RU2004114558A - Поливинилбутиральная пленка (пвб-пленка) для триплекса триплексная область техники - Google Patents

Поливинилбутиральная пленка (пвб-пленка) для триплекса триплексная область техники Download PDF

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Publication number
RU2004114558A
RU2004114558A RU2004114558/04A RU2004114558A RU2004114558A RU 2004114558 A RU2004114558 A RU 2004114558A RU 2004114558/04 A RU2004114558/04 A RU 2004114558/04A RU 2004114558 A RU2004114558 A RU 2004114558A RU 2004114558 A RU2004114558 A RU 2004114558A
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Russia
Prior art keywords
film
adhesion
plasticizer
additive
group
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RU2004114558/04A
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English (en)
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Уве КЕЛЛЕР (DE)
Уве КЕЛЛЕР
Хольгер ШТЕНЦЕЛЬ (DE)
Хольгер ШТЕНЦЕЛЬ
Манфред ХОСС (DE)
Манфред ХОСС
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Курарей Спешиэлитиз Юроп ГмбХ (DE)
Курарей Спешиэлитиз Юроп ГмбХ
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Publication of RU2004114558A publication Critical patent/RU2004114558A/ru

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10688—Adjustment of the adherence to the glass layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10816—Making laminated safety glass or glazing; Apparatus therefor by pressing
    • B32B17/10825—Isostatic pressing, i.e. using non rigid pressure-exerting members against rigid parts
    • B32B17/10834—Isostatic pressing, i.e. using non rigid pressure-exerting members against rigid parts using a fluid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645—Next to addition polymer from unsaturated monomers
    • Y10T428/31649—Ester, halide or nitrile of addition polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Glass Compositions (AREA)

Claims (7)

1. Пленка на основе содержащего пластификатор частично ацеталированного поливинилового спирта для применения в качестве промежуточного слоя в триплексах, содержащая от 0,001 до 0,25 мас.% от общего состава пленки одной или нескольких добавок, понижающих адгезию пленки на поверхности стекла, выбранных из группы, состоящей из
магниевых солей органических кислот,
кальциевых солей органических кислот,
и добавку, компенсирующую колебания адгезии, содержащую одно или несколько соединений фосфора, выбранных из группы, состоящей из
симметричных или асимметричных триэфиров фосфористой кислоты с арильными или арилалкильными и/или алкильными заместителями,
симметричных или асимметричных триэфиров ортофосфорной кислоты с арильными или арилалкильными и/или алкильными заместителями
причем соединения фосфора добавлены в таком количестве, что
охарактеризованный в описании показатель проколачивания композиционного стекла, полученного с промежуточным слоем пленки, в каждом из следующих случаев
после стандартного способа автоклавирования в течение 90 мин,
после продленного способа автоклавирования в течение 330 мин и
после выдерживания при тепловом воздействии при 125°С в течение 72 ч,
на обеих сторонах стекла находится в области значений более или равных 1,5 и менее или равных 8, и
охарактеризованный в описании максимальный Δ-показатель проколачивания имеет значение менее или равное 2,5.
2. Пленка по п.1, отличающаяся тем, что в качестве добавки, понижающей адгезию пленки на поверхности стекла, используют октаноат магния в концентрации от 0,001 до 0,2 мас.% от общего состава пленки.
3. Пленка по п.2, отличающаяся тем, что в качестве пластификатора использован пластификатор 3G8, 3G7 или ДГА, а октаноат магния использован в количестве:
от 0,01 до 0,1 мас.% от общего состава пленки при использовании пластификатора 3G8,
от 0,005 до 0,05 мас.% от общего состава пленки при использовании пластификатора 3G7,
от 0,005 до 0,05 мас.% от общего состава пленки при использовании пластификатора ДГА,
в количестве, соответствующем промежуточному значению количества магний-2-этилгексаноата от общего состава пленки, при использовании смеси пластификаторов.
4. Пленка п.1, отличающаяся тем, что в качестве добавки, компенсирующей колебания адгезии, использованы один или несколько фосфитов из группы, состоящей из трис-(нонилфенил)-фосфита, трифенилфосфита и дифенилоктилфосфита в концентрации от 0,05 до 0,5 мас.%.
5. Пленка по п.4, отличающаяся тем, что в качестве добавки, компенсирующей колебания адгезии, использован трис(нолилфенил)фосфит, трифенилфосфит и/или дифенилоктилфосфит в концентрации от 0,1 до 0,2 мас.%.
6. Ламинат, включающий, по меньшей мере, один слой силикатного стекла, а также пленку по 1, или 2, или 3, или 4, или 5.
7. Применение соединений фосфора, выбранных из группы, состоящей из
симметричных или асимметричных триэфиров фосфористой кислоты с арильными или арилалкильными и/или алкильными заместителями,
симметричных или асимметричных триэфиров ортофосфорной кислоты с арильными или арилалкильными и/или алкильными заместителями, в качестве добавки, компенсирующей колебания адгезии при дальнейшей обработке, в пленках на основе содержащего пластификатор частично ацеталированного поливинилового спирта.
RU2004114558/04A 2001-10-11 2002-10-10 Поливинилбутиральная пленка (пвб-пленка) для триплекса триплексная область техники RU2004114558A (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10150091.2 2001-10-11
DE10150091A DE10150091A1 (de) 2001-10-11 2001-10-11 PVB-Folie für Verbundsicherheitsglas und Verbundsicherheitsglas

Publications (1)

Publication Number Publication Date
RU2004114558A true RU2004114558A (ru) 2005-10-27

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Country Status (9)

Country Link
US (1) US20050256258A1 (ru)
EP (1) EP1470182B8 (ru)
JP (1) JP2005505670A (ru)
AT (1) ATE292654T1 (ru)
DE (3) DE10150091A1 (ru)
ES (1) ES2240818T3 (ru)
RU (1) RU2004114558A (ru)
UA (1) UA77450C2 (ru)
WO (1) WO2003033583A1 (ru)

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ES2240818T3 (es) 2005-10-16
DE10294709D2 (de) 2004-09-16
DE10150091A1 (de) 2003-04-17
JP2005505670A (ja) 2005-02-24
EP1470182B8 (de) 2005-06-01
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EP1470182A1 (de) 2004-10-27
US20050256258A1 (en) 2005-11-17

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