RU2615153C2 - Катализатор для полимеризации олефинов и способ его получения - Google Patents

Катализатор для полимеризации олефинов и способ его получения Download PDF

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RU2615153C2
RU2615153C2 RU2015105287A RU2015105287A RU2615153C2 RU 2615153 C2 RU2615153 C2 RU 2615153C2 RU 2015105287 A RU2015105287 A RU 2015105287A RU 2015105287 A RU2015105287 A RU 2015105287A RU 2615153 C2 RU2615153 C2 RU 2615153C2
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titanium
magnesium
group
compound
reaction mixture
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RU2015105287A
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Russian (ru)
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RU2015105287A (ru
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Гурмеет Сингх
Нареш Кумар
Сукхдееп КАУР
Гурпреет Сингх КАПУР
Шаши КАНТ
Бисваджит БАСУ
Равиндер Кумар МАЛХОТРА
Свейн НЕНСЕТХ
Ярмо Линдроос
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Индийская Нефтяная Корпорация Лимитэд
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6541—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof and metals of C08F4/64 or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6546—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof organo-magnesium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/02—Low molecular weight, e.g. <100,000 Da.
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
RU2015105287A 2012-09-24 2013-09-24 Катализатор для полимеризации олефинов и способ его получения RU2615153C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IN2244/MUM/2012 2012-09-24
IN2244MU2012 2012-09-24
PCT/IB2013/058791 WO2014045258A2 (en) 2012-09-24 2013-09-24 Catalyst for polymerization of olefins and process thereof

Publications (2)

Publication Number Publication Date
RU2015105287A RU2015105287A (ru) 2016-09-10
RU2615153C2 true RU2615153C2 (ru) 2017-04-04

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US (1) US9676876B2 (ko)
EP (1) EP2897985B1 (ko)
JP (1) JP5984173B2 (ko)
KR (1) KR101677694B1 (ko)
CN (1) CN104583244B (ko)
RU (1) RU2615153C2 (ko)
SA (1) SA515360121B1 (ko)
WO (1) WO2014045258A2 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6026661B2 (ja) * 2012-09-24 2016-11-16 インディアン オイル コーポレーション リミテッド 触媒用前駆体を調製するプロセス、触媒組成物を調製するプロセス、触媒系を調製するプロセス、及び、オレフィンを重合するおよび共重合するうちの少なくとも一方である方法
EP2966099B1 (en) * 2014-07-08 2020-03-11 Indian Oil Corporation Limited Particle size distribution control through internal donor in ziegler-natta catalyst
EP3018150B1 (en) * 2014-11-07 2020-03-11 Indian Oil Corporation Limited Process for the preparation of spherical catalyst particles
CN105111336B (zh) * 2015-09-29 2018-09-21 四川锦成化学催化剂有限公司 一种乙烯聚合催化剂的给电子体、类球形催化剂、制备方法
CN107936151B (zh) * 2016-10-13 2020-06-09 中国石油化工股份有限公司 烯烃聚合催化剂球形组分及其制备方法和应用和烯烃聚合催化剂及其应用及烯烃的聚合方法
CN109206545B (zh) * 2017-07-01 2021-07-02 中国石油化工股份有限公司 丙烯类聚合物微粒和用于烯烃聚合的固体催化剂组分及烯烃聚合催化剂
CN110144022B (zh) * 2019-05-28 2020-02-21 国家能源集团宁夏煤业有限责任公司 Ziegler-Natta催化剂的工业制备方法
IN201921051272A (ko) * 2019-12-11 2022-01-06

