RU99123528A - COLORING COMPOSITION CONTAINING DIRECT CATION DYE AND PYRAZOL- [1,5-A] -PYRIMIDIN CONNECTION AS AN OXIDABLE BASE, AND COLORING METHOD - Google Patents

COLORING COMPOSITION CONTAINING DIRECT CATION DYE AND PYRAZOL- [1,5-A] -PYRIMIDIN CONNECTION AS AN OXIDABLE BASE, AND COLORING METHOD

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RU99123528A
RU99123528A RU99123528/14A RU99123528A RU99123528A RU 99123528 A RU99123528 A RU 99123528A RU 99123528/14 A RU99123528/14 A RU 99123528/14A RU 99123528 A RU99123528 A RU 99123528A RU 99123528 A RU99123528 A RU 99123528A
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alkyl
denotes
amino
group
composition according
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RU99123528/14A
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RU2185811C2 (en
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Мари-Паскаль ОДУССЕ
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Л`Ореаль
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1. Композиция для окислительного окрашивания кератиновых волокон, в частности, кератиновых волокон человека, таких как волосы, отличающаяся тем, что она содержит в подходящей для окрашивания среде по меньшей мере одно пиразоло-[1,5-а] -пиримидиновое соединение в качестве окисляемого основания, и по меньшей мере один прямой катионный краситель, причем композиция не содержит ферментной системы, способной вызывать окисление пиразоло-[1,5-а]-пиримидинов.1. Composition for oxidative dyeing of keratin fibers, in particular, human keratin fibers, such as hair, characterized in that it contains at least one pyrazolo- [1,5-a] -pyrimidine compound as oxidizable in a suitable medium for dyeing base, and at least one direct cationic dye, and the composition does not contain an enzyme system capable of causing the oxidation of pyrazolo [1,5-a] pyrimidines. 2. Композиция по п.1, отличающаяся тем,, что пиразоло-[1,5-а]-пиримидины выбирают из числа соединений приведенной ниже формулы V и их солевых аддуктов с кислотами и основаниями
Figure 00000001

в которой R33, R34, R35 и R36, одинаковые или разные, обозначают атом водорода, С1-С4-алкил, арил, гидрокси-С1-С4-алкил, поли-гидрокси-С2-С4-алкил, С1-С4-алкокси-С1-С4-алкил, амино-С1-С4-алкил (аминогруппа может быть защищена ацетильной, уреидо- или сульфонильной группой), С1-С4-алкиламино-С1-С4-алкил, ди(С1-С4-алкил)амино-С1-С4-алкил (диалкилы могут образовывать 5- или 6-членный алифатический цикл или гетероцикл), гидрокси-С1-С4-алкил- или ди(гидрокси-С1-С4-алкил) амино-С1-С4-алкил;
радикалы R, одинаковые или разные, обозначают атом водорода, С1-С4-алкил, арил, гидрокси-С1-С4-алкил, полигидрокси-С2-С4-алкил, амино-С1-С4-алкил, С1-С4-алкиламино-С1-С4-алкил, ди(С1-С4-алкил)амино-С1-С4-алкил (диалкилы могут образовывать 5- или 6-членный алифатический цикл или гетероцикл), гидрокси-С1-С4-алкил- или ди(гидрокси-С1-С4-алкил) амино-С1-С4-алкил, аминогруппу, С1-С4-алкил- или ди(С1-С4-алкил) аминогруппу, галоген, остаток карбоновой кислоты или сульфокислоты;
i = 0, 1, 2 или 3;
р = 0 или 1;
q = 0 или 1;
n = 0 или 1;
при условии что (i) сумма p+q отлична от 0; (ii) когда p+q=2, то n=0, а группы NR33R34 и NR35R36 занимают положения (2, 3), (5, 6), (6, 7), (3, 5) или (3, 7); (ii) когда p+q=1, то n=1, а группа NR33R34 (или NR35R36) и группа ОН занимают положения (2, 3), (5, 6), (6, 7), (3, 5) или (3, 7).2. The composition according to claim 1, characterized in that the pyrazolo [1,5-a] pyrimidines are chosen from among the compounds of the formula V below and their salt adducts with acids and bases
Figure 00000001

in which R 33 , R 34 , R 35 and R 36 , identical or different, denote a hydrogen atom, C 1 -C 4 -alkyl, aryl, hydroxy-C 1 -C 4 -alkyl, poly-hydroxy-C 2 -C 4- alkyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, amino-C 1 -C 4 -alkyl (amino group can be protected by acetyl, ureido or sulfonyl group), C 1 -C 4 -alkylamino -C 1 -C 4 -alkyl, di (C 1 -C 4 -alkyl) amino-C 1 -C 4 -alkyl (dialkyls can form a 5- or 6-membered aliphatic cycle or heterocycle), hydroxy-C 1 -C 4- alkyl - or di (hydroxy-C 1 -C 4 -alkyl) amino-C 1 -C 4 -alkyl;
radicals R, identical or different, denote a hydrogen atom, C 1 -C 4 -alkyl, aryl, hydroxy-C 1 -C 4 -alkyl, polyhydroxy-C 2 -C 4 -alkyl, amino-C 1 -C 4 -alkyl , C 1 -C 4 -alkylamino-C 1 -C 4 -alkyl, di (C 1 -C 4 -alkyl) amino-C 1 -C 4 -alkyl (dialkyls can form a 5- or 6-membered aliphatic or heterocycle ), hydroxy-C 1 -C 4 -alkyl - or di (hydroxy-C 1 -C 4 -alkyl) amino-C 1 -C 4 -alkyl, amino, C 1 -C 4 -alkyl - or di (C 1 -C 4 -alkyl) amino group, halogen, carboxylic acid or sulfonic acid residue;
i = 0, 1, 2 or 3;
p = 0 or 1;
q = 0 or 1;
n = 0 or 1;
provided that (i) the sum of p + q is different from 0; (ii) when p + q = 2, then n = 0, and the groups NR 33 R 34 and NR 35 R 36 occupy the positions (2, 3), (5, 6), (6, 7), (3, 5 ) or (3, 7); (ii) when p + q = 1, then n = 1, and the group NR 33 R 34 (or NR 35 R 36 ) and the OH group occupy positions (2, 3), (5, 6), (6, 7) , (3, 5) or (3, 7). 3. Композиция по п.2, отличающаяся тем, что пиразоло-[1,5-а]-пиримидины формулы V могут быть выбраны из следующих соединений:
пиразоло-[1,5-а]-пиримидин-3,7-диамин;
2-метил-пиразоло-[1,5-а]-пиримидин-3,7-диамин;
2,5-диметил-пиразоло-[1,5-a]-пиримидин-3,7-диамин;
пиразоло-[1,5-a]-пиримидин-3,5-диамин;
2,7-диметилпиразоло-[1,5-a]-пиримидин-3,5-диамин;
3-аминопиразоло-[1,5-a]-пиримидин-7-ол;
3-амино-5-метилпиразоло-[1,5-a]-пиримидин-7-ол;
3-аминопиразоло-[1,5-a]-пиримидин-5-ол;
2-(3-аминопиразоло-[1,5-a]-пиримидин-7-иламино)этанол;
3-амино-5-метил-7-имидазолилпропиламино пиразоло-Г1,5-a]-пиримидин;
3-амино-7-β-гидроксиэтиламино-5-метил-пиразоло-[1,5-a]-пиримидин;
2-(7-аминопиразоло-[1,5-a]-пиримидин-3-иламино)этанол;
2[(3-аминопиразоло-[1,5-a]-пиримидин-7-ил)-(2-гидроксиэтил)амино]этанол;
2[(7-аминопиразоло-[1,5-a]-пиримидин-3-ил)-(2-гидроксиэтил)амино]этанол;
5,6-диметилпиразоло-[1,5-а]--пиримидин-3,7-диамин;
2,6-диметилпиразоло-[1,5-a]-пиримидин-3,7-диамин;
2,5,N-7, N-7-тетраметилпиразоло-[1,5-a]-пиримидин-3,7-диамин;
и их солевые аддукты с кислотами или основаниями.3. The composition according to claim 2, characterized in that the pyrazolo [1,5-a] -pyrimidines of the formula V can be selected from the following compounds:
pyrazolo- [1,5-a] pyrimidine-3,7-diamine;
2-methyl-pyrazolo- [1,5-a] pyrimidine-3,7-diamine;
2,5-dimethyl-pyrazolo- [1,5-a] -pyrimidine-3,7-diamine;
pyrazolo- [1,5-a] pyrimidine-3,5-diamine;
2,7-dimethylpyrazolo- [1,5-a] -pyrimidine-3,5-diamine;
3-aminopyrazolo- [1,5-a] -pyrimidin-7-ol;
3-amino-5-methylpyrazolo- [1,5-a] pyrimidine-7-ol;
3-aminopyrazolo- [1,5-a] -pyrimidine-5-ol;
2- (3-aminopyrazolo- [1,5-a] pyrimidin-7-ylamino) ethanol;
3-amino-5-methyl-7-imidazolyl-propylamino-pyrazolo-G1,5-a] -pyrimidine;
3-amino-7-β-hydroxyethylamino-5-methyl-pyrazolo- [1,5-a] pyrimidine;
2- (7-aminopyrazolo- [1,5-a] pyrimidin-3-ylamino) ethanol;
2 [(3-aminopyrazolo- [1,5-a] pyrimidin-7-yl) - (2-hydroxyethyl) amino] ethanol;
2 [(7-aminopyrazolo- [1,5-a] pyrimidin-3-yl) - (2-hydroxyethyl) amino] ethanol;
5,6-dimethylpyrazolo- [1,5-a] - pyrimidine-3,7-diamine;
2,6-dimethylpyrazolo- [1,5-a] -pyrimidine-3,7-diamine;
2,5, N-7, N-7-tetramethylpyrazolo- [1,5-a] -pyrimidine-3,7-diamine;
and their salt adducts with acids or bases. 4. Композиция по любому из предыдущих пунктов, отличающаяся тем, что прямой катионный краситель или красители выбирают из числа катионных аминоантрахиноновых соединений, катионных моно- и диазосоединений и катионных нафтохинонов. 4. Composition according to any one of the preceding paragraphs, characterized in that the direct cationic dye or dyes are selected from among cationic aminoanthraquinone compounds, cationic mono- and diazo compounds and cationic naphthoquinones. 5. Композиция по п.4, отличающаяся тем, что прямые катионные красители выбирают из следующих соединений: хлорид [8-[(п-аминофенил)азол]-7-гидрокси-2-нафтил]триметиламмония, комбинация хлорида 3[(4-амино-6-бром-5, 8-дигидро-1-гидрокси-8-имино-5-оксо-2-нафталенил)амино]-N, N, N-триметилбензаминия и хлорида 3-[(2,6-дибром-5,8-дигидро-1-гидрокси-8-имино-5-оксо-3-нафтил)амино] -N, N, N-триметилбензаминия, хлорид 7-гидрокси-8-[(2-метоксифенил)азо] -N,N,N-триметил-2-нафтаминия, хлорид [8-[(4-амино-2-нитрофенил)азо] -7-гидрокси-2-нафтил] триметиламмония, комбинация хлорида [(8-[(4-амино-3-нитрофенил)азо] -7-гидрокси-2-нафтил] триметиламмония и хлорида [8-[(4-амино-2-нитрофенил)азо]-7-гидрокси-2-нафтил]триметиламмония, хлорид 3-[(4,5-дигидро-3-метил-5-оксо-1-фенил-1Н-пиразол-4-ил)азо] -N,N,N-триметилбензаминия, гидрохлорид 1-(γ-аминопропил)аминоантрахинона, метилсульфат 1-N-(метилморфолинийпропил)амино-4-гидроксиантрахинон и Basic Orange 69®.5. The composition according to claim 4, characterized in that the direct cationic dyes are selected from the following compounds: chloride [8 - [(p-aminophenyl) azole] -7-hydroxy-2-naphthyl] trimethylammonium, a combination of chloride 3 [(4- amino-6-bromo-5, 8-dihydro-1-hydroxy-8-imino-5-oxo-2-naphthalenyl) amino] -N, N, N-trimethylbenzene and chloride 3 - [(2,6-dibromo- 5,8-dihydro-1-hydroxy-8-imino-5-oxo-3-naphthyl) amino] -N, N, N-trimethylbenzene, 7-hydroxy-8 - [(2-methoxyphenyl) azo] -N chloride , N, N-trimethyl-2-naphthamynium, [8 - [(4-amino-2-nitrophenyl) azo] -7-hydroxy-2-naphthyl] trimethylammonium chloride, chloride combination [(8 - [(4-amino- 3-nit rofenyl) azo] -7-hydroxy-2-naphthyl] trimethylammonium and chloride [8 - [(4-amino-2-nitrophenyl) azo] -7-hydroxy-2-naphthyl] trimethylammonium, chloride 3 - [(4,5 -dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl) azo] -N, N, N-trimethylbenzene, 1- (γ-aminopropyl) aminoanthraquinone hydrochloride, 1-N- methyl sulfate ( methyl morpholine-propyl) amino-4-hydroxyanthraquinone and Basic Orange 69 ® . 6. Композиция по любому из пп.1-3, отличающаяся тем, что прямой катионный краситель или красители выбирают из соединений приведенных ниже формул I, II, III, III' и IV:
а) соединения формулы I
Figure 00000002

