KR101315527B1 - 활성 수소 함유 화합물의 알콕시화를 위한 개량된 방법 및그로부터 제조된 알콕시화 화합물 - Google Patents
활성 수소 함유 화합물의 알콕시화를 위한 개량된 방법 및그로부터 제조된 알콕시화 화합물 Download PDFInfo
- Publication number
- KR101315527B1 KR101315527B1 KR1020077009345A KR20077009345A KR101315527B1 KR 101315527 B1 KR101315527 B1 KR 101315527B1 KR 1020077009345 A KR1020077009345 A KR 1020077009345A KR 20077009345 A KR20077009345 A KR 20077009345A KR 101315527 B1 KR101315527 B1 KR 101315527B1
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- mixture
- functionalized
- delete delete
- initiator compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US62229804P | 2004-10-26 | 2004-10-26 | |
| US60/622,298 | 2004-10-26 | ||
| PCT/US2005/038220 WO2006047436A1 (en) | 2004-10-26 | 2005-10-24 | Improved method for alkoxylating active hydrogen containing compounds and the alkoxylated compounds made therefrom |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137015892A Division KR101386288B1 (ko) | 2004-10-26 | 2005-10-24 | 활성 수소 함유 화합물의 알콕시화를 위한 개량된 방법 및 그로부터 제조된 알콕시화 화합물 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20070083789A KR20070083789A (ko) | 2007-08-24 |
| KR101315527B1 true KR101315527B1 (ko) | 2013-10-08 |
Family
ID=35945247
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020077009345A Expired - Fee Related KR101315527B1 (ko) | 2004-10-26 | 2005-10-24 | 활성 수소 함유 화합물의 알콕시화를 위한 개량된 방법 및그로부터 제조된 알콕시화 화합물 |
| KR1020137015892A Expired - Fee Related KR101386288B1 (ko) | 2004-10-26 | 2005-10-24 | 활성 수소 함유 화합물의 알콕시화를 위한 개량된 방법 및 그로부터 제조된 알콕시화 화합물 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137015892A Expired - Fee Related KR101386288B1 (ko) | 2004-10-26 | 2005-10-24 | 활성 수소 함유 화합물의 알콕시화를 위한 개량된 방법 및 그로부터 제조된 알콕시화 화합물 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20080125569A1 (enExample) |
| EP (1) | EP1807466B1 (enExample) |
| JP (1) | JP2008518088A (enExample) |
| KR (2) | KR101315527B1 (enExample) |
| CN (1) | CN101048441B (enExample) |
| AR (1) | AR051606A1 (enExample) |
| AT (1) | ATE460450T1 (enExample) |
| AU (1) | AU2005299522B2 (enExample) |
| BR (1) | BRPI0516890A (enExample) |
| CA (1) | CA2580569C (enExample) |
| DE (1) | DE602005019906D1 (enExample) |
| ES (1) | ES2338803T3 (enExample) |
| MX (1) | MX2007004969A (enExample) |
| MY (1) | MY144025A (enExample) |
| RU (1) | RU2007119396A (enExample) |
| WO (1) | WO2006047436A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060229375A1 (en) * | 2005-04-06 | 2006-10-12 | Yu-Ling Hsiao | Polyurethane foams made with alkoxylated vegetable oil hydroxylate |
| US8692030B1 (en) * | 2006-04-20 | 2014-04-08 | Pittsburg State University | Biobased-petrochemical hybrid polyols |
| CN100393767C (zh) * | 2006-07-24 | 2008-06-11 | 句容市宁武化工有限公司 | 聚氨酯泡沫用聚醚多元醇的制备方法及制得产品的应用 |
| WO2008026657A1 (fr) | 2006-08-31 | 2008-03-06 | Asahi Glass Company, Limited | Procédé de purification d'un composé polyéther |
| CN101802046B (zh) * | 2007-07-12 | 2014-06-18 | 陶氏环球技术有限责任公司 | 室温可固化聚合物及其前体 |
| PT2238195E (pt) * | 2008-01-29 | 2015-04-02 | Basf Se | Método para a produção de poliéter álcoois |
| DE102008011683A1 (de) * | 2008-02-28 | 2009-09-03 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyolen |
| EP2350191B1 (en) * | 2008-11-14 | 2013-09-11 | Dow Global Technologies LLC | Modified natural oils and products made therefrom |
| JP5342421B2 (ja) * | 2009-03-11 | 2013-11-13 | 信越化学工業株式会社 | 分子固定用基板の製造方法 |
| US20100317824A1 (en) * | 2009-06-15 | 2010-12-16 | Dow Global Technologies Inc. | Polyether derivatives of secondary hydroxy fatty acids and derivatives thereof |
| CN102471220A (zh) | 2009-07-10 | 2012-05-23 | 陶氏环球技术有限责任公司 | 仲羟基脂肪酸低聚物的酯及其制备 |
