RU2013142949A - Выхлопная система, содержащая катализатор восстановления nox и контур рециркуляции выхлопных газов - Google Patents

Выхлопная система, содержащая катализатор восстановления nox и контур рециркуляции выхлопных газов Download PDF

Info

Publication number
RU2013142949A
RU2013142949A RU2013142949/06A RU2013142949A RU2013142949A RU 2013142949 A RU2013142949 A RU 2013142949A RU 2013142949/06 A RU2013142949/06 A RU 2013142949/06A RU 2013142949 A RU2013142949 A RU 2013142949A RU 2013142949 A RU2013142949 A RU 2013142949A
Authority
RU
Russia
Prior art keywords
exhaust system
adsorbent
reducing agent
oxide
filter
Prior art date
Application number
RU2013142949/06A
Other languages
English (en)
Other versions
RU2584084C2 (ru
Inventor
Гай Ричард ЧЭНДЛЕР
Александр Николас Майкл ГРИН
Стюарт Дэвид РИД
Original Assignee
Джонсон Мэтти Паблик Лимитед Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Джонсон Мэтти Паблик Лимитед Компани filed Critical Джонсон Мэтти Паблик Лимитед Компани
Publication of RU2013142949A publication Critical patent/RU2013142949A/ru
Application granted granted Critical
Publication of RU2584084C2 publication Critical patent/RU2584084C2/ru

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9422—Processes characterised by a specific catalyst for removing nitrogen oxides by NOx storage or reduction by cyclic switching between lean and rich exhaust gases (LNT, NSC, NSR)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1021—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2065—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/40—Mixed oxides
    • B01D2255/407—Zr-Ce mixed oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/91—NOx-storage component incorporated in the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/915—Catalyst supported on particulate filters
    • B01D2255/9155—Wall flow filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/404—Nitrogen oxides other than dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/02—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
    • F01N2560/026—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting NOx
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/18—Ammonia
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/105—General auxiliary catalysts, e.g. upstream or downstream of the main catalyst
    • F01N3/106—Auxiliary oxidation catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066—Selective catalytic reduction [SCR]
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
    • F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
    • F02M26/35—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with means for cleaning or treating the recirculated gases, e.g. catalysts, condensate traps, particle filters or heaters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Organic Chemistry (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust-Gas Circulating Devices (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Processes For Solid Components From Exhaust (AREA)

Abstract

1. Выхлопная система для автомобильного двигателя внутреннего сгорания, работающего на бедных смесях, который выделяет оксиды азота (NO) и твердые частицы (PM), причем система содержит катализатор восстановления NOдля восстановления NOв присутствии восстановителя, устройство для введения восстановителя в поток выхлопного газа и источник восстановителя, выбранный из группы, состоящей из углеводородного восстановителя, азотсодержащего восстановителя, водорода и смесей любых двух и более из них, фильтр для удаления PM из выхлопного газа, протекающего в выхлопной системе, и контур рециркуляции выхлопного газа (EGR) низкого давления для соединения выхлопной системы ниже по потоку относительно фильтра с воздухозаборником двигателя, причем контур EGR содержит катализатор-адсорбент NO(NAC), содержащий адсорбент оксида азота (NO).2. Выхлопная система по п. 1, в которой адсорбент NO состоит из палладия и оксида церия, или смешанного оксида, или композитного оксида, содержащего церий и по меньшей мере один другой переходный металл.3. Выхлопная система по п. 2, в которой по меньшей мере один другой переходный металл в смешанном оксиде или композитном оксиде представляет собой цирконий.4. Выхлопная система по п. 1, 2 или 3, в которой адсорбент NO имеет содержание палладия от 0,1 до 200 г/фут(0,0035-7,1 г/л).5. Выхлопная система по п. 1, 2 или 3, в которой адсорбент NO комбинируется с термически регенерируемым адсорбентом NOдля прямой адсорбции NOпри температуре выше 200°C и прямой десорбции NOпри температуре выше 250°C, причем термически регенерируемый абсорбент NOсодержит платину и оксид металла.6. Выхлопная система по п. 5, в которой термически регенерируемый а�

Claims (15)

