RU2008140313A - Способ получения алкиленкарбоната и применение алкиленкарбоната, полученного таким образом, в производстве алкандиола и диалкилкарбоната - Google Patents
Способ получения алкиленкарбоната и применение алкиленкарбоната, полученного таким образом, в производстве алкандиола и диалкилкарбоната Download PDFInfo
- Publication number
- RU2008140313A RU2008140313A RU2008140313/04A RU2008140313A RU2008140313A RU 2008140313 A RU2008140313 A RU 2008140313A RU 2008140313/04 A RU2008140313/04 A RU 2008140313/04A RU 2008140313 A RU2008140313 A RU 2008140313A RU 2008140313 A RU2008140313 A RU 2008140313A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- phosphonium
- phosphonium catalyst
- spent
- purified
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 18
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title claims 5
- 238000004519 manufacturing process Methods 0.000 title claims 3
- 239000003054 catalyst Substances 0.000 claims abstract 29
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims abstract 24
- -1 alkylene carbonate Chemical compound 0.000 claims abstract 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract 10
- 238000006243 chemical reaction Methods 0.000 claims abstract 10
- 238000004821 distillation Methods 0.000 claims abstract 7
- 125000002947 alkylene group Chemical group 0.000 claims abstract 5
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract 5
- 239000001569 carbon dioxide Substances 0.000 claims abstract 5
- 239000000203 mixture Substances 0.000 claims abstract 4
- 239000002904 solvent Substances 0.000 claims abstract 3
- 125000003342 alkenyl group Chemical group 0.000 claims abstract 2
- 125000000217 alkyl group Chemical group 0.000 claims abstract 2
- 125000003118 aryl group Chemical group 0.000 claims abstract 2
- 150000004820 halides Chemical class 0.000 claims abstract 2
- RKHXQBLJXBGEKF-UHFFFAOYSA-M tetrabutylphosphanium;bromide Chemical group [Br-].CCCC[P+](CCCC)(CCCC)CCCC RKHXQBLJXBGEKF-UHFFFAOYSA-M 0.000 claims abstract 2
- 238000000746 purification Methods 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 238000005809 transesterification reaction Methods 0.000 claims 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
- C07C68/065—Preparation of esters of carbonic or haloformic acids from organic carbonates from alkylene carbonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D317/34—Oxygen atoms
- C07D317/36—Alkylene carbonates; Substituted alkylene carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0255—Phosphorus containing compounds
- B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
- B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/12—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/96—Esters of carbonic or haloformic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06110999.7 | 2006-03-13 | ||
| EP06110999 | 2006-03-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2008140313A true RU2008140313A (ru) | 2010-04-20 |
Family
ID=36838664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008140313/04A RU2008140313A (ru) | 2006-03-13 | 2007-03-12 | Способ получения алкиленкарбоната и применение алкиленкарбоната, полученного таким образом, в производстве алкандиола и диалкилкарбоната |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20070213542A1 (enExample) |
| EP (1) | EP1994018B1 (enExample) |
| JP (2) | JP5551876B2 (enExample) |
| KR (1) | KR20080110782A (enExample) |
| CN (1) | CN101553479B (enExample) |
| AU (1) | AU2007224469A1 (enExample) |
| BR (1) | BRPI0708285A2 (enExample) |
| CA (1) | CA2641997A1 (enExample) |
| ES (1) | ES2396866T3 (enExample) |
| MX (1) | MX2008011415A (enExample) |
| RU (1) | RU2008140313A (enExample) |
| TW (1) | TWI387584B (enExample) |