| CN102656209A (zh) * | 2009-12-09 | 2012-09-05 | 陶氏环球技术有限责任公司 | 仲羟基脂肪酸及其衍生物的聚醚衍生物 |
| US20110213170A1 (en) * | 2010-02-26 | 2011-09-01 | Daniele Vinci | Estolide derivatives useful as biolubricants |
| CN102906155A (zh) * | 2010-04-29 | 2013-01-30 | 陶氏环球技术有限责任公司 | 低聚酯烷氧基化物组合物 |
| US9115246B2 (en) | 2010-04-30 | 2015-08-25 | Basf Se | Polyether polyols, process for preparing polyether polyols and their use for producing polyurethanes |
| EP2563839B1 (de) * | 2010-04-30 | 2014-12-17 | Basf Se | Polyetherpolyole, verfahren zur herstellung von polyetherpolyolen, sowie deren verwendung zur herstellung von polyurethanen |
| JP5731651B2 (ja) * | 2010-08-20 | 2015-06-10 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | ポリエーテルエステルポリオールの製造方法 |
| JP2014501826A (ja) * | 2010-12-20 | 2014-01-23 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | ポリエーテルエステルポリオールの製造方法 |
| WO2012091968A1 (en) | 2010-12-27 | 2012-07-05 | Dow Global Technologies Llc | Alkylene oxide polymerization using a double metal cyanide catalyst complex and a magnesium, group 3-group 15 metal or lanthanide series metal compound |
| US9012598B2 (en) * | 2012-08-01 | 2015-04-21 | Seeo, Inc. | Poly(ethyleneoxide) functionalization through alkylation |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4543369A (en) * | 1982-09-07 | 1985-09-24 | Henkel Corporation | Alkoxylated polyester polyols and polyurethanes made therefrom |
| JPH05163342A (ja) * | 1991-12-11 | 1993-06-29 | Asahi Glass Co Ltd | ポリエーテル類の製造方法 |
| US20030204045A1 (en) * | 2001-05-02 | 2003-10-30 | Jorg Hofmann | Double-metal cyanide catalysts for preparing polyether polyols |
| WO2004067633A1 (ja) * | 2003-01-28 | 2004-08-12 | Asahi Glass Company, Limited | ポリエーテルポリオール組成物およびその用途 |
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| US2332849A (en) * | 1940-03-15 | 1943-10-26 | Gruber Wolfgang | Softening agent for high polymeric substances |
| US2444328A (en) * | 1943-12-31 | 1948-06-29 | Petrolite Corp | Composition of matter |
| US2452029A (en) * | 1945-06-21 | 1948-10-26 | Rohm & Haas | Addition products from acrylic esters |
| US2485160A (en) * | 1948-10-23 | 1949-10-18 | Rohm & Haas | Process for the epoxidation of esters of oleic and linoleic acids |
| US2774774A (en) * | 1954-03-26 | 1956-12-18 | Fmc Corp | In situ epoxidation of oleic acid using formic acid |
| US2759953A (en) * | 1955-09-07 | 1956-08-21 | Hogan B Knight | Addition of organic acids to the double bond of unsaturated fatty compounds |
| US3169139A (en) * | 1960-01-20 | 1965-02-09 | Du Pont | Hydroxylation process for olefinic higher fatty acid and fatty acid ester |
| GB1032364A (en) * | 1962-09-21 | 1966-06-08 | Bibby & Sons Ltd J | Improvements in or relating to the preparation of water-soluble alkyd resins |
| US3427335A (en) * | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanides complexed with an acyclic aliphatic saturated monoether,an ester and a cyclic ether and methods for making the same |
| US3427334A (en) * | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity |
| US3278457A (en) * | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| US3278459A (en) * | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| US3427256A (en) * | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanide complex compounds |
| GB1063525A (en) * | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3278458A (en) * | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| DE1770548A1 (de) * | 1967-06-02 | 1972-02-10 | Gen Tire & Rubber Co | Polyester und ihre Herstellung |
| US3787459A (en) * | 1970-10-23 | 1974-01-22 | Us Agriculture | Selective hydroformylation of unsaturated fatty compounds |
