RU2013146326A - Ускоритель отверждения смол - Google Patents
Ускоритель отверждения смол Download PDFInfo
- Publication number
- RU2013146326A RU2013146326A RU2013146326/05A RU2013146326A RU2013146326A RU 2013146326 A RU2013146326 A RU 2013146326A RU 2013146326/05 A RU2013146326/05 A RU 2013146326/05A RU 2013146326 A RU2013146326 A RU 2013146326A RU 2013146326 A RU2013146326 A RU 2013146326A
- Authority
- RU
- Russia
- Prior art keywords
- compound
- accelerator
- component
- phosphorus
- resin composition
- Prior art date
Links
- 239000011347 resin Substances 0.000 title claims abstract 3
- 229920005989 resin Polymers 0.000 title claims abstract 3
- 150000001875 compounds Chemical class 0.000 claims abstract 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract 8
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract 8
- 239000011574 phosphorus Substances 0.000 claims abstract 8
- 239000011342 resin composition Substances 0.000 claims abstract 8
- 150000002978 peroxides Chemical class 0.000 claims abstract 6
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000003513 alkali Substances 0.000 claims abstract 4
- 239000002585 base Substances 0.000 claims abstract 4
- 229910017052 cobalt Inorganic materials 0.000 claims abstract 4
- 239000010941 cobalt Substances 0.000 claims abstract 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims abstract 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract 4
- 239000010452 phosphate Substances 0.000 claims abstract 4
- 239000002904 solvent Substances 0.000 claims abstract 4
- 239000010936 titanium Substances 0.000 claims abstract 4
- 229910052719 titanium Inorganic materials 0.000 claims abstract 4
- 229910052723 transition metal Inorganic materials 0.000 claims abstract 4
- 150000003624 transition metals Chemical class 0.000 claims abstract 4
- 150000001339 alkali metal compounds Chemical class 0.000 claims abstract 3
- 150000001341 alkaline earth metal compounds Chemical class 0.000 claims abstract 3
- 150000002432 hydroperoxides Chemical class 0.000 claims abstract 2
- -1 ketone peroxides Chemical class 0.000 claims abstract 2
- 150000004978 peroxycarbonates Chemical class 0.000 claims abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/241—Preventing premature crosslinking by physical separation of components, e.g. encapsulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/248—Measuring crosslinking reactions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/11—Compounds containing metals of Groups 4 to 10 or of Groups 14 to 16 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
Abstract
1. Раствор ускорителя, подходящий для использования при получении окислительно-восстановительной системы совместно с пероксидами, содержащий соединение Cu(I), переходный металл, выбираемый из кобальта и титана, фосфорсодержащее соединение, азотсодержащее основание и гидроксифункциональный растворитель.2. Раствор ускорителя по п. 1, где фосфорсодержащее соединение представляет собой диалкилфосфат.3. Раствор ускорителя по любому из предшествующих пунктов, дополнительно содержащий соединение щелочного или щелочноземельного металла и/или 1,3-дикетон.4. Композиция смолы, предварительно подвергнутая воздействию ускорителя, содержащая отверждаемую смолу, соединение Cu(I); переходный металл, выбираемый из кобальта и титана, фосфорсодержащее соединение, азотсодержащее основание и гидроксифункциональный растворитель.5. Композиция смолы, предварительно подвергнутая воздействию ускорителя, по п. 4, где фосфорсодержащее соединение представляет собой диалкилфосфат.6. Композиция смолы, предварительно подвергнутая воздействию ускорителя, по п. 4 или 5, дополнительно содержащая соединение щелочного или щелочноземельного металла и/или 1,3-дикетон.7. Двухкомпонентная композиция, содержащая первый компонент и второй компонент, при этом первый компонент содержит композицию смолы, предварительно подвергнутой воздействию ускорителя, по любому из пп. 4-6, а второй компонент содержит пероксид.8. Двухкомпонентная композиция по п. 7, где пероксид выбирают из группы, состоящей из органических гидропероксидов, кетонпероксидов, пероксикарбонатов и сложных пероксиэфиров.
Claims (8)
1. Раствор ускорителя, подходящий для использования при получении окислительно-восстановительной системы совместно с пероксидами, содержащий соединение Cu(I), переходный металл, выбираемый из кобальта и титана, фосфорсодержащее соединение, азотсодержащее основание и гидроксифункциональный растворитель.
