RU2008128304A - Rim-эластомеры на основе изоциануратов изофорондиизоцианата и их форполимеров - Google Patents
Rim-эластомеры на основе изоциануратов изофорондиизоцианата и их форполимеров Download PDFInfo
- Publication number
- RU2008128304A RU2008128304A RU2008128304/04A RU2008128304A RU2008128304A RU 2008128304 A RU2008128304 A RU 2008128304A RU 2008128304/04 A RU2008128304/04 A RU 2008128304/04A RU 2008128304 A RU2008128304 A RU 2008128304A RU 2008128304 A RU2008128304 A RU 2008128304A
- Authority
- RU
- Russia
- Prior art keywords
- molecular weight
- groups
- amine groups
- functionality
- hydroxyl
- Prior art date
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract 9
- 239000000806 elastomer Substances 0.000 title claims abstract 9
- 229920005862 polyol Polymers 0.000 claims abstract 11
- 150000003077 polyols Chemical class 0.000 claims abstract 11
- 125000001931 aliphatic group Chemical group 0.000 claims abstract 5
- 239000000203 mixture Substances 0.000 claims abstract 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 14
- 239000004970 Chain extender Substances 0.000 claims 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims 9
- 229920000570 polyether Polymers 0.000 claims 9
- 150000003141 primary amines Chemical class 0.000 claims 9
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims 9
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical group COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 claims 6
- HOSGXJWQVBHGLT-UHFFFAOYSA-N 6-hydroxy-3,4-dihydro-1h-quinolin-2-one Chemical group N1C(=O)CCC2=CC(O)=CC=C21 HOSGXJWQVBHGLT-UHFFFAOYSA-N 0.000 claims 6
- 239000003431 cross linking reagent Substances 0.000 claims 6
- 239000012948 isocyanate Substances 0.000 claims 6
- 150000002513 isocyanates Chemical class 0.000 claims 6
- 238000000034 method Methods 0.000 claims 6
- 125000001302 tertiary amino group Chemical group 0.000 claims 6
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 claims 5
- 239000003054 catalyst Substances 0.000 claims 4
- HLJDOURGTRAFHE-UHFFFAOYSA-N isocyanic acid;3,5,5-trimethylcyclohex-2-en-1-one Chemical compound N=C=O.N=C=O.CC1=CC(=O)CC(C)(C)C1 HLJDOURGTRAFHE-UHFFFAOYSA-N 0.000 claims 4
- 229920000582 polyisocyanurate Polymers 0.000 claims 4
- 239000011495 polyisocyanurate Substances 0.000 claims 4
- 239000000047 product Substances 0.000 claims 4
- 239000011541 reaction mixture Substances 0.000 claims 4
- 238000005829 trimerization reaction Methods 0.000 claims 4
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 claims 3
- -1 diamine compound Chemical class 0.000 claims 3
- 229920005903 polyol mixture Polymers 0.000 claims 3
- 239000012963 UV stabilizer Substances 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- 125000003277 amino group Chemical group 0.000 claims 2
- 239000003963 antioxidant agent Substances 0.000 claims 2
- 230000003078 antioxidant effect Effects 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 229920003225 polyurethane elastomer Polymers 0.000 claims 2
- 239000003381 stabilizer Substances 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 238000001746 injection moulding Methods 0.000 claims 1
- 238000010422 painting Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/3278—Hydroxyamines containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/300,837 | 2005-12-15 | ||