в которой D обозначает атом азота или группу -СН;
R1 и R2, одинаковые или разные, обозначают атом водорода, радикал С1-С4-алкил, который может быть замещен радикалом -CN, ОН или NH2, или вместе с атомом углерода бензольного цикла образуют кислород- или азотсодержащий гетероцикл, который может быть замещен одним или несколькими С1-С4-алкилами, или радикал 4'-аминофенил;
R3 и R'3 одинаковые или разные, обозначают атом водорода или галогена, выбранный из хлора, брома, иода и фтора, радикал циано, С1-С4-алкокси или ацетокси;
X- обозначает анион, преимущественно выбранный из хлорида, метилсульфата и ацетата;
А обозначает группу, выбранную из приведенных ниже структур А1-А19:
Figure 00000003

Figure 00000004

Figure 00000005

Figure 00000006

Figure 00000007

Figure 00000008

Figure 00000009

Figure 00000010

Figure 00000011

Figure 00000012

в которых R4 обозначает С1-С4-алкил, который может быть замещен гидроксилом, а R5 обозначает С1-С4-алкокси-радикал при условии, что, когда D обозначает -СН, А обозначает А4 или А13 и R3 не является алкокси-радикалом, тогда R1 и R2 не могут быть одновременно атомами водорода;
b) соединения формулы II:
Figure 00000013

в которой R6 обозначает атом водорода или С1-С4-алкил;
R7 обозначает атом водорода, радикал алкил, который может быть замещен радикалом -CN или аминогруппой, радикал 4'-аминофенил, или вместе с R6 образует кислород- и/или азотсодержащий гетероцикл, который может быть замещен С1-С4-алкилом;
R8 и R9, одинаковые или разные, обозначают атом водорода или галогена, выбранный из хлора, брома, иода и фтора, радикалы С1-С4-алкил, С1-С4-алкокси и -CN;
X- обозначает анион, преимущественно выбранный из хлорида, метилсульфата и ацетата;
В обозначает группу, выбранную из приведенных ниже структур В1-В6
Figure 00000014

Figure 00000015

Figure 00000016

Figure 00000017

в которых R10 обозначает С1-С4-алкил, R11 и R12, одинаковые или разные, обозначают атом водорода или С1-С4-алкил;
с) соединения формул III и III'
Figure 00000018

Figure 00000019

в которых R13 обозначает атом водорода, С1-С4-алкокси или атом галогена, выбранный из хлора, брома, иода и фтора, или аминогруппу;
R14 обозначает атом водорода, С1-С4-алкил или, вместе с атомом углерода бензольного цикла, образует гетероцикл, который может включать атом кислорода и/или быть замещенным одним или несколькими C1-С4-алкил-радикалами;
R15 обозначает атом водорода или галогена, такого как хлор, бром, иод или фтор;
R16 и R17, одинаковые или разные, обозначают атом водорода или С1-С4-алкил;
D1 и D2, одинаковые или разные, обозначают атом азота или группу -СН; m = 0 или 1,
при условии, что, когда R13 обозначает незамещенную аминогруппу, тогда D1 и D2 одновременно обозначают группу -СН, а m=0,
X- обозначает анион, преимущественно выбранный из хлорида, метилсульфата и ацетата;
Е обозначает группу, выбранную из приведенных ниже структур Е1-Е8:
Figure 00000020

Figure 00000021

Figure 00000022

Figure 00000023

в которых R' обозначает С1-С4-алкил; когда m=0 и D1 обозначает атом азота, тогда Е может также обозначать группу, имеющую приведенную ниже структуру Е9:
Figure 00000024

в которой R' обозначает С1-С4-алкил.6. Composition according to any one of claims 1 to 3, characterized in that the direct cationic dye or dyes are selected from the compounds of the following formulas I, II, III, III 'and IV:
a) compounds of formula I
Figure 00000002

in which D represents a nitrogen atom or a —CH group;
R 1 and R 2 , which are the same or different, denote a hydrogen atom, a C 1 -C 4 -alkyl radical which may be substituted by a -CN, OH or NH 2 radical, or together with a carbon atom of the benzene ring form an oxygen or nitrogen-containing heterocycle, which may be substituted by one or more C 1 -C 4 -alkyls, or the 4'-aminophenyl radical;
R 3 and R ' 3 are the same or different, represent a hydrogen or halogen atom selected from chlorine, bromine, iodine and fluorine, a cyano radical, C 1 -C 4 alkoxy or acetoxy;
X - denotes an anion predominantly selected from chloride, methyl sulfate and acetate;
And indicates a group selected from the following structures A1-A19:
Figure 00000003

Figure 00000004

Figure 00000005

Figure 00000006

Figure 00000007

Figure 00000008

Figure 00000009

Figure 00000010

Figure 00000011

Figure 00000012

in which R 4 denotes C 1 -C 4 -alkyl, which may be substituted by hydroxyl, and R 5 denotes a C 1 -C 4 -alkoxy radical with the proviso that when D denotes -CH, A denotes A4 or A13 and R 3 is not an alkoxy radical, then R 1 and R 2 cannot be simultaneously hydrogen atoms;
b) compounds of formula II:
Figure 00000013

in which R 6 denotes a hydrogen atom or C 1 -C 4 -alkyl;
R7 represents a hydrogen atom, an alkyl radical, which may be substituted by a -CN or an amino group, a 4'-aminophenyl radical, or together with R 6 forms an oxygen- and / or nitrogen-containing heterocycle, which may be substituted with C 1 -C 4 -alkyl;
R 8 and R 9 , which are the same or different, represent a hydrogen or halogen atom selected from chlorine, bromine, iodine and fluorine, C 1 -C 4 -alkyl radicals, C 1 -C 4 -alkoxy and -CN;
X - denotes an anion predominantly selected from chloride, methyl sulfate and acetate;
B stands for a group selected from the structures B1-B6 below.
Figure 00000014

Figure 00000015

Figure 00000016

Figure 00000017

in which R 10 is C 1 -C 4 -alkyl, R 11 and R 12 are the same or different, they represent a hydrogen atom or C 1 -C 4 -alkyl;
c) compounds of formulas III and III '
Figure 00000018

Figure 00000019

in which R 13 represents a hydrogen atom, C 1 -C 4 alkoxy or a halogen atom selected from chlorine, bromine, iodine and fluorine, or an amino group;
R 14 represents a hydrogen atom, C 1 -C 4 alkyl or, together with a carbon atom of a benzene ring, forms a heterocycle, which may include an oxygen atom and / or be substituted by one or more C 1 -C 4 alkyl radicals;
R 15 denotes a hydrogen atom or a halogen, such as chlorine, bromine, iodine or fluorine;
R 16 and R 17 , which are the same or different, represent a hydrogen atom or C 1 -C 4 -alkyl;
D 1 and D 2 , the same or different, represent a nitrogen atom or a —CH group; m = 0 or 1,
provided that when R 13 denotes an unsubstituted amino group, then D 1 and D 2 simultaneously denote the group —CH, and m = 0,
X - denotes an anion predominantly selected from chloride, methyl sulfate and acetate;
E denotes a group selected from the following structures E1-E8:
Figure 00000020

Figure 00000021

Figure 00000022

Figure 00000023

in which R ′ is C 1 -C 4 alkyl; when m = 0 and D 1 denotes a nitrogen atom, then E may also denote a group having the structure E9 below:
Figure 00000024

in which R 'denotes C 1 -C 4 -alkyl. d) соединения формулы IV
G-N=N-J
в которой G обозначает группу, выбранную из приведенных ниже структур G1-G3:
Figure 00000025

