RU2323874C2 - Способ превращения полисульфанов - Google Patents
Способ превращения полисульфанов Download PDFInfo
- Publication number
- RU2323874C2 RU2323874C2 RU2005112707/15A RU2005112707A RU2323874C2 RU 2323874 C2 RU2323874 C2 RU 2323874C2 RU 2005112707/15 A RU2005112707/15 A RU 2005112707/15A RU 2005112707 A RU2005112707 A RU 2005112707A RU 2323874 C2 RU2323874 C2 RU 2323874C2
- Authority
- RU
- Russia
- Prior art keywords
- gas
- polysulfanes
- vol
- methanol
- washing
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 18
- 238000006243 chemical reaction Methods 0.000 title description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 36
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 43
- 229910000057 polysulfane Inorganic materials 0.000 claims description 41
- 238000005406 washing Methods 0.000 claims description 14
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 8
- 238000001179 sorption measurement Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000001414 amino alcohols Chemical class 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 238000010926 purge Methods 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 17
- 229910052717 sulfur Inorganic materials 0.000 description 16
- 239000011593 sulfur Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000004679 hydroxides Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001021 polysulfide Polymers 0.000 description 2
- 239000005077 polysulfide Substances 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229940087646 methanolamine Drugs 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/167—Separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/168—Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Gas Separation By Absorption (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10245164.8 | 2002-09-26 | ||
| DE10245164.8A DE10245164B4 (de) | 2002-09-26 | 2002-09-26 | Verfahren zur Umwandlung von Polysulfanen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2005112707A RU2005112707A (ru) | 2006-01-27 |
| RU2323874C2 true RU2323874C2 (ru) | 2008-05-10 |
Family
ID=31984167
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005112707/15A RU2323874C2 (ru) | 2002-09-26 | 2003-08-26 | Способ превращения полисульфанов |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7326393B2 (https=) |
| EP (1) | EP1542925B1 (https=) |
| JP (1) | JP4423199B2 (https=) |
| CN (1) | CN1292980C (https=) |
| AT (1) | ATE425121T1 (https=) |
| AU (1) | AU2003255483A1 (https=) |
| BR (1) | BR0314663A (https=) |
| DE (2) | DE10245164B4 (https=) |
| ES (1) | ES2323060T3 (https=) |
| RU (1) | RU2323874C2 (https=) |
| WO (1) | WO2004028963A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2428374C2 (ru) * | 2009-08-10 | 2011-09-10 | Федеральное образовательное учреждение высшего профессионального образования"Астраханский государственный технический университет"ФГОУ ВПО"АГТУ" | Способ деструкции полисульфанов в товарной сере |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7604788B2 (en) * | 2002-09-26 | 2009-10-20 | Evonik Degussa Gmbh | Process for the conversion of polysulfanes |
| DE102005043151A1 (de) * | 2005-09-10 | 2007-03-22 | Degussa Ag | Verfahren zur Herstellung von Methylmercaptan |
| WO2008087086A1 (de) * | 2007-01-16 | 2008-07-24 | Basf Se | Reaktor und verfahren zur herstellung von schwefelwasserstoff |
| CN101583563B (zh) * | 2007-01-16 | 2013-07-17 | 巴斯夫欧洲公司 | 连续生产硫化氢的方法和装置 |
| ES2578402T3 (es) | 2007-01-16 | 2016-07-26 | Basf Se | Dispositivo para la producción continua de sulfuro de hidrógeno |
| BE1018534A3 (fr) | 2007-07-11 | 2011-03-01 | Basf Se | Procede pour la separation avec purification de cristaux acrylique, d'acide methacrylique, de n-vinulpyrrolidone ou de p-xylene a partir de leur suspension dans une lessive-mere. |
| JP4968207B2 (ja) * | 2008-07-31 | 2012-07-04 | 住友化学株式会社 | 硫化水素ガスの精製方法。 |
| KR101676888B1 (ko) | 2008-12-23 | 2016-11-16 | 바스프 에스이 | 황화수소 함유 기체의 압축 방법 |
| EP2676925A1 (de) * | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676927A1 (de) * | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676928A1 (de) | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676926A1 (de) | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2765127A1 (de) | 2013-02-06 | 2014-08-13 | Evonik Industries AG | Verfahren zur Abtrennung von Acrolein aus dem Prozessgas einer heterogen katalysierten Oxidation von Propen |
| US10773958B2 (en) | 2014-03-21 | 2020-09-15 | Chevron Phillips Chemical Company Lp | Processes for removing polysulfanes and elemental sulfur from hydrogen sulfide |
| JP7121049B2 (ja) * | 2017-12-25 | 2022-08-17 | 住友化学株式会社 | 硫化水素の製造方法及び硫黄の回収方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2474066A (en) * | 1946-01-04 | 1949-06-21 | Barium Reduction Corp | Method of making hydrogen sulfide |