| US11/300,837 US20070142601A1 (en) | 2005-12-15 | 2005-12-15 | RIM elastomers based on isocyanurates of isophorone diisocyanate and prepolymers thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2008128304A true RU2008128304A (ru) | 2010-01-20 |
Family
ID=37890913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008128304/04A RU2008128304A (ru) | 2005-12-15 | 2006-12-12 | Rim-эластомеры на основе изоциануратов изофорондиизоцианата и их форполимеров |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20070142601A1 (enExample) |
| EP (1) | EP1963390B1 (enExample) |
| JP (1) | JP2009520066A (enExample) |
| KR (1) | KR101360649B1 (enExample) |
| CN (2) | CN101321795B (enExample) |
| AT (1) | ATE471955T1 (enExample) |
| BR (1) | BRPI0619949A2 (enExample) |
| CA (1) | CA2633037A1 (enExample) |
| DE (1) | DE602006015102D1 (enExample) |
| RU (1) | RU2008128304A (enExample) |
| WO (1) | WO2007075329A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2824358C1 (ru) * | 2022-08-18 | 2024-08-07 | Шандонг Инов Полиуретан Ко., Лтд. | Полиуретановый эластомер для контактного кольца компьютерного томографа и способ его получения |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8247079B2 (en) * | 2006-09-01 | 2012-08-21 | Momentive Performance Materials Inc. | Laminate containing a silylated polyurethane adhesive composition |
| US8193257B2 (en) * | 2007-01-30 | 2012-06-05 | Dow Global Technologies Llc | Amine-initiated polyols and rigid polyurethane foam made therefrom |
| US20110028661A1 (en) * | 2007-12-20 | 2011-02-03 | Dsm Ip Assets B.V. | Hybrid polyurethane block copolymers with thermoplastic processability and thermoset properties |
| WO2012078322A1 (en) * | 2010-12-07 | 2012-06-14 | Dow Global Technologies Llc | Polyurethane elastomers made using mixtures of aliphatic diol chain extender and secondary amine |
| EP2758443B1 (en) | 2011-09-21 | 2019-02-27 | Dow Global Technologies LLC | Polyurethanes made using mixtures of tertiary amine compounds and lewis acids as catalysts |
| CN103224606B (zh) * | 2013-05-03 | 2015-03-11 | 中国海洋石油总公司 | 海底油气管道接口湿式保温用聚氨酯节点材料及其制备方法 |
| CN103275300A (zh) * | 2013-05-31 | 2013-09-04 | 东莞市精伦实业有限公司 | 一种耐黄、抗紫外线的聚氨酯弹性体及其制备方法 |
| JP6750236B2 (ja) * | 2016-02-03 | 2020-09-02 | 株式会社デンソー | 電子デバイス |
| CN108250391B (zh) | 2016-12-28 | 2021-10-22 | 科思创德国股份有限公司 | 一种用于制备聚氨酯的多元醇体系 |
| US11046850B2 (en) * | 2017-09-27 | 2021-06-29 | Evonik Operations Gmbh | Mixed metal catalyst compositions and methods for making polyurethane foam |
| CN111196871A (zh) * | 2018-11-19 | 2020-05-26 | 科思创德国股份有限公司 | 一种制备聚氨酯弹性体的方法 |
| WO2020104238A1 (en) * | 2018-11-19 | 2020-05-28 | Covestro Deutschland Ag | A process for producing a polyurethane elastomer |
| CN116178669B (zh) * | 2023-03-08 | 2024-05-14 | 安徽开捷汽车部件有限公司 | 一种高韧性反应注射成型的材料及其应用 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2513817C3 (de) * | 1975-03-27 | 1986-11-13 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Schaumstoff-Formkörpern kompakter Randzone und zelligem Kern |
| US4218543A (en) * | 1976-05-21 | 1980-08-19 | Bayer Aktiengesellschaft | Rim process for the production of elastic moldings |
| US4269945A (en) * | 1980-01-24 | 1981-05-26 | The Dow Chemical Company | Reaction injection molded polyurethanes employing aliphatic amine chain extenders |
| DE3014161A1 (de) * | 1980-04-12 | 1981-10-22 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von polyurethan-formkoerpern |
| US4642320A (en) * | 1983-11-02 | 1987-02-10 | The Dow Chemical Company | Reaction injection molded polyureas employing high molecular weight amine-terminated polyethers |