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4564606A (en) * 1984-08-06 1986-01-14 Exxon Research & Engineering Co. Polymerization catalyst, production and use
US4724255A (en) * 1985-01-22 1988-02-09 Neste Oy Catalyst components, a catalyst and a process for the polymerization olefins
EP0926165A1 (en) * 1997-12-23 1999-06-30 Borealis A/S Catalyst component comprising magnesium, titanium, a halogen and a electron donor, its preparation and use
EP1336625A1 (en) * 2002-02-14 2003-08-20 Novolen Technology Holdings C.V. Solid catalytic component and catalytic system of the Ziegler-Natta type, process for their preparation and their use in the polymerisation of alk-1-enes
EP1598379A1 (en) * 2004-05-18 2005-11-23 Borealis Technology OY Process for producing polypropylene film
EA011828B1 (ru) * 2004-11-26 2009-06-30 Сауди Бейсик Индастриз Корпорейшн Способ получения катализаторного компонента для полимеризации олефинов
EA012159B1 (ru) * 2005-12-30 2009-08-28 Бореалис Текнолоджи Ой Частицы катализатора
US7659223B2 (en) * 2002-09-30 2010-02-09 Borealis Technology Oy Process for preparing an olefin polymerization catalyst component with improved high temperature activity

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4156063A (en) 1971-06-25 1979-05-22 Montecanti Edison, S.p.A. Process for the stereoregular polymerization of alpha olefins
US4174299A (en) 1975-07-21 1979-11-13 Montedison S.P.A. Catalysts for the polymerization of olefins
IT1054410B (it) 1975-11-21 1981-11-10 Mitsui Petrochemical Ind Catalizzatori per la polimerizzazione delle alfa olefine
IT1068112B (it) 1976-08-09 1985-03-21 Montedison Spa Componenti di catalizzatori per la polimerizzazione delle alfa olefine e catalizzatori da essi ottenuti
IT1092448B (it) 1978-02-09 1985-07-12 Montedison Spa Catalizzatori per la polimerizzazione delle alfa-olefine
IT1190682B (it) 1982-02-12 1988-02-24 Montedison Spa Catalizzatori per la polimerizzazione di olefine
JPS59207904A (ja) 1983-05-11 1984-11-26 Mitsui Petrochem Ind Ltd オレフイン重合体の製造方法
US4866022A (en) 1984-03-23 1989-09-12 Amoco Corporation Olefin polymerization catalyst
US4988656A (en) 1984-03-23 1991-01-29 Amoco Corporation Olefin polymerization catalyst
US5013702A (en) 1984-03-23 1991-05-07 Amoco Corporation Olefin polymerization catalyst
US5567665A (en) * 1994-03-31 1996-10-22 Union Carbide Chemicals & Plastics Technology Corporation Shape-shifted magnesium alkoxide component for polymerizing olefins
AR243554A1 (es) * 1987-11-24 1993-08-31 Shell Oil Co Un proceso para la preparacion de un componente catalizador apropiado para ser usado en la polimerizacion de alfa olefinas.
JPH01247441A (ja) * 1988-03-30 1989-10-03 Mitsui Petrochem Ind Ltd 熱可塑性エラストマー組成物
EP0350170B2 (en) 1988-06-17 2001-09-12 Mitsui Chemicals, Inc. Process for polymerising olefins and polymerisation catalyst therefor
US4946816A (en) 1989-08-21 1990-08-07 Amoco Corporation Morphology-controlled olefin polymerization catalyst
DE4024421A1 (de) 1990-08-01 1992-02-06 Basf Ag Ziegler-natta-katalysatorsysteme mit metallorganischen verbindungen
US5124297A (en) 1990-12-07 1992-06-23 Amoco Corporation Olefin polymerization and copolymerization catalyst
DE4130353A1 (de) 1991-09-12 1993-03-18 Basf Ag Verfahren zur herstellung von ziegler-natta-katalysatorsystemen
TW300235B (ko) 1992-12-04 1997-03-11 Mitsui Petroleum Chemicals Ind
US5459116A (en) 1993-05-07 1995-10-17 Samsung General Chemicals Co., Ltd. Highly active catalyst for the polymerization of olefins and method for the preparation of the same
FI96615C (fi) * 1993-06-04 1996-07-25 Neste Oy Menetelmä C4-C40- -olefiinien polymeroimiseksi tai kopolymeroimiseksi muiden -olefiinien kanssa
DE4419845A1 (de) 1994-06-07 1995-12-14 Basf Ag Verfahren zur Aufbereitung von Katalysatorsystemen vom Typ der Ziegler-Natta-Katalysatoren
DE19637367A1 (de) 1996-09-13 1998-03-19 Basf Ag Bei ihrer Herstellung modifizierte Ziegler-Natta-Katalysatorsysteme
GB2325004B (en) 1997-05-09 1999-09-01 Samsung General Chemicals Co A catalyst for polymerization and copolymerization of olefins
FI981717A (fi) 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
FI991069A0 (fi) 1999-05-10 1999-05-10 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
JP2001302718A (ja) * 2000-04-24 2001-10-31 Idemitsu Petrochem Co Ltd 気相重合用触媒、それを用いた気相重合方法およびオレフィン重合体
EP1205496A1 (en) 2000-11-10 2002-05-15 Borealis Technology Oy Catalyst component comprising magnesium, titanium, a halogen and an electron donor, its preparation and use
WO2003085006A1 (en) 2002-04-04 2003-10-16 Mitsui Chemicals, Inc Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization
EP1375528A1 (en) 2002-06-18 2004-01-02 Borealis Polymers Oy Method for the preparation of olefin polymerisation catalysts
US8288606B2 (en) * 2005-03-08 2012-10-16 Ineos Usa Llc Propylene polymer catalyst donor component
WO2010118641A1 (zh) * 2009-04-17 2010-10-21 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分、其制备方法及包含该催化剂组分的催化剂
KR20110078924A (ko) * 2009-12-31 2011-07-07 주식회사 효성 폴리프로필렌 중합용 지글러-나타 촉매의 제조방법
BR112013010748B1 (pt) * 2010-11-04 2020-11-03 Toho Titanium Co., Ltd catalisador para polimerização de olefina, e, método para produzir um polímero de olefina

