RU2016144153A - Волокна с наполнителем - Google Patents

Волокна с наполнителем Download PDF

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RU2016144153A
RU2016144153A RU2016144153A RU2016144153A RU2016144153A RU 2016144153 A RU2016144153 A RU 2016144153A RU 2016144153 A RU2016144153 A RU 2016144153A RU 2016144153 A RU2016144153 A RU 2016144153A RU 2016144153 A RU2016144153 A RU 2016144153A
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product
cellulosic
filler
fiber
pvoh
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RU2016144153A
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RU2016144153A3 (ru
RU2676430C2 (ru
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Дэниел У. ЗУМНИХТ
Томас ШУЛЬЦЕ
Франк-Гюнтер НИМЗ
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Джорджия-Пэсифик Консьюмер Продактс Лп
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/14—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00—Fibrous raw materials or their mechanical treatment
    • D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/06—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00—Fibrous raw materials or their mechanical treatment
    • D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/06—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods
    • D21B1/08—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods the raw material being waste paper; the raw material being rags
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/02—Working-up waste paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/14—Secondary fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/18—Highly hydrated, swollen or fibrillatable fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2001/00—Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/731—Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
    • C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/40—Formation of filaments, threads, or the like by applying a shearing force to a dispersion or solution of filament formable polymers, e.g. by stirring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/64—Paper recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Artificial Filaments (AREA)

Claims (33)

1. Продукт производства, включающий связующее вещество и наполнитель, причем связующее вещество представляет собой поливиниловый спирт (PVOH), целлюлозные нанофибриллы или сочетание PVOH и целлюлозных нанофибрилл, и наполнитель представляет собой очищенные от краски твердые отходы, включающей золу и мелкие целлюлозные частицы.
2. Продукт по п. 1, причем данный продукт представляет собой волокно или пленку.
3. Продукт по п. 2, в котором связующее вещество пропитывается наполнителем.
4. Продукт по п. 2, в котором связующее вещество представляет собой инкапсулирующий наполнитель.
5. Продукт по п. 2, в котором наполнитель присутствует в интервале от приблизительно 1 мас.% до приблизительно 80 мас.% по отношению к полной массе волокна.
6. Продукт по пункту 2, в котором PVOH присутствует в интервале от приблизительно 20 мас.% до приблизительно 99 мас.% по отношению к полной массе волокна.
7. Продукт по п. 2, в котором целлюлозные нанофибриллы присутствуют в интервале от приблизительно 1 мас.% до приблизительно 80 мас.% по отношению к полной массе волокна.
8. Продукт по пункту 2, в котором в качестве золы присутствует осажденный карбонат кальция, тонкодисперсный карбонат кальция, гипс, диоксид титана, глина, диоксид кремния или любое их сочетание.
9. Продукт по п. 2, в котором наполнитель включает частицы, у которых средний размер составляет менее чем приблизительно 20 микрометров в диаметре.
10. Продукт по п. 2, дополнительно включающий технологическую добавку.
11. Продукт по п. 10, в котором технологическая добавка присутствует в интервале от приблизительно 0,5 мас.% до приблизительно 10 мас.% по отношению к полной массе волокна.
12. Продукт по п. 10, в котором в качестве технологической добавки присутствует карбоксиметилцеллюлоза, крахмал, глиоксаль, глутаровый альдегид, диальдегиды, борная кислота, карбонат, двойной карбонат циркония и аммония, глиоксалированный полиакриламид, полиамидоэпихлоргидрин, полиаминоэпихлоргидрин, карбамидоформальдегид, меламиноформальдегид, полиэтиленимин, пропиленгликоль, диэтиленгликоль, триэтиленгликоль, дипропиленгликоль, глицерин или любое их сочетание.
13. Бумажное полотно, включающее продукт по п. 2, причем данный продукт представляет собой волокно.
14. Бумажное полотно включающий продукт по пункту 1, причем данное бумажное полотно включает целлюлозную подложку, имеющую поверхность, и продукт, в основном, находится на поверхности или пропитывает объем целлюлозной подложки.
15. Бумажное полотно по п. 14, причем данный продукт пропитывает объем целлюлозной подложки и имеет частицы такого размера, что средний диаметр находится в интервале от приблизительно 1 микрометра до приблизительно 80 микрометров.
16. Продукт производства, включающий целлюлозные нанофибриллы и наполнитель, причем наполнитель представляет собой очищенные от краски твердые отходы, включающие золу и мелкие целлюлозные частицы, и целлюлозные нанофибриллы представляет собой, по меньшей мере, один материал из нанофибриллированной целлюлозы или целлюлозных фибрид.
17. Продукт по п. 16, причем данный продукт представляет собой волокно или пленку.
18. Продукт по п. 17, в котором целлюлозные нанофибриллы пропитываются наполнителем.
19. Продукт по п. 17, в котором целлюлозные нанофибриллы инкапсулируют наполнитель.
20. Продукт по п. 17, в котором наполнитель присутствует в интервале от приблизительно 5 мас.% до приблизительно 50 мас.% по отношению к полной массе волокна.
21. Продукт производства, включающий PVOH и наполнитель, причем PVOH присутствует в интервале от приблизительно 20 мас.% до приблизительно 85 мас.% по отношению к полной массе волокна, и наполнитель представляет собой очищенные от краски твердые отходы, включающие золу и мелкие целлюлозные частицы.
22. Продукт по п. 21, причем данный продукт представляет собой волокно или пленку.
23. Продукт по п. 21, в котором PVOH имеет степень полимеризации в интервале от приблизительно 500 до приблизительно 3000.
24. Продукт по п. 23, в котором степень полимеризации находится в интервале от приблизительно 1000 до приблизительно 1600.
25. Продукт по п. 21, в котором PVOH имеет степень гидролиза, составляющую более чем приблизительно 95%.
26. Продукт по п. 25, в котором PVOH имеет степень гидролиза, составляющую более чем приблизительно 98%.
27. Способ изготовления продукт производства, причем данный способ включает:
пропитывание наполнителем или его инкапсулирование в связующем веществе, наполнитель представляет собой очищенные от краски твердые отходы, включающие золу и мелкие целлюлозные частицы, и связующее вещество представляет собой PVOH, целлюлозные нанофибриллы или сочетание PVOH и целлюлозных нанофибрилл; и
изготовление экструдируемого прядильного раствора.
28. Способ по п. 27, причем данный продукт представляет собой волокно или пленку.
29. Способ по п. 28, дополнительно включающий влажное прядение, сухое прядение, ротационное прядение или щелевую экструзию экструдируемого прядильного раствора для изготовления волокна или пленки.
30. Способ по п. 28, в котором целлюлозные нанофибриллы представляют собой, по меньшей мере, один материал из целлюлозных нанофибрилл и целлюлозных фибрид.
31. Способ по п. 28, дополнительно включающий гомогенизацию древесных целлюлозных волокон или другой фибриллируемой целлюлозы для изготовления целлюлозных нанофибрилл.
RU2016144153A 2014-04-11 2015-04-06 Волокна с наполнителем RU2676430C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201461978323P 2014-04-11 2014-04-11
US61/978,323 2014-04-11
US14/677,011 2015-04-02
US14/677,011 US9777129B2 (en) 2014-04-11 2015-04-02 Fibers with filler
PCT/US2015/024507 WO2015157168A1 (en) 2014-04-11 2015-04-06 Fibers with filler

