RU2471811C2 - Способ получения полимеров пропилена с высокой текучестью - Google Patents

Способ получения полимеров пропилена с высокой текучестью Download PDF

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Publication number
RU2471811C2
RU2471811C2 RU2010119499/04A RU2010119499A RU2471811C2 RU 2471811 C2 RU2471811 C2 RU 2471811C2 RU 2010119499/04 A RU2010119499/04 A RU 2010119499/04A RU 2010119499 A RU2010119499 A RU 2010119499A RU 2471811 C2 RU2471811 C2 RU 2471811C2
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Russia
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succinate
propylene
diethyl
branched alkyl
alkyl
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RU2010119499/04A
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English (en)
Russian (ru)
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RU2010119499A (ru
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Паола МАССАРИ
Марко ЧЬЯРАФОНИ
Офелия ФУСКО
Хирофуми МУРАКАМИ
Такеси НАКАДЗИМА
Синтаро ТАКЕМИЯ
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Базелль Полиолефин Италия С.Р.Л.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
RU2010119499/04A 2007-10-15 2008-10-02 Способ получения полимеров пропилена с высокой текучестью RU2471811C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP07118446 2007-10-15
EP07118446.9 2007-10-15
US99943607P 2007-10-18 2007-10-18
US60/999,436 2007-10-18
PCT/EP2008/063243 WO2009050045A2 (en) 2007-10-15 2008-10-02 Process for the preparation of high fluidity propylene polymers

Publications (2)

Publication Number Publication Date
RU2010119499A RU2010119499A (ru) 2011-11-27
RU2471811C2 true RU2471811C2 (ru) 2013-01-10

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Country Status (8)

Country Link
US (1) US20100249330A1 (https=)
EP (1) EP2201049B1 (https=)
JP (1) JP5524068B2 (https=)
CN (1) CN101821303B (https=)
BR (1) BRPI0818758B1 (https=)
RU (1) RU2471811C2 (https=)
TW (1) TW200930731A (https=)
WO (1) WO2009050045A2 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2802810C2 (ru) * 2018-06-11 2023-09-04 В.Р. Грейс Энд Ко.-Конн. Статистические сополимеры пропилена и этилена с низким соотношением xs/et и высоким mfr
US11905347B2 (en) 2018-06-11 2024-02-20 W.R. Grace & Co .- Conn. Propylene-ethylene random copolymers with low XS/ET ratio and high MFR

