RU2014152878A - Катализатор для получения высших спиртов - Google Patents

Катализатор для получения высших спиртов Download PDF

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RU2014152878A
RU2014152878A RU2014152878A RU2014152878A RU2014152878A RU 2014152878 A RU2014152878 A RU 2014152878A RU 2014152878 A RU2014152878 A RU 2014152878A RU 2014152878 A RU2014152878 A RU 2014152878A RU 2014152878 A RU2014152878 A RU 2014152878A
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catalyst
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RU2014152878A
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АНТОЛИН Рикардо АРХОНА
ЯГУЭ Хуан Луис САНС
Канос Авелино Корма
Марсело Эдуардо ДОМИНЕ
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Абенгоа Биоэнерхия Нуэвас Текнолохиас, С. А.
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Publication of RU2014152878A publication Critical patent/RU2014152878A/ru

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/825Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007Mixed salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
RU2014152878A 2012-06-29 2013-06-28 Катализатор для получения высших спиртов RU2014152878A (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12382262.9 2012-06-29
EP12382262.9A EP2679303B1 (en) 2012-06-29 2012-06-29 Catalyst and its preparation process for obtaining higher alcohols
PCT/ES2013/070442 WO2014001595A1 (es) 2012-06-29 2013-06-28 Catalizador para la obtención de alcoholes superiores

Publications (1)

Publication Number Publication Date
RU2014152878A true RU2014152878A (ru) 2016-08-20

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RU2014152878A RU2014152878A (ru) 2012-06-29 2013-06-28 Катализатор для получения высших спиртов

Country Status (12)

Country Link
US (1) US9266096B2 (cs)
EP (1) EP2679303B1 (cs)
KR (1) KR102113105B1 (cs)
CN (1) CN104736238B (cs)
BR (1) BR112014032469B1 (cs)
CA (1) CA2877970C (cs)
ES (1) ES2855323T3 (cs)
HU (1) HUE053582T2 (cs)
IN (1) IN2014MN02642A (cs)
MX (1) MX357222B (cs)
RU (1) RU2014152878A (cs)
WO (1) WO2014001595A1 (cs)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2899318C (en) * 2013-02-19 2019-12-24 Greenyug, Llc Production of higher alcohols
WO2015085002A1 (en) 2013-12-04 2015-06-11 Greenyug, Llc Production of butyl acetate from ethanol
WO2015097285A1 (en) 2013-12-27 2015-07-02 Abengoa Bioenergia Nuevas Tecnologias, S.A. Process for the preparation of higher alcohols from lower alcohols by guerbet condensation
ES2570231B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
ES2570233B1 (es) 2014-11-14 2017-02-22 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
ES2570227B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
EP3218339B1 (en) 2014-11-14 2022-01-05 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for the preparation of higher alcohols from ethanol and n-hexanol by guerbet condensation
BR112018003036B1 (pt) * 2015-08-19 2021-11-09 Rescurve, Llc Método para produção de um álcool superior
WO2017093473A1 (en) 2015-12-02 2017-06-08 Universiteit Gent Guerbet condensation reaction
ES2647963B1 (es) 2016-05-26 2018-10-03 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
CN107983356B (zh) * 2017-12-07 2020-12-25 中国科学院山西煤炭化学研究所 一种合成高级支链醇的催化剂及制备方法和应用
CN111604056B (zh) * 2020-06-03 2023-05-12 中国科学院山西煤炭化学研究所 一种负载型金属氧化物催化剂及其制备方法和应用
CN112619654A (zh) * 2020-11-06 2021-04-09 上海簇睿低碳能源技术有限公司 一种甲烷二氧化碳重整制合成气的催化剂及其制备方法
CN112827483B (zh) * 2020-12-29 2022-10-25 宁波申江科技股份有限公司 一种制氢催化剂及其制备方法和应用
CN112916010B (zh) * 2021-01-26 2022-09-16 北京化工大学 一种炔烃选择性加氢用Cuy/MMgOx催化剂及其制备方法
CN117920221B (zh) * 2024-01-08 2024-12-03 东北农业大学 一种花球状镍钴铝层状氧化物催化剂及其制备方法和应用

Family Cites Families (12)

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DE8600273U1 (de) * 1986-01-08 1986-03-06 Paul Hellermann Gmbh, 2080 Pinneberg Spannband, insbesondere zum Binden von langgestreckten Gegenständen
US5219816A (en) * 1991-12-20 1993-06-15 Exxon Research & Engineering Company Dehydrogenation catalysts and process for preparing the catalysts
US5300695A (en) 1992-12-07 1994-04-05 Amoco Corporation Process for preparing alcohols
US5387570A (en) 1993-05-07 1995-02-07 Exxon Research & Engineering Co. Catalysts for iso-alcohol synthesis from CO + H2
NO312126B1 (no) * 1998-12-23 2002-03-25 Norske Stats Oljeselskap Forbedret fremgangsmåte for fremstilling av katalysatorer bestående av metaller på hydrotalcitt-baserte b¶rermaterialer
CA2589125C (en) 2004-12-03 2010-10-19 Kabushiki Kaisha Sangi Method of synthesizing higher-molecular alcohol
WO2009026510A1 (en) 2007-08-22 2009-02-26 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst
WO2009026523A1 (en) 2007-08-22 2009-02-26 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
US8071822B2 (en) 2008-01-28 2011-12-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid
US8071823B2 (en) 2008-01-28 2011-12-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
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Also Published As

Publication number Publication date
BR112014032469B1 (pt) 2021-02-09
MX2015000225A (es) 2015-08-12
KR102113105B1 (ko) 2020-05-21
EP2679303A1 (en) 2014-01-01
MX357222B (es) 2018-06-28
EP2679303B1 (en) 2020-11-11
US20150148569A1 (en) 2015-05-28
BR112014032469A2 (pt) 2017-06-27
KR20150090019A (ko) 2015-08-05
HUE053582T2 (hu) 2021-07-28
CA2877970C (en) 2020-11-17
ES2855323T3 (es) 2021-09-23
IN2014MN02642A (cs) 2015-10-16
US9266096B2 (en) 2016-02-23
CA2877970A1 (en) 2014-01-03
WO2014001595A1 (es) 2014-01-03
CN104736238A (zh) 2015-06-24
CN104736238B (zh) 2017-09-08

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