RU2005130515A - Диспергаторы в нанокомпозитах - Google Patents

Диспергаторы в нанокомпозитах Download PDF

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Publication number
RU2005130515A
RU2005130515A RU2005130515/04A RU2005130515A RU2005130515A RU 2005130515 A RU2005130515 A RU 2005130515A RU 2005130515/04 A RU2005130515/04 A RU 2005130515/04A RU 2005130515 A RU2005130515 A RU 2005130515A RU 2005130515 A RU2005130515 A RU 2005130515A
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RU
Russia
Prior art keywords
component
composition according
filler
free radical
radical polymerization
Prior art date
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RU2005130515/04A
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English (en)
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RU2404208C2 (ru
Inventor
Грейм МОАД (AU)
Грейм МОАД
Джорж Филип САЙМОН (AU)
Джорж Филип САЙМОН
Кэтрин Мари ДИН (AU)
Кэтрин Мари ДИН
Гуосинь ЛИ (AU)
Гуосинь ЛИ
Рошан Тиррел Антон МАЯДАННЕ (AU)
Рошан Тиррел Антон МАЯДАННЕ
Хендрик ВЕРМТЕР (DE)
Хендрик ВЕРМТЕР
Рудольф ПФЭНДНЕР (DE)
Рудольф ПФЭНДНЕР
Original Assignee
Полимерс Острейлиа Пти. Лимитед (Au)
Полимерс Острейлиа Пти. Лимитед
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Publication of RU2005130515A publication Critical patent/RU2005130515A/ru
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Publication of RU2404208C2 publication Critical patent/RU2404208C2/ru

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66—Substances characterised by their function in the composition

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Polymerisation Methods In General (AREA)

Claims (17)

1. Композиция, включающая
а) синтетический полимер,
б) наполнитель и
в) диспергатор, полученный регулируемой свободно-радикальной полимеризацией (РСРП).
2. Композиция по п.1, в которой компонент (а) представляет собой полиолефин.
3. Композиция по п.1, в которой компонент (б) представляет собой наполнитель в виде наночастиц.
4. Композиция по п.1, в которой компонент (б) представляет собой природный или синтетический филлосиликат или смесь таких филлосиликатов.
5. Композиция по п.1, в которой компонент (б) представляет собой слоистую силикатную глину.
6. Композиция по п.1, в которой компонент (б) представляет собой монтмориллонит, бентонит, бейделлит, слюду, гекторит, сапонит, нонтронит, соконит, вермикулит, ледикит, магадит, кенияит, стевенсит, волконскоит, гидроталькит или их смесь.
7. Композиция по п.1, в которой компонент (в) представляет собой статистический, блочный, звездообразный или гребенчатый сополимер, полученный регулируемой свободно-радикальной полимеризацией.
8. Композиция по п.1, в которой компонент (в) представляет собой блочный или гребенчатый акриловый сополимер, полученный регулируемой свободно-радикальной полимеризацией.
9. Композиция по п.1, в которой компонент (б) содержится в количестве от 0,1 до 40% в пересчете на массу компонента (а).
10. Композиция по п.1, в которой компонент (в) содержится в количестве от 0,1 до 20% в пересчете на массу компонента (а).
11. Композиция по п.1, включающая, кроме компонентов (а), (б) и (в), дополнительные добавки.
12. Композиция по п.11, включающая в качестве дополнительных добавок фенольные антиоксиданты, светостабилизаторы, стабилизаторы для переработки, растворители, пигменты, красители, пластификаторы, агенты, улучшающие совместимость, добавки, повышающие ударную прочность, и/или тиксотропные добавки.
13. Композиция по п.1 в форме маточной смеси или концентрата, включающая компонент (а) в количестве от 5 до 90%, компонент (б) в количестве от 5 до 80% и компонент (в) в количестве от 0,5 до 50 мас.%.
14. Способ приготовления синтетического полимерного нанокомпозитного материала, включающий смешение в расплаве смеси а) синтетического полимера, б) наполнителя и в) диспергатора, полученного регулируемой свободно-радикальной полимеризацией (РСРП).
15. Способ по п.14, в котором смешение в расплаве проводят в пределах от 120 до 290°С.
16. Синтетический полимерный нанокомпозит, приготовленный согласно способу по п.14.
17. Применение диспергатора, полученного регулируемой свободно-радикальной полимеризацией, для интеркаляции и расслаивания наполнителя и диспергирования наполнителя в синтетической полимерной матрице с получением нанокомпозитного материала.
RU2005130515/05A 2003-03-03 2004-02-23 Диспергаторы в нанокомпозитах RU2404208C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03405141 2003-03-03
EP03405141.7 2003-03-03

Publications (2)

Publication Number Publication Date
RU2005130515A true RU2005130515A (ru) 2006-04-27
RU2404208C2 RU2404208C2 (ru) 2010-11-20

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Family Applications (1)

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Country Status (12)

Country Link
US (2) US7837899B2 (ru)
EP (1) EP1599500A1 (ru)
JP (1) JP4795227B2 (ru)
KR (1) KR101111146B1 (ru)
CN (1) CN100558806C (ru)
AR (1) AR043446A1 (ru)
AU (1) AU2004218252B2 (ru)
BR (1) BRPI0408020A (ru)
CA (1) CA2517851C (ru)
RU (1) RU2404208C2 (ru)
TW (1) TW200427747A (ru)
WO (1) WO2004078785A1 (ru)

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WO2004078785A1 (en) 2004-09-16
AU2004218252A1 (en) 2004-09-16
US20070072979A1 (en) 2007-03-29
JP4795227B2 (ja) 2011-10-19
CN1756766A (zh) 2006-04-05
US7837899B2 (en) 2010-11-23
CA2517851A1 (en) 2004-09-16
CA2517851C (en) 2012-11-06
JP2007527927A (ja) 2007-10-04
US20110028633A1 (en) 2011-02-03
TW200427747A (en) 2004-12-16
AR043446A1 (es) 2005-07-27
KR101111146B1 (ko) 2012-02-17
EP1599500A1 (en) 2005-11-30
CN100558806C (zh) 2009-11-11
RU2404208C2 (ru) 2010-11-20
KR20050109955A (ko) 2005-11-22
AU2004218252B2 (en) 2011-04-28
WO2004078785A8 (en) 2007-11-08

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