RU2007119396A - Улучшенный способ алкоксилирования соединений, содержащих активный водород, и алкоксилированные соединения, получаемые таким способом - Google Patents
Улучшенный способ алкоксилирования соединений, содержащих активный водород, и алкоксилированные соединения, получаемые таким способом Download PDFInfo
- Publication number
- RU2007119396A RU2007119396A RU2007119396/04A RU2007119396A RU2007119396A RU 2007119396 A RU2007119396 A RU 2007119396A RU 2007119396/04 A RU2007119396/04 A RU 2007119396/04A RU 2007119396 A RU2007119396 A RU 2007119396A RU 2007119396 A RU2007119396 A RU 2007119396A
- Authority
- RU
- Russia
- Prior art keywords
- range
- catalyst
- initiator
- vegetable oil
- zero
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 22
- 150000001875 compounds Chemical class 0.000 title claims abstract 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 title 1
- 239000001257 hydrogen Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims abstract 31
- 239000003999 initiator Substances 0.000 claims abstract 22
- 239000000203 mixture Substances 0.000 claims abstract 20
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract 17
- 239000008158 vegetable oil Substances 0.000 claims abstract 17
- 229920005862 polyol Polymers 0.000 claims abstract 14
- 150000003077 polyols Chemical class 0.000 claims abstract 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract 8
- 229920000570 polyether Polymers 0.000 claims abstract 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 7
- 229910052718 tin Inorganic materials 0.000 claims abstract 7
- 239000010936 titanium Substances 0.000 claims abstract 7
- 229910052719 titanium Inorganic materials 0.000 claims abstract 7
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 claims abstract 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract 6
- 229930195729 fatty acid Natural products 0.000 claims abstract 6
- 239000000194 fatty acid Substances 0.000 claims abstract 6
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims abstract 6
- 239000002253 acid Substances 0.000 claims abstract 5
- 125000002947 alkylene group Chemical group 0.000 claims abstract 5
- 230000003197 catalytic effect Effects 0.000 claims abstract 5
- 150000004665 fatty acids Chemical class 0.000 claims abstract 5
- 235000019737 Animal fat Nutrition 0.000 claims abstract 4
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims abstract 4
- 102000004190 Enzymes Human genes 0.000 claims abstract 4
- 108090000790 Enzymes Proteins 0.000 claims abstract 4
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052751 metal Inorganic materials 0.000 claims abstract 4
- 239000002184 metal Substances 0.000 claims abstract 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract 4
- 229920000768 polyamine Polymers 0.000 claims abstract 4
- 229910052703 rhodium Inorganic materials 0.000 claims abstract 4
- 239000010948 rhodium Substances 0.000 claims abstract 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000011135 tin Substances 0.000 claims abstract 4
- SNOJPWLNAMAYSX-UHFFFAOYSA-N 2-methylpropan-1-ol;titanium Chemical compound [Ti].CC(C)CO.CC(C)CO.CC(C)CO.CC(C)CO SNOJPWLNAMAYSX-UHFFFAOYSA-N 0.000 claims abstract 3
- JQZRVMZHTADUSY-UHFFFAOYSA-L di(octanoyloxy)tin Chemical group [Sn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O JQZRVMZHTADUSY-UHFFFAOYSA-L 0.000 claims abstract 3
- VLECYJGCGDPVSO-UHFFFAOYSA-L 2-ethylheptanoate;tin(2+) Chemical compound [Sn+2].CCCCCC(CC)C([O-])=O.CCCCCC(CC)C([O-])=O VLECYJGCGDPVSO-UHFFFAOYSA-L 0.000 claims abstract 2