| WO (1) | WO2007104730A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200906774A (en) * | 2007-04-23 | 2009-02-16 | Shell Int Research | Process for the preparation of an 1,2-alkylene diol and a dialkylcarbonate |
| WO2009141377A1 (en) * | 2008-05-20 | 2009-11-26 | Shell Internationale Research Maatschappij B.V. | Process for preparing an 1,2-alkylene carbonate |
| TWI457317B (zh) | 2008-05-20 | 2014-10-21 | Shell Int Research | 碳酸伸烷酯之製造方法 |
| DE102010042937A1 (de) * | 2010-10-08 | 2012-04-12 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung von Diarylcarbonaten aus Dialkylcarbonaten |
| CN103028440B (zh) * | 2011-09-29 | 2015-06-10 | 中国石油化工股份有限公司 | 用于制备碳酸亚烷酯的大孔型树脂催化剂 |
| TWI623525B (zh) * | 2013-07-19 | 2018-05-11 | Maruzen Petrochemical Co Ltd | Continuous manufacturing method of cyclic carbonate |
| CN105492448A (zh) * | 2013-09-03 | 2016-04-13 | 巴斯夫欧洲公司 | 无定形材料及其用途 |
| WO2024214491A1 (ja) * | 2023-04-14 | 2024-10-17 | 信越化学工業株式会社 | フェノール部位を有する固定化第四級ホスホニウム塩およびその製造方法、並びにこれを用いた環状カーボネートの製造方法 |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2873282A (en) * | 1952-04-05 | 1959-02-10 | Jefferson Chem Co Inc | Catalytic process for producing alkylene carbonates |
| US2773070A (en) * | 1952-10-31 | 1956-12-04 | Jefferson Chem Co Inc | Catalytic process for producing alkylene carbonates |
| US2924608A (en) * | 1957-12-30 | 1960-02-09 | Olin Mathieson | Ethylene carbonates |
| US2994705A (en) * | 1958-12-08 | 1961-08-01 | Pure Oil Co | Preparation of cyclic alkylene carbonates in the presence of organic phosphonium compounds |
| DE1274578B (de) * | 1965-01-21 | 1968-08-08 | Bayer Ag | Verfahren zur Herstellung von Cycloalkylaminverbindungen |
| US3803201A (en) * | 1971-02-22 | 1974-04-09 | Dow Chemical Co | Synthesis of dimethyl carbonate |
| US3748345A (en) * | 1971-07-02 | 1973-07-24 | Shell Oil Co | Preparation of alkylene carbonates by reaction of alkylene oxides with carbon dioxide |
| DE2748718A1 (de) * | 1977-10-29 | 1979-05-03 | Bayer Ag | Verfahren zur herstellung von dialkylcarbonaten |
| US4314945A (en) * | 1977-12-22 | 1982-02-09 | Union Carbide Corporation | Alkylene carbonate process |
| CA1224793A (en) * | 1981-12-02 | 1987-07-28 | Halcon Sd Group, Inc. (The) | Preparation of alkylene carbonates |
| US4400559A (en) * | 1982-06-14 | 1983-08-23 | The Halcon Sd Group, Inc. | Process for preparing ethylene glycol |
| US4508927A (en) * | 1983-08-02 | 1985-04-02 | The Halcon Sd Group, Inc. | Preparation of glycols from ethylene oxide |
| US4691041A (en) * | 1986-01-03 | 1987-09-01 | Texaco Inc. | Process for production of ethylene glycol and dimethyl carbonate |
| DE4030283A1 (de) * | 1990-09-25 | 1992-03-26 | Ruetgerswerke Ag | Verfahren zur herstellung cyclischer carbonate |
| JP3079560B2 (ja) * | 1990-11-07 | 2000-08-21 | 松下電器産業株式会社 | プリプラ式射出成形機およびその制御方法 |
| GB2255972A (en) * | 1991-04-12 | 1992-11-25 | Davy Res & Dev Ltd | Production of diaryl carbonates. |
| DE4129316A1 (de) * | 1991-09-03 | 1993-03-04 | Bayer Ag | Verfahren zur kontinuierlichen herstellung von dialkylcarbonaten |
| DE4216121A1 (de) * | 1992-05-15 | 1993-11-18 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Dialkylcarbonaten |
| DE4318892A1 (de) * | 1993-06-07 | 1994-12-08 | Bayer Ag | Verfahren zur Herstellung von Propylenglykolcarbonat |
| DE4318893A1 (de) * | 1993-06-07 | 1994-12-08 | Bayer Ag | Reaktor und damit durchzuführendes kontinuierliches Verfahren zur Herstellung von Ethylenglykolcarbonat bzw. Propylenglykolcarbonat |
| DE4342713A1 (de) * | 1993-12-15 | 1995-06-22 | Bayer Ag | Verfahren zur Abtrennung von Methanol aus einem Gemisch von Dimethylcarbonat und Methanol |
| EP0889025B1 (en) * | 1995-12-22 | 2002-04-03 | Asahi Kasei Kabushiki Kaisha | Process for continuously preparing dialkyl carbonates and diols |
