RU2013115633A - Способ получения полиэфирных карбонатных полиолов - Google Patents
Способ получения полиэфирных карбонатных полиолов Download PDFInfo
- Publication number
- RU2013115633A RU2013115633A RU2013115633/04A RU2013115633A RU2013115633A RU 2013115633 A RU2013115633 A RU 2013115633A RU 2013115633/04 A RU2013115633/04 A RU 2013115633/04A RU 2013115633 A RU2013115633 A RU 2013115633A RU 2013115633 A RU2013115633 A RU 2013115633A
- Authority
- RU
- Russia
- Prior art keywords
- metal cyanide
- double metal
- methyl
- zinc
- alkylene oxides
- Prior art date
Links
- -1 CARBONATE POLYOLS Chemical class 0.000 title claims abstract 8
- 229920000728 polyester Polymers 0.000 title claims abstract 3
- 229920005862 polyol Polymers 0.000 title claims abstract 3
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 229910052751 metal Inorganic materials 0.000 claims abstract 24
- 239000002184 metal Substances 0.000 claims abstract 24
- 239000003054 catalyst Substances 0.000 claims abstract 19
- 238000000034 method Methods 0.000 claims abstract 19
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims abstract 18
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract 12
- 125000002947 alkylene group Chemical group 0.000 claims abstract 12
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 claims abstract 11
- 239000007858 starting material Substances 0.000 claims abstract 10
- 230000000536 complexating effect Effects 0.000 claims abstract 8
- 239000003446 ligand Substances 0.000 claims abstract 8
- HNVRRHSXBLFLIG-UHFFFAOYSA-N 3-hydroxy-3-methylbut-1-ene Chemical compound CC(C)(O)C=C HNVRRHSXBLFLIG-UHFFFAOYSA-N 0.000 claims abstract 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract 6
- 239000001569 carbon dioxide Substances 0.000 claims abstract 6
- ZSPTYLOMNJNZNG-UHFFFAOYSA-N 3-Buten-1-ol Chemical compound OCCC=C ZSPTYLOMNJNZNG-UHFFFAOYSA-N 0.000 claims abstract 4
- 150000001298 alcohols Chemical class 0.000 claims abstract 4
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims abstract 4
- OTJZCIYGRUNXTP-UHFFFAOYSA-N but-3-yn-1-ol Chemical compound OCCC#C OTJZCIYGRUNXTP-UHFFFAOYSA-N 0.000 claims abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 4
- QXLPXWSKPNOQLE-UHFFFAOYSA-N methylpentynol Chemical compound CCC(C)(O)C#C QXLPXWSKPNOQLE-UHFFFAOYSA-N 0.000 claims abstract 4
- BZAZNULYLRVMSW-UHFFFAOYSA-N 2-Methyl-2-buten-3-ol Natural products CC(C)=C(C)O BZAZNULYLRVMSW-UHFFFAOYSA-N 0.000 claims abstract 3
- CEBKHWWANWSNTI-UHFFFAOYSA-N 2-methylbut-3-yn-2-ol Chemical compound CC(C)(O)C#C CEBKHWWANWSNTI-UHFFFAOYSA-N 0.000 claims abstract 3
- HFYAEUXHCMTPOL-UHFFFAOYSA-N 3-Methyl-1-penten-3-ol Chemical compound CCC(C)(O)C=C HFYAEUXHCMTPOL-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000005843 halogen group Chemical group 0.000 claims abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 2
- 239000001257 hydrogen Substances 0.000 claims abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims 9
- 230000004913 activation Effects 0.000 claims 6
- 239000007864 aqueous solution Substances 0.000 claims 6
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 claims 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims 6
- 238000006243 chemical reaction Methods 0.000 claims 4
- 238000007334 copolymerization reaction Methods 0.000 claims 4
- 238000001035 drying Methods 0.000 claims 4
- 150000003839 salts Chemical class 0.000 claims 4
- 239000007787 solid Substances 0.000 claims 3
- 229940102001 zinc bromide Drugs 0.000 claims 3
- 239000011592 zinc chloride Substances 0.000 claims 3
- 235000005074 zinc chloride Nutrition 0.000 claims 3
- SZAVHWMCBDFDCM-KTTJZPQESA-N cobalt-60(3+);hexacyanide Chemical compound [60Co+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] SZAVHWMCBDFDCM-KTTJZPQESA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims 2
- AWDBHOZBRXWRKS-UHFFFAOYSA-N tetrapotassium;iron(6+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] AWDBHOZBRXWRKS-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 claims 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 claims 1
- 229910021575 Iron(II) bromide Inorganic materials 0.000 claims 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims 1
