RU2012111663A - Электрохромные устройства, блоки, содержащие электрохромные устройства, и/или способы их изготовления - Google Patents

Электрохромные устройства, блоки, содержащие электрохромные устройства, и/или способы их изготовления Download PDF

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RU2012111663A
RU2012111663A RU2012111663/28A RU2012111663A RU2012111663A RU 2012111663 A RU2012111663 A RU 2012111663A RU 2012111663/28 A RU2012111663/28 A RU 2012111663/28A RU 2012111663 A RU2012111663 A RU 2012111663A RU 2012111663 A RU2012111663 A RU 2012111663A
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Виджайен С. ВЕЕРАСАМИ
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Гардиан Индастриз Корп.
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    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
    • G02F1/1524—Transition metal compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B32B17/10045—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets with at least one intermediate layer consisting of a glass sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10981—Pre-treatment of the layers
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/67—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light
    • E06B3/6715—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light
    • E06B3/6722—Units comprising two or more parallel glass or like panes permanently secured together characterised by additional arrangements or devices for heat or sound insulation or for controlled passage of light specially adapted for increased thermal insulation or for controlled passage of light with adjustable passage of light
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
    • G02F1/1525—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material characterised by a particular ion transporting layer, e.g. electrolyte
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153—Constructional details
    • G02F1/1533—Constructional details structural features not otherwise provided for
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
    • E06B2009/2464—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1506—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect caused by electrodeposition, e.g. electrolytic deposition of an inorganic material on or close to an electrode
    • G02F1/1508—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect caused by electrodeposition, e.g. electrolytic deposition of an inorganic material on or close to an electrode using a solid electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y10T156/1052—Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1062—Prior to assembly

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Abstract

1. Способ изготовления электрохромных окон, содержащий:обеспечение первой стеклянной подложки;нанесение на первую подложку слоев электрохромного устройства, включая по меньшей мере слои противоэлектрода (ПЭ), ионного проводника (ИП) и электрохромного материала (ЭХМ);формирование рисунка слоев электрохромного устройства (ЭХУ) и разрезание первой стеклянной подложки с нанесенными на нее слоями электрохромного устройства так, чтобы образовалось множество подложек с ЭХУ;обеспечение множества вторых стеклянных подложек;ламинирование или соединение множества подложек с ЭХУ с множеством вторых стеклянных подложек соответственно;обеспечение множества третьих стеклянных подложек;формирование множества стеклопакетов (СП), соответственно содержающих первую и вторую подложки в практически параллельном расположении на расстоянии от третьих стеклянных подложек.2. Способ по п. 1, при этом множество вторых подложек подвергнуты термической закалке.3. Способ по п. 2, при этом слои ЭХУ нанесены напылением.4. Способ по п. 3, при этом напыление осуществляют с помощью ионного пучка.5. Способ по п. 2, при этом слои ЭХУ обращены ко вторым подложкам при сборке в стеклопакеты.6. Способ по п. 2, при этом слои ЭХУ обращены к третьим подложкам при сборке в стеклопакеты.7. Способ по п. 2, дополнительно содержащий обеспечение первого и второго прозрачных проводящих покрытий (ППП) на противоположных сторонах слоев электрохромного устройства.8. Способ по п. 7, при этом каждое упомянутое ППП включает в себя слой серебра, расположенный между слоями ITO, и при этом, кроме того, предусмотрены включающие NiCr или Cu слои между слоем серебра и слоями ITO.9. Спо

Claims (25)

