RU2004114558A - Поливинилбутиральная пленка (пвб-пленка) для триплекса триплексная область техники - Google Patents

Поливинилбутиральная пленка (пвб-пленка) для триплекса триплексная область техники Download PDF

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RU2004114558A
RU2004114558A RU2004114558/04A RU2004114558A RU2004114558A RU 2004114558 A RU2004114558 A RU 2004114558A RU 2004114558/04 A RU2004114558/04 A RU 2004114558/04A RU 2004114558 A RU2004114558 A RU 2004114558A RU 2004114558 A RU2004114558 A RU 2004114558A
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film
adhesion
plasticizer
additive
group
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RU2004114558/04A
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Уве КЕЛЛЕР (DE)
Уве КЕЛЛЕР
Хольгер ШТЕНЦЕЛЬ (DE)
Хольгер ШТЕНЦЕЛЬ
Манфред ХОСС (DE)
Манфред ХОСС
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Курарей Спешиэлитиз Юроп ГмбХ (DE)
Курарей Спешиэлитиз Юроп ГмбХ
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Publication of RU2004114558A publication Critical patent/RU2004114558A/ru

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10688Adjustment of the adherence to the glass layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10816Making laminated safety glass or glazing; Apparatus therefor by pressing
    • B32B17/10825Isostatic pressing, i.e. using non rigid pressure-exerting members against rigid parts
    • B32B17/10834Isostatic pressing, i.e. using non rigid pressure-exerting members against rigid parts using a fluid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/14Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645Next to addition polymer from unsaturated monomers
    • Y10T428/31649Ester, halide or nitrile of addition polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Glass Compositions (AREA)

Claims (7)

1. Пленка на основе содержащего пластификатор частично ацеталированного поливинилового спирта для применения в качестве промежуточного слоя в триплексах, содержащая от 0,001 до 0,25 мас.% от общего состава пленки одной или нескольких добавок, понижающих адгезию пленки на поверхности стекла, выбранных из группы, состоящей из
магниевых солей органических кислот,
кальциевых солей органических кислот,
и добавку, компенсирующую колебания адгезии, содержащую одно или несколько соединений фосфора, выбранных из группы, состоящей из
симметричных или асимметричных триэфиров фосфористой кислоты с арильными или арилалкильными и/или алкильными заместителями,
симметричных или асимметричных триэфиров ортофосфорной кислоты с арильными или арилалкильными и/или алкильными заместителями
причем соединения фосфора добавлены в таком количестве, что
охарактеризованный в описании показатель проколачивания композиционного стекла, полученного с промежуточным слоем пленки, в каждом из следующих случаев
после стандартного способа автоклавирования в течение 90 мин,
после продленного способа автоклавирования в течение 330 мин и
после выдерживания при тепловом воздействии при 125°С в течение 72 ч,
на обеих сторонах стекла находится в области значений более или равных 1,5 и менее или равных 8, и
охарактеризованный в описании максимальный Δ-показатель проколачивания имеет значение менее или равное 2,5.
2. Пленка по п.1, отличающаяся тем, что в качестве добавки, понижающей адгезию пленки на поверхности стекла, используют октаноат магния в концентрации от 0,001 до 0,2 мас.% от общего состава пленки.
3. Пленка по п.2, отличающаяся тем, что в качестве пластификатора использован пластификатор 3G8, 3G7 или ДГА, а октаноат магния использован в количестве:
от 0,01 до 0,1 мас.% от общего состава пленки при использовании пластификатора 3G8,
от 0,005 до 0,05 мас.% от общего состава пленки при использовании пластификатора 3G7,
от 0,005 до 0,05 мас.% от общего состава пленки при использовании пластификатора ДГА,
в количестве, соответствующем промежуточному значению количества магний-2-этилгексаноата от общего состава пленки, при использовании смеси пластификаторов.
4. Пленка п.1, отличающаяся тем, что в качестве добавки, компенсирующей колебания адгезии, использованы один или несколько фосфитов из группы, состоящей из трис-(нонилфенил)-фосфита, трифенилфосфита и дифенилоктилфосфита в концентрации от 0,05 до 0,5 мас.%.
5. Пленка по п.4, отличающаяся тем, что в качестве добавки, компенсирующей колебания адгезии, использован трис(нолилфенил)фосфит, трифенилфосфит и/или дифенилоктилфосфит в концентрации от 0,1 до 0,2 мас.%.
6. Ламинат, включающий, по меньшей мере, один слой силикатного стекла, а также пленку по 1, или 2, или 3, или 4, или 5.
7. Применение соединений фосфора, выбранных из группы, состоящей из
симметричных или асимметричных триэфиров фосфористой кислоты с арильными или арилалкильными и/или алкильными заместителями,
симметричных или асимметричных триэфиров ортофосфорной кислоты с арильными или арилалкильными и/или алкильными заместителями, в качестве добавки, компенсирующей колебания адгезии при дальнейшей обработке, в пленках на основе содержащего пластификатор частично ацеталированного поливинилового спирта.
RU2004114558/04A 2001-10-11 2002-10-10 Поливинилбутиральная пленка (пвб-пленка) для триплекса триплексная область техники RU2004114558A (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10150091.2 2001-10-11
DE10150091A DE10150091A1 (de) 2001-10-11 2001-10-11 PVB-Folie für Verbundsicherheitsglas und Verbundsicherheitsglas

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RU2004114558A true RU2004114558A (ru) 2005-10-27

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US (1) US20050256258A1 (ru)
EP (1) EP1470182B8 (ru)
JP (1) JP2005505670A (ru)
AT (1) ATE292654T1 (ru)
DE (3) DE10150091A1 (ru)
ES (1) ES2240818T3 (ru)
RU (1) RU2004114558A (ru)
UA (1) UA77450C2 (ru)
WO (1) WO2003033583A1 (ru)

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US20050256258A1 (en) 2005-11-17
JP2005505670A (ja) 2005-02-24
EP1470182B8 (de) 2005-06-01
DE10294709D2 (de) 2004-09-16
DE50202750D1 (de) 2005-05-12
EP1470182A1 (de) 2004-10-27
UA77450C2 (en) 2006-12-15
DE10150091A1 (de) 2003-04-17

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