RU2018109760A - Огнестойкий термопластичный полиуретан - Google Patents
Огнестойкий термопластичный полиуретан Download PDFInfo
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- thermoplastic polyurethane
- flame retardant
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- 239000004433 Thermoplastic polyurethane Substances 0.000 title claims 8
- 229920002803 thermoplastic polyurethane Polymers 0.000 title claims 8
- 230000009970 fire resistant effect Effects 0.000 title 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 13
- 239000003063 flame retardant Substances 0.000 claims 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 4
- 229910052698 phosphorus Inorganic materials 0.000 claims 4
- 239000011574 phosphorus Substances 0.000 claims 4
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims 2
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 claims 1
- PAUHLEIGHAUFAK-UHFFFAOYSA-N 1-isocyanato-1-[(1-isocyanatocyclohexyl)methyl]cyclohexane Chemical compound C1CCCCC1(N=C=O)CC1(N=C=O)CCCCC1 PAUHLEIGHAUFAK-UHFFFAOYSA-N 0.000 claims 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims 1
- BQPNUOYXSVUVMY-UHFFFAOYSA-N [4-[2-(4-diphenoxyphosphoryloxyphenyl)propan-2-yl]phenyl] diphenyl phosphate Chemical compound C=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 BQPNUOYXSVUVMY-UHFFFAOYSA-N 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- ZJKCITHLCNCAHA-UHFFFAOYSA-K aluminum dioxidophosphanium Chemical class [Al+3].[O-][PH2]=O.[O-][PH2]=O.[O-][PH2]=O ZJKCITHLCNCAHA-UHFFFAOYSA-K 0.000 claims 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 claims 1
- 229940042400 direct acting antivirals phosphonic acid derivative Drugs 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims 1
- 150000003007 phosphonic acid derivatives Chemical class 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- AKUSJWHFFBLJLN-UHFFFAOYSA-L zinc dioxidophosphanium Chemical class [Zn+2].[O-][PH2]=O.[O-][PH2]=O AKUSJWHFFBLJLN-UHFFFAOYSA-L 0.000 claims 1
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
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- C08G18/3206—Polyhydroxy compounds aliphatic
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
- C08G18/3851—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring
- C08G18/3853—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring containing cyanurate and/or isocyanurate groups
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
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- C08K5/00—Use of organic ingredients
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- C08K5/0066—Flame-proofing or flame-retarding additives
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- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
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- C08K5/51—Phosphorus bound to oxygen
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- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
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- C08K5/51—Phosphorus bound to oxygen
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Claims (20)
1. Композиция, содержащая по меньшей мере компоненты с (i) по (v):
(i) термопластичный полиуретан ТПУ-1, который имеет в основе алифатический диизоцианат,
(ii) термопластичный полиуретан ТПУ-2, который имеет в основе ароматический диизоцианат,
(iii) меламинцианурат,
(iv) первое фосфорсодержащее огнезащитное средство (F1), выбранное из группы, состоящей из производных фосфорной кислоты и производных фосфоновой кислоты, и
(v) другое фосфорсодержащее огнезащитное средство (F2), выбранное из группы, состоящей из производных фосфиновой кислоты.
2. Композиция по п. 1, причем фосфорсодержащее огнезащитное средство (F2) представляет собой фосфинат.
3. Композиция по п. 2, причем фосфинат выбирается из группы, состоящей из фосфинатов алюминия или фосфинатов цинка.
4. Композиция по п. 1, причем фосфорсодержащее огнезащитное средство (F1) представляет собой сложный эфир фосфорной кислоты.
5. Композиция по п. 1, причем огнезащитное средство (F1) выбирается из группы, состоящей из резорцинол-бис-дифенилфосфата (RDP), бисфенол-А-бис(дифенилфосфата) (BDP) и дифенилкрезилфосфата (DPK).
6. Композиция по п. 1, причем меламинцианурат имеет размер частиц в диапазоне от 0,1 до 100 мкм.
7. Композиция по п. 1, причем термопластичный полиуретан ТПУ-1 имеет твердость по Шору в диапазоне от 85А до 65D, определенную согласно стандарту DIN ISO 7619-1.
8. Композиция по п. 1, причем термопластичный полиуретан ТПУ-1 имеет в основе по меньшей мере один алифатический диизоцианат, выбранный из группы, состоящей из гексаметилендиизоцианата и ди(изоцианатоциклогексил)метана.
9. Композиция по п. 1, причем термопластичный полиуретан ТПУ-2 имеет твердость по Шору в диапазоне 70А до 65D, определенную согласно стандарту DIN ISO 7619-1.
10. Композиция по п. 1, причем термопластичный полиуретан ТПУ-2 имеет в основе дифенилметандиизоцианат (МДИ).
11. Композиция по п. 1, причем доля суммы термопластичных полиуретанов в композиции находится в диапазоне от 30 до 75% масс., в пересчете на всю композицию.
12. Композиция по п. 1, причем доля меламинцианурата в композиции находится в диапазоне от 20 до 40% масс., в пересчете на всю композицию.
13. Композиция по п. 1, причем доля огнезащитного средства (F2) в композиции находится в диапазоне от 3 до 15% масс., в пересчете на всю композицию.