Figure 00000026

Figure 00000027

в которых R18 обозначает С1-С4-алкил, фенил, который может быть замещен С1-С4-алкилом, или атом галогена (бром, хлор, иод или фтор);
R19 обозначает С1-С4-алкил или фенил;
R20 и R21, одинаковые или разные, обозначают C1-C4-алкил, фенил или вместе образуют в G1 бензольный цикл, замещенный одним или несколькими С1-С4-алкилами, С1-С4-алкокси или NO2, или образуют в G2 бензольный цикл, возможно замещенный одним или несколькими С1-С4-алкилами, С1-С4-алкокси или NO2;
R20 может кроме того обозначать атом водорода;
Z обозначает атом кислорода, серы или группу -NR19;
М обозначает группу -СН, -CR'' (R'' обозначает С1-С4-алкил) или -NR22(X-)r;
К обозначает группу -СН, -CR'' (R'' обозначает С1-С4-алкил) или -NR22(X-)r;
Р обозначает группу -СН, -CR" (R" обозначает С1-С4-алкил) или -NR22(X-)r, где r = 0 или 1;
R22 обозначает атом O-, радикал С1-С4-алкокси или С1-С4-алкил;
R23 и R24, одинаковые или разные, обозначают атом водорода или галогена (бром, хлор, иод или фтор), С1-С4-алкил, С1-С4-алкокси или радикал -NO2;
Х- обозначает анион, преимущественно выбранный из хлорида, иодида, метилсульфата, этилсульфата, ацетата и перхлората;
при условии, что, если R22 обозначает O-, то r равно 0; если K или P или М обозначает -N-(С1-С4-алкил)Х-, то по меньшей мере один из радикалов R23 и R24 отличен от атома водорода; если К обозначает -NR22(X-)r, то М=Р и обозначают -СН или -CR''; если М обозначает -NR22(X-)r, то К=Р и обозначают -СН или -CR''; если Р обозначает -NR22(X-)r, то К=М и обозначают -СН или -CR''; если Z обозначает атом серы, a R21 обозначает С1-С4-алкил, то R20 отличен от атома водорода; если Z обозначает -NR22, a R19 обозначает С1-С4-алкил, то по меньшей мере один из радикалов R18, R19 или R20 группы со структурой G2 не является С1-С4-алкилом;
J обозначает:
либо группу, приведенной ниже структуры J1:
Figure 00000028

в которой R25 обозначает атом водорода, атом галогена (бром, хлор, иод или фтор), С1-С4-алкил, С1-С4-алкокси, радикал -ОН, -NO2, -NHR28, -NR29R30, -NHCO(С1-С4-алкил) или образует вместе с R26 5- или 6-членный цикл, который может содержать один или несколько гетероатомов, выбранных из азота, кислорода или серы;
R26 обозначает атом водорода, атом галогена (бром, хлор, иод или фтор), С1-С4-алкил, С1-С4-алкокси или образует вместе с R27 или R28 5- или 6-членный цикл, который может содержать один или несколько гетероатомов, выбранных из азота, кислорода или серы;
R27 обозначает атом водорода, радикал -ОН, -NHR28 или -NR29R30;
R28 обозначает атом водорода, С1-С4-алкил, моногидрокси-С1-С4-алкил, полигидрокси-С2-С4-алкил или фенил;
R29 и R30, одинаковые или разные, обозначают С1-С4-алкил, моногидрокси-С1-С4-алкил или полигидрокси-С2-С4-алкил;
либо азотсодержащую 5- или 6-членную гетероциклическую группу, которая может также содержать другие гетероатомы и/или карбонильные группы и быть замещенной одним или несколькими радикалами: С1-С4-алкилом, аминогруппой или фенилом, в частности, группу, имеющую приведенную ниже структуру J2:
Figure 00000029

в которой R31 и R32, одинаковые или разные, обозначают атом водорода, С1-С4-алкил или фенил;
Y обозначает радикал -СО- или радикал
Figure 00000030

n = 0 или 1, причем, когда n=1, тогда U обозначает радикал -СО-.d) compounds of formula IV
GN = NJ
in which G denotes a group selected from the following structures G 1 -G 3 :
Figure 00000025

Figure 00000026

Figure 00000027

in which R 18 is C 1 -C 4 -alkyl, phenyl, which may be substituted with C 1 -C 4 -alkyl, or a halogen atom (bromine, chlorine, iodine or fluorine);
R 19 is C 1 -C 4 alkyl or phenyl;
R 20 and R 21 , the same or different, denote C 1 -C 4 -alkyl, phenyl or together form a G 1 benzene cycle, substituted by one or more C 1 -C 4 -alkyls, C 1 -C 4 -alkoxy or NO 2 , or form a benzene ring in G 2 , possibly substituted by one or more C 1 -C 4 -alkyls, C 1 -C 4 -alkoxy, or NO 2 ;
R 20 may also denote a hydrogen atom;
Z represents an oxygen atom, a sulfur or the group —NR 19 ;
M represents a group —CH, —CR ″ (R ″ means C 1 -C 4 alkyl) or —NR 22 (X - ) r ;
K represents a group —CH, —CR ″ (R ″ means C 1 -C 4 alkyl) or —NR 22 (X - ) r ;
P denotes the group -CH, -CR "(R" denotes C 1 -C 4 alkyl) or -NR 22 (X - ) r , where r = 0 or 1;
R 22 denotes an O - atom, a C 1 -C 4 -alkoxy or C 1 -C 4 -alkyl radical;
R 23 and R 24 , which are the same or different, represent a hydrogen or halogen atom (bromine, chlorine, iodine or fluorine), C 1 -C 4 alkyl, C 1 -C 4 alkoxy, or the radical —NO 2 ;
X - denotes an anion predominantly selected from chloride, iodide, methyl sulfate, ethyl sulfate, acetate and perchlorate;
provided that if R 22 is O - , then r is 0; if K or P or M represents -N- (C 1 -C 4 -alkyl) X - , then at least one of the radicals R 23 and R 24 is different from a hydrogen atom; if K represents -NR 22 (X - ) r , then M = P and represent -CH or -CR "; if M represents -NR 22 (X - ) r , then K = P and represent -CH or -CR "; if P is —NR 22 (X - ) r , then K = M and is —CH or —CR "; if Z denotes a sulfur atom, and R 21 denotes C 1 -C 4 -alkyl, then R 20 is different from a hydrogen atom; if Z is -NR 22 , and R 19 is C 1 -C 4 alkyl, then at least one of the radicals R 18 , R 19 or R 20 of the group with the structure of G 2 is not C 1 -C 4 alkyl;
J stands for:
or a group of structure J 1 below:
Figure 00000028

in which R 25 denotes a hydrogen atom, a halogen atom (bromine, chlorine, iodine or fluorine), C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, radical -OH, -NO 2 , -NHR 28 , -NR 29 R 30 , -NHCO (C 1 -C 4 -alkyl) or forms together with R 26 a 5- or 6-membered cycle, which may contain one or more heteroatoms selected from nitrogen, oxygen or sulfur;
R26 denotes a hydrogen atom, a halogen atom (bromine, chlorine, iodine or fluorine), C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or forms together with R 27 or R 28 a 5- or 6-membered cycle, which may contain one or more heteroatoms selected from nitrogen, oxygen or sulfur;
R 27 represents a hydrogen atom, —OH, —NHR 28 or —NR 29 R 30 ;
R 28 represents a hydrogen atom, C 1 -C 4 alkyl, monohydroxy C 1 -C 4 alkyl, polyhydroxy C 2 -C 4 alkyl or phenyl;
R 29 and R 30 , the same or different, are C 1 -C 4 -alkyl, mono-hydroxy-C 1 -C 4 -alkyl or polyhydroxy-C 2 -C 4 -alkyl;
or a nitrogen-containing 5- or 6-membered heterocyclic group which may contain other heteroatoms and / or carbonyl groups and be substituted by one or more radicals: C 1 -C 4 alkyl, amino or phenyl, in particular, a group having the following J 2 structure:
Figure 00000029

in which R 31 and R 32 , identical or different, represent a hydrogen atom, C 1 -C 4 alkyl or phenyl;
Y denotes the radical —CO— or radical
Figure 00000030

n = 0 or 1, and when n = 1, then U denotes the radical -CO-. 7. Композиция по п.6, отличающаяся тем, что прямые катионные красители формулы I выбирают из соединений, отвечающих приведенным ниже структурам I1-I52:
Figure 00000031

Figure 00000032

Figure 00000033

Figure 00000034

Figure 00000035

Figure 00000036

Figure 00000037

Figure 00000038

Figure 00000039

Figure 00000040

Figure 00000041

Figure 00000042

Figure 00000043

Figure 00000044

Figure 00000045

Figure 00000046

Figure 00000047

Figure 00000048

Figure 00000049

Figure 00000050

Figure 00000051

Figure 00000052

Figure 00000053

Figure 00000054

Figure 00000055

Figure 00000056

Figure 00000057

Figure 00000058

Figure 00000059

Figure 00000060

Figure 00000061

Figure 00000062

Figure 00000063

Figure 00000064

Figure 00000065

Figure 00000066

Figure 00000067

Figure 00000068

Figure 00000069

Figure 00000070

Figure 00000071

Figure 00000072

Figure 00000073

Figure 00000074

Figure 00000075

Figure 00000076

Figure 00000077

Figure 00000078

Figure 00000079

Figure 00000080

Figure 00000081

Figure 00000082

8. Композиция по п.6, отличающаяся тем, что прямые катионные красители формулы II выбирают из соединений, отвечающих приведенным ниже структурам II1-II12:
Figure 00000083

Figure 00000084

Figure 00000085

Figure 00000086

Figure 00000087

Figure 00000088

Figure 00000089

Figure 00000090

Figure 00000091

Figure 00000092

Figure 00000093

Figure 00000094

9. Композиция по п.6, отличающаяся тем, что прямые катионные красители формулы III выбирают из соединений, отвечающих приведенным ниже структурам III1-III18:
Figure 00000095

Figure 00000096

Figure 00000097

Figure 00000098

Figure 00000099

Figure 00000100

Figure 00000101

Figure 00000102

Figure 00000103

Figure 00000104

Figure 00000105

Figure 00000106

Figure 00000107

Figure 00000108

Figure 00000109

Figure 00000110

Figure 00000111

Figure 00000112

10. Композиция по п.6, отличающаяся тем, что прямые катионные красители формулы III' выбирают из соединений, отвечающих приведенным ниже структурам III'1-III'3:
Figure 00000113

Figure 00000114

Figure 00000115

11. Композиция по п.6, отличающаяся тем, что прямые катионные красители формулы IV выбирают из соединений, отвечающих приведенным ниже структурам IV1-IV77:
Figure 00000116

