RU2015128060A - Углеродные тела и ферромагнитные углеродные тела - Google Patents

Углеродные тела и ферромагнитные углеродные тела Download PDF

Info

Publication number
RU2015128060A
RU2015128060A RU2015128060A RU2015128060A RU2015128060A RU 2015128060 A RU2015128060 A RU 2015128060A RU 2015128060 A RU2015128060 A RU 2015128060A RU 2015128060 A RU2015128060 A RU 2015128060A RU 2015128060 A RU2015128060 A RU 2015128060A
Authority
RU
Russia
Prior art keywords
ferromagnetic
carbon
metal
carbon body
graphitized
Prior art date
Application number
RU2015128060A
Other languages
English (en)
Other versions
RU2641124C2 (ru
Inventor
Якобус ХУКСТРА
Йим Алойсиус Мария БРАНДТС
Лорианне ВАГЕМАКЕР
Джон Вильхельм Геус
Леонардус Вейнанд ЕННЕСКЕНС
Original Assignee
Басф Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Басф Корпорейшн filed Critical Басф Корпорейшн
Publication of RU2015128060A publication Critical patent/RU2015128060A/ru
Application granted granted Critical
Publication of RU2641124C2 publication Critical patent/RU2641124C2/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B01J20/205—Carbon nanostructures, e.g. nanotubes, nanohorns, nanocones, nanoballs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28009—Magnetic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3268—Macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/33—Electric or magnetic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/0036—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties showing low dimensional magnetism, i.e. spin rearrangements due to a restriction of dimensions, e.g. showing giant magnetoresistivity
    • H01F1/0045—Zero dimensional, e.g. nanoparticles, soft nanoparticles for medical/biological use
    • H01F1/0063—Zero dimensional, e.g. nanoparticles, soft nanoparticles for medical/biological use in a non-magnetic matrix, e.g. granular solids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/20—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
    • H01F1/28—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder dispersed or suspended in a bonding agent
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0253—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
    • H01F41/0266—Moulding; Pressing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/008—Methods or theories
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/488—Treatment of water, waste water, or sewage with magnetic or electric fields for separation of magnetic materials, e.g. magnetic flocculation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00—Use of specific compounds during water treatment
    • C02F2305/08—Nanoparticles or nanotubes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Power Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Water Supply & Treatment (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Water Treatment By Sorption (AREA)

Claims (21)

