropylene with improved properties |
| TWI253451B (en) * | 2002-08-29 | 2006-04-21 | Toho Catalyst Co Ltd | Solid catalyst component, catalyst for polymerization of olefins, and polymerizing method of olefins |
| EP2261292B1 (en) * | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7541402B2 (en) * | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) * | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| TW200427763A (en) | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
| US7572860B2 (en) | 2003-08-05 | 2009-08-11 | Basell Poliolefine Italia S.R.L. | Polyolefin articles |
| US7649052B2 (en) | 2004-05-21 | 2010-01-19 | Basell Poliolefine Italia S.R.L. | Impact resistant polyolefin compositions |
| CN1328293C (zh) * | 2004-09-02 | 2007-07-25 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分和催化剂 |
| CN1318457C (zh) * | 2004-09-02 | 2007-05-30 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分和催化剂 |
| CN100338103C (zh) * | 2004-09-02 | 2007-09-19 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分和催化剂 |
| KR20070112105A (ko) | 2004-10-04 | 2007-11-22 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 엘라스토머 폴리올레핀 조성물 |
| JP4688135B2 (ja) * | 2005-01-18 | 2011-05-25 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒 |
| TWI315318B (en) | 2005-01-19 | 2009-10-01 | Mitsui Chemicals Inc | Process for producing olefin polymer and solid titanium catalyst component |
| US7888438B2 (en) | 2005-01-19 | 2011-02-15 | Mitsui Chemicals, Inc. | Catalyst for olefin polymerization and process for olefin polymerization |
| JP4632299B2 (ja) * | 2005-01-26 | 2011-02-16 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法および触媒 |
| JP2008528779A (ja) | 2005-02-03 | 2008-07-31 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 射出成形用プロピレンポリマー組成物 |
| WO2006102106A1 (en) * | 2005-03-17 | 2006-09-28 | University Of Maryland, College Park | Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby |
| CN101163738B (zh) * | 2005-04-21 | 2011-07-13 | 巴塞尔聚烯烃意大利有限责任公司 | 双轴取向丙烯聚合物膜 |
| US8153217B2 (en) | 2005-04-28 | 2012-04-10 | Basell Poliolefine Italia S.R.L. | Reinforced polypropylene pipe |
| ATE435245T1 (de) | 2005-05-12 | 2009-07-15 | Basell Poliolefine Srl | Propylen-ethylen-copolymere und herstellungsverfahren dafür |
| JP4540056B2 (ja) * | 2005-05-30 | 2010-09-08 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒並びにこれを用いたオレフィン類重合体の製造方法 |
| JP5178512B2 (ja) | 2005-07-01 | 2013-04-10 | サンアロマー株式会社 | 広い分子量分布を示すプロピレンポリマー |
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| BRPI0620531B1 (pt) | 2005-11-22 | 2018-01-30 | Basell Poliolefine Italia S.R.L. | Composições poliolefínicas resistentes a impacto |
| US20090029621A1 (en) * | 2005-12-20 | 2009-01-29 | Basell Poliolefine Italia S.R.L. | Soft Non-Woven Fabrics |
| US7947348B2 (en) * | 2005-12-20 | 2011-05-24 | Basell Poliolefine Italia, s.r.l. | Polypropylene compositions for stretched articles |
| ATE461244T1 (de) | 2006-02-23 | 2010-04-15 | Basell Poliolefine Srl | Propylenpolymere für spritzgiessanwendungen |
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- 2001-09-24 EP EP01986701A patent/EP1272533B1/en not_active Expired - Lifetime
- 2001-09-24 CN CNA2005100885631A patent/CN1721455A/zh active Pending
- 2001-09-24 KR KR1020027007526A patent/KR100899958B1/ko not_active Expired - Fee Related
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- 2001-09-24 AT AT01986701T patent/ATE407153T1/de active
- 2001-09-24 AU AU15897/02A patent/AU781278B2/en not_active Ceased
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- 2001-09-24 ES ES01986701T patent/ES2312484T3/es not_active Expired - Lifetime
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| CA2396232A1 (en) | 2002-04-18 |
| ATE407153T1 (de) | 2008-09-15 |
| DE60135643D1 (de) | 2008-10-16 |
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| US6825309B2 (en) | 2004-11-30 |
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