- 125000005907 alkyl ester group Chemical group 0.000 claims abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 2
- 229920000728 polyester Polymers 0.000 claims 16
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 3
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 claims 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- 238000005698 Diels-Alder reaction Methods 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 230000009977 dual effect Effects 0.000 claims 1
- KIONPQSPGFQNGJ-UHFFFAOYSA-N ethyl heptanoate tin(2+) Chemical compound [Sn++].CCCCCCC(=O)OCC KIONPQSPGFQNGJ-UHFFFAOYSA-N 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 150000001414 amino alcohols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US62229804P | 2004-10-26 | 2004-10-26 | |
| US60/622,298 | 2004-10-26 | ||
| PCT/US2005/038220 WO2006047436A1 (en) | 2004-10-26 | 2005-10-24 | Improved method for alkoxylating active hydrogen containing compounds and the alkoxylated compounds made therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2007119396A true RU2007119396A (ru) | 2008-12-10 |
Family
ID=35945247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2007119396/04A RU2007119396A (ru) | 2004-10-26 | 2005-10-24 | Улучшенный способ алкоксилирования соединений, содержащих активный водород, и алкоксилированные соединения, получаемые таким способом |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20080125569A1 (enExample) |
| EP (1) | EP1807466B1 (enExample) |
| JP (1) | JP2008518088A (enExample) |
| KR (2) | KR101315527B1 (enExample) |
| CN (1) | CN101048441B (enExample) |
| AR (1) | AR051606A1 (enExample) |
| AT (1) | ATE460450T1 (enExample) |
| AU (1) | AU2005299522B2 (enExample) |
| BR (1) | BRPI0516890A (enExample) |
| CA (1) | CA2580569C (enExample) |
| DE (1) | DE602005019906D1 (enExample) |
| ES (1) | ES2338803T3 (enExample) |
| MX (1) | MX2007004969A (enExample) |
| MY (1) | MY144025A (enExample) |
| RU (1) | RU2007119396A (enExample) |
| WO (1) | WO2006047436A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060229375A1 (en) * | 2005-04-06 | 2006-10-12 | Yu-Ling Hsiao | Polyurethane foams made with alkoxylated vegetable oil hydroxylate |
| US8692030B1 (en) * | 2006-04-20 | 2014-04-08 | Pittsburg State University | Biobased-petrochemical hybrid polyols |
| CN100393767C (zh) * | 2006-07-24 | 2008-06-11 | 句容市宁武化工有限公司 | 聚氨酯泡沫用聚醚多元醇的制备方法及制得产品的应用 |
| WO2008026657A1 (fr) | 2006-08-31 | 2008-03-06 | Asahi Glass Company, Limited | Procédé de purification d'un composé polyéther |
| CN101802046B (zh) * | 2007-07-12 | 2014-06-18 | 陶氏环球技术有限责任公司 | 室温可固化聚合物及其前体 |
| PT2238195E (pt) * | 2008-01-29 | 2015-04-02 | Basf Se | Método para a produção de poliéter álcoois |
| DE102008011683A1 (de) * | 2008-02-28 | 2009-09-03 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyolen |
| EP2350191B1 (en) * | 2008-11-14 | 2013-09-11 | Dow Global Technologies LLC | Modified natural oils and products made therefrom |
| JP5342421B2 (ja) * | 2009-03-11 | 2013-11-13 | 信越化学工業株式会社 | 分子固定用基板の製造方法 |
| US20100317824A1 (en) * | 2009-06-15 | 2010-12-16 | Dow Global Technologies Inc. | Polyether derivatives of secondary hydroxy fatty acids and derivatives thereof |
| CN102471220A (zh) | 2009-07-10 | 2012-05-23 | 陶氏环球技术有限责任公司 | 仲羟基脂肪酸低聚物的酯及其制备 |
| CN102656209A (zh) * | 2009-12-09 | 2012-09-05 | 陶氏环球技术有限责任公司 | 仲羟基脂肪酸及其衍生物的聚醚衍生物 |
