RU2456232C2 - Способ и устройство для каталитического окисления кислородом газов, содержащих so2 - Google Patents
Способ и устройство для каталитического окисления кислородом газов, содержащих so2 Download PDFInfo
- Publication number
- RU2456232C2 RU2456232C2 RU2009120402/05A RU2009120402A RU2456232C2 RU 2456232 C2 RU2456232 C2 RU 2456232C2 RU 2009120402/05 A RU2009120402/05 A RU 2009120402/05A RU 2009120402 A RU2009120402 A RU 2009120402A RU 2456232 C2 RU2456232 C2 RU 2456232C2
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- Prior art keywords
- catalyst
- gas
- tubes
- temperature
- volume percent
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- 239000007789 gas Substances 0.000 title claims abstract description 160
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 21
- 239000001301 oxygen Substances 0.000 title claims abstract description 21
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 15
- 230000003647 oxidation Effects 0.000 title claims abstract description 12
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 title description 62
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 112
- 239000003054 catalyst Substances 0.000 claims abstract description 99
- 239000006096 absorbing agent Substances 0.000 claims abstract description 38
- 238000012546 transfer Methods 0.000 claims abstract description 6
- 238000009434 installation Methods 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 16
- 238000013461 design Methods 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 2
- 239000004291 sulphur dioxide Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 40
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 34
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 32
- 238000001816 cooling Methods 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 19
- 230000008901 benefit Effects 0.000 description 16
- 230000008569 process Effects 0.000 description 16
- 239000000203 mixture Substances 0.000 description 14
- 238000004088 simulation Methods 0.000 description 14
- 229910052792 caesium Inorganic materials 0.000 description 11
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000010586 diagram Methods 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 239000012895 dilution Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000002826 coolant Substances 0.000 description 7
- 229910052720 vanadium Inorganic materials 0.000 description 7
- 238000004364 calculation method Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- -1 for example Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000009420 retrofitting Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012223 aqueous fraction Substances 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
- C01B17/7655—Multi-stage SO3-conversion with intermediate absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8609—Sulfur oxides
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- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0476—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
- B01J8/048—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being superimposed one above the other
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0476—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
- B01J8/0488—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being placed in separate reactors
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
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- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/78—Preparation by contact processes characterised by the catalyst used
- C01B17/79—Preparation by contact processes characterised by the catalyst used containing vanadium
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
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- C01B17/803—Converters
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- B01D2255/207—Transition metals
- B01D2255/20723—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00203—Coils
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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- B01J2219/00006—Large-scale industrial plants
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006051899.3 | 2006-10-31 | ||
| DE102006051899A DE102006051899A1 (de) | 2006-10-31 | 2006-10-31 | Verfahren und Vorrichtung zur katalytischen Oxidation von SO2-haltigen Gasen mit Sauerstoff |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012109567/04A Division RU2012109567A (ru) | 2006-10-31 | 2012-03-14 | Способ и устройство для непрерывного каталитического полного или частичного окисления исходного газа, содержащего диоксид серы и кислород |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2009120402A RU2009120402A (ru) | 2010-12-10 |
| RU2456232C2 true RU2456232C2 (ru) | 2012-07-20 |
Family
ID=38984433
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2009120402/05A RU2456232C2 (ru) | 2006-10-31 | 2007-10-13 | Способ и устройство для каталитического окисления кислородом газов, содержащих so2 |
| RU2012109567/04A RU2012109567A (ru) | 2006-10-31 | 2012-03-14 | Способ и устройство для непрерывного каталитического полного или частичного окисления исходного газа, содержащего диоксид серы и кислород |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012109567/04A RU2012109567A (ru) | 2006-10-31 | 2012-03-14 | Способ и устройство для непрерывного каталитического полного или частичного окисления исходного газа, содержащего диоксид серы и кислород |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US7871593B2 (enExample) |
| EP (2) | EP1979270B1 (enExample) |
| JP (2) | JP5570216B2 (enExample) |
| KR (1) | KR101420127B1 (enExample) |
| CN (1) | CN101573291B (enExample) |
| AT (1) | ATE503721T1 (enExample) |
| AU (1) | AU2007315318B2 (enExample) |
| BR (1) | BRPI0718270B1 (enExample) |
| CA (1) | CA2668059C (enExample) |
| CL (1) | CL2007003153A1 (enExample) |
| CY (2) | CY1112064T1 (enExample) |
| DE (2) | DE102006051899A1 (enExample) |
| DK (2) | DK2256085T3 (enExample) |
| ES (2) | ES2394635T3 (enExample) |
| MA (1) | MA30915B1 (enExample) |
| MX (1) | MX2009004483A (enExample) |
| NO (1) | NO342026B1 (enExample) |
| PL (2) | PL1979270T3 (enExample) |
| PT (2) | PT1979270E (enExample) |
| RU (2) | RU2456232C2 (enExample) |
| SI (2) | SI2256085T1 (enExample) |
| TN (1) | TN2009000150A1 (enExample) |
| UA (2) | UA97381C2 (enExample) |
| WO (1) | WO2008052649A1 (enExample) |
| ZA (1) | ZA200902892B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2688858C2 (ru) * | 2014-06-12 | 2019-05-22 | Басф Се | Установка и способ для проведения гетерогенных каталитических газофазных реакций |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009025510A1 (de) | 2008-12-20 | 2010-06-24 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Schwefeltrioxid |
| DE102010018172A1 (de) | 2010-04-22 | 2011-10-27 | Bayer Technology Services Gmbh | Verfahren zur Aufarbeitung schwefelwasserstoffhaltiger Abgase |
| ES2621501T3 (es) | 2009-12-01 | 2017-07-04 | Chemetics, Inc. | Dispositivo y procedimiento para la combustión de azufre y compuestos que contienen azufre |
| PL2507164T3 (pl) | 2009-12-01 | 2018-03-30 | Chemetics, Inc. | Sposób wytwarzania kwasu siarkowego |
| ES2554179T3 (es) * | 2009-12-01 | 2015-12-16 | Bayer Intellectual Property Gmbh | Procedimiento para la preparación de ácido sulfúrico |
| PE20140486A1 (es) * | 2011-04-06 | 2014-05-15 | Haldor Topsoe As | Proceso para la produccion de acido sulfurico |
| US8790611B2 (en) * | 2012-07-05 | 2014-07-29 | Basf Se | Reactor for carrying out an exothermic reaction in the gas phase |
| RU2502546C1 (ru) * | 2012-07-20 | 2013-12-27 | Андрей Владиславович Курочкин | Способ очистки углеводородных газов |
| AT513414B1 (de) * | 2012-10-08 | 2014-06-15 | Kanzler Walter | Verfahren zur zweistufigen katalytischen Oxidation von Schwefel-Verbindungen in Abgasen |
| WO2014094146A1 (en) * | 2012-12-17 | 2014-06-26 | Chemetics Inc. | Contact apparatus for oxidizing sulfur dioxide and systems for producing sulfuric acid |
| WO2015191212A1 (en) | 2014-06-09 | 2015-12-17 | Chemetics Inc. | Single contact, single absorption system for producing sulfuric acid with high conversion efficiency |
| CN104084094A (zh) * | 2014-07-17 | 2014-10-08 | 科洋环境工程（上海）有限公司 | 一种转化so2浓度的装置及so2转化系统及转化方法 |
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