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RU2016144153A true RU2016144153A (ru) 2018-05-11
RU2016144153A3 RU2016144153A3 (ru) 2018-06-25
RU2676430C2 RU2676430C2 (ru) 2018-12-28

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US (2) US9777129B2 (ru)
EP (1) EP3129547B1 (ru)
JP (1) JP6526710B2 (ru)
CN (1) CN106164348B (ru)
CA (1) CA2944522C (ru)
MX (1) MX2016013367A (ru)
RU (1) RU2676430C2 (ru)
SG (2) SG11201606905YA (ru)
WO (1) WO2015157168A1 (ru)

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US9777143B2 (en) 2014-04-11 2017-10-03 Georgia-Pacific Consumer Products Lp Polyvinyl alcohol fibers and films with mineral fillers and small cellulose particles
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JP6491467B2 (ja) 2014-10-14 2019-03-27 花王株式会社 三次元造形用可溶性材料
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SE543174C2 (en) * 2018-10-08 2020-10-20 Stora Enso Oyj A flexible barrier layer comprising microfibrillated dialdehyde cellulose
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SG11201606905YA (en) 2016-10-28
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CN106164348A (zh) 2016-11-23
JP2017514026A (ja) 2017-06-01
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JP6526710B2 (ja) 2019-06-05
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RU2676430C2 (ru) 2018-12-28
US20170349719A1 (en) 2017-12-07
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