1. Ферромагнитное углеродное тело, содержащее частично графитизированный активированный уголь и частицы по меньшей мере одного ферромагнитного металла; где размер указанного ферромагнитного углеродного тела составляет от 100 нм до 20 мм, вычисленная БЭТ-методом площадь поверхности данного ферромагнитного углеродного тела составляет от 200 до 1000 м2/г, общий объем пор составляет от 0,1 до 1 мл/г, и средний диаметр пор составляет от 2 до 10 нм.
2. Ферромагнитное углеродное тело по п. 1, в котором указанный ферромагнитный металл выбран из группы, состоящей из металлических железа, никеля, кобальта и/или их сплавов, а также их комбинаций, причем указанное ферромагнитное углеродное тело содержит 10-90% по весу графитизированного углерода, предпочтительно 20-80% по весу графитизированного углерода, более предпочтительно 25-70% по весу графитизированного углерода, и еще более предпочтительно 30-60% по весу графитизированного углерода.
3. Ферромагнитное углеродное тело по п. 1, в котором частицы металла полностью инкапсулированы графитизированным углеродом.
4. Ферромагнитное углеродное тело по п. 1, дополнительно содержащий дополнительные частицы металла и/или оксида металла.
5. Ферромагнитное углеродное тело по п. 1, дополнительно содержащее полимер.
6. Ферромагнитное углеродное тело по п. 1, дополнительно содержащее углеродные нанотрубки и/или углеродные нановолокна.
7. Способ производства ферромагнитного углеродного тела по предыдущим пунктам, включающий в себя пропитку активированного угля водным раствором нелетучего металлосодержащего соединения, высушивание пропитанного активированного угля и пиролиз высушенного пропитанного активированного угля в атмосфере инертного газа, посредством чего обеспечивается восстановление металлосодержащего соединения до соответствующего металла.
8. Способ по п. 7, отличающийся тем, что металлосодержащее соединение является прекурсором ферромагнитного металла и/или сплава, и, предпочтительно, представляет собой нитрат железа(III) или цитрат железа(III) аммония.
9. Способ по п. 7, отличающийся тем, что ферромагнитное углеродное тело контактирует с потоком газа, содержащего водород и углеродосодержащее соединение, при температуре >800°С.
10. Способ по п. 7, отличающийся тем, что полимер адсорбируется на графитовой поверхности ферромагнитного углеродного тела.
11. Способ по п. 7, отличающийся тем, что ферромагнитное углеродное тело загружается металлом и/или оксидом металла, и, предпочтительно, указанное ферромагнитное углеродное тело содержит частицы ферромагнитного металла, полностью инкапсулированные слоями графитизированного углерода.
12. Способ производства ферромагнитного углеродного тела размером от 100 нм до 20 мм, включающий смешивание порошка активированного угля с порошком нелетучего металлосодержащего соединения, формование тела из полученного смешанного порошка и пиролиз формованного тела в инертной атмосфере, чем обеспечивается восстановление металлосодержащего соединения до соответствующего металла.
13. Способ по п. 12, отличающийся тем, что металлосодержащее соединение является прекурсором ферромагнитного металла и/или сплава, и, предпочтительно, представляет собой нитрат железа(III) или цитрат железа(III) аммония.
14. Способ по п. 12, отличающийся тем, что ферромагнитное углеродное тело контактирует с потоком газа, содержащего водород и углеродосодержащее соединение, при температуре >800°С.
15. Способ по п. 12, отличающийся тем, что полимер адсорбируется на графитовой поверхности ферромагнитного углеродного тела.
16. Способ по п. 12, отличающийся тем, что ферромагнитное углеродное тело загружается металлом и/или оксидом металла, и, предпочтительно, указанное ферромагнитное углеродное тело содержит частицы ферромагнитного металла, полностью инкапсулированные слоями графитизированного углерода.
17. Ферромагнитное углеродное тело, содержащее частично графитизированный активированный уголь и металлические частицы по меньшей мере одного ферромагнитный металла, получаемое с помощью способа по пп. 7-16.
18. Способ производства углеродного тела, представляющего собой частично графитизированный активированный уголь, включающий введение ферромагнитного углеродного тела по пп. 1-6 или 17 в контакт с кислотой для растворения частиц металла, и последующую промывку обработанного кислотой ферромагнитного углеродного тела в жидкости для удаления растворенных частиц металла.
19. Углеродное тело, содержащее частично графитизированный активированный уголь, получаемый с помощью способа по п. 18.
20. Применение ферромагнитного углеродного тела по пп. 1-6 или углеродного тела по п. 19 в качестве адсорбента, носителя катализатора, катализатора, при очистке воды или в области электрохимии.
21. Катализатор, подходящий для использования в производстве олефинов путем гидрирования оксида углерода, содержащий ферромагнитное углеродное тело по пп. 1-2.
RU2015128060A 2012-12-13 2013-12-12 Углеродные тела и ферромагнитные углеродные тела RU2641124C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12197061.0 2012-12-13
EP12197061 2012-12-13
PCT/IB2013/060863 WO2014091447A1 (en) 2012-12-13 2013-12-12 Carbon bodies and ferromagnetic carbon bodies

Publications (2)

Publication Number Publication Date
RU2015128060A true RU2015128060A (ru) 2017-01-16
RU2641124C2 RU2641124C2 (ru) 2018-01-16

Family

ID=47355900

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015128060A RU2641124C2 (ru) 2012-12-13 2013-12-12 Углеродные тела и ферромагнитные углеродные тела

Country Status (12)