2. Раствор ускорителя по п. 1, где фосфорсодержащее соединение представляет собой диалкилфосфат.
3. Раствор ускорителя по любому из предшествующих пунктов, дополнительно содержащий соединение щелочного или щелочноземельного металла и/или 1,3-дикетон.
4. Композиция смолы, предварительно подвергнутая воздействию ускорителя, содержащая отверждаемую смолу, соединение Cu(I); переходный металл, выбираемый из кобальта и титана, фосфорсодержащее соединение, азотсодержащее основание и гидроксифункциональный растворитель.
5. Композиция смолы, предварительно подвергнутая воздействию ускорителя, по п. 4, где фосфорсодержащее соединение представляет собой диалкилфосфат.
6. Композиция смолы, предварительно подвергнутая воздействию ускорителя, по п. 4 или 5, дополнительно содержащая соединение щелочного или щелочноземельного металла и/или 1,3-дикетон.
7. Двухкомпонентная композиция, содержащая первый компонент и второй компонент, при этом первый компонент содержит композицию смолы, предварительно подвергнутой воздействию ускорителя, по любому из пп. 4-6, а второй компонент содержит пероксид.
8. Двухкомпонентная композиция по п. 7, где пероксид выбирают из группы, состоящей из органических гидропероксидов, кетонпероксидов, пероксикарбонатов и сложных пероксиэфиров.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11159562.5 | 2011-03-24 | ||
| EP11159562 | 2011-03-24 | ||
| US201161467516P | 2011-03-25 | 2011-03-25 | |
| US61/467,516 | 2011-03-25 | ||
| PCT/EP2012/054932 WO2012126918A1 (en) | 2011-03-24 | 2012-03-21 | Accelerator for curing resins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2013146326A true RU2013146326A (ru) | 2015-04-27 |
| RU2599287C2 RU2599287C2 (ru) | 2016-10-10 |
Family
ID=44303664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2013146326/05A RU2599287C2 (ru) | 2011-03-24 | 2012-03-21 | Ускоритель отверждения смол |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US9255196B2 (ru) |
| EP (1) | EP2688949B1 (ru) |
| JP (1) | JP5764253B2 (ru) |
| KR (1) | KR101898146B1 (ru) |
| CN (1) | CN103443185B (ru) |
| AU (1) | AU2012230374B2 (ru) |
| BR (1) | BR112013023687A2 (ru) |
| CA (1) | CA2828083C (ru) |
| DK (1) | DK2688949T3 (ru) |
| ES (1) | ES2542780T3 (ru) |
| IL (1) | IL228074A (ru) |
| MX (1) | MX336192B (ru) |
| MY (1) | MY163170A (ru) |
| PL (1) | PL2688949T3 (ru) |
| RU (1) | RU2599287C2 (ru) |
| SI (1) | SI2688949T1 (ru) |
| TW (1) | TWI548658B (ru) |
| WO (1) | WO2012126918A1 (ru) |
| ZA (1) | ZA201306756B (ru) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9255196B2 (en) * | 2011-03-24 | 2016-02-09 | Akzo Nobel Chemicals International B.V. | Accelerator for curing resins |
| TWI439451B (zh) * | 2011-03-24 | 2014-06-01 | Hoffmann La Roche | 雜環胺衍生物 |
| CA2881505C (en) | 2012-08-29 | 2020-04-14 | Akzo Nobel Chemicals International B.V. | Iron-based accelerator for curing resins |
| KR102054967B1 (ko) * | 2012-12-28 | 2019-12-12 | 삼성전기주식회사 | 절연 재료, 이를 포함하는 절연층 조성물, 및 상기 절연층 조성물을 이용한 기판 |
| DK2951233T3 (en) * | 2013-01-29 | 2017-03-13 | Akzo Nobel Chemicals Int Bv | PROCEDURE FOR MANUFACTURING FIBER REINFORCED COMPOSITION MATERIAL |
| US9068045B2 (en) | 2013-04-05 | 2015-06-30 | Reichhold, Inc. | Curing of liquid thermosetting resins |