- INDBQWVYFLTCFF-UHFFFAOYSA-L cobalt(2+);dithiocyanate Chemical compound [Co+2].[S-]C#N.[S-]C#N INDBQWVYFLTCFF-UHFFFAOYSA-L 0.000 claims 1
- RKBAPHPQTADBIK-UHFFFAOYSA-N cobalt;hexacyanide Chemical compound [Co].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] RKBAPHPQTADBIK-UHFFFAOYSA-N 0.000 claims 1
- 230000008021 deposition Effects 0.000 claims 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims 1
- GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 229910001428 transition metal ion Inorganic materials 0.000 claims 1
- 239000004246 zinc acetate Substances 0.000 claims 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 claims 1
- NHXVNEDMKGDNPR-UHFFFAOYSA-N zinc;pentane-2,4-dione Chemical compound [Zn+2].CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O NHXVNEDMKGDNPR-UHFFFAOYSA-N 0.000 claims 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 1
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
- C08G64/183—Block or graft polymers containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyethers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010040517A DE102010040517A1 (de) | 2010-09-09 | 2010-09-09 | Verfahren zur Herstellung von Polyetherpolyolen |
| DE102010040517.5 | 2010-09-09 | ||
| PCT/EP2011/065364 WO2012032028A1 (de) | 2010-09-09 | 2011-09-06 | Verfahren zur herstellung von polyethercarbonatpolyolen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2013115633A true RU2013115633A (ru) | 2014-10-20 |
Family
ID=44653291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2013115633/04A RU2013115633A (ru) | 2010-09-09 | 2011-09-06 | Способ получения полиэфирных карбонатных полиолов |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9045592B2 (enExample) |
| EP (1) | EP2614102B1 (enExample) |
| JP (1) | JP5792310B2 (enExample) |
| KR (1) | KR20130102588A (enExample) |
| CN (1) | CN103189417B (enExample) |
| BR (1) | BR112013005783A2 (enExample) |
| CA (1) | CA2810559A1 (enExample) |
| DE (1) | DE102010040517A1 (enExample) |
| ES (1) | ES2506440T3 (enExample) |
| MX (1) | MX2013002484A (enExample) |
| RU (1) | RU2013115633A (enExample) |
| SG (1) | SG188278A1 (enExample) |
| WO (1) | WO2012032028A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2548908A1 (de) * | 2011-07-18 | 2013-01-23 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyetherpolyolen |
| WO2014198689A1 (de) * | 2013-06-13 | 2014-12-18 | Bayer Materialscience Ag | Polyethercarbonat-polyoxymethylen-block-copolymere |
| EP2837648A1 (en) | 2013-08-12 | 2015-02-18 | Repsol, S.A. | Process for preparing polyether carbonate polyols |
| EP2845871A1 (de) * | 2013-09-05 | 2015-03-11 | Bayer MaterialScience AG | Vernetzung von Doppelbindungen enthaltenden Polyethercarbonatpolyolen durch Addition von Mercaptanen |
| EP2865700A1 (de) * | 2013-10-23 | 2015-04-29 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
| US9527958B2 (en) | 2014-05-02 | 2016-12-27 | Covestro Llc | Process for purification of polyether carbonate polyols |
| CN106471040B (zh) * | 2014-07-03 | 2019-05-14 | 科思创德国股份有限公司 | 制备聚醚碳酸酯多元醇的方法 |
| US10119223B2 (en) | 2016-07-15 | 2018-11-06 | Covestro Llc | Carpet and synthetic turf backings prepared from a polyether carbonate polyol |
| US10040903B2 (en) | 2016-09-13 | 2018-08-07 | Covestro Llc | Polymer polyol quality |
| PL3538588T3 (pl) | 2016-11-11 | 2023-04-11 | Dow Global Technologies Llc | Poliole na bazie poliwęglanu |
| GB201703323D0 (en) * | 2017-03-01 | 2017-04-12 | Econic Tech Ltd | Method for preparing polyols |
| CN110964191B (zh) * | 2018-09-29 | 2021-02-02 | 杭州普力材料科技有限公司 | 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法 |
| US20220315698A1 (en) * | 2019-07-31 | 2022-10-06 | Covestro Deutschland Ag | Method for producing polyether carbonate polyols |
| EP4093539B1 (de) * | 2020-01-21 | 2023-10-04 | Covestro Deutschland AG | Verfahren zur herstellung von doppelmetallcyanid-katalysatoren |
| KR102717144B1 (ko) * | 2021-07-15 | 2024-10-11 | 아주대학교산학협력단 | 하이드로젠 헥사시아노코발테이트와 아연 카복실레이트의 조합으로 제조된 더블메탈시아나이드 촉매 및 이를 이용한 프로필렌 옥사이드 중합 |
| WO2023038406A1 (ko) | 2021-09-08 | 2023-03-16 | 주식회사 엘지화학 | 이중 금속 시아나이드 촉매, 이의 제조방법 및 상기 촉매를 이용한 폴리알킬렌 카보네이트의 제조방법 |