Figure 00000117

Figure 00000118

Figure 00000119

Figure 00000120

Figure 00000121

Figure 00000122

Figure 00000123

Figure 00000124

Figure 00000125

Figure 00000126

Figure 00000127

Figure 00000128

Figure 00000129

Figure 00000130

Figure 00000131

Figure 00000132

Figure 00000133

Figure 00000134

Figure 00000135

Figure 00000136

Figure 00000137

Figure 00000138

Figure 00000139

Figure 00000140

Figure 00000141

Figure 00000142

Figure 00000143

Figure 00000144

Figure 00000145

Figure 00000146

Figure 00000147

Figure 00000148

Figure 00000149

Figure 00000150

Figure 00000151

Figure 00000152

Figure 00000153

Figure 00000154

Figure 00000155

Figure 00000156

Figure 00000157

Figure 00000158

Figure 00000159

Figure 00000160

Figure 00000161

Figure 00000162

Figure 00000163

Figure 00000164

Figure 00000165

Figure 00000166

Figure 00000167

Figure 00000168

Figure 00000169

Figure 00000170

Figure 00000171

Figure 00000172

Figure 00000173

Figure 00000174

Figure 00000175

Figure 00000176

Figure 00000177

Figure 00000178

Figure 00000179

Figure 00000180

Figure 00000181

Figure 00000182

Figure 00000183

Figure 00000184

Figure 00000185

Figure 00000186

Figure 00000187

Figure 00000188

Figure 00000189

Figure 00000190

Figure 00000191

Figure 00000192

12. Композиция по любому из предыдущих пунктов, отличающаяся тем, что пиразоло-[1,5-а] -пиримидины и/или их солевые аддукты с кислотами или основаниями составляют 0,0005 - 12% от общей массы красящей композиции.7. The composition according to claim 6, characterized in that the direct cationic dyes of the formula I are selected from compounds corresponding to the structures I1-I52 below:
Figure 00000031

Figure 00000032

Figure 00000033

Figure 00000034

Figure 00000035

Figure 00000036

Figure 00000037

Figure 00000038

Figure 00000039

Figure 00000040

Figure 00000041

Figure 00000042

Figure 00000043

Figure 00000044

Figure 00000045

Figure 00000046

Figure 00000047

Figure 00000048

Figure 00000049

Figure 00000050

Figure 00000051

Figure 00000052

Figure 00000053

Figure 00000054

Figure 00000055

Figure 00000056

Figure 00000057

Figure 00000058

Figure 00000059

Figure 00000060

Figure 00000061

Figure 00000062

Figure 00000063

Figure 00000064

Figure 00000065

Figure 00000066

Figure 00000067

Figure 00000068

Figure 00000069

Figure 00000070

Figure 00000071

Figure 00000072

Figure 00000073

Figure 00000074

Figure 00000075

Figure 00000076

Figure 00000077

Figure 00000078

Figure 00000079

Figure 00000080

Figure 00000081

Figure 00000082

8. The composition according to claim 6, characterized in that the direct cationic dyes of the formula II are selected from compounds corresponding to the structures II1-II12 below:
Figure 00000083

Figure 00000084

Figure 00000085

Figure 00000086

Figure 00000087

Figure 00000088

Figure 00000089

Figure 00000090

Figure 00000091

Figure 00000092

Figure 00000093

Figure 00000094

9. The composition according to p. 6, characterized in that the direct cationic dyes of the formula III are selected from compounds corresponding to the structures III1-III18 below:
Figure 00000095

Figure 00000096

Figure 00000097

Figure 00000098

Figure 00000099

Figure 00000100

Figure 00000101

Figure 00000102

Figure 00000103

Figure 00000104

Figure 00000105

Figure 00000106

Figure 00000107

Figure 00000108

Figure 00000109

Figure 00000110

Figure 00000111

Figure 00000112

10. The composition according to claim 6, characterized in that the direct cationic dyes of the formula III 'are selected from compounds corresponding to the structures III'1-III'3 below:
Figure 00000113

Figure 00000114

Figure 00000115

11. The composition according to p. 6, characterized in that the direct cationic dyes of formula IV are selected from compounds corresponding to the structures IV1-IV77 below:
Figure 00000116

Figure 00000117

Figure 00000118

Figure 00000119

Figure 00000120

Figure 00000121

Figure 00000122

Figure 00000123

Figure 00000124

Figure 00000125

Figure 00000126

Figure 00000127

Figure 00000128

Figure 00000129

Figure 00000130

Figure 00000131

Figure 00000132

Figure 00000133

Figure 00000134

Figure 00000135

Figure 00000136

Figure 00000137

Figure 00000138

Figure 00000139

Figure 00000140

Figure 00000141

Figure 00000142

Figure 00000143

Figure 00000144

Figure 00000145

Figure 00000146

Figure 00000147

Figure 00000148

Figure 00000149

Figure 00000150

Figure 00000151

Figure 00000152

Figure 00000153

Figure 00000154

Figure 00000155

Figure 00000156

Figure 00000157

Figure 00000158

Figure 00000159

Figure 00000160

Figure 00000161

Figure 00000162

Figure 00000163

Figure 00000164

Figure 00000165

Figure 00000166

Figure 00000167

Figure 00000168

Figure 00000169

Figure 00000170

Figure 00000171

Figure 00000172

Figure 00000173

Figure 00000174

Figure 00000175

Figure 00000176

Figure 00000177

Figure 00000178

Figure 00000179

Figure 00000180

Figure 00000181

Figure 00000182

Figure 00000183

Figure 00000184

Figure 00000185

Figure 00000186

Figure 00000187

Figure 00000188

Figure 00000189

Figure 00000190

Figure 00000191

Figure 00000192

12. Composition according to any one of the preceding paragraphs, characterized in that the pyrazolo- [1,5-a] -pyrimidines and / or their salt adducts with acids or bases comprise 0.0005 - 12% of the total mass of the coloring composition. 13. Композиция по п.12, отличающаяся тем, что пиразоло-[1,5-а]-пиримидины и/или их солевые аддукты с кислотами или основаниями составляют 0,005 - 6% от общей массы красящей композиции. 13. The composition according to p. 12, characterized in that the pyrazolo [1,5-a] -pyrimidines and / or their salt adducts with acids or bases are 0.005 - 6% of the total mass of the coloring composition. 14. Композиция по любому из предыдущих пунктов, отличающаяся тем, что прямой катионный краситель или красители составляют 0,001 - 10% от общей массы красящей композиции. 14. Composition according to any one of the preceding paragraphs, characterized in that the direct cationic dye or dyes comprise 0.001 - 10% of the total mass of the coloring composition. 15. Композиция по п.14, отличающаяся тем, что прямой катионный краситель или красители составляют 0,005 - 5% от общей массы композиции. 15. The composition according to p. 14, characterized in that the direct cationic dye or dyes make up 0.005 - 5% of the total weight of the composition. 16. Композиция по любому из предыдущим пунктов, отличающаяся тем, что она содержит одно или несколько краскообразующих веществ, выбираемых из м-фенилендиаминов, м-аминофенолов, м-дифенолов и гетероциклических краскообразующих веществ, таких, например, как производные индола, производные индолина, производные пиридина и пиразолоны и их солевых аддуктов с кислотами. 16. Composition according to any one of the preceding paragraphs, characterized in that it contains one or more paint-forming substances selected from m-phenylenediamines, m-aminophenols, m-diphenols and heterocyclic paint-forming substances, such as, for example, indole derivatives, indoline derivatives, pyridine derivatives and pyrazolones and their salt adducts with acids. 17. Композиция по любому из предыдущих пунктов, отличающаяся тем, что она содержит одно или несколько дополнительных окисляемых оснований, отличных от пиразоло-[1,5-а]-пиримидинов и/или один или несколько прямых некатионных красителей. 17. Composition according to any one of the preceding paragraphs, characterized in that it contains one or more additional oxidizable bases other than pyrazolo- [1,5-a] -pyrimidines and / or one or more direct non-cationic dyes. 18. Композиция по п.17, отличающаяся тем, что дополнительные окисляемые основания выбирают из п-фенилендиаминов, бис-фенилалкилендиаминов, п-аминофенолов, о-аминофенолов и гетероциклических оснований. 18. The composition according to claim 17, wherein the additional oxidizable bases are selected from p-phenylenediamines, bis-phenylalkylenediamines, p-aminophenols, o-aminophenols and heterocyclic bases. 19. Композиция по любому из предыдущих пунктов, отличающаяся тем, что солевые аддукты с кислотами выбирают из гидрохлоридов, гидробромидов, сульфатов, цитратов, сукцинатов, тартратов, лактатов и ацетатов, а солевые аддукты с основаниями получают с гидроксидами натрия, калия, аммония и аминами. 19. Composition according to any one of the preceding paragraphs, characterized in that the salt adducts with acids are selected from hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates and acetates, and salt adducts with bases are obtained with sodium, potassium, ammonium hydroxides and amines . 20. Способ окислительного окрашивания кератиновых волокон, в частности, кератиновых волокон человека, таких как волосы, отличающийся тем, что на названные волокна наносят по меньшей мере одну определенную в пп.1-19 красящую композицию и проявляют цвет при кислых, нейтральных или щелочных значениях рН с помощью неферментативного окисляющего агента, который добавляют непосредственно в момент применения красящей композиции или который присутствует в окислительной композиции, применяемой одновременно с красящей или после нее. 20. Method of oxidative dyeing of keratin fibers, in particular, human keratin fibers, such as hair, characterized in that at least one coloring composition defined in paragraphs 1-19 is applied to the fibers and exhibits color at acidic, neutral or alkaline values pH using non-enzymatic oxidizing agent, which is added directly at the time of application of the coloring composition or which is present in the oxidizing composition used simultaneously with the coloring or after it. 21. Способ по п.20, отличающийся тем, что окисляющий агент выбирают из перекиси водорода, перекиси мочевины, броматов щелочных металлов, надкислот и персолей. 21. The method according to p. 20, characterized in that the oxidizing agent is chosen from hydrogen peroxide, urea peroxide, alkali metal bromates, peracids and persalts. 22. Устройство с несколькими отделениями, или красильный "набор", первое отделение которого содержит определенную в пп.1-19 красящую композицию и второе отделение содержит окислительную композицию, содержащую неферментативный окислительный агент. 22. A device with several compartments, or a dye "kit", the first compartment of which contains the dye composition defined in paragraphs 1-19 and the second compartment contains an oxidizing composition containing a non-enzymatic oxidizing agent.
RU99123528/14A 1998-11-04 1999-11-03 Composite for oxidative keratin fibers staining, method of their staining, set for oxidative staining keratin fibers RU2185811C2 (en)