| US4631298A (en) * | 1985-12-16 | 1986-12-23 | Ethyl Corporation | Mixed diamine chain extender |
| EP0275010B1 (de) * | 1987-01-14 | 1991-11-21 | Bayer Ag | Verfahren zur Herstellung von Polyurethan-Formteilen |
| US4764543A (en) * | 1987-08-03 | 1988-08-16 | The Dow Chemical Company | Microcellular foamed or reaction injection molded polyurethane/polyureas employing amine terminated polymers and diamine chain extenders |
| US5656677A (en) * | 1989-01-20 | 1997-08-12 | Recticel | Method for preparing and applying a sprayable, light stable polyurethane |
| GB9125918D0 (en) * | 1991-12-05 | 1992-02-05 | Ici Plc | Reaction system for preparing polyurethane/polyurea |
| US5502147A (en) * | 1993-12-21 | 1996-03-26 | Bayer Corporation | Aliphatic rim elastomers |
| US5502150A (en) * | 1994-06-29 | 1996-03-26 | Bayer Corporation | Linear HDI urethane prepolymers for rim application |
| IN1997CH00157A (enExample) * | 1996-10-01 | 2006-06-09 | Recticel | |
| US6005016A (en) * | 1998-10-06 | 1999-12-21 | Bayer Corporation | Rigid polyurethane foam based on polyethers of TDA |
| KR100771910B1 (ko) * | 2001-09-28 | 2007-11-01 | 주식회사 엘지이아이 | 탈형성이 우수한 경질 폴리우레탄 폼 조성물 |
| JP3808006B2 (ja) * | 2002-05-29 | 2006-08-09 | 住化バイエルウレタン株式会社 | 意匠面に使用されるインストルメントパネル用インテグラルスキンポリウレタンフォームの製造方法 |
| US6765080B2 (en) * | 2002-06-06 | 2004-07-20 | Bayer Corporation | High performance RIM elastomers and a process for their production |
| CN1182175C (zh) * | 2002-12-12 | 2004-12-29 | 拜耳（中国）有限公司 | 生产硬质聚氨酯泡沫用组合多元醇 |
-
2005
- 2005-12-15 US US11/300,837 patent/US20070142601A1/en not_active Abandoned
-
2006
- 2006-12-12 DE DE602006015102T patent/DE602006015102D1/de active Active
- 2006-12-12 EP EP06845290A patent/EP1963390B1/en not_active Not-in-force
- 2006-12-12 CA CA002633037A patent/CA2633037A1/en not_active Abandoned
- 2006-12-12 JP JP2008545736A patent/JP2009520066A/ja active Pending
- 2006-12-12 CN CN2006800452267A patent/CN101321795B/zh not_active Expired - Fee Related
- 2006-12-12 KR KR1020087014125A patent/KR101360649B1/ko not_active Expired - Fee Related
- 2006-12-12 WO PCT/US2006/047378 patent/WO2007075329A1/en not_active Ceased
- 2006-12-12 BR BRPI0619949-6A patent/BRPI0619949A2/pt not_active Application Discontinuation
- 2006-12-12 AT AT06845290T patent/ATE471955T1/de not_active IP Right Cessation
- 2006-12-12 CN CN201110245131.2A patent/CN102432799B/zh not_active Expired - Fee Related
- 2006-12-12 RU RU2008128304/04A patent/RU2008128304A/ru not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2824358C1 (ru) * | 2022-08-18 | 2024-08-07 | Шандонг Инов Полиуретан Ко., Лтд. | Полиуретановый эластомер для контактного кольца компьютерного томографа и способ его получения |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1963390B1 (en) | 2010-06-23 |
| KR20080080536A (ko) | 2008-09-04 |
| ATE471955T1 (de) | 2010-07-15 |
| JP2009520066A (ja) | 2009-05-21 |
| EP1963390A1 (en) | 2008-09-03 |
| BRPI0619949A2 (pt) | 2011-10-25 |
| WO2007075329A8 (en) | 2008-06-19 |
| CA2633037A1 (en) | 2007-07-05 |
| CN102432799B (zh) | 2014-08-13 |
| CN101321795A (zh) | 2008-12-10 |
| US20070142601A1 (en) | 2007-06-21 |
| KR101360649B1 (ko) | 2014-02-07 |
| DE602006015102D1 (de) | 2010-08-05 |
| CN102432799A (zh) | 2012-05-02 |
| CN101321795B (zh) | 2011-09-28 |
| WO2007075329A1 (en) | 2007-07-05 |
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