CN103189417B - 制备聚醚碳酸酯多元醇的方法 - Google Patents

制备聚醚碳酸酯多元醇的方法 Download PDF

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Publication number
CN103189417B
CN103189417B CN201180043627.XA CN201180043627A CN103189417B CN 103189417 B CN103189417 B CN 103189417B CN 201180043627 A CN201180043627 A CN 201180043627A CN 103189417 B CN103189417 B CN 103189417B
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China
Prior art keywords
alcohol
zinc
mixture
methyl
carbon dioxide
Prior art date
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Expired - Fee Related
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CN201180043627.XA
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English (en)
Chinese (zh)
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CN103189417A (zh
Inventor
C.居特勒
J.霍夫曼
A.沃尔夫
S.格拉泽
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Covestro Deutschland AG
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Covestro Deutschland AG
Bayer Intellectual Property GmbH
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Publication of CN103189417A publication Critical patent/CN103189417A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18—Block or graft polymers
    • C08G64/183—Block or graft polymers containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyethers (AREA)
CN201180043627.XA 2010-09-09 2011-09-06 制备聚醚碳酸酯多元醇的方法 Expired - Fee Related CN103189417B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102010040517A DE102010040517A1 (de) 2010-09-09 2010-09-09 Verfahren zur Herstellung von Polyetherpolyolen
DE102010040517.5 2010-09-09
PCT/EP2011/065364 WO2012032028A1 (de) 2010-09-09 2011-09-06 Verfahren zur herstellung von polyethercarbonatpolyolen

Publications (2)

Publication Number Publication Date
CN103189417A CN103189417A (zh) 2013-07-03
CN103189417B true CN103189417B (zh) 2016-08-03

Family

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Family Applications (1)

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CN201180043627.XA Expired - Fee Related CN103189417B (zh) 2010-09-09 2011-09-06 制备聚醚碳酸酯多元醇的方法

Country Status (13)

Country Link
US (1) US9045592B2 (enExample)
EP (1) EP2614102B1 (enExample)
JP (1) JP5792310B2 (enExample)
KR (1) KR20130102588A (enExample)
CN (1) CN103189417B (enExample)
BR (1) BR112013005783A2 (enExample)
CA (1) CA2810559A1 (enExample)
DE (1) DE102010040517A1 (enExample)
ES (1) ES2506440T3 (enExample)
MX (1) MX2013002484A (enExample)
RU (1) RU2013115633A (enExample)
SG (1) SG188278A1 (enExample)
WO (1) WO2012032028A1 (enExample)

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EP2548908A1 (de) * 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
EP3008100B1 (de) * 2013-06-13 2017-03-15 Covestro Deutschland AG Polyethercarbonat-polyoxymethylen-block-copolymere
EP2837648A1 (en) 2013-08-12 2015-02-18 Repsol, S.A. Process for preparing polyether carbonate polyols
EP2845871A1 (de) * 2013-09-05 2015-03-11 Bayer MaterialScience AG Vernetzung von Doppelbindungen enthaltenden Polyethercarbonatpolyolen durch Addition von Mercaptanen
EP2865700A1 (de) * 2013-10-23 2015-04-29 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
US9527958B2 (en) 2014-05-02 2016-12-27 Covestro Llc Process for purification of polyether carbonate polyols
SG11201610701TA (en) * 2014-07-03 2017-01-27 Covestro Deutschland Ag Method for producing polyether carbonate polyols
US10119223B2 (en) 2016-07-15 2018-11-06 Covestro Llc Carpet and synthetic turf backings prepared from a polyether carbonate polyol
US10040903B2 (en) 2016-09-13 2018-08-07 Covestro Llc Polymer polyol quality
PL3538588T3 (pl) 2016-11-11 2023-04-11 Dow Global Technologies Llc Poliole na bazie poliwęglanu
GB201703323D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyols
CN110964191B (zh) * 2018-09-29 2021-02-02 杭州普力材料科技有限公司 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法
US20220315698A1 (en) * 2019-07-31 2022-10-06 Covestro Deutschland Ag Method for producing polyether carbonate polyols
WO2021148272A1 (de) * 2020-01-21 2021-07-29 Covestro Deutschland Ag Verfahren zur herstellung von doppelmetallcyanid-katalysatoren
KR102717144B1 (ko) * 2021-07-15 2024-10-11 아주대학교산학협력단 하이드로젠 헥사시아노코발테이트와 아연 카복실레이트의 조합으로 제조된 더블메탈시아나이드 촉매 및 이를 이용한 프로필렌 옥사이드 중합
CN117916020A (zh) 2021-09-08 2024-04-19 株式会社Lg化学 双金属氰化物催化剂、制备其的方法和使用其制备聚亚烷基碳酸酯的方法
CN114524929B (zh) * 2021-09-24 2023-07-25 山东联欣环保科技有限公司 一种二氧化碳基四元共聚物的制备方法
CN116848175A (zh) * 2021-09-29 2023-10-03 株式会社Lg化学 制备聚碳酸亚烷基酯树脂的方法
CN114381252B (zh) * 2022-01-19 2023-02-10 成都理工大学 一种超高温下耐多价金属阳离子无固相修井液的制备方法