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DE102004049363A1 (en) 2004-10-08 2006-04-13 Henkel Kgaa Agent for dyeing keratinous fibers
DE102004052480A1 (en) 2004-10-28 2006-05-04 Henkel Kgaa Dyeing composition for keratin fibres which contains a reducing agent
DE102005011924A1 (en) 2005-03-14 2006-10-19 Henkel Kgaa New dyes and colorants with special carbonyl compounds
DE102005025494A1 (en) 2005-06-01 2006-12-14 Henkel Kgaa Multi-stage staining procedure for keratin fibers
DE102005038771A1 (en) 2005-08-15 2007-02-22 Henkel Kgaa Hair dyeing and treatment kit with dye and color protectant
WO2007025889A2 (en) 2005-08-30 2007-03-08 Ciba Specialty Chemicals Holding Inc. Dyes containing a thiol group
DE102005043187A1 (en) 2005-09-09 2007-03-15 Henkel Kgaa Polymers with a low molecular weight
DE102005055892A1 (en) 2005-11-22 2007-05-24 Henkel Kgaa New coupler components
DE102005057183A1 (en) 2005-11-29 2007-06-06 Henkel Kgaa Biomimetic melanin pigments
DE102005062360A1 (en) 2005-12-23 2007-06-28 Henkel Kgaa Method for gentle dyeing of keratinic fibers, especially human hair, includes treatment, after oxidation dyeing, with a foam-forming composition that includes a care agent
DE102005062356A1 (en) 2005-12-23 2007-06-28 Henkel Kgaa Reduction of hair aging
DE102005062651A1 (en) 2005-12-23 2007-06-28 Henkel Kgaa Product for conditioning keratinic fibers, especially hair, comprises an amphodipropionate surfactant, a cationic or amphoteric polymer and a polyammonium polysiloxane
DE102006005450A1 (en) 2006-02-07 2007-08-09 Henkel Kgaa Polymer-based hair coloring cream
EP2277598B1 (en) 2006-03-21 2017-08-02 Henkel AG & Co. KGaA Reductive colour removal
EP2001557A2 (en) 2006-03-21 2008-12-17 Henkel AG & Co. KGaA Reductive colour removal
WO2007107310A2 (en) 2006-03-21 2007-09-27 Henkel Ag & Co. Kgaa Reductive colour removal
EP2001559A2 (en) 2006-03-21 2008-12-17 Henkel AG & Co. KGaA Reductive colour removal
DE102006017835A1 (en) 2006-04-13 2007-10-18 Henkel Kgaa Brightening and / or coloring agent with piperidones
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DE102006045965A1 (en) 2006-09-27 2008-04-03 Henkel Kgaa Styling agent with a high degree of hold
DE102006051729A1 (en) 2006-10-30 2008-05-08 Henkel Kgaa Cosmetic agent
DE102006060150A1 (en) 2006-12-18 2008-06-19 Henkel Kgaa Agent for dyeing keratinous fibers
DE102007002582A1 (en) 2007-01-11 2008-07-17 Henkel Kgaa Brightening and / or coloring agent with acrylic acid derivative (s)
DE102007005645A1 (en) 2007-01-31 2008-08-07 Henkel Ag & Co. Kgaa Polymer effect coated light effect pigments
DE102007005646A1 (en) 2007-01-31 2008-08-07 Henkel Ag & Co. Kgaa Colorant containing luminescent pigments which can be excited by visible light
DE102007007050A1 (en) 2007-02-08 2008-08-14 Henkel Ag & Co. Kgaa Lightening agent and piperidone (s) and imidazole (s)
DE102007014630A1 (en) 2007-03-23 2008-09-25 Henkel Ag & Co. Kgaa Hair Dye
DE102007018380A1 (en) 2007-04-17 2008-10-30 Henkel Ag & Co. Kgaa New cationic aza-benzene compounds useful for the preparation of the agent for dyeing and brightening keratin fibers, preferably human hairs, wool, fur and feathers
DE102007019370A1 (en) 2007-04-23 2008-10-30 Henkel Ag & Co. Kgaa Dyeing process with shortened application time
DE102007022916A1 (en) 2007-05-14 2008-11-20 Henkel Ag & Co. Kgaa Pheromone-containing cosmetic products
DE102007027856A1 (en) 2007-06-13 2008-12-24 Henkel Ag & Co. Kgaa Oxidation colorant for coloring keratin-containing fibers with atmospheric oxygen as the sole oxidant
DE102007027862A1 (en) 2007-06-13 2008-12-24 Henkel Ag & Co. Kgaa Method for filling hair color-changing agents
DE102007028266A1 (en) 2007-06-15 2008-12-18 Henkel Ag & Co. Kgaa Kit for providing storage-stable formulations
DE102007031202A1 (en) 2007-07-04 2009-03-19 Henkel Ag & Co. Kgaa New protein hydrolysate obtained from wool of Vicugna useful as laundry detergent, wool detergent, manual dishwashing agent and cosmetic agent, which is useful for treating skin and hair
DE102007031661A1 (en) 2007-07-06 2009-01-08 Henkel Ag & Co. Kgaa Self-tanning compositions with natural tanning effect
DE102007033093A1 (en) 2007-07-13 2009-01-15 Henkel Ag & Co. Kgaa Agent with anti-irritating agent
DE102007033184A1 (en) 2007-07-13 2009-07-02 Henkel Ag & Co. Kgaa Cosmetic composition, useful for the care and preservation of natural functions of keratin fibers and increasing the brightness of keratin fibers, preferably human hairs, comprises a powder of a gemstone or semi-precious stone
DE102007033091A1 (en) 2007-07-13 2009-01-15 Henkel Ag & Co. Kgaa Agent with anti-irritating agent
DE102007033362A1 (en) 2007-07-16 2009-01-22 Henkel Ag & Co. Kgaa Agent for dyeing keratinous fibers
DE102007034482A1 (en) 2007-07-20 2009-01-22 Henkel Ag & Co. Kgaa Oxidative hair treatment with Litchi extract and catechins
DE102007036499A1 (en) 2007-08-01 2009-02-05 Henkel Ag & Co. Kgaa Natural cosmetic hair treatment agent
DE102007036911A1 (en) 2007-08-06 2009-02-12 Henkel Ag & Co. Kgaa Hair Dye
DE102007037427A1 (en) 2007-08-08 2009-02-12 Henkel Ag & Co. Kgaa Evaporator solution and dyeing process
DE102007037429A1 (en) 2007-08-08 2009-02-12 Henkel Ag & Co. Kgaa Styling agent based on aqueous silicone dispersions
DE102007038484A1 (en) 2007-08-14 2009-02-19 Henkel Ag & Co. Kgaa Hair treatment agent with bacterial fermentation (s)
DE102007039330A1 (en) 2007-08-20 2009-02-26 Henkel Ag & Co. Kgaa Hair treatment agents
DE102007039954A1 (en) 2007-08-23 2009-02-26 Henkel Ag & Co. Kgaa Reductive discoloration of keratinous fibers
DE102007040313A1 (en) 2007-08-24 2009-02-26 Henkel Ag & Co. Kgaa Hair treatment agents
DE102007040314A1 (en) 2007-08-24 2009-02-26 Henkel Ag & Co. Kgaa Kit for providing colorants
DE102007041490A1 (en) 2007-08-31 2009-03-05 Henkel Ag & Co. Kgaa Blondiermittel and Blondierverfahren
DE102007041493A1 (en) 2007-08-31 2009-03-05 Henkel Ag & Co. Kgaa pastel color
DE102007041492A1 (en) 2007-08-31 2009-03-05 Henkel Ag & Co. Kgaa Bleaching agent with delayed Blleichbeginn
DE102007042286A1 (en) 2007-09-06 2009-03-12 Henkel Ag & Co. Kgaa Colorants with natural dyes and 1,3-dihydroxyacetone
DE102007045974A1 (en) 2007-09-25 2009-04-09 Henkel Ag & Co. Kgaa Biotin and silica against hair aging
DE102007046628A1 (en) 2007-09-27 2009-04-02 Henkel Ag & Co. Kgaa Hair dyeing process with oxidative pretreatment
DE102007047687A1 (en) 2007-10-04 2009-04-09 Henkel Ag & Co. Kgaa Hair treatment preparations, in particular styling agents, containing two copolymers
DE102007047688A1 (en) 2007-10-04 2009-04-09 Henkel Ag & Co. Kgaa Brightening agent with cationic 3,4-Dihydroisochinoliniumderivaten and hydrogen peroxide
DE102007047685A1 (en) 2007-10-04 2008-07-31 Henkel Ag & Co. Kgaa Product for lightening the color of keratinic fibers, especially hair, comprises an acylpyridinium derivative, an imidazole compound and hydrogen peroxide
DE102007048140A1 (en) 2007-10-05 2009-04-09 Henkel Ag & Co. Kgaa Oxidative hair treatment with reduced hair damage
DE102007050766A1 (en) 2007-10-22 2009-04-23 Henkel Ag & Co. Kgaa Process for the continuous production of coloring agents for keratinic fibers
DE102008014368A1 (en) 2008-03-17 2009-10-08 Henkel Ag & Co. Kgaa Cosmetic composition for hair treatment, for use e.g. in shampoos, rinses, hair-care products or hair dyes, contains a special flavonoid and a vitamin of the B group, especially tiliroside and pantolactone
EP2057979A1 (en) 2007-11-09 2009-05-13 Henkel AG & Co. KGaA Coloured hair treatment substance
DE102008038138A1 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Agent, useful for coloring keratin fibers, which are fur, wool or feathers, preferably human hair, comprises a dye starting product and a browning product, where the browning product is obtained by heating sugar
DE102007053952A1 (en) 2007-11-09 2009-05-14 Henkel Ag & Co. Kgaa Agent containing ester compound with wax alcohol component
DE102007053950A1 (en) 2007-11-09 2009-05-14 Henkel Ag & Co. Kgaa Agent with bioflavonoid
DE102007054708A1 (en) 2007-11-14 2009-05-20 Henkel Ag & Co. Kgaa Hair treatment with Litchi extract and imidazole derivatives
DE102007054706A1 (en) 2007-11-14 2009-05-20 Henkel Ag & Co. Kgaa Hair treatment with Litchi extract and taurine
DE102007056934A1 (en) 2007-11-23 2009-05-28 Henkel Ag & Co. Kgaa Oxidation colorant for coloring keratin-containing fibers with atmospheric oxygen as the sole oxidant
DE102007056935A1 (en) 2007-11-23 2009-05-28 Henkel Ag & Co. Kgaa Two-component aerosol hair color
DE102007057584A1 (en) 2007-11-28 2009-06-04 Henkel Ag & Co. Kgaa Oxidative dyeing process for keratin fibers
DE102007058921A1 (en) 2007-12-05 2009-06-10 Henkel Ag & Co. Kgaa styling agents
DE102007060530A1 (en) 2007-12-13 2009-09-17 Henkel Ag & Co. Kgaa Hair conditioning agents with cationic behenyl compounds and selected silicones and / or cosmetic oils
DE102007060532A1 (en) 2007-12-13 2009-09-17 Henkel Ag & Co. Kgaa Hair conditioning agents with cationic compounds and selected silicones and / or cosmetic oils