| US20110213170A1 (en) * | 2010-02-26 | 2011-09-01 | Daniele Vinci | Estolide derivatives useful as biolubricants |
| CN102906155A (zh) * | 2010-04-29 | 2013-01-30 | 陶氏环球技术有限责任公司 | 低聚酯烷氧基化物组合物 |
| US9115246B2 (en) | 2010-04-30 | 2015-08-25 | Basf Se | Polyether polyols, process for preparing polyether polyols and their use for producing polyurethanes |
| EP2563839B1 (de) * | 2010-04-30 | 2014-12-17 | Basf Se | Polyetherpolyole, verfahren zur herstellung von polyetherpolyolen, sowie deren verwendung zur herstellung von polyurethanen |
| JP5731651B2 (ja) * | 2010-08-20 | 2015-06-10 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | ポリエーテルエステルポリオールの製造方法 |
| JP2014501826A (ja) * | 2010-12-20 | 2014-01-23 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | ポリエーテルエステルポリオールの製造方法 |
| WO2012091968A1 (en) | 2010-12-27 | 2012-07-05 | Dow Global Technologies Llc | Alkylene oxide polymerization using a double metal cyanide catalyst complex and a magnesium, group 3-group 15 metal or lanthanide series metal compound |
| US9012598B2 (en) * | 2012-08-01 | 2015-04-21 | Seeo, Inc. | Poly(ethyleneoxide) functionalization through alkylation |
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-
2005
- 2005-10-24 JP JP2007539026A patent/JP2008518088A/ja active Pending
- 2005-10-24 RU RU2007119396/04A patent/RU2007119396A/ru not_active Application Discontinuation
- 2005-10-24 WO PCT/US2005/038220 patent/WO2006047436A1/en not_active Ceased
- 2005-10-24 KR KR1020077009345A patent/KR101315527B1/ko not_active Expired - Fee Related
- 2005-10-24 CA CA2580569A patent/CA2580569C/en not_active Expired - Fee Related
- 2005-10-24 CN CN2005800367842A patent/CN101048441B/zh not_active Expired - Fee Related
- 2005-10-24 DE DE602005019906T patent/DE602005019906D1/de not_active Expired - Lifetime
- 2005-10-24 MY MYPI20054982A patent/MY144025A/en unknown
- 2005-10-24 AU AU2005299522A patent/AU2005299522B2/en not_active Ceased
- 2005-10-24 US US11/664,463 patent/US20080125569A1/en not_active Abandoned
- 2005-10-24 ES ES05817318T patent/ES2338803T3/es not_active Expired - Lifetime
- 2005-10-24 KR KR1020137015892A patent/KR101386288B1/ko not_active Expired - Fee Related
- 2005-10-24 EP EP05817318A patent/EP1807466B1/en not_active Expired - Lifetime
- 2005-10-24 MX MX2007004969A patent/MX2007004969A/es active IP Right Grant
- 2005-10-24 AT AT05817318T patent/ATE460450T1/de not_active IP Right Cessation
- 2005-10-24 BR BRPI0516890-2A patent/BRPI0516890A/pt not_active IP Right Cessation
- 2005-10-25 AR ARP050104460A patent/AR051606A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AR051606A1 (es) | 2007-01-24 |
| EP1807466A1 (en) | 2007-07-18 |
| KR101386288B1 (ko) | 2014-04-17 |
| CN101048441A (zh) | 2007-10-03 |
| AU2005299522B2 (en) | 2010-11-25 |
| BRPI0516890A (pt) | 2008-09-23 |
| MX2007004969A (es) | 2007-06-14 |
| ATE460450T1 (de) | 2010-03-15 |
| CN101048441B (zh) | 2010-11-03 |
| ES2338803T3 (es) | 2010-05-12 |
| JP2008518088A (ja) | 2008-05-29 |
| CA2580569A1 (en) | 2006-05-04 |
| DE602005019906D1 (de) | 2010-04-22 |
| WO2006047436A1 (en) | 2006-05-04 |
| CA2580569C (en) | 2013-11-19 |
| US20080125569A1 (en) | 2008-05-29 |
| MY144025A (en) | 2011-07-29 |
| EP1807466B1 (en) | 2010-03-10 |
| KR20070083789A (ko) | 2007-08-24 |
| KR101315527B1 (ko) | 2013-10-08 |
| KR20130077902A (ko) | 2013-07-09 |
| AU2005299522A1 (en) | 2006-05-04 |
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| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20100812 |