1. Выхлопная система для автомобильного двигателя внутреннего сгорания, работающего на бедных смесях, который выделяет оксиды азота (NOx) и твердые частицы (PM), причем система содержит катализатор восстановления NOx для восстановления NOx в присутствии восстановителя, устройство для введения восстановителя в поток выхлопного газа и источник восстановителя, выбранный из группы, состоящей из углеводородного восстановителя, азотсодержащего восстановителя, водорода и смесей любых двух и более из них, фильтр для удаления PM из выхлопного газа, протекающего в выхлопной системе, и контур рециркуляции выхлопного газа (EGR) низкого давления для соединения выхлопной системы ниже по потоку относительно фильтра с воздухозаборником двигателя, причем контур EGR содержит катализатор-адсорбент NOx (NAC), содержащий адсорбент оксида азота (NO).
2. Выхлопная система по п. 1, в которой адсорбент NO состоит из палладия и оксида церия, или смешанного оксида, или композитного оксида, содержащего церий и по меньшей мере один другой переходный металл.
3. Выхлопная система по п. 2, в которой по меньшей мере один другой переходный металл в смешанном оксиде или композитном оксиде представляет собой цирконий.
4. Выхлопная система по п. 1, 2 или 3, в которой адсорбент NO имеет содержание палладия от 0,1 до 200 г/фут3 (0,0035-7,1 г/л).
5. Выхлопная система по п. 1, 2 или 3, в которой адсорбент NO комбинируется с термически регенерируемым адсорбентом NOx для прямой адсорбции NOx при температуре выше 200°C и прямой десорбции NOx при температуре выше 250°C, причем термически регенерируемый абсорбент NOx содержит платину и оксид металла.
6. Выхлопная система по п. 5, в которой термически регенерируемый абсорбент NOx содержит платину, диспергированную на оксиде алюминия и/или диоксиде циркония.
7. Выхлопная система по п. 5, в которой адсорбент NO находится в нижележащем слое, а термически регенерируемый абсорбент NOx находится в слое, перекрывающем нижележащий слой.
8. Выхлопная система по п. 1, 2 или 3, в которой катализатор восстановления NOx находится ниже по потоку относительно фильтра.
9. Выхлопная система по п. 8, в которой устройство для введения восстановителя в поток выхлопного газа находится между фильтром и катализатором восстановления NOx.
10. Выхлопная система по п. 1, 2 или 3, в которой катализатор восстановления NOx находится на фильтре.
11. Выхлопная система по п. 10, в которой устройство для введения восстановителя в поток выхлопного газа находится ниже по потоку относительно фильтра.
12. Выхлопная система по п. 1, 2 или 3, содержащая катализатор окисления для окисления NO до диоксида азота, находящийся выше по потоку относительно фильтра и/или катализатора восстановления NOx.
13. Выхлопная система п. 1, 2 или 3, в которой катализатор
восстановления NOx селективно катализирует восстановление NOx с использованием азотсодержащего восстановителя.
14. Выхлопная система по п. 13, в которой азотсодержащий восстановитель представляет собой аммиак, гидразин или прекурсор аммиака, выбранный из группы, состоящей из мочевины ((NH2)2CO), карбоната аммония, карбамата аммония, гидрокарбоната аммония и формиата аммония.
15. Двигатель внутреннего сгорания, работающий на бедных смесях, содержащий выхлопную систему по п. 1.
RU2013142949/06A 2011-02-21 2012-02-21 ВЫХЛОПНАЯ СИСТЕМА, СОДЕРЖАЩАЯ КАТАЛИЗАТОР ВОССТАНОВЛЕНИЯ NOx И КОНТУР РЕЦИРКУЛЯЦИИ ВЫХЛОПНЫХ ГАЗОВ RU2584084C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161444881P 2011-02-21 2011-02-21
US61/444,881 2011-02-21
PCT/IB2012/000308 WO2012114187A2 (en) 2011-02-21 2012-02-21 Exhaust system including nox reduction catalyst and egr circuit

Publications (2)

Publication Number Publication Date
RU2013142949A true RU2013142949A (ru) 2015-03-27
RU2584084C2 RU2584084C2 (ru) 2016-05-20

Family

ID=45878974

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2013142949/06A RU2584084C2 (ru) 2011-02-21 2012-02-21 ВЫХЛОПНАЯ СИСТЕМА, СОДЕРЖАЩАЯ КАТАЛИЗАТОР ВОССТАНОВЛЕНИЯ NOx И КОНТУР РЕЦИРКУЛЯЦИИ ВЫХЛОПНЫХ ГАЗОВ

Country Status (8)