DE102007060528A1 (en) 2007-12-13 2009-06-18 Henkel Ag & Co. Kgaa Hair conditioning compositions containing imidazolines and selected silicones and / or cosmetic oils
DE102007061505A1 (en) 2007-12-18 2009-06-25 Henkel Ag & Co. Kgaa Toning gel-foam
DE102008003361A1 (en) 2008-01-08 2008-11-27 Henkel Ag & Co. Kgaa Agent, useful e.g. to color keratin containing fibers, preferably human hairs, comprises a combination of a vinylether compound with a hydrocarbon acid compound, in a cosmetic carrier
WO2009103798A1 (en) 2008-02-22 2009-08-27 Henkel Ag & Co. Kgaa 9-[4-(amino) phenyl] acridinium salts as cationic direct dyes for coloring keratinous fibers
DE102008012059A1 (en) 2008-02-29 2009-09-03 Henkel Ag & Co. Kgaa Hair treatment remedy with goji extract
DE102008012058A1 (en) 2008-02-29 2009-09-03 Henkel Ag & Co. Kgaa Hair treatment with acai extract
DE102008012068A1 (en) 2008-02-29 2009-09-10 Henkel Ag & Co. Kgaa Hair treatment with cranberry extract
DE102008017104A1 (en) 2008-04-02 2009-10-29 Henkel Ag & Co. Kgaa Dispenser for stocking and releasing multi-component hair treatment unit, has housing with multiple chambers for respective components, where chambers are separated from each other
DE102008018132A1 (en) 2008-04-09 2009-10-15 Henkel Ag & Co. Kgaa Cationic direct drawers and agents for dyeing keratinous fibers
DE102008019340A1 (en) 2008-04-16 2009-10-22 Henkel Ag & Co. Kgaa Hair treatment with cloudberry fruit extract
DE102008022710A1 (en) 2008-05-07 2009-11-12 Henkel Ag & Co. Kgaa Brightening agent with cationic acylpyridinium derivatives, co-bleach activators and hydrogen peroxide
DE102008024030A1 (en) 2008-05-16 2009-11-19 Henkel Ag & Co. Kgaa Brightening agent with cationic 3,4-Dihydroisochinoliniumderivaten, special alkanolamines and hydrogen peroxide
DE102008027239A1 (en) 2008-06-06 2009-03-19 Henkel Ag & Co. Kgaa Agent, useful for oxidative coloring of keratinic fibers, preferably human hair, comprises at least one p-phenylenediamine derivative, as developer component, and further a coupler component
DE102008030660A1 (en) 2008-07-01 2010-01-07 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one specific cellulose and at least one additional film-forming and / or setting polymer
DE102008030661A1 (en) 2008-07-01 2010-01-07 Henkel Ag & Co. Kgaa Keratin-containing fibers containing at least one specific betaine compound and at least one film-forming and / or setting polymer
DE102008030947A1 (en) 2008-07-02 2009-05-07 Henkel Ag & Co. Kgaa Agent, useful for coloring keratin fibers, preferably human hairs, animal hairs, wool, horse hair, angora hair, fur, feathers or textiles, comprises 4-(3-(1H-pyridin-4-ylidene)-cyclopenta-1,4-dienyl)-pyridinium compound as a direct dye
DE102008031748A1 (en) 2008-07-04 2010-01-07 Henkel Ag & Co. Kgaa Hair conditioning agents with imidazolines
DE102008031701A1 (en) 2008-07-04 2010-01-07 Henkel Ag & Co. Kgaa Hair conditioning agents with imidazolines
DE102008031700A1 (en) 2008-07-04 2010-01-07 Henkel Ag & Co. Kgaa Hair conditioning agents with imidazolines
DE102008031726A1 (en) 2008-07-04 2010-01-07 Henkel Ag & Co. Kgaa Hair conditioning agents with imidazolines
DE102008031749A1 (en) 2008-07-04 2010-01-07 Henkel Ag & Co. Kgaa Hair conditioning agents with imidazolines
DE102008031715A1 (en) 2008-07-04 2010-01-07 Henkel Ag & Co. Kgaa Hair conditioning agents with imidazolines
DE102008031702A1 (en) 2008-07-04 2010-01-07 Henkel Ag & Co. Kgaa Hair conditioning agents with imidazolines
DE102008031556A1 (en) 2008-07-07 2009-04-30 Henkel Ag & Co. Kgaa Composition, useful e.g. as shampoo, hair coloring agent, lotion and gel or cream, comprises e.g. tyrosine and/or its derivative, protein hydrolysate, adenosine-triphosphate and a substance comprising riboflavin and lyxoflavin
DE102008032178A1 (en) 2008-07-09 2010-01-21 Henkel Ag & Co. Kgaa Yellow-oxidized oxidation colorants of highly ethoxylated fatty alcohols and polysaccharide thickener for pH reduced express dyeing
DE102008032208A1 (en) 2008-07-09 2010-01-14 Henkel Ag & Co. Kgaa Oxidation stain with basic amino acid, ammonium sulfate and alkanolamines
DE102008033875A1 (en) 2008-07-18 2009-05-07 Henkel Ag & Co. Kgaa Agent, useful for oxidative coloring of keratin fibers, preferably e.g. human hairs, comprises 6-amino-2-hydroxy-pyridine derivative, as coupler component, in a carrier, further developer component and direct dye
DE102008034845A1 (en) 2008-07-24 2010-02-04 Henkel Ag & Co. Kgaa Composition, useful e.g. for coloring and/or lightening keratin fibers, preferably human hair, comprises color-modifying component in a carrier and further contains a combination of thiolactic acid and/or its salt, and functional additive
DE102008035861A1 (en) 2008-08-01 2009-06-04 Henkel Ag & Co. Kgaa Agent, useful for coloring keratin fiber, preferably human hair, comprises at least one new or known 1-hydroxyalkyl-3,5-diaminobenzene compound as a coupler component in a cosmetic acceptable carrier
DE102008036535A1 (en) 2008-08-06 2010-02-11 Henkel Ag & Co. Kgaa Coloration with cationizable polymer
DE102008036717A1 (en) 2008-08-07 2010-02-11 Henkel Ag & Co. Kgaa Coloring conditioner
DE102008037633A1 (en) 2008-08-14 2010-02-18 Henkel Ag & Co. Kgaa Cosmetic composition containing oil from the fruits of the Sumac family
DE102008038104A1 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one specific amphiphilic cationic polymer and at least one polymer with silicone-containing side chains and anionic groups
DE102008038106A1 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Keratin-containing fiber composition comprising at least one specific amphiphilic cationic polymer and at least one specific additional film-forming anionic and / or setting anionic polymer
EP2323621B1 (en) 2008-08-18 2016-10-05 Henkel AG & Co. KGaA Agent for fibres containing keratin, comprising at least one specific amphiphilic cationic polymer, at least one cationic styling polymer that is different therefrom and at least one film-forming non-ionic and/or stabilizing non-ionic polymer
DE102008038105A1 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one specific amphiphilic, cationic polymer and at least one specific amphiphilic, anionic polymer
DE102008059479A1 (en) 2008-11-28 2010-06-10 Henkel Ag & Co. Kgaa Agent, useful e.g. to treat human hair, comprises an amphiphilic, cationic polymer having pyrrolidin-2-one-, azepan-2-one- or nitrogen containing- structural unit, and a film-forming cationic and/or stabilizing cationic polymer
DE102008038110A1 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Keratin-containing fiber compositions comprising at least one specific amphiphilic cationic polymer and at least one additional special film-forming nonionic and / or setting nonionic polymer
DE102008038112A1 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one specific amphiphilic, cationic polymer and at least one polyol
WO2010020500A2 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Agent for fibres containing keratin, containing at least one specific amphiphilic cationic polymer and at least one additional film-forming cationic and/or stabilizing polymer
DE102008059480A1 (en) 2008-11-28 2010-06-02 Henkel Ag & Co. Kgaa Agent, useful e.g. to treat keratin fibers, comprises amphiphilic, cationic polymer having e.g. pyrrolidin-2-one structural unit, film-forming cationic/stabilizing cationic polymer, and film-forming non-ionic/stabilizing non-ionic polymer
DE102008038107A1 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one particular amphiphilic cationic polymer and at least one additional film-forming and / or setting polymer selected from chitosan and its derivatives
DE102008038109A1 (en) 2008-08-18 2010-02-25 Henkel Ag & Co. Kgaa Agent, useful e.g. to treat keratin fibers, especially human hair, comprises amphiphilic, cationic polymer comprising e.g. pyrrolidin-2-one unit, and amine unit, and film-forming cationic and/or solid cationic polymer in a carrier
DE102008044715A1 (en) 2008-08-28 2010-03-04 Henkel Ag & Co. Kgaa Cationic acylpyridinium derivatives as bleach activators
DE102008044714A1 (en) 2008-08-28 2010-03-04 Henkel Ag & Co. Kgaa Cationic dihydroisoquinolinium derivatives as bleach activators
DE102008046178A1 (en) 2008-09-06 2010-03-11 Henkel Ag & Co. Kgaa Composition, useful for the treatment of skin and keratin fibers (hair), comprises oil extracted from fruits, UV filter e.g. p-aminobenzoic acid, compound having film-forming properties e.g. vitamin B5, and cosmetic carrier
DE102008046433A1 (en) 2008-09-09 2010-03-11 Henkel Ag & Co. Kgaa Brightening agent with 2-acylpyridinium derivatives
DE102008046883A1 (en) 2008-09-11 2010-03-18 Henkel Ag & Co. Kgaa Hair treatment with spirulina extract
DE102008046882A1 (en) 2008-09-11 2010-03-18 Henkel Ag & Co. Kgaa Hair treatment agent with chitosan succinamide
DE102008047945A1 (en) 2008-09-18 2009-06-25 Henkel Ag & Co. Kgaa Cosmetic or dermatological composition, useful e.g. for artifical skin tanning or repigmenting hair, includes tyrosine compound and acetyl-methionyl-arginine ethyl ester