| US2479781A (en) * | 1945-08-31 | 1949-08-23 | Phillips Petroleum Co | Purification of hydrogen sulfide |
| SU618341A1 (ru) * | 1976-06-15 | 1978-08-05 | Институт Газа Ан Украинской Сср | Способ получени восстановительного газа |
| US5866721A (en) * | 1996-12-27 | 1999-02-02 | Degussa Aktiengesellschaft | Process for separating the product gas mixture from the catalytic synthesis of methyl mercaptan |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2784055A (en) * | 1951-05-04 | 1957-03-05 | North Thames Gas Board | Process for the treatment of gases rich in hydrogen sulphide |
| DE1768826B1 (de) | 1968-07-04 | 1971-08-26 | Degussa | Verfahren zur Gewinnung von niederen aliphatischen Mercaptanen |
| CA1088276A (en) * | 1976-08-02 | 1980-10-28 | Paul T. Pendergraft | Process for removal of hydrogen sulfide and hydrogen polysulfide from liquid sulfur |
| US4444259A (en) * | 1982-01-15 | 1984-04-24 | Schwall Joseph A | Apparatus and method for purging hydrogen sulfide gases from well water |
| FR2601350B1 (fr) * | 1986-07-10 | 1988-09-30 | Elf Aquitaine | Procede pour l'elimination rapide de l'hydrogene sulfure contenu dans le soufre liquide et systeme catalytique utilisable pour sa mise en oeuvre |
| DE4014018A1 (de) * | 1990-05-01 | 1991-11-07 | Metallgesellschaft Ag | Verfahren zum reinigen eines h(pfeil abwaerts)2(pfeil abwaerts)s und co(pfeil abwaerts)2(pfeil abwaerts) enthaltenden gases |
| CN1030905C (zh) * | 1992-02-27 | 1996-02-07 | 天津市化工厂 | 硫化氢连续发生和精制工艺 |
| US5622682A (en) * | 1994-04-06 | 1997-04-22 | Atmi Ecosys Corporation | Method for concentration and recovery of halocarbons from effluent gas streams |
| NL1003085C2 (nl) * | 1995-09-15 | 1997-03-20 | Stork Comprimo Bv | Werkwijze en inrichting voor het ontgassen van zwavel. |
| US5686056A (en) * | 1996-02-05 | 1997-11-11 | Bechtel Group, Inc. | Methods and apparatus for purifying hydrogen sulfide |
| FR2844208B1 (fr) * | 2002-09-06 | 2004-10-15 | Atofina | Purification du h2s par supports poreux |
-
2002
- 2002-09-26 DE DE10245164.8A patent/DE10245164B4/de not_active Expired - Fee Related
-
2003
- 2003-08-26 ES ES03798130T patent/ES2323060T3/es not_active Expired - Lifetime
- 2003-08-26 EP EP03798130A patent/EP1542925B1/en not_active Expired - Lifetime
- 2003-08-26 AU AU2003255483A patent/AU2003255483A1/en not_active Abandoned
- 2003-08-26 JP JP2004538838A patent/JP4423199B2/ja not_active Expired - Fee Related
- 2003-08-26 AT AT03798130T patent/ATE425121T1/de not_active IP Right Cessation
- 2003-08-26 BR BR0314663-4A patent/BR0314663A/pt not_active Application Discontinuation
- 2003-08-26 RU RU2005112707/15A patent/RU2323874C2/ru active
- 2003-08-26 US US10/529,148 patent/US7326393B2/en not_active Expired - Lifetime
- 2003-08-26 CN CNB038230240A patent/CN1292980C/zh not_active Expired - Fee Related
- 2003-08-26 WO PCT/EP2003/009432 patent/WO2004028963A1/en not_active Ceased
- 2003-08-26 DE DE60326604T patent/DE60326604D1/de not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2479781A (en) * | 1945-08-31 | 1949-08-23 | Phillips Petroleum Co | Purification of hydrogen sulfide |
| US2474066A (en) * | 1946-01-04 | 1949-06-21 | Barium Reduction Corp | Method of making hydrogen sulfide |
| SU618341A1 (ru) * | 1976-06-15 | 1978-08-05 | Институт Газа Ан Украинской Сср | Способ получени восстановительного газа |
| US5866721A (en) * | 1996-12-27 | 1999-02-02 | Degussa Aktiengesellschaft | Process for separating the product gas mixture from the catalytic synthesis of methyl mercaptan |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2428374C2 (ru) * | 2009-08-10 | 2011-09-10 | Федеральное образовательное учреждение высшего профессионального образования"Астраханский государственный технический университет"ФГОУ ВПО"АГТУ" | Способ деструкции полисульфанов в товарной сере |
Also Published As
| Publication number | Publication date |
|---|---|
| US7326393B2 (en) | 2008-02-05 |
| JP4423199B2 (ja) | 2010-03-03 |
| DE60326604D1 (de) | 2009-04-23 |
| AU2003255483A1 (en) | 2004-04-19 |
| BR0314663A (pt) | 2005-08-02 |
| JP2006500309A (ja) | 2006-01-05 |
| EP1542925A1 (en) | 2005-06-22 |
| ATE425121T1 (de) | 2009-03-15 |
| CN1684905A (zh) | 2005-10-19 |
| DE10245164B4 (de) | 2014-11-13 |
| WO2004028963A1 (en) | 2004-04-08 |
| CN1292980C (zh) | 2007-01-03 |
| EP1542925B1 (en) | 2009-03-11 |
| DE10245164A1 (de) | 2004-04-08 |
| US20050265913A1 (en) | 2005-12-01 |
| RU2005112707A (ru) | 2006-01-27 |
| ES2323060T3 (es) | 2009-07-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PC43 | Official registration of the transfer of the exclusive right without contract for inventions |
Effective date: 20100901 |
|
| PD4A | Correction of name of patent owner |