14. Композиция по одному из пп. 1-13, причем доля огнезащитного средства (F1) находится в диапазоне от 2 до 15% масс., в пересчете на всю композицию.
15. Применение композиции по одному из пп. 1-14 для изготовления оболочек кабелей.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15181934 | 2015-08-21 | ||
| EP15181934.9 | 2015-08-21 | ||
| PCT/EP2016/069491 WO2017032659A1 (de) | 2015-08-21 | 2016-08-17 | Flammgeschütztes thermoplastisches polyurethan |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2018109760A true RU2018109760A (ru) | 2019-09-23 |
| RU2018109760A3 RU2018109760A3 (ru) | 2019-11-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| RU2018109760A RU2018109760A (ru) | 2015-08-21 | 2016-08-17 | Огнестойкий термопластичный полиуретан |
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| Country | Link |
|---|---|
| US (1) | US11015053B2 (ru) |
| EP (1) | EP3337855B1 (ru) |
| JP (2) | JP2018525515A (ru) |
| KR (1) | KR20180044938A (ru) |
| CN (2) | CN108137919A (ru) |
| AU (1) | AU2016312894A1 (ru) |
| ES (1) | ES2751693T3 (ru) |
| MX (1) | MX2018002245A (ru) |
| PL (1) | PL3337855T3 (ru) |
| RU (1) | RU2018109760A (ru) |
| WO (1) | WO2017032659A1 (ru) |
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| JP6942131B2 (ja) * | 2015-08-21 | 2021-09-29 | ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ | 難燃性熱可塑性ポリウレタン |
| CN107828204B (zh) * | 2017-11-22 | 2019-08-13 | 江苏利思德新材料有限公司 | 一种聚氨酯用无卤阻燃复配体系及其在无卤阻燃聚氨酯中的应用 |
| CN107892808B (zh) * | 2017-11-22 | 2019-08-13 | 江苏利思德新材料有限公司 | 一种电线电缆用无卤阻燃tpu弹性体组合物及其制备方法 |
| KR20210022745A (ko) * | 2018-06-25 | 2021-03-03 | 바스프 에스이 | 난연성 열가소성 폴리우레탄 |
| JP7400156B2 (ja) * | 2019-03-05 | 2023-12-19 | 大和化学工業株式会社 | 難燃性ポリウレタン樹脂組成物 |
| CN113518795A (zh) | 2019-03-14 | 2021-10-19 | 巴斯夫欧洲公司 | 包含热塑性多异氰酸酯加聚产物和阻燃剂的组合物 |
| JP2022553958A (ja) * | 2019-10-21 | 2022-12-27 | オーエフエス ファイテル，エルエルシー | 低摩擦スキン層を備えた屋外／屋内光学ケーブル |
| CN112480651B (zh) * | 2020-11-05 | 2022-07-08 | 苏州市雄林新材料科技有限公司 | 一种彩色超薄tpu薄膜及其制备方法 |
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| DE3063066D1 (en) | 1979-06-02 | 1983-06-16 | Basf Ag | Flameproof polyamide moulding compositions containing a filler |
| JPS6140340A (ja) * | 1984-07-31 | 1986-02-26 | Dainippon Ink & Chem Inc | ポリウレタン用安定剤 |
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-
2016
- 2016-08-17 JP JP2018528383A patent/JP2018525515A/ja active Pending
- 2016-08-17 WO PCT/EP2016/069491 patent/WO2017032659A1/de active Application Filing
- 2016-08-17 US US15/753,619 patent/US11015053B2/en active Active
- 2016-08-17 RU RU2018109760A patent/RU2018109760A/ru not_active Application Discontinuation
- 2016-08-17 PL PL16754268T patent/PL3337855T3/pl unknown
- 2016-08-17 CN CN201680056290.9A patent/CN108137919A/zh active Pending
- 2016-08-17 EP EP16754268.7A patent/EP3337855B1/de active Active
- 2016-08-17 AU AU2016312894A patent/AU2016312894A1/en not_active Abandoned
- 2016-08-17 KR KR1020187007837A patent/KR20180044938A/ko unknown
- 2016-08-17 MX MX2018002245A patent/MX2018002245A/es unknown
- 2016-08-17 CN CN202310851732.0A patent/CN116904016A/zh active Pending
- 2016-08-17 ES ES16754268T patent/ES2751693T3/es active Active
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2021
- 2021-06-03 JP JP2021093832A patent/JP7213917B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2021155744A (ja) | 2021-10-07 |
| MX2018002245A (es) | 2018-03-23 |
| PL3337855T3 (pl) | 2019-12-31 |
| CN116904016A (zh) | 2023-10-20 |
| JP2018525515A (ja) | 2018-09-06 |
| US20190270884A1 (en) | 2019-09-05 |
| EP3337855A1 (de) | 2018-06-27 |
| RU2018109760A3 (ru) | 2019-11-21 |
| AU2016312894A1 (en) | 2018-03-15 |
| WO2017032659A1 (de) | 2017-03-02 |
| ES2751693T3 (es) | 2020-04-01 |
| KR20180044938A (ko) | 2018-05-03 |
| EP3337855B1 (de) | 2019-07-24 |
| US11015053B2 (en) | 2021-05-25 |
| CN108137919A (zh) | 2018-06-08 |
| JP7213917B2 (ja) | 2023-01-27 |
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