DE102008048438A1 (en) 2008-09-23 2010-03-25 Henkel Ag & Co. Kgaa Compositions for reducing breakage of keratinic fibers
DE102008049323A1 (en) 2008-09-29 2010-04-01 Henkel Ag & Co. Kgaa New developer components
DE102008052618A1 (en) 2008-10-21 2010-04-22 Henkel Ag & Co. Kgaa Tricyclic aldehydes and C, H-acidic compounds
DE102008061863A1 (en) 2008-10-22 2010-04-29 Henkel Ag & Co. Kgaa Process for lamination of gray hair
DE102008061855A1 (en) 2008-10-22 2010-04-29 Henkel Ag & Co. Kgaa Agent for dyeing keratinous fibers
DE102008061857A1 (en) 2008-10-22 2010-04-29 Henkel Ag & Co. Kgaa Colorants based on CH-acidic compounds
DE102008055615A1 (en) 2008-11-03 2010-05-06 Henkel Ag & Co. Kgaa Hair dyeing process with after-treatment
DE102008056811A1 (en) 2008-11-11 2009-09-17 Henkel Ag & Co. Kgaa Agent, useful e.g. for oxidative coloring of keratin fibers e.g. human hair, wool and feathers, comprises substituted 4-aminophenyl compounds and/or their salt as oxidation dyestuff precursor of developer-type in a cosmetic carrier
DE102008057018A1 (en) 2008-11-12 2010-07-08 Henkel Ag & Co. Kgaa Combination of cationic bleach activators and dyes
DE102008058921A1 (en) 2008-11-25 2010-05-27 Henkel Ag & Co. Kgaa New dyes
DE102008060670A1 (en) 2008-12-08 2010-06-10 Henkel Ag & Co. Kgaa Alternative oxidizers
DE102008060671A1 (en) 2008-12-08 2010-06-10 Henkel Ag & Co. Kgaa Accelerated brightening agents
DE102008061133A1 (en) 2008-12-11 2010-06-17 Henkel Ag & Co. Kgaa Increased lightening with simultaneous hair strengthening
DE102008061342A1 (en) 2008-12-11 2010-06-17 Henkel Ag & Co. Kgaa Hair color with cocoa butter
DE102008061040A1 (en) 2008-12-11 2010-06-17 Henkel Ag & Co. Kgaa Strengthening coloration
DE102008061046A1 (en) 2008-12-11 2010-06-17 Henkel Ag & Co. Kgaa Hair dye with color indicator
DE102008061702A1 (en) 2008-12-12 2009-11-12 Henkel Ag & Co. Kgaa Agent, useful for coloring keratin fibers, preferably human hairs, comprises N-(4-amino-3-methylphenyl)-N-(3-(1H-imidazol-1-yl)propyl)amine or its salt, as a developer component, in a cosmetic carrier
DE102008061676A1 (en) 2008-12-12 2009-11-19 Henkel Ag & Co. Kgaa Agent in a carrier, useful for coloring keratin fibers, preferably human hairs, comprises developer component comprising N-(4-amino-3-methylphenyl)-N-(3-(1H-imidazol-1-yl)propyl)amine in combination with a pyrazole compound
DE102008061675A1 (en) 2008-12-12 2009-11-19 Henkel Ag & Co. Kgaa Agent, useful for coloring keratin fibers, preferably human hairs, comprises N-(4-amino-3-methylphenyl)-N-(3-(1H-imidazol-1-yl)propyl)amine, as developer component in a carrier
DE102008061862A1 (en) 2008-12-15 2010-06-17 Henkel Ag & Co. Kgaa Colorants containing specific halogen-substituted catecholaldehydes and special CH-acidic compounds
DE102008061860A1 (en) 2008-12-15 2010-06-17 Henkel Ag & Co. Kgaa Nourishing hair color
DE102008061864A1 (en) 2008-12-15 2010-10-21 Henkel Ag & Co. Kgaa Agent, useful for oxidative coloring of keratin fibers e.g. human hair, comprises p-phenylene diamine derivatives, as developer component, in a carrier
DE102008061861A1 (en) 2008-12-15 2010-06-17 Henkel Ag & Co. Kgaa Nourishing hair color
DE102008062236A1 (en) 2008-12-16 2009-10-15 Henkel Ag & Co. Kgaa Agent, useful e.g. to color keratin fibers including human hairs cotton and silk, comprises substituted benzene sulfonate compound e.g. 3-methyl-1,3-benzothiazolium-2-sulfonate, and hydrocarbon acid compound in a carrier
DE102008062234A1 (en) 2008-12-16 2009-10-15 Henkel Ag & Co. Kgaa Agent, useful e.g. to color keratin fibers including human hairs cotton and silk, comprises a hydrocarbon acid compound and a reactive carbonyl compound in a cosmetic carrier
DE102008062239A1 (en) 2008-12-16 2010-06-17 Henkel Ag & Co. Kgaa Process for decolorizing keratin-containing fibers
DE102008062237A1 (en) 2008-12-16 2010-06-17 Henkel Ag & Co. Kgaa Reductive discoloration of keratinous fibers
DE202009000769U1 (en) 2009-01-21 2009-03-19 Henkel Ag & Co. Kgaa New dyes
DE102009001576A1 (en) 2009-03-16 2010-01-07 Henkel Ag & Co. Kgaa Agent, useful for coloring keratin fibers, preferably human hair, comprises at least a new or known p-phenylenediamine derivate as a developer component in a carrier
DE102009001687A1 (en) 2009-03-20 2010-01-14 Henkel Ag & Co. Kgaa Agent, useful for dyeing keratin fibers, preferably human hair, comprises a cationic benzo(cd)indolium compound
DE102009002729A1 (en) 2009-04-29 2010-11-04 Henkel Ag & Co. Kgaa Filmbildner in hair colors
DE102009020552A1 (en) 2009-05-08 2010-11-18 Henkel Ag & Co. Kgaa Polymer combination of at least two different N-vinylpyrrolidone / N-vinylcaprolactam copolymers for glossy cosmetic hair treatment agents
DE102009020553A1 (en) 2009-05-08 2010-11-11 Henkel Ag & Co. Kgaa Polymer combination of at least two different N-vinylpyrrolidone / N-vinylcaprolactam copolymers for glossy cosmetic hair treatment agents
DE102009026671A1 (en) 2009-06-03 2011-06-16 Henkel Ag & Co. Kgaa Composition, useful for coloring keratin fibers, preferably human hair, comprises a p-phenylene diamine compound containing a cyclic acetal group as a developer component in a carrier
DE102009026769A1 (en) 2009-06-05 2010-11-25 Henkel Ag & Co. Kgaa Agent, useful e.g. for coloring and brightening of keratin fibers, preferably human hairs, and increasing the skin compatibility of colors and/or brighteners, comprises a cationic 9-phenyl-4a,9a-dihydro-acridine salt
DE102009027485A1 (en) 2009-07-06 2011-01-13 Henkel Ag & Co. Kgaa Foamy colorants
DE102009027925A1 (en) 2009-07-22 2011-01-27 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one acrylate / glyceryl acrylate copolymer, at least one film-forming and / or setting polymer and at least one ester oil
DE102009028054A1 (en) 2009-07-28 2011-02-10 Henkel Ag & Co. Kgaa Cosmetic agent
DE102009028209A1 (en) 2009-08-04 2011-02-10 Henkel Ag & Co. Kgaa Hair treatment compositions with polyether-modified organic compounds and hair-setting polymers
DE102009028207A1 (en) 2009-08-04 2011-02-17 Henkel Ag & Co. Kgaa Hair treatment agent with polyether-modified solid particles and hair-setting polymers
DE102009028206A1 (en) 2009-08-04 2011-02-10 Henkel Ag & Co. Kgaa Hair treatment products with special polyethers and hair-setting polymers
DE102009028523A1 (en) 2009-08-13 2011-02-17 Henkel Ag & Co. Kgaa Foamy colorants II
DE102009028593A1 (en) 2009-08-17 2011-02-24 Henkel Ag & Co. Kgaa Oxidative colorants
DE102009029270A1 (en) 2009-09-08 2010-07-01 Henkel Ag & Co. Kgaa Agent, useful for coloring and simultaneously brightening of keratin fibers, preferably human hair, comprises 2-phenyl-(1,4)naphthoquinone compounds
DE102009045176A1 (en) 2009-09-30 2011-04-07 Henkel Ag & Co. Kgaa Heat-assisting reductive decolorization of keratin-containing fibers
DE102009045575A1 (en) 2009-10-12 2010-07-29 Henkel Ag & Co. Kgaa Agent, useful for dyeing and optionally bleaching keratin fibers, preferably human hair, comprises at least one new or known (1H-benzotriazol-5-yl)-phenyl-diazene compound
DE102009045842A1 (en) 2009-10-20 2011-04-21 Henkel Ag & Co. Kgaa Polyamides of fatty acid dimers and diamines for hair fixation
DE102009045855A1 (en) 2009-10-20 2010-08-05 Henkel Ag & Co. Kgaa Agent, useful for coloring and simultaneously brightening of keratin fibers, preferably human hairs, comprises naphthoquinone compounds
DE102009045839A1 (en) 2009-10-20 2011-04-21 Henkel Ag & Co. Kgaa Polyamides of fatty acid dimers and diamines in combination with special acrylamide copolymers for hair fixation
DE102009045840A1 (en) 2009-10-20 2011-04-21 Henkel Ag & Co. Kgaa Method for remodeling a hairstyle
DE102009045841A1 (en) 2009-10-20 2011-04-21 Henkel Ag & Co. Kgaa Cosmetic agent for the reduction of overcrowded, stubborn hair
EP2490659B1 (en) 2009-10-22 2017-03-01 Henkel AG & Co. KGaA Composition for the temporary shaping of keratinic fibres comprising a nonionic propyleneoxide-modified starch and a chitosan
DE102009045925A1 (en) 2009-10-22 2011-04-28 Henkel Ag & Co. Kgaa Compositions for shaping keratinic fibers
DE102009045933A1 (en) 2009-10-22 2011-04-28 Henkel Ag & Co. Kgaa Composition for shaping keratinic fibers
DE102009046196A1 (en) 2009-10-30 2011-05-05 Henkel Ag & Co. Kgaa tint
DE102010001360A1 (en) 2009-11-18 2011-05-19 Henkel Ag & Co. Kgaa Foamy colorants
DE102009054516A1 (en) 2009-12-10 2011-06-16 Henkel Ag & Co. Kgaa Polymer combination for glossy cosmetic hair treatment products with strong hold and good hair feel
DE102009055281A1 (en) 2009-12-23 2011-06-30 Henkel AG & Co. KGaA, 40589 Emulsion for keratin-containing fibers containing at least one anionic thickening polymer, at least one nonionic hair-setting polymer, at least one ester oil, at least one wax and water
DE102009055354A1 (en) 2009-12-29 2011-06-30 Henkel AG & Co. KGaA, 40589 Keratin-containing fiber compositions comprising at least one specific cationic polymer having vinyl imidazole structural units and at least one specific alkoxylated cationic surfactant