| KR101987305B1 (ko) * | 2013-11-19 | 2019-06-10 | 삼성전기주식회사 | 인쇄회로기판용 절연 수지 조성물 및 이를 이용한 제품 |
| KR101987310B1 (ko) * | 2013-12-16 | 2019-06-10 | 삼성전기주식회사 | 인쇄회로기판용 절연 수지조성물 및 이를 이용한 제품 |
| AR099141A1 (es) * | 2014-02-11 | 2016-06-29 | Akzo Nobel Chemicals Int Bv | Proceso para el curado de una resina de poliéster insaturado o resina de éster de vinilo que contiene (met)acrilato y composición de resina curable radicalmente resultante |
| US10000602B2 (en) | 2014-10-02 | 2018-06-19 | Reichhold Llc 2 | Curable compositions |
| CN106240088A (zh) * | 2016-07-27 | 2016-12-21 | 重庆德凯实业股份有限公司 | 无卤素覆铜板的制备方法 |
| EP3555018A4 (en) | 2016-12-14 | 2020-05-27 | Arkema France | VACUUM REGULATION COMPOSITION FOR POLYMERIZATION OF CARBONYL CONTAINING MONOMERS |
| CA3091340A1 (en) * | 2018-02-19 | 2019-08-22 | Arkema Inc. | Accelerator solutions useful for resin curing |
| CA3091005A1 (en) | 2018-02-19 | 2019-08-22 | Arkema Inc. | Accelerated peroxide-cured resin compositions having extended open times |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA994937A (en) | 1974-02-25 | 1976-08-10 | Air Products And Chemicals | Metal-amine complex accelerator for polyester resin curing |
| JPS5934725B2 (ja) | 1977-04-27 | 1984-08-24 | 株式会社日本触媒 | 不飽和ポリエステル樹脂組成物 |
| JPS55149314A (en) * | 1979-05-09 | 1980-11-20 | Nippon Mining Co Ltd | Cure promoting method for unsaturated polyester resin |
| US4309511A (en) * | 1979-06-04 | 1982-01-05 | Air Products And Chemicals, Inc. | Process for promoting the low temperature cure of polyester resins |
| DE3025222A1 (de) * | 1980-07-03 | 1982-01-28 | Bayer Ag, 5090 Leverkusen | Bei raumtemperatur haertbare ungesaettigte polyesterharzmassen, verfahren zu ihrer haertung und daraus hergestellte formkoerper |
| JPS57147509A (en) * | 1981-03-09 | 1982-09-11 | Nippon Kagaku Sangyo Kk | Cure accelerator for unsaturated polyester resin |
| US4607082A (en) * | 1982-09-09 | 1986-08-19 | Three Bond Co., Ltd. | Catalyst systems and adhesion promoter for two-pack acrylic adhesive formulations |
| DE3244814A1 (de) | 1982-12-03 | 1984-06-07 | Bayer Ag, 5090 Leverkusen | Verwendung von 1.4-dihydroxynaphthalin bei der polymerisation ethylenisch ungesaettigter verbindungen |
| IT1232850B (it) | 1989-04-26 | 1992-03-05 | Saint Peter Srl | Acceleranti per l'indurimento di resine poliesteri insature, maleiche, alliliche ed epossidiche e procedimenti di indurimento che li utlizzano |
| CN101027349A (zh) * | 2004-09-28 | 2007-08-29 | 阿克佐诺贝尔股份有限公司 | 包含钴促进剂和配位化合物的含水不饱和聚酯树脂的固化 |
| JP4831980B2 (ja) | 2005-02-25 | 2011-12-07 | 富士フイルム株式会社 | セルロースエステルフィルム、偏光板、液晶表示装置、およびセルロースエステルフィルムの製造方法 |
| PL1899386T3 (pl) | 2005-05-31 | 2011-09-30 | Akzo Nobel Chemicals Int Bv | Roztwór przyspieszacza trwały podczas przechowywania |
| ES1063481Y (es) | 2006-07-03 | 2007-03-01 | Saez Rosanna Pastor | Protector para pies |
| WO2008003500A1 (en) | 2006-07-06 | 2008-01-10 | Dsm Ip Assets B.V. | Unsaturated polyester resin compositions |
| CN101484516B (zh) | 2006-07-06 | 2012-07-04 | 帝斯曼知识产权资产管理有限公司 | 不饱和聚酯树脂或乙烯基酯树脂组合物 |
| WO2008003501A1 (en) * | 2006-07-06 | 2008-01-10 | Dsm Ip Assets B.V. | Unsaturated polyester resin compositions |
| ES2364590T3 (es) | 2006-07-06 | 2011-09-07 | Dsm Ip Assets B.V. | Composiciones de resina poliéster insaturada o resina de vinil-éster. |