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CN102803310A (zh) 2009-06-19 2012-11-28 巴塞尔聚烯烃意大利有限责任公司 制备抗冲击性丙烯聚合物组合物的方法
EP2452956A1 (en) * 2010-11-12 2012-05-16 Borealis AG Improved process for polymerising propylene
EP2452957A1 (en) * 2010-11-12 2012-05-16 Borealis AG Improved process for producing heterophasic propylene copolymers
WO2013050384A2 (en) * 2011-10-07 2013-04-11 Total Research & Technology Feluy High-fluidity heterophasic propylene copolymer with improved rigidity
JP6144044B2 (ja) * 2011-12-28 2017-06-07 サンアロマー株式会社 バッテリーケース用ポリマー組成物
CN104736627B (zh) 2012-10-03 2018-04-17 胜亚诺盟股份有限公司 蒸煮膜用丙烯树脂组合物
JP6235805B2 (ja) * 2013-06-17 2017-11-22 サンアロマー株式会社 二軸延伸フィルム用ポリプロピレン樹脂組成物
JP6235804B2 (ja) * 2013-06-17 2017-11-22 サンアロマー株式会社 シート成形用ポリプロピレン樹脂組成物
CN105283503A (zh) * 2013-06-19 2016-01-27 博里利斯股份公司 具有宽分子量分布的聚丙烯
EP2829397A1 (en) 2013-07-22 2015-01-28 Basell Poliolefine Italia S.r.l. Heat sealable polyolefin films and sheets
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US9428598B2 (en) 2014-02-07 2016-08-30 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
JP6598284B2 (ja) * 2014-03-26 2019-10-30 サンアロマー株式会社 α−オレフィン類の重合方法
JP6384019B2 (ja) * 2014-07-22 2018-09-05 サンアロマー株式会社 ポリプロピレン系樹脂組成物及びその製造方法
JP6831218B2 (ja) * 2016-11-15 2021-02-17 サンアロマー株式会社 マスターバッチ組成物およびこれを含むポリプロピレン樹脂組成物
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
JP7096682B2 (ja) 2018-03-16 2022-07-06 サンアロマー株式会社 ポリプロピレン組成物および成形品
JP7096681B2 (ja) 2018-03-16 2022-07-06 サンアロマー株式会社 ポリプロピレン組成物および成形品
JP7114361B2 (ja) 2018-06-19 2022-08-08 サンアロマー株式会社 ポリプロピレン組成物および成形品
US12172359B2 (en) 2018-10-09 2024-12-24 Sunallomer Ltd. Production method of polypropylene sheet
JP7249126B2 (ja) 2018-10-18 2023-03-30 サンアロマー株式会社 ポリプロピレン組成物および成形品
JP7580375B2 (ja) 2019-06-17 2024-11-11 サンアロマー株式会社 超高分子量プロピレン（共）重合体
EP3985035A4 (en) 2019-06-17 2023-06-14 Sunallomer Ltd Polypropylene resin composition containing ultra-high-molecular-weight propylene (co)polymer
WO2022102705A1 (ja) 2020-11-13 2022-05-19 株式会社エフピコ ポリプロピレン多層シート
TWI762127B (zh) 2020-12-29 2022-04-21 臺灣塑膠工業股份有限公司 聚丙烯與其製作方法及熔噴纖維布
EP4361211A4 (en) 2021-06-25 2025-04-30 Basell Poliolefine Italia S.r.l. Polypropylene-based resin composition and method for producing same, film molded article, package to be brought into contact with food, container to be brought into contact with food, and retort pouch
CN117693555A (zh) 2021-06-25 2024-03-12 巴塞尔聚烯烃意大利有限公司 聚丙烯基树脂组合物及其生产方法、片材模塑品和容器
US20250154348A1 (en) 2021-06-25 2025-05-15 Basell Poliolefine Italia S.R.L. Polypropylene resin composition, sheet molded body, and container
JPWO2023171433A1 (https=) * 2022-03-11 2023-09-14

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JPH06145269A (ja) * 1992-11-04 1994-05-24 Tosoh Corp プロピレンブロック共重合体の製造方法
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EP0086473A2 (en) * 1982-02-12 1983-08-24 Montedison S.p.A. Components and catalysts for the polymerization of olefins
EP0640624A1 (en) * 1992-04-14 1995-03-01 Showa Denko Kabushiki Kaisha Catalyst for polymerization of olefin and process for the preparation of olefin polymer
JPH06145269A (ja) * 1992-11-04 1994-05-24 Tosoh Corp プロピレンブロック共重合体の製造方法
RU2138514C1 (ru) * 1993-12-16 1999-09-27 Монтелл Норт Америка, Инк. Гомополимер пропилена, волокно, холст, тканевый материал, пленка
WO2003054035A1 (en) * 2001-12-12 2003-07-03 Basell Poliolefine Italia S.P.A. Process for the polymerization of olefins
WO2005113672A1 (en) * 2004-05-21 2005-12-01 Basell Poliolefine Italia S.R.L. Impact resistant polyolefin compositions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2802810C2 (ru) * 2018-06-11 2023-09-04 В.Р. Грейс Энд Ко.-Конн. Статистические сополимеры пропилена и этилена с низким соотношением xs/et и высоким mfr
US11905347B2 (en) 2018-06-11 2024-02-20 W.R. Grace & Co .- Conn. Propylene-ethylene random copolymers with low XS/ET ratio and high MFR

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JP5524068B2 (ja) 2014-06-18
RU2010119499A (ru) 2011-11-27
JP2011500907A (ja) 2011-01-06
US20100249330A1 (en) 2010-09-30
BRPI0818758B1 (pt) 2018-11-21
CN101821303A (zh) 2010-09-01
WO2009050045A3 (en) 2009-07-02
EP2201049A2 (en) 2010-06-30
TW200930731A (en) 2009-07-16
WO2009050045A2 (en) 2009-04-23
EP2201049B1 (en) 2017-05-31
BRPI0818758A2 (pt) 2015-04-07
CN101821303B (zh) 2013-10-30

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