1. Способ изготовления электрохромных окон, содержащий:
обеспечение первой стеклянной подложки;
нанесение на первую подложку слоев электрохромного устройства, включая по меньшей мере слои противоэлектрода (ПЭ), ионного проводника (ИП) и электрохромного материала (ЭХМ);
формирование рисунка слоев электрохромного устройства (ЭХУ) и разрезание первой стеклянной подложки с нанесенными на нее слоями электрохромного устройства так, чтобы образовалось множество подложек с ЭХУ;
обеспечение множества вторых стеклянных подложек;
ламинирование или соединение множества подложек с ЭХУ с множеством вторых стеклянных подложек соответственно;
обеспечение множества третьих стеклянных подложек;
формирование множества стеклопакетов (СП), соответственно содержающих первую и вторую подложки в практически параллельном расположении на расстоянии от третьих стеклянных подложек.
2. Способ по п. 1, при этом множество вторых подложек подвергнуты термической закалке.
3. Способ по п. 2, при этом слои ЭХУ нанесены напылением.
4. Способ по п. 3, при этом напыление осуществляют с помощью ионного пучка.
5. Способ по п. 2, при этом слои ЭХУ обращены ко вторым подложкам при сборке в стеклопакеты.
6. Способ по п. 2, при этом слои ЭХУ обращены к третьим подложкам при сборке в стеклопакеты.
7. Способ по п. 2, дополнительно содержащий обеспечение первого и второго прозрачных проводящих покрытий (ППП) на противоположных сторонах слоев электрохромного устройства.
8. Способ по п. 7, при этом каждое упомянутое ППП включает в себя слой серебра, расположенный между слоями ITO, и при этом, кроме того, предусмотрены включающие NiCr или Cu слои между слоем серебра и слоями ITO.
9. Способ по п. 8, при этом поверхностное сопротивление каждого упомянутого ППП составляет примерно 5 Ом/квадрат.
10. Способ по п. 2, при этом слой ИП включает в себя LiPON.
11. Способ по п. 2, при этом слой ЭХМ содержит WOx.
12. Способ по п. 11, при этом WOx является субстехиометрическим.
13. Способ по п. 12, при этом 2,6<x<3.
14. Способ по п. 11, при этом слой ПЭ, слой ИП и/или слой ЭХМ легирован(ы) магнием (Mg).
15. Способ по п. 14, дополнительно содержащий обеспечение одного или более низкоэмиссионных покрытий, причем данные низкоэмиссионные покрытия обеспечивают на внутренних поверхностях вторых подложек, на одной или обеих поверхностях первой подложки и/или на внутренних поверхностях третьих стеклянных подложек.
16. Способ по п. 15, дополнительно содержащий обеспечение блокирующих УФ покрытий на внутренних поверхностях вторых подложек.
17. Способ по п. 2, при этом множество подложек с ЭХУ ламинируют или соединяют с множеством вторых стеклянных подложек посредством соответствующих слоев на полимерной основе.
18. Способ изготовления электрохромного блока (ЭХБ), содержающий:
обеспечение первой, второй и третьей стеклянных подложек, при этом вторая подложка подвергнута термической закалке, а первая подложка не подвергнута термической закалке;
осаждение напылением множества слоев электрохромного устройства (ЭХУ), непосредственно или опосредованно, на первую подложку, причем данное множество слоев ЭХУ содержит первое прозрачное проводящее покрытие (ППП), слой противоэлектрода (ПЭ), слой ионного проводника (ИП), слой ЭХМ и второе ППП;
ламинирование или соединение первой и второй подложек друг с другом; и
обеспечение второй и третьей подложек в практически параллельном расположении на расстоянии друг от друга,
при этом слои ПЭ и ЭХМ оба способны изменять свой цвет, когда ЭХБ находится в рабочем состоянии.
19. Способ изготовления электрохромного блока (ЭХБ), содержающий:
осаждение напылением множества слоев электрохромного устройства (ЭХУ), непосредственно или опосредованно, на первую подложку, причем данное множество слоев устройства содержит, в порядке удаления от первой подложки, первое прозрачное проводящее покрытие (ППП), слой катода, слой электролита, анодно окрашивающийся слой анода и второе ППП; и
соединение первой подложки с множеством осажденных на нее напылением слоев устройства со второй подложкой так, что первая и вторая подложки находятся в практически параллельном расположении на расстоянии друг от друга.
20. Способ по п. 19, при этом первое и/или второе ППП представляют собой комплекты диэлектрических слоев на основе серебра.
21. Способ по п. 19, при этом слой электролита содержит LiPON.
22. Способ по п. 19, при этом слой катода, слой электролита и/или анодно окрашивающийся слой анода легирован(ы) магнием (Mg).
23. Способ по п. 19, при этом слой катода содержит субстехиометрический WOx.
24. Способ по п. 19, при этом слой катода содержит субстехиометрический WOx, и 2,6<x<3.
25. Способ по п. 19, при этом слои ПЭ и ЭХМ оба способны изменять свой цвет, когда ЭХБ находится в рабочем состоянии.
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