Country Link
US (1) US9579635B2 (ru)
EP (1) EP2932513B1 (ru)
JP (1) JP6042560B2 (ru)
KR (1) KR101724979B1 (ru)
CN (1) CN105164766B (ru)
AR (1) AR093986A1 (ru)
AU (1) AU2013358592B2 (ru)
BR (1) BR112015013859B1 (ru)
DK (1) DK2932513T3 (ru)
RU (1) RU2641124C2 (ru)
TW (1) TWI641002B (ru)
WO (1) WO2014091447A1 (ru)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2015253175A1 (en) 2014-04-29 2016-09-29 Archer-Daniels-Midland Company Carbon black based shaped porous products
US11253839B2 (en) 2014-04-29 2022-02-22 Archer-Daniels-Midland Company Shaped porous carbon products
RU2593392C1 (ru) * 2015-06-03 2016-08-10 федеральное государственное автономное образовательное учреждение высшего образования "Санкт-петербургский политехнический университет Петра Великого" ФГАОУ ВО "СПбПУ" Способ получения ферромагнитной жидкости
US10464048B2 (en) 2015-10-28 2019-11-05 Archer-Daniels-Midland Company Porous shaped metal-carbon products
US10722867B2 (en) 2015-10-28 2020-07-28 Archer-Daniels-Midland Company Porous shaped carbon products
JP6642916B2 (ja) * 2016-02-09 2020-02-12 太平洋セメント株式会社 フライアッシュの活性度指数予測方法、およびフライアッシュ混合セメントの製造方法
MY197926A (en) * 2016-05-11 2023-07-25 Basf Corp Catalyst composition comprising magnetic material adapted for inductive heating
TWI641698B (zh) * 2017-12-12 2018-11-21 國立清華大學 適用於高溫的磁感測瓷金材料
CN110026050B (zh) * 2019-01-14 2021-07-09 广州华芳烟用香精有限公司 一种Fe基蚕沙生物炭对苯乙醇的吸附缓释方法
CN111111612B (zh) * 2019-12-19 2022-06-03 燕山大学 一种去除水中铬的磁性多孔生物炭的制备和使用方法
CN113680322B (zh) * 2021-09-03 2024-01-30 中国科学院城市环境研究所 一种铁磁性碳基复合材料及其制备方法与应用
JP7482164B2 (ja) * 2022-03-11 2024-05-13 三菱重工業株式会社 炭化水素の直接分解方法
CN114436258B (zh) * 2022-04-08 2022-07-01 中国科学院生态环境研究中心 一种针对土霉味物质去除的石墨化多孔碳制备方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE631220A (ru) 1962-04-20
US3388077A (en) 1963-04-01 1968-06-11 Universal Oil Prod Co Catalyst for treatment of combustible waste products
US4206020A (en) 1966-05-24 1980-06-03 National Research Development Corporation Electrochemical process using a fluidized electrode
US4176038A (en) 1974-07-11 1979-11-27 Westinghouse Electric Corp. Water purification method and apparatus
NL8502992A (nl) 1985-11-01 1987-06-01 Dow Chemical Nederland Werkwijze voor het beladen van een gevormd dragermateriaal met een katalytisch actief materiaal of met een precursor van een katalytisch actief materiaal en gevormde katalysator verkregen onder toepassing van de werkwijze.
RU1836145C (ru) * 1991-02-04 1993-08-23 Николай Федорович Федоров Способ получени палладиевого катализатора
JPH05139712A (ja) * 1991-11-19 1993-06-08 Koa Oil Co Ltd 導電性多孔質炭素材の製造方法
JP3709267B2 (ja) * 1997-02-26 2005-10-26 エア・ウォーター株式会社 メソポアカーボンおよびその製造方法
JP2000107598A (ja) * 1998-09-30 2000-04-18 Honda Motor Co Ltd 高導電性活性炭及びその製造方法
US6843919B2 (en) * 2002-10-04 2005-01-18 Kansas State University Research Foundation Carbon-coated metal oxide nanoparticles
EA011516B1 (ru) * 2005-01-13 2009-04-28 Синвеншен Аг Композиционный материал и способ его изготовления
JP4963616B2 (ja) * 2006-03-23 2012-06-27 Ｊｘ日鉱日石エネルギー株式会社 炭化水素油中の微量成分を除去する吸着剤及びその製造方法
DE102006022866A1 (de) 2006-05-16 2007-11-22 Glatt Systemtechnik Gmbh Kohlenstoff-Granulat, Verfahren zu dessen Herstellung und dessen Verwendung
CN101642708B (zh) * 2008-08-08 2011-11-30 中国科学院大连化学物理研究所 一种非贵金属催化剂及其制备和应用
JP5471142B2 (ja) * 2008-09-29 2014-04-16 ソニー株式会社 多孔質炭素材料複合体及びその製造方法、並びに、吸着剤、化粧料、浄化剤及び光触媒複合材料
EP2233207A1 (en) * 2009-02-27 2010-09-29 Basf Se Process for the preparation of metal-carbon containing bodies
EP2224045A1 (en) 2009-02-27 2010-09-01 Basf Se Process for producing carbon nanofibres and/or carbon nanotubes
GB0905222D0 (en) * 2009-03-26 2009-05-13 Johnson Matthey Plc Method for producing a supported metal nitrate
JP5610900B2 (ja) * 2009-07-28 2014-10-22 新日鐵住金株式会社 Ｆｔ合成用触媒の製造方法、及び当該触媒を用いた炭化水素の製造方法
KR101157382B1 (ko) * 2009-12-24 2012-06-20 서울대학교산학협력단 질소를 포함한 자성 탄소나노입자의 제조방법과 중금속 흡착제로서의 응용
EP2383374A1 (en) * 2010-04-29 2011-11-02 BASF Corporation Nano-particles containing carbon and a ferromagnetic metal or alloy
CN102110506B (zh) * 2010-11-17 2013-01-09 安徽工业大学 一种碳基磁性介孔复合微球及其制备方法