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| US4081462A (en) * | 1975-10-14 | 1978-03-28 | Westvaco Corporation | C22 -Cycloaliphatic tricarboxylic fatty acid soaps |
| US4083816A (en) * | 1976-06-25 | 1978-04-11 | The United States Of America As Represented By The Secretary Of Agriculture | Acetoxymethyl derivatives of polyunsaturated fatty triglycerides as primary plasticizers for polyvinylchloride |
| US4196134A (en) * | 1977-01-31 | 1980-04-01 | Westvaco Corporation | Vegetable oil adducts |
| US4229562A (en) * | 1979-04-04 | 1980-10-21 | Henkel Corporation | Polyurethanes based on high molecular weight formyl alcohols |
| US4216343A (en) * | 1979-04-04 | 1980-08-05 | Henkel Corporation | High molecular weight polyhydric alcohols |
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| US4216344A (en) * | 1979-04-04 | 1980-08-05 | Henkel Corporation | High molecular weight polyol mixtures |
| DE3032612A1 (de) * | 1980-08-29 | 1982-03-25 | Grillo-Werke Ag, 4100 Duisburg | Gewuenschtenfalls sulfierte partialester von mehrwertigen alkoholen - verfahren zu ihrer herstellung und ihre verwendung als hautfreundliche, nicht ionogene und/oder anionenaktive oberflaechenaktive substanzen |
| US4496487A (en) * | 1982-09-07 | 1985-01-29 | Henkel Corporation | Hydroxymethyl polyols |
| US4423162A (en) * | 1982-09-07 | 1983-12-27 | Henkel Corporation | Polyurethanes from hydroxymethyl polyols and polyisocyanates |
| DE3317194A1 (de) * | 1983-05-11 | 1984-11-15 | Henkel KGaA, 4000 Düsseldorf | Polyurethan-prepolymere auf basis oleochemischer polyole, ihre herstellung und verwendung |
| DE3626223A1 (de) * | 1986-08-02 | 1988-02-04 | Henkel Kgaa | Polyurethan-praepolymere auf basis oleochemischer polyole, ihre herstellung und verwendung |
| US5300535A (en) * | 1988-10-25 | 1994-04-05 | Asahi Glass Company Ltd. | Method for producing polyurethane flexible foam |
| JP3097854B2 (ja) * | 1989-05-12 | 2000-10-10 | 旭硝子株式会社 | ポリウレタン類の製造方法 |
| US5053534A (en) * | 1990-10-11 | 1991-10-01 | Westvaco Corporation | Process for making a dicarboxylic acid |
| US5194640A (en) * | 1991-06-10 | 1993-03-16 | Westvaco Corporation | Process for making high-purity oleic acid |
| DE4315841A1 (de) * | 1993-05-12 | 1994-11-17 | Bayer Ag | Harte hyrophobe Polyurethane |
| US5470813A (en) * | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5482908A (en) * | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5525702A (en) * | 1995-05-18 | 1996-06-11 | The Dow Chemical Company | Biodegradable alkylene oxide-lactone copolymers |
| US5627122A (en) * | 1995-07-24 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| US5740367A (en) * | 1995-11-03 | 1998-04-14 | Spilo; Michael L. | Method and apparatus for improving the throughput of a local area network |
| US5639705A (en) * | 1996-01-19 | 1997-06-17 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts and methods for making them |
| US5627120A (en) * | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5714428A (en) * | 1996-10-16 | 1998-02-03 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing functionalized polymers |
| US5783513A (en) * | 1997-03-13 | 1998-07-21 | Arco Chemical Technology, L.P. | Process for making double metal cyanide catalysts |
| US6121398A (en) * | 1997-10-27 | 2000-09-19 | University Of Delaware | High modulus polymers and composites from plant oils |
| US6107433A (en) * | 1998-11-06 | 2000-08-22 | Pittsburg State University | Process for the preparation of vegetable oil-based polyols and electroninsulating casting compounds created from vegetable oil-based polyols |