| CN103172800B (zh) | 2006-07-06 | 2016-04-20 | 帝斯曼知识产权资产管理有限公司 | 不饱和聚酯树脂或乙烯基酯树脂组合物 |
| KR101538413B1 (ko) | 2007-04-02 | 2015-07-22 | 아크조 노벨 엔.브이. | 촉진 용액 |
| EP2343336A1 (en) | 2010-01-06 | 2011-07-13 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Curing liquids |
| US9034785B2 (en) | 2010-06-16 | 2015-05-19 | Akzo Nobel Chemicals International B.V. | Accelerator solution and process for curing curable resins |
| US9255196B2 (en) * | 2011-03-24 | 2016-02-09 | Akzo Nobel Chemicals International B.V. | Accelerator for curing resins |
| CA2881505C (en) | 2012-08-29 | 2020-04-14 | Akzo Nobel Chemicals International B.V. | Iron-based accelerator for curing resins |
-
2012
- 2012-03-21 US US14/005,697 patent/US9255196B2/en not_active Expired - Fee Related
- 2012-03-21 CA CA2828083A patent/CA2828083C/en not_active Expired - Fee Related
- 2012-03-21 EP EP20120709333 patent/EP2688949B1/en active Active
- 2012-03-21 SI SI201230270T patent/SI2688949T1/sl unknown
- 2012-03-21 DK DK12709333.4T patent/DK2688949T3/en active
- 2012-03-21 AU AU2012230374A patent/AU2012230374B2/en not_active Ceased
- 2012-03-21 ES ES12709333.4T patent/ES2542780T3/es active Active
- 2012-03-21 RU RU2013146326/05A patent/RU2599287C2/ru not_active IP Right Cessation
- 2012-03-21 JP JP2014500356A patent/JP5764253B2/ja not_active Expired - Fee Related
- 2012-03-21 WO PCT/EP2012/054932 patent/WO2012126918A1/en active Application Filing
- 2012-03-21 PL PL12709333T patent/PL2688949T3/pl unknown
- 2012-03-21 MX MX2013010683A patent/MX336192B/es unknown
- 2012-03-21 MY MYPI2013701671A patent/MY163170A/en unknown
- 2012-03-21 CN CN201280012256.3A patent/CN103443185B/zh not_active Expired - Fee Related
- 2012-03-21 KR KR1020137027045A patent/KR101898146B1/ko active IP Right Grant
- 2012-03-23 TW TW101110248A patent/TWI548658B/zh not_active IP Right Cessation
-
2013
- 2013-03-21 BR BR112013023687A patent/BR112013023687A2/pt active Search and Examination
- 2013-08-22 IL IL228074A patent/IL228074A/en not_active IP Right Cessation
- 2013-09-09 ZA ZA2013/06756A patent/ZA201306756B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA201306756B (en) | 2015-05-27 |
| IL228074A (en) | 2016-12-29 |
| EP2688949A1 (en) | 2014-01-29 |
| US20140005343A1 (en) | 2014-01-02 |
| ES2542780T3 (es) | 2015-08-11 |
| JP5764253B2 (ja) | 2015-08-19 |
| KR101898146B1 (ko) | 2018-09-12 |
| BR112013023687A2 (pt) | 2016-12-13 |
| TWI548658B (zh) | 2016-09-11 |
| MX2013010683A (es) | 2013-10-03 |
| PL2688949T3 (pl) | 2015-10-30 |
| RU2599287C2 (ru) | 2016-10-10 |
| CN103443185A (zh) | 2013-12-11 |
| MY163170A (en) | 2017-08-15 |
| KR20140015471A (ko) | 2014-02-06 |
| TW201245255A (en) | 2012-11-16 |
| AU2012230374B2 (en) | 2015-10-08 |
| IL228074A0 (en) | 2013-09-30 |
| AU2012230374A1 (en) | 2013-09-12 |
| CA2828083A1 (en) | 2012-09-27 |
| US9255196B2 (en) | 2016-02-09 |
| MX336192B (es) | 2016-01-11 |
| CA2828083C (en) | 2019-04-30 |
| SI2688949T1 (sl) | 2015-09-30 |
| WO2012126918A1 (en) | 2012-09-27 |
| EP2688949B1 (en) | 2015-05-06 |
| DK2688949T3 (en) | 2015-08-17 |
| JP2014515769A (ja) | 2014-07-03 |
| CN103443185B (zh) | 2015-06-10 |
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