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CN1628905A (zh) * 2003-11-07 2005-06-22 拜尔材料科学有限责任公司 不饱和叔醇作为配体在活性dmc催化剂中的应用
WO2006103214A1 (en) * 2005-03-29 2006-10-05 Basf Aktiengesellschaft A method of forming a polyethercarbonate polyol

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GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
JP2653236B2 (ja) 1990-10-05 1997-09-17 旭硝子株式会社 ポリエーテル化合物の製造方法
US5158922A (en) 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5482908A (en) 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
CA2306378C (en) 1997-10-13 2007-07-17 Bayer Aktiengesellschaft Crystalline double metal cyanide catalysts for producing polyether polyols
US6376645B1 (en) 1999-07-09 2002-04-23 The Dow Chemical Company Complexing agent-modified hexacyanometallate hexanitrometallate catalysts
DE19958355A1 (de) 1999-12-03 2001-06-07 Bayer Ag Verfahren zur Herstellung von DMC-Katalysatoren
KR100769003B1 (ko) 2000-04-20 2007-10-22 바이엘 악티엔게젤샤프트 이중 금속 시아나이드 (ｄｍｃ) 촉매의 제조 방법
DE10122019A1 (de) 2001-05-07 2002-11-14 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE10147712A1 (de) 2001-09-27 2003-04-17 Basf Ag Verfahren zur Herstellung aliphatischer Polycarbonate
US6762278B2 (en) 2002-02-04 2004-07-13 Basf Corporation Process for the copolymerization of alkylene oxides and carbon dioxide using suspensions of multi-metal cyanide compounds
DE10219028A1 (de) 2002-04-29 2003-11-06 Bayer Ag Herstellung und Verwendung von hochmolekularen aliphatischen Polycarbonaten
BR0315469A (pt) 2002-11-07 2005-08-23 Dow Global Technologies Inc Complexo catalisador, polìmero, método para produzir um catalisador de polimerização e método para produzir um poliéter
KR20050107604A (ko) 2003-03-07 2005-11-14 다우 글로벌 테크놀로지스 인크. 폴리에테르 폴리올을 제조하기 위한 연속식 방법 및 시스템
US7977501B2 (en) * 2006-07-24 2011-07-12 Bayer Materialscience Llc Polyether carbonate polyols made via double metal cyanide (DMC) catalysis

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CN1628905A (zh) * 2003-11-07 2005-06-22 拜尔材料科学有限责任公司 不饱和叔醇作为配体在活性dmc催化剂中的应用
WO2006103214A1 (en) * 2005-03-29 2006-10-05 Basf Aktiengesellschaft A method of forming a polyethercarbonate polyol

Also Published As

Publication number Publication date
BR112013005783A2 (pt) 2017-03-21
US20130184432A1 (en) 2013-07-18
JP5792310B2 (ja) 2015-10-07
DE102010040517A1 (de) 2012-03-15
EP2614102B1 (de) 2014-07-23
KR20130102588A (ko) 2013-09-17
CA2810559A1 (en) 2012-03-15
MX2013002484A (es) 2013-04-03
EP2614102A1 (de) 2013-07-17
JP2013537245A (ja) 2013-09-30
CN103189417A (zh) 2013-07-03
ES2506440T3 (es) 2014-10-13
RU2013115633A (ru) 2014-10-20
SG188278A1 (en) 2013-04-30
US9045592B2 (en) 2015-06-02
WO2012032028A1 (de) 2012-03-15

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