DE102009055357A1 (en) 2009-12-29 2011-06-30 Henkel AG & Co. KGaA, 40589 Keratin-containing fibers containing at least one specific amphiphilic cationic polymer and at least one specific cationic polymer having vinylimidazole structural units
DE102010001375A1 (en) 2010-01-29 2011-08-04 Henkel AG & Co. KGaA, 40589 Foamy colorants II
DE102010003395A1 (en) 2010-03-29 2011-09-29 Henkel Ag & Co. Kgaa Colorant with lipophilic acylpyridinium complex
DE102010027824A1 (en) 2010-04-15 2011-10-20 Henkel Ag & Co. Kgaa Process for the preparation of a colorant
DE102010027949A1 (en) 2010-04-20 2011-10-20 Henkel Ag & Co. Kgaa Hair and scalp-friendly hair dye and perming agent
DE102010030434A1 (en) 2010-06-23 2011-04-07 Henkel Ag & Co. Kgaa Composition, useful for coloring and optionally simultaneous lightening of keratin fibers, preferably human hair, comprises a cationic compound containing a substituted dimethyl-(2-oxo-(1,3)dioxolan-4-yl-methyl)-ammonium compounds
DE102010030439A1 (en) 2010-06-23 2011-12-29 Henkel Ag & Co. Kgaa Cationic azo dyes with a special grouping of 4-aza-1-azoniabicyclo [2.2.2] octane and means for dyeing keratin-containing fibers
DE102010030589A1 (en) 2010-06-28 2011-03-31 Henkel Ag & Co. Kgaa Agent, useful e.g. for dyeing and optionally simultaneous brightening of keratin fibers, preferably human hair, and increasing skin compatibility of dyes or brightening agent, comprises a cationic compound having a quinolinium salt
DE102010030726A1 (en) 2010-06-30 2011-05-19 Henkel Ag & Co. Kgaa Composition, useful for dyeing and optionally simultaneous lightening of keratin fibers, preferably human hair, comprises a cationic compound comprising phenyl-piperazinium compound
DE102010031243A1 (en) 2010-07-12 2011-06-01 Henkel Ag & Co. Kgaa Composition, useful for dyeing and optionally simultaneous lightening of keratin fibers, preferably human hair, comprises a cationic derivative of a polycyclic coumarin compound
DE102010031472A1 (en) 2010-07-16 2011-10-06 Henkel Ag & Co. Kgaa Composition, useful for dyeing and optionally simultaneous lightening of keratin fibers, preferably human hair, comprises triazacyanine compounds
DE102010038404A1 (en) 2010-07-26 2011-06-01 Henkel Ag & Co. Kgaa Composition, useful for dyeing and optionally simultaneous lightening of keratin fibers, preferably human hair, comprises an anthraquinone dye
DE102010038714A1 (en) 2010-07-30 2011-06-01 Henkel Ag & Co. Kgaa Composition, useful for coloring keratin fibers, preferably human hair, comprises a cationic 1-(3-amino-benzyl)-4-aza-1-azonia-bicyclo(2.2.2)octane phenylamine compound as developer component, in a carrier
DE102010040567A1 (en) 2010-09-10 2012-03-15 Henkel Ag & Co. Kgaa Cosmetic agent with microcapsules
DE102010040925A1 (en) 2010-09-16 2011-07-28 Henkel AG & Co. KGaA, 40589 Composition, useful for coloring and optionally simultaneous brightening of keratin fibers, preferably human hair, comprises manganese salt complex
DE102010041267A1 (en) 2010-09-23 2012-03-29 Henkel Ag & Co. Kgaa Means for temporary deformation of keratinous fibers
DE102010042696A1 (en) 2010-10-20 2012-04-26 Henkel Ag & Co. Kgaa Dicationic 4-aza-1-azoniabicyclo [2.2.2] octanes and agents for coloring keratinous fibers
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DE102010051725A1 (en) 2010-11-19 2012-05-24 Merck Patent Gmbh Use of ascorbic acid derivatives for coloring keratin-containing fibers
DE102010063247A1 (en) 2010-12-16 2012-06-21 Henkel Ag & Co. Kgaa Temporary transformation of keratin-containing fibers by using at least one specific cycloalkane derivative
DE102010063371A1 (en) 2010-12-17 2012-06-21 Henkel Ag & Co. Kgaa Lightening agent of moldings containing acylpyridinium compounds
DE102010064054A1 (en) 2010-12-23 2012-06-28 Henkel Ag & Co. Kgaa Process for reshaping keratin-containing fibers
DE102010064052A1 (en) 2010-12-23 2012-06-28 Henkel Ag & Co. Kgaa Process for reshaping keratin-containing fibers
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DE102011010841A1 (en) 2011-02-10 2012-08-16 Merck Patent Gmbh (1,3) -dioxane-5-one compounds
KR102052423B1 (en) 2011-05-03 2019-12-05 바스프 에스이 Disulfide dyes
DE102011077420A1 (en) 2011-06-10 2012-02-16 Henkel Ag & Co. Kgaa Use of dialkylsulfone for improving the condition e.g. hardening, strengthening and restructuring of hairs, preventing and reducing hair splittings and increasing the glossiness, volume, combability, firmness and elasticity of the hair
DE102011077418A1 (en) 2011-06-10 2012-12-13 Henkel Ag & Co. Kgaa Process for reshaping keratin-containing fibers
DE102011079664A1 (en) 2011-07-22 2012-04-26 Henkel Kgaa Composition useful e.g. for treating skin and keratin fibers, caring and conditioning of skin and/or keratin fibers and restructuring keratin fibers, comprises oil obtained from seeds of cape chestnut, surfactants and aqueous carrier
DE102011081108A1 (en) 2011-08-17 2013-02-21 Henkel Ag & Co. Kgaa Use of an agent for keratin-containing fibers, comprising at least one nonionic, propylene oxide-modified starch and at least one additional film-forming and / or setting agent for improving the color content of oxidative hair colorations
DE102011116165A1 (en) 2011-10-14 2013-04-18 Merck Patent Gmbh Benzodioxepin-3-one compounds
ES2581505T3 (en) 2011-12-08 2016-09-06 Merck Patent Gmbh Glucuronolactone derivatives as self-tanning substances
DE102011088397A1 (en) 2011-12-13 2013-06-13 Henkel Ag & Co. Kgaa Compositions for coloring keratinic fibers
DE102011089063A1 (en) 2011-12-19 2013-06-20 Henkel Ag & Co. Kgaa Compositions for coloring keratin-containing fibers
DE102011088398A1 (en) 2011-12-13 2013-06-13 Henkel Ag & Co. Kgaa Gentle oxidative hair treatment with oxidizing agent and special starch derivative
DE102011089060A1 (en) 2011-12-19 2013-06-20 Henkel Ag & Co. Kgaa Use of an active ingredient combination comprising a water-soluble polymer including a group, and a polar alkoxysilane compound for improving artificial colors of coloring compounds on keratin fibers, preferably human hair
WO2013087319A2 (en) 2011-12-13 2013-06-20 Henkel Ag & Co. Kgaa Compositions for colouring keratinous fibres
DE102011089040A1 (en) 2011-12-19 2013-06-20 Henkel Ag & Co. Kgaa Cosmetic with alkoxysilyl-functionalized, water-soluble polymers and special polar alkoxysilanes
DE102011089627A1 (en) 2011-12-22 2013-06-27 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one cationic structural unit cellulose and at least one specific copolymer
DE102011089564A1 (en) 2011-12-22 2013-06-27 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one specific amphiphilic cationic polymer and at least one polymer having structural units derived from the maleic acid ester
DE102011089628A1 (en) 2011-12-22 2013-06-27 Henkel Ag & Co. Kgaa Agent for keratin-containing fibers containing at least one specific copolymer of N-vinylpyrrolidone and at least one polymer having structural units derived from the maleic acid ester
DE102011089562A1 (en) 2011-12-22 2013-06-27 Henkel Ag & Co. Kgaa Keratin-containing fiber containing at least one specific amphiphilic cationic polymer and at least one specific copolymer
DE102012223838A1 (en) 2012-12-19 2014-06-26 Henkel Ag & Co. Kgaa Process for the gentle heat-assisted transformation of keratin-containing fibers
DE102012224051A1 (en) 2012-12-20 2014-06-26 Henkel Ag & Co. Kgaa Use of an agent for keratin-containing fibers, containing at least one special polymer combination for improving the color content of oxidative hair colorations
DE102012224143A1 (en) 2012-12-21 2014-06-26 Henkel Ag & Co. Kgaa Process for the gentle heat-assisted transformation of keratin-containing fibers
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WO2015059368A1 (en) 2013-09-02 2015-04-30 L'oreal Method for dyeing keratin fibres using cationic styryl disulphide dyes, and composition including said dyes
DE102013225585A1 (en) 2013-12-11 2015-06-11 Henkel Ag & Co. Kgaa Foam-based colorants with improved application properties
DE102013225924A1 (en) 2013-12-13 2015-06-18 Henkel Ag & Co. Kgaa Oxidative hair dyeing process using conditioners and minimal color shift
DE102013226284A1 (en) 2013-12-17 2015-06-18 Henkel Ag & Co. Kgaa Foam stabilized colorants I
DE102013226283A1 (en) 2013-12-17 2015-06-18 Henkel Ag & Co. Kgaa Foam-stabilized colorants II
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DE102013226587A1 (en) 2013-12-19 2015-06-25 Henkel Ag & Co. Kgaa Oxidation dye with reduced hair damage
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FR2750048B1 (en) * 1996-06-21 1998-08-14 Oreal KERATIN FIBER DYEING COMPOSITIONS CONTAINING PYRAZOLO- (1, 5-A) -PYRIMIDINE DERIVATIVES, DYEING PROCESS, NOVEL PYRAZOLO- (1, 5-A) -PYRIMIDINE DERIVATIVES AND THEIR PREPARATION METHOD
FR2767685B1 (en) * 1997-09-01 2004-12-17 Oreal COMPOSITION FOR OXIDATION DYEING OF KERATINIC FIBERS COMPRISING 2-CHLORO 6-METHYL 3-AMINOPHENOL AND AN OXIDATION BASE, AND DYEING METHOD

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