RU2014142981A - Способ производства стального листа с черным покрытием и способ производства формованного изделия из стального листа с черным покрытием - Google Patents

Способ производства стального листа с черным покрытием и способ производства формованного изделия из стального листа с черным покрытием Download PDF

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RU2014142981A
RU2014142981A RU2014142981A RU2014142981A RU2014142981A RU 2014142981 A RU2014142981 A RU 2014142981A RU 2014142981 A RU2014142981 A RU 2014142981A RU 2014142981 A RU2014142981 A RU 2014142981A RU 2014142981 A RU2014142981 A RU 2014142981A
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steel sheet
valve metal
magnesium
immersion
aluminum
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RU2014142981A
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RU2621518C2 (ru
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Тадаси НАКАНО
Масая ЯМАМОТО
Хирофуми ТАКЕЦУ
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Ниссин Стил Ко., Лтд.
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/10—Oxidising
    • C23C8/16—Oxidising using oxygen-containing compounds, e.g. water, carbon dioxide
    • C—CHEMISTRY; METALLURGY
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    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
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    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C1/02—Making non-ferrous alloys by melting
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    • C22C38/00—Ferrous alloys, e.g. steel alloys
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    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
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    • C23C2/12—Aluminium or alloys based thereon
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    • C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
    • C23C22/42—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also phosphates
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    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
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    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
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    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
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    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
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    • C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
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    • C23C8/10—Oxidising
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    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
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    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/72—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes more than one element being applied in one step

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  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Coating With Molten Metal (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Laminated Bodies (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

1. Способ производства стального листа с черным покрытием, включающий в себя:обеспечение стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав, который включает в себя полученный способом погружения в расплав слой содержащего алюминий и магний цинкового покрытия, содержащий 0,1 масc.% или более и 22,0 масc.% или менее алюминия, 0,1 масc.% или более и менее 1,5 масc.% магния; иконтактирование стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав, с водяным паром в замкнутом сосуде, причем:концентрация кислорода в замкнутом сосуде составляет 13% или менее.2. Способ по п. 1, дополнительно включающий в себя формирование пленки неорганического покрытия на поверхности стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав.3. Способ по п. 2, в котором пленка неорганического покрытия включает в себя одно или более соединений, выбранных из группы, состоящей из оксида вентильного металла, оксоата вентильного металла, гидроксида вентильного металла, фосфата вентильного металла и фторида вентильного металла.4. Способ по п. 3, в котором вентильный металл является одним или более металлами, выбранными из группы, состоящей из титана, циркония, гафния, ванадия, ниобия, тантала, вольфрама, кремния и алюминия.5. Способ по п. 1, дополнительно включающий в себя формирование пленки покрытия из органической смолы на поверхности стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав.6. Способ по п. 5, в котором:органическая смола, содержащаяся в пленке покрытия из органической смолы, я

Claims (13)

1. Способ производства стального листа с черным покрытием, включающий в себя:
обеспечение стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав, который включает в себя полученный способом погружения в расплав слой содержащего алюминий и магний цинкового покрытия, содержащий 0,1 масc.% или более и 22,0 масc.% или менее алюминия, 0,1 масc.% или более и менее 1,5 масc.% магния; и
контактирование стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав, с водяным паром в замкнутом сосуде, причем:
концентрация кислорода в замкнутом сосуде составляет 13% или менее.
2. Способ по п. 1, дополнительно включающий в себя формирование пленки неорганического покрытия на поверхности стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав.
3. Способ по п. 2, в котором пленка неорганического покрытия включает в себя одно или более соединений, выбранных из группы, состоящей из оксида вентильного металла, оксоата вентильного металла, гидроксида вентильного металла, фосфата вентильного металла и фторида вентильного металла.
4. Способ по п. 3, в котором вентильный металл является одним или более металлами, выбранными из группы, состоящей из титана, циркония, гафния, ванадия, ниобия, тантала, вольфрама, кремния и алюминия.
5. Способ по п. 1, дополнительно включающий в себя формирование пленки покрытия из органической смолы на поверхности стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав.
6. Способ по п. 5, в котором:
органическая смола, содержащаяся в пленке покрытия из органической смолы, является смолой на основе уретана, полученной путем реакции многоатомных спиртов, состоящих из многоатомного спирта на основе эфира и многоатомного спирта на
основе сложного эфира, с полиизоцианатом,
причем доля многоатомного спирта на основе эфира в многоатомных спиртах составляет от 5 масc.% до 30 масc.%.
7. Способ по п. 6, в котором пленка покрытия из органической смолы дополнительно включает в себя поливалентный фенол.
8. Способ по п. 5, в котором пленка покрытия из органической смолы включает в себя смазку.
9. Способ по п. 5, в котором пленка покрытия из органической смолы включает в себя одно или более соединений, выбранных из группы, состоящей из оксида вентильного металла, оксоата вентильного металла, гидроксида вентильного металла, фосфата вентильного металла и фторида вентильного металла.
10. Способ для по п. 9, в котором вентильный металл является одним или более металлами, выбранными из группы, состоящей из титана, циркония, гафния, ванадия, ниобия, тантала, вольфрама, кремния и алюминия.
11. Способ по п. 5, в котором пленка покрытия из органической смолы является слоем ламината или слоем покрытия.
12. Способ по п. 5, в котором пленка покрытия из органической смолы является прозрачной пленкой покрытия.
13. Способ производства формованного изделия из стального листа с черным покрытием, включающий в себя:
обеспечение стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав, который включает в себя полученный способом погружения в расплав слой содержащего алюминий и магний цинкового покрытия, содержащий 0,1 масc.% или более и 22,0 масc.% или менее алюминия и 0,1 масc.% или более и менее 1,5 масc.% магния;
контактирование стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав, с водяным паром в замкнутом сосуде; и
формование стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав, до или после контактирования стального листа с содержащим алюминий и магний цинковым покрытием, полученным способом погружения в расплав, с водяным паром, причем:
концентрация кислорода в замкнутом сосуде составляет 13% или менее.
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