Country Link
US (1) US9464547B2 (ru)
EP (1) EP2678095B1 (ru)
JP (1) JP6300527B2 (ru)
KR (1) KR101926206B1 (ru)
CN (2) CN109026455B (ru)
BR (1) BR112013020884B8 (ru)
RU (1) RU2584084C2 (ru)
WO (1) WO2012114187A2 (ru)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0620883D0 (en) * 2006-10-20 2006-11-29 Johnson Matthey Plc Exhaust system for a lean-burn internal combustion engine
DE102011111590A1 (de) * 2011-08-25 2013-02-28 Volkswagen Aktiengesellschaft Abgasbehandlungseinrichtung, Verfahren zur Aufbereitung von Abgas und Kraftfahrzeug
US20140069086A1 (en) * 2012-09-13 2014-03-13 Leon A. LaPointe Exhaust system for spark-ignited gaseous fuel internal combustion engine
GB2514177A (en) * 2013-05-17 2014-11-19 Johnson Matthey Plc Oxidation catalyst for a compression ignition engine
DE102015102830A1 (de) 2014-02-27 2015-08-27 Johnson Matthey Public Limited Company Abgassystem mit N2O-Katalysator im AGR-Kreislauf
EP3120008B1 (en) 2014-02-27 2018-07-25 Johnson Matthey Public Limited Company Exhaust system having n2o catalyst in egr circuit
US10087803B2 (en) * 2016-08-04 2018-10-02 Ford Global Technologies, Llc Method and system for an exhaust catalyst
WO2018178849A1 (en) 2017-03-28 2018-10-04 Johnson Matthey Public Limited Company Egr urea hydrolysis
BR112019020841A2 (pt) * 2017-04-04 2020-04-28 Basf Corp artigo catalítico de filtro de fluxo de parede monolítico, veículos, sistemas de tratamento de gases de escape e métodos para tratar uma corrente de escape
DK3607178T3 (da) * 2017-04-06 2021-03-15 Umicore Ag & Co Kg Fremgangsmåde og system til fjernelse af skadelige forbindelser fra motorudstødningsgas
CN107939498B (zh) * 2017-10-26 2020-09-22 中车长春轨道客车股份有限公司 一种sscr系统固态还原剂消耗量计算方法
GB2572396A (en) 2018-03-28 2019-10-02 Johnson Matthey Plc Passive NOx adsorber
KR20190127296A (ko) 2018-05-04 2019-11-13 현대자동차주식회사 엔진의 배기조절밸브
CN109821523B (zh) * 2019-01-23 2021-10-08 内蒙古科技大学 一种稀土尾矿基scr催化剂的制备方法及其应用
CN112156646B (zh) * 2020-08-27 2021-06-22 昆明理工大学 一种铜基载氧体前驱体煅烧原位脱硝的分时段进气装置
JP2023540136A (ja) * 2020-09-08 2023-09-21 ビーエーエスエフ コーポレーション 排気ガス水素濃縮を介した触媒の性能強化
CN115013196B (zh) * 2022-04-28 2023-11-03 南通职业大学 一种用于柴油机高压热端egr系统的净化装置及净化方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9226434D0 (en) 1992-12-18 1993-02-10 Johnson Matthey Plc Catalyst
SE521713C2 (sv) * 1998-11-09 2003-12-02 Stt Emtec Ab Förfarande och anordning för ett EGR-system, samt dylik ventil
JP3225957B2 (ja) * 1999-02-02 2001-11-05 トヨタ自動車株式会社 内燃機関
JP3937635B2 (ja) * 1999-03-01 2007-06-27 いすゞ自動車株式会社 排気ガス浄化機能付きｅｇｒクーラー
US6758036B1 (en) * 2000-10-27 2004-07-06 Delphi Technologies, Inc. Method for sulfur protection of NOx adsorber
JP2004060494A (ja) * 2002-07-26 2004-02-26 Toyota Motor Corp 内燃機関の排気浄化装置
US7043901B2 (en) * 2003-03-20 2006-05-16 Ford Global Technologies, Llc Device and method for internal combustion engine control
JP2005240641A (ja) * 2004-02-25 2005-09-08 Toyota Motor Corp 排気浄化触媒の保持構造
JP4799046B2 (ja) * 2005-05-20 2011-10-19 日野自動車株式会社 エンジンの排ガス浄化装置
US7879295B2 (en) * 2005-06-30 2011-02-01 General Electric Company Conversion system for reducing NOx emissions
JP4337809B2 (ja) * 2005-12-09 2009-09-30 トヨタ自動車株式会社 内燃機関の排気浄化システム
JP4715568B2 (ja) * 2006-03-09 2011-07-06 トヨタ自動車株式会社 内燃機関の排気浄化装置
KR100766725B1 (ko) * 2006-05-24 2007-10-12 에스케이에너지 주식회사 배기가스 재순환 라인을 구비한 디젤 엔진의 배기가스 정화장치
US7469531B2 (en) * 2006-09-20 2008-12-30 Gm Global Technology Operations, Inc. Method and apparatus to control injection of a reductant into an exhaust gas feedstream
GB0620883D0 (en) * 2006-10-20 2006-11-29 Johnson Matthey Plc Exhaust system for a lean-burn internal combustion engine
US8407987B2 (en) * 2007-02-21 2013-04-02 Volvo Lastvagnar Ab Control method for controlling an exhaust aftertreatment system and exhaust aftertreatment system
JP5115052B2 (ja) * 2007-06-22 2013-01-09 トヨタ自動車株式会社 ハイブリッド車両の排気浄化装置
JP4730366B2 (ja) * 2007-10-17 2011-07-20 トヨタ自動車株式会社 内燃機関の排気還流装置
US8151558B2 (en) 2008-01-31 2012-04-10 Caterpillar Inc. Exhaust system implementing SCR and EGR
FR2933746A3 (fr) 2008-07-08 2010-01-15 Renault Sas Circuit de recirculation des gaz d'echappement (egr) dit basse pression avec vannage a l'admission du moteur a combustion interne et recuperation de la chaleur dans la ligne d'echappement
JP2010112313A (ja) * 2008-11-07 2010-05-20 Toyota Motor Corp 内燃機関の排気浄化装置
DE102009022938A1 (de) * 2008-12-03 2010-06-10 Audi Ag Brennkraftmaschine mit Abgasturbolader und Nachbehandlung von rückgeführtem Abgas
KR100999646B1 (ko) * 2008-12-05 2010-12-08 현대자동차주식회사 배기가스 재순환 시스템
FR2941499B1 (fr) * 2009-01-27 2011-07-15 Peugeot Citroen Automobiles Sa Moteur a combustion interne comportant un moyen de production d'hydrogene
US8978360B2 (en) * 2009-09-15 2015-03-17 Ford Global Technologies, Llc Hydrocarbon and NOx trap
US8096125B2 (en) * 2009-12-23 2012-01-17 Ford Global Technologies, Llc Methods and systems for emission system control
DE102010050406A1 (de) 2010-11-04 2012-05-10 Daimler Ag Kraftfahrzeug-Brennkraftmaschine und Betriebsverfahren für eine Kraftfahrzeug-Brennkraftmaschine