Also Published As

Publication number Publication date
EP2932513A1 (en) 2015-10-21
DK2932513T3 (da) 2020-07-27
AU2013358592A1 (en) 2015-07-02
US20150328621A1 (en) 2015-11-19
EP2932513B1 (en) 2020-04-22
AR093986A1 (es) 2015-07-01
AU2013358592B2 (en) 2016-12-22
CN105164766B (zh) 2019-02-01
BR112015013859A2 (pt) 2017-07-11
JP6042560B2 (ja) 2016-12-14
JP2015536901A (ja) 2015-12-24
BR112015013859B1 (pt) 2021-11-30
KR101724979B1 (ko) 2017-04-07
TW201438035A (zh) 2014-10-01
TWI641002B (zh) 2018-11-11
WO2014091447A1 (en) 2014-06-19
RU2641124C2 (ru) 2018-01-16
KR20150102036A (ko) 2015-09-04
US9579635B2 (en) 2017-02-28
CN105164766A (zh) 2015-12-16

Similar Documents

Publication Publication Date Title
RU2015128060A (ru) Углеродные тела и ферромагнитные углеродные тела
Fu et al. Composites of metal oxides and intrinsically conducting polymers as supercapacitor electrode materials: the best of both worlds?
Ji et al. In-situ reduction of Ag nanoparticles on oxygenated mesoporous carbon fabric: Exceptional catalyst for nitroaromatics reduction
Lu et al. Core–shell nanocomposites based on gold nanoparticle@ zinc–iron-embedded porous carbons derived from metal–organic frameworks as efficient dual catalysts for oxygen reduction and hydrogen evolution reactions
Ke et al. An efficient room temperature core–shell AgPd@ MOF catalyst for hydrogen production from formic acid
Wood et al. Recent progress on nitrogen/carbon structures designed for use in energy and sustainability applications
Zhu et al. Review on the progress in synthesis and application of magnetic carbon nanocomposites
Chen et al. Facile deposition of Pd nanoparticles on carbon nanotube microparticles and their catalytic activity for Suzuki coupling reactions
Acharya et al. Adsorbed Cr (VI) based activated carbon/polyaniline nanocomposite: a superior electrode material for asymmetric supercapacitor device
Yu et al. Facile synthesis of uniform AuPd@ Pd nanocrystals supported on three-dimensional porous N-doped reduced graphene oxide hydrogels as highly active catalyst for methanol oxidation reaction
JP2012101155A5 (ru)
Sun et al. Fe/IRMOF-3 derived porous carbons as non-precious metal electrocatalysts with high activity and stability towards oxygen reduction reaction
CA2914210A1 (en) Porous carbon catalyst, method for producing same, electrode and battery
Ding et al. Rational design, synthesis, and applications of carbon-assisted dispersive Ni-based composites
Jin et al. In situ assembly of well-dispersed gold nanoparticles on hierarchical double-walled nickel silicate hollow nanofibers as an efficient and reusable hydrogenation catalyst
Chen et al. Solid–solid grinding/templating route to magnetically separable nitrogen-doped mesoporous carbon for the removal of Cu2+ ions
Huang et al. Fluorine and nitrogen dual-doped carbon material as metal-free peroxymonosulfate activator for efficient tetracycline degradation: Radical-free mechanism
Tang et al. Decorating multi-walled carbon nanotubes with nickel nanoparticles for selective hydrogenation of citral
Leelavathi et al. Graphene-oxide-supported ultrathin Au nanowires: efficient electrocatalysts for borohydride oxidation
Jiang et al. Spatial self-confinement of heterogeneous metallic CoX (X= Cu, Ni, Fe) within laminated porous carbon assemblies to efficiently activate peroxymonosulfate for tetracycline destruction
Li et al. Yolk-shell Fe3O4 nanoparticles loaded on persimmon-derived porous carbon for supercapacitor assembly and As (V) removal
KR20160101402A (ko) 휘발성 유기화합물 농축 및 제거 장치
Guo et al. Hydroxyl-rich nanoporous carbon nanosheets synthesized by a one-pot method and their application in the in situ preparation of well-dispersed Ag nanoparticles
Jiang et al. Probing the spontaneous reduction mechanism of platinum ions confined in the nanospace by X-ray absorption fine structure spectroscopy
Zhang et al. Structural and compositional analysis of MOF-derived carbon nanomaterials for the oxygen reduction reaction