| DE19928156A1 (de) * | 1999-06-19 | 2000-12-28 | Bayer Ag | Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume |
| US6423662B1 (en) * | 1999-07-09 | 2002-07-23 | Dow Global Technologies Inc. | Incipient wetness method for making metal-containing cyanide catalysts |
| US6429166B1 (en) * | 2000-05-19 | 2002-08-06 | Dow Global Technologies Inc. | Method for preparing metal cyanide catalyst/polyol initiator slurries |
| DE10122020A1 (de) * | 2001-05-07 | 2002-11-14 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| MY139564A (en) * | 2003-04-25 | 2009-10-30 | Dow Global Technologies Inc | Polyurethane foams made from hydroxymethyl-containing polyester polyols |
| ATE388177T1 (de) * | 2003-04-25 | 2008-03-15 | Dow Global Technologies Inc | Auf pflanzenöl basierende polyole und verfahren zu seiner herstellung |
-
2005
- 2005-10-24 JP JP2007539026A patent/JP2008518088A/ja active Pending
- 2005-10-24 RU RU2007119396/04A patent/RU2007119396A/ru not_active Application Discontinuation
- 2005-10-24 WO PCT/US2005/038220 patent/WO2006047436A1/en not_active Ceased
- 2005-10-24 KR KR1020077009345A patent/KR101315527B1/ko not_active Expired - Fee Related
- 2005-10-24 CA CA2580569A patent/CA2580569C/en not_active Expired - Fee Related
- 2005-10-24 CN CN2005800367842A patent/CN101048441B/zh not_active Expired - Fee Related
- 2005-10-24 DE DE602005019906T patent/DE602005019906D1/de not_active Expired - Lifetime
- 2005-10-24 MY MYPI20054982A patent/MY144025A/en unknown
- 2005-10-24 AU AU2005299522A patent/AU2005299522B2/en not_active Ceased
- 2005-10-24 US US11/664,463 patent/US20080125569A1/en not_active Abandoned
- 2005-10-24 ES ES05817318T patent/ES2338803T3/es not_active Expired - Lifetime
- 2005-10-24 KR KR1020137015892A patent/KR101386288B1/ko not_active Expired - Fee Related
- 2005-10-24 EP EP05817318A patent/EP1807466B1/en not_active Expired - Lifetime
- 2005-10-24 MX MX2007004969A patent/MX2007004969A/es active IP Right Grant
- 2005-10-24 AT AT05817318T patent/ATE460450T1/de not_active IP Right Cessation
- 2005-10-24 BR BRPI0516890-2A patent/BRPI0516890A/pt not_active IP Right Cessation
- 2005-10-25 AR ARP050104460A patent/AR051606A1/es not_active Application Discontinuation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4543369A (en) * | 1982-09-07 | 1985-09-24 | Henkel Corporation | Alkoxylated polyester polyols and polyurethanes made therefrom |
| JPH05163342A (ja) * | 1991-12-11 | 1993-06-29 | Asahi Glass Co Ltd | ポリエーテル類の製造方法 |
| US20030204045A1 (en) * | 2001-05-02 | 2003-10-30 | Jorg Hofmann | Double-metal cyanide catalysts for preparing polyether polyols |
| WO2004067633A1 (ja) * | 2003-01-28 | 2004-08-12 | Asahi Glass Company, Limited | ポリエーテルポリオール組成物およびその用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| AR051606A1 (es) | 2007-01-24 |
| EP1807466A1 (en) | 2007-07-18 |
| KR101386288B1 (ko) | 2014-04-17 |
| RU2007119396A (ru) | 2008-12-10 |
| CN101048441A (zh) | 2007-10-03 |
| AU2005299522B2 (en) | 2010-11-25 |
| BRPI0516890A (pt) | 2008-09-23 |
| MX2007004969A (es) | 2007-06-14 |
| ATE460450T1 (de) | 2010-03-15 |
| CN101048441B (zh) | 2010-11-03 |
| ES2338803T3 (es) | 2010-05-12 |
| JP2008518088A (ja) | 2008-05-29 |
| CA2580569A1 (en) | 2006-05-04 |
| DE602005019906D1 (de) | 2010-04-22 |
| WO2006047436A1 (en) | 2006-05-04 |
| CA2580569C (en) | 2013-11-19 |
| US20080125569A1 (en) | 2008-05-29 |
| MY144025A (en) | 2011-07-29 |
| EP1807466B1 (en) | 2010-03-10 |
| KR20070083789A (ko) | 2007-08-24 |
| KR20130077902A (ko) | 2013-07-09 |
| AU2005299522A1 (en) | 2006-05-04 |
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