| SG77264A1 (en) * | 1998-08-10 | 2000-12-19 | Mitsubishi Chem Corp | Process for producing an alkylene glycol |
| US6156160A (en) * | 1998-10-07 | 2000-12-05 | Huntsman Petrochemical Corporation | Alkylene carbonate process |
| JP3659038B2 (ja) * | 1998-12-22 | 2005-06-15 | 三菱化学株式会社 | エチレングリコールの製造方法 |
| WO2000051954A1 (en) * | 1999-03-03 | 2000-09-08 | Asahi Kasei Kabushiki Kaisha | Process for continuously producing dialkyl carbonate and diol |
| US6407279B1 (en) * | 1999-11-19 | 2002-06-18 | Exxonmobil Chemical Patents Inc. | Integrated process for preparing dialkyl carbonates and diols |
| US6294684B1 (en) * | 1999-12-08 | 2001-09-25 | General Electric Company | Method and apparatus for the continuous production of diaryl carbonates |
| JP3659109B2 (ja) * | 2000-01-19 | 2005-06-15 | 三菱化学株式会社 | エチレングリコールと炭酸エステルの併産方法 |
| US6392078B1 (en) * | 2000-06-12 | 2002-05-21 | Catalytic Distillation Technologies | Process and catalyst for making dialkyl carbonates |
| US6774256B2 (en) * | 2001-06-22 | 2004-08-10 | Exxonmobil Chemical Patents Inc. | Low corrosive integrated process for preparing dialkyl carbonates |
| US6573396B2 (en) * | 2001-10-12 | 2003-06-03 | Exxonmobil Chemical Patents Inc. | Co-production of dialkyl carbonates and diols with treatment of hydroxy alkyl carbonate |
| JP2003267970A (ja) * | 2002-03-13 | 2003-09-25 | Mitsubishi Chemicals Corp | エチレンカーボネートの製造方法 |
| JP2004099554A (ja) * | 2002-09-11 | 2004-04-02 | Mitsubishi Chemicals Corp | アルキレングリコール及びジアルキルカーボネートの併産方法 |
| TW200503997A (en) * | 2002-12-20 | 2005-02-01 | Shell Int Research | Process for the preparation of alkylene glycol |
| DE602004010144T2 (de) * | 2003-06-30 | 2008-09-11 | Shell Internationale Research Maatschappij B.V. | Verfahren zur herstellung von propylencarbonat |
| TWI382979B (zh) * | 2006-02-22 | 2013-01-21 | Shell Int Research | 碳酸伸烷酯之生產方法及由此生產的碳酸伸烷酯於烷二醇及碳酸二烷酯之製造中的用途 |
-
2007
- 2007-03-09 TW TW096108219A patent/TWI387584B/zh not_active IP Right Cessation
- 2007-03-12 US US11/684,873 patent/US20070213542A1/en not_active Abandoned
- 2007-03-12 KR KR1020087024405A patent/KR20080110782A/ko not_active Withdrawn
- 2007-03-12 EP EP07726784A patent/EP1994018B1/en not_active Not-in-force
- 2007-03-12 WO PCT/EP2007/052270 patent/WO2007104730A1/en not_active Ceased
- 2007-03-12 CA CA002641997A patent/CA2641997A1/en not_active Abandoned
- 2007-03-12 ES ES07726784T patent/ES2396866T3/es active Active
- 2007-03-12 BR BRPI0708285-1A patent/BRPI0708285A2/pt not_active Application Discontinuation
- 2007-03-12 MX MX2008011415A patent/MX2008011415A/es not_active Application Discontinuation
- 2007-03-12 JP JP2008558796A patent/JP5551876B2/ja not_active Expired - Fee Related
- 2007-03-12 RU RU2008140313/04A patent/RU2008140313A/ru not_active Application Discontinuation
- 2007-03-12 CN CN2007800075665A patent/CN101553479B/zh not_active Expired - Fee Related
- 2007-03-12 AU AU2007224469A patent/AU2007224469A1/en not_active Abandoned
-
2013
- 2013-11-29 JP JP2013247358A patent/JP5726278B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101553479B (zh) | 2013-11-27 |
| TWI387584B (zh) | 2013-03-01 |
| BRPI0708285A2 (pt) | 2011-05-24 |
| MX2008011415A (es) | 2008-09-18 |
| ES2396866T3 (es) | 2013-02-28 |
| CN101553479A (zh) | 2009-10-07 |
| JP2014088387A (ja) | 2014-05-15 |
| EP1994018A1 (en) | 2008-11-26 |
| EP1994018B1 (en) | 2012-11-28 |
| TW200800882A (en) | 2008-01-01 |
| KR20080110782A (ko) | 2008-12-19 |
| WO2007104730A1 (en) | 2007-09-20 |
| JP5726278B2 (ja) | 2015-05-27 |
| JP2009530240A (ja) | 2009-08-27 |
| JP5551876B2 (ja) | 2014-07-16 |
| AU2007224469A1 (en) | 2007-09-20 |
| US20070213542A1 (en) | 2007-09-13 |
| CA2641997A1 (en) | 2007-09-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA93 | Acknowledgement of application withdrawn (no request for examination) |
Effective date: 20110216 |