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4564606A (en) * 1984-08-06 1986-01-14 Exxon Research & Engineering Co. Polymerization catalyst, production and use
US4724255A (en) * 1985-01-22 1988-02-09 Neste Oy Catalyst components, a catalyst and a process for the polymerization olefins
EP0926165A1 (en) * 1997-12-23 1999-06-30 Borealis A/S Catalyst component comprising magnesium, titanium, a halogen and a electron donor, its preparation and use
EP1336625A1 (en) * 2002-02-14 2003-08-20 Novolen Technology Holdings C.V. Solid catalytic component and catalytic system of the Ziegler-Natta type, process for their preparation and their use in the polymerisation of alk-1-enes
US7659223B2 (en) * 2002-09-30 2010-02-09 Borealis Technology Oy Process for preparing an olefin polymerization catalyst component with improved high temperature activity
EP1598379A1 (en) * 2004-05-18 2005-11-23 Borealis Technology OY Process for producing polypropylene film
EA011828B1 (ru) * 2004-11-26 2009-06-30 Сауди Бейсик Индастриз Корпорейшн Способ получения катализаторного компонента для полимеризации олефинов
EA012159B1 (ru) * 2005-12-30 2009-08-28 Бореалис Текнолоджи Ой Частицы катализатора

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CN104583244B (zh) 2017-10-24
SA515360121B1 (ar) 2016-06-23
US9676876B2 (en) 2017-06-13
US20150203604A1 (en) 2015-07-23
KR101677694B1 (ko) 2016-11-18
KR20150036735A (ko) 2015-04-07
WO2014045258A3 (en) 2014-10-30
CN104583244A (zh) 2015-04-29
JP2015526563A (ja) 2015-09-10
WO2014045258A2 (en) 2014-03-27
EP2897985B1 (en) 2017-03-08
RU2015105287A (ru) 2016-09-10
JP5984173B2 (ja) 2016-09-06
EP2897985A2 (en) 2015-07-29

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