| CN114524929B (zh) * | 2021-09-24 | 2023-07-25 | 山东联欣环保科技有限公司 | 一种二氧化碳基四元共聚物的制备方法 |
| WO2023054999A1 (ko) * | 2021-09-29 | 2023-04-06 | 주식회사 엘지화학 | 폴리알킬렌 카보네이트 수지의 제조방법 |
| CN114381252B (zh) * | 2022-01-19 | 2023-02-10 | 成都理工大学 | 一种超高温下耐多价金属阳离子无固相修井液的制备方法 |
| EP4768514A1 (en) | 2024-12-30 | 2026-07-01 | Covestro LLC | POLYOLS, POLYMERS AND PROCESSES FOR THEIR PREPARATION |
| EP4768515A1 (en) | 2024-12-30 | 2026-07-01 | Covestro LLC | POLYOLS, POLYMERS AND PREPARATION PROCESSES |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| JP2653236B2 (ja) | 1990-10-05 | 1997-09-17 | 旭硝子株式会社 | ポリエーテル化合物の製造方法 |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| ID24172A (id) * | 1997-10-13 | 2000-07-13 | Bayer Ag | Katalis logam ganda yang sangat aktif untuk memproduksi poliol-poliol poliester |
| US6376645B1 (en) | 1999-07-09 | 2002-04-23 | The Dow Chemical Company | Complexing agent-modified hexacyanometallate hexanitrometallate catalysts |
| DE19958355A1 (de) | 1999-12-03 | 2001-06-07 | Bayer Ag | Verfahren zur Herstellung von DMC-Katalysatoren |
| WO2001080994A1 (de) | 2000-04-20 | 2001-11-01 | Bayer Aktiengesellschaft | Verfahren zur herstellung von dmc-katalysatoren |
| DE10122019A1 (de) | 2001-05-07 | 2002-11-14 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE10147712A1 (de) | 2001-09-27 | 2003-04-17 | Basf Ag | Verfahren zur Herstellung aliphatischer Polycarbonate |
| US6762278B2 (en) | 2002-02-04 | 2004-07-13 | Basf Corporation | Process for the copolymerization of alkylene oxides and carbon dioxide using suspensions of multi-metal cyanide compounds |
| DE10219028A1 (de) | 2002-04-29 | 2003-11-06 | Bayer Ag | Herstellung und Verwendung von hochmolekularen aliphatischen Polycarbonaten |
| ES2400709T3 (es) * | 2002-11-07 | 2013-04-11 | Dow Global Technologies Inc. | Método para preparar catalizadores de cianuro metálico usando agentes complejantes polimerizables |
| MXPA05009512A (es) | 2003-03-07 | 2006-02-22 | Dow Global Technologies Inc | Proceso continuo y sistema para producir polioles de polieter. |
| US20050101477A1 (en) | 2003-11-07 | 2005-05-12 | George Combs | Unsaturated tertiary alcohols as ligands for active dmc catalysts |
| US20060223973A1 (en) | 2005-03-29 | 2006-10-05 | Basf Corporation | Method of forming a polyethercarbonate polyol |
| US7977501B2 (en) | 2006-07-24 | 2011-07-12 | Bayer Materialscience Llc | Polyether carbonate polyols made via double metal cyanide (DMC) catalysis |
-
2010
- 2010-09-09 DE DE102010040517A patent/DE102010040517A1/de not_active Withdrawn
-
2011
- 2011-09-06 RU RU2013115633/04A patent/RU2013115633A/ru not_active Application Discontinuation
- 2011-09-06 BR BR112013005783A patent/BR112013005783A2/pt unknown
- 2011-09-06 CA CA2810559A patent/CA2810559A1/en not_active Abandoned
- 2011-09-06 JP JP2013527572A patent/JP5792310B2/ja not_active Expired - Fee Related
- 2011-09-06 KR KR1020137008882A patent/KR20130102588A/ko not_active Ceased
- 2011-09-06 MX MX2013002484A patent/MX2013002484A/es active IP Right Grant
- 2011-09-06 CN CN201180043627.XA patent/CN103189417B/zh not_active Expired - Fee Related
- 2011-09-06 SG SG2013013461A patent/SG188278A1/en unknown
- 2011-09-06 WO PCT/EP2011/065364 patent/WO2012032028A1/de not_active Ceased
- 2011-09-06 US US13/821,254 patent/US9045592B2/en active Active
- 2011-09-06 ES ES11757815.3T patent/ES2506440T3/es active Active
- 2011-09-06 EP EP11757815.3A patent/EP2614102B1/de not_active Not-in-force
Also Published As
| Publication number | Publication date |
|---|---|
| JP5792310B2 (ja) | 2015-10-07 |
| EP2614102B1 (de) | 2014-07-23 |
| SG188278A1 (en) | 2013-04-30 |
| CN103189417A (zh) | 2013-07-03 |
| JP2013537245A (ja) | 2013-09-30 |
| ES2506440T3 (es) | 2014-10-13 |
| BR112013005783A2 (pt) | 2017-03-21 |
| EP2614102A1 (de) | 2013-07-17 |
| CA2810559A1 (en) | 2012-03-15 |
| US20130184432A1 (en) | 2013-07-18 |
| MX2013002484A (es) | 2013-04-03 |
| US9045592B2 (en) | 2015-06-02 |
| KR20130102588A (ko) | 2013-09-17 |
| WO2012032028A1 (de) | 2012-03-15 |
| DE102010040517A1 (de) | 2012-03-15 |
| CN103189417B (zh) | 2016-08-03 |
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