Also Published As

Publication number Publication date
KR20140020251A (ko) 2014-02-18
JP2014508880A (ja) 2014-04-10
US20130340413A1 (en) 2013-12-26
BR112013020884B8 (pt) 2021-04-06
KR101926206B1 (ko) 2018-12-06
WO2012114187A3 (en) 2012-11-01
BR112013020884A2 (pt) 2016-09-27
JP6300527B2 (ja) 2018-03-28
US9464547B2 (en) 2016-10-11
WO2012114187A2 (en) 2012-08-30
BR112013020884B1 (pt) 2020-12-15
RU2584084C2 (ru) 2016-05-20
CN109026455B (zh) 2021-02-23
CN103402609A (zh) 2013-11-20
EP2678095A2 (en) 2014-01-01
CN109026455A (zh) 2018-12-18
EP2678095B1 (en) 2016-11-02

Similar Documents

Publication Publication Date Title
RU2013142949A (ru) Выхлопная система, содержащая катализатор восстановления nox и контур рециркуляции выхлопных газов
JP2014508880A5 (ru)
RU2009118911A (ru) Термически регенерируемый адсорбент оксидов азота
JP5630024B2 (ja) ディーゼルエンジンの排気浄化装置及び排気浄化方法
US8141352B2 (en) Exhaust purification device of an internal combustion engine
RU2591753C2 (ru) Выхлопная система, содержащая катализатор предотвращения проскока аммиака в контуре рециркуляции выхлопных газов
JP2010507480A5 (ru)
RU2011132163A (ru) Синергические конфигурации scr/doc для снижения выбросов дизельного двигателя
JP5630025B2 (ja) ディーゼルエンジンの排気浄化装置及び排気浄化方法
ATE480700T1 (de) Anordnung zur verminderung von stickoxiden in abgasen
WO2013168677A1 (ja) 排気ガス浄化システム及び排気ガス浄化方法
GB2473999A (en) Exhaust system for a lean burn ic engine
RU2014128568A (ru) Монолитная подложка с катализатором scr
JP2013241859A (ja) 排気ガス浄化システム及び排気ガス浄化方法
RU2018146947A (ru) Ванадиевые катализаторы для систем двигателей с высокими уровнями выбросов no2
ES2661672T3 (es) Dispositivo de purificación de gases de escape para motor de combustión interna
GB2478638A (en) Exhaust system comprising NOx storage catalyst and CSF
JP2014224525A (ja) 定置式のリッチバーンエンジンの中で同時に排出物を制御するための後処理システム
GB201009775D0 (en) Method of treating nitrogen oxides and/or particulate matter in lean gas
WO2008022751A3 (de) Verfahren zum betreiben einer abgasreinigungsanlage an einem mager betriebenen ottomotor
JP2020045860A (ja) 排ガス浄化装置
JP2003286827A (ja) 内燃機関の排気浄化装置
JP2012087703A (ja) 内燃機関の排気処理装置
JP2020045861A (ja) 排ガス浄化装置
JP2020045862A (ja) 排ガス浄化装置