RU2001114511A - Катализатор и способ получения 1,3-пропандиола - Google Patents
Катализатор и способ получения 1,3-пропандиолаInfo
- Publication number
- RU2001114511A RU2001114511A RU2001114511/04A RU2001114511A RU2001114511A RU 2001114511 A RU2001114511 A RU 2001114511A RU 2001114511/04 A RU2001114511/04 A RU 2001114511/04A RU 2001114511 A RU2001114511 A RU 2001114511A RU 2001114511 A RU2001114511 A RU 2001114511A
- Authority
- RU
- Russia
- Prior art keywords
- weight
- composition
- catalyst
- catalyst composition
- zinc
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 19
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-Propanediol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 title claims 13
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 239000000203 mixture Substances 0.000 claims 31
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 8
- 229910052791 calcium Inorganic materials 0.000 claims 8
- 239000011575 calcium Substances 0.000 claims 8
- 230000003197 catalytic Effects 0.000 claims 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 8
- 229910052750 molybdenum Inorganic materials 0.000 claims 8
- 239000011733 molybdenum Substances 0.000 claims 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 8
- 229910052725 zinc Inorganic materials 0.000 claims 8
- 239000011701 zinc Substances 0.000 claims 8
- 229910052759 nickel Inorganic materials 0.000 claims 7
- AKXKFZDCRYJKTF-UHFFFAOYSA-N 3-hydroxypropanal Chemical compound OCCC=O AKXKFZDCRYJKTF-UHFFFAOYSA-N 0.000 claims 6
- 229910052782 aluminium Inorganic materials 0.000 claims 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 6
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims 6
- 239000000047 product Substances 0.000 claims 4
- 239000007787 solid Substances 0.000 claims 4
- LIVNPJMFVYWSIS-UHFFFAOYSA-N Silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims 3
- 239000007864 aqueous solution Substances 0.000 claims 3
- 239000011230 binding agent Substances 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 238000005984 hydrogenation reaction Methods 0.000 claims 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 3
- 229910052749 magnesium Inorganic materials 0.000 claims 3
- 239000011777 magnesium Substances 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 150000004760 silicates Chemical class 0.000 claims 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 3
- 229910052726 zirconium Inorganic materials 0.000 claims 3
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 238000007037 hydroformylation reaction Methods 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 238000005755 formation reaction Methods 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
Claims (10)
1. Каталитическая композиция в виде твердых гранул, содержащая: a) компонент активного никеля, в котором никель составляет 25 - 60 мас.% от композиции катализатора; b) молибденовый компонент, в котором содержание молибдена составляет 5 - 20 мас.% от композиции катализатора, и c) 10 - 50 мас.% в расчете на вес композиции катализатора, материала и связующего, содержащего по меньшей мере один из оксидов кремния и силикаты и оксиды цинка, алюминия, циркония, магния и кальция, причем каждый из указанных алюминия, кальция и цинка присутствует в количестве не больше, чем 2 мас.% в расчете на вес каталитической композиции.
2. Каталитическая композиция по п.1, в которой молибден составляет 6 - 16 мас.% от композиции катализатора.
3. Каталитическая композиция по п.1 или 2, в которой диаметр частиц меньше, чем 0,32 см.
4. Каталитическая композиция по любому из пп.1, 2 или 3, в которой никель составляет 25 - 45 мас.% от композиции катализатора.
5. Каталитическая композиция по любому из предшествующих пунктов, в которой каждый из цинка и кальция присутствует в количестве не больше, чем 1 мас.% в расчете на вес каталитической композиции.
6. Способ получения 1,3-пропандиола, включающий: а) контактирование 3-гидроксипропаналя и водорода в водной реакционной смеси при температуре по меньшей мере 30°С в присутствии твердой гранулированной каталитической композиции, содержащей i) компонент активного никеля, в котором никель составляет 25 - 60 мас.% от композиции катализатора; ii) молибденовый компонент, в котором содержание молибдена составляет 5 - 20 мас.% от каталитической композиции; и iii) 10 - 50 мас.% в расчете на вес каталитической композиции, материала связующего, содержащего по меньшей мере один из оксидов кремния и силикаты и оксиды цинка, алюминия, циркония, магния и кальция, причем каждый из указанных алюминия, кальция и цинка присутствует в количестве не больше, чем 2 мас.%, в расчете на вес каталитической композиции, с образованием водной смеси продуктов, содержащей 1,3-пропандиол, и b) выделение 1,3-пропандиола из водной смеси продуктов.
7. Способ по п.6, в котором молибден составляет 6 - 16 мас.% от композиции катализатора.
8. Способ по п.6 или 7, в котором диаметр твердых частиц меньше, чем 0,32 см.
9. Способ по любому из пп.6, 7 или 8, в котором в каталитической композиции каждый из цинка и кальция присутствует в количестве не больше, чем 1 мас.%, в расчете на вес каталитической композиции.
10. Способ получения 1,3-пропандиола, включающий: а) контактирование этиленоксида с монооксидом углерода и водородом в условиях гидроформилирования и в присутствии эффективного количества катализатора гидроформилирования, с образованием смеси продуктов реакции, содержащей 3-гидрокси-пропаналь, b) удаление 3-гидроксипропаналя из смеси продуктов реакции с образованием водного раствора 3-гидроксипропаналя; c) добавление в водный раствор 3-гидроксипропаналя твердой гранулированной композиции катализатора гидрирования, содержащей i) компонент активного никеля, в котором никель составляет 25 - 60 мас.% от композиции катализатора; ii) молибденовый компонент, в котором содержание молибдена составляет 5 - 20 мас.% от каталитической композиции, и iii) 10 - 50 мас.% в расчете на вес каталитической композиции, материала связующего, содержащего по меньшей мере один из оксидов кремния и силикаты и оксиды цинка, алюминия, циркония, магния и кальция, причем каждый из указанных алюминия, кальция и цинка присутствует в количестве не больше, чем 2 мас.% в расчете на вес каталитической композиции, d) нагревание водного раствора 3-гидроксипропаналя до температуры по меньшей мере 30°С, при избыточном давлении водорода по меньшей мере 68948 кПа, для получения смеси продуктов гидрирования, содержащей 1,3-пропандиол; и e) выделение 1,3-пропандиола из смеси продуктов гидрирования.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/182,380 | 1998-10-29 | ||
| US09/182,380 US5945570A (en) | 1998-10-29 | 1998-10-29 | Catalyst and process for preparing 1,3-propanediol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2001114511A true RU2001114511A (ru) | 2003-08-10 |
| RU2232048C2 RU2232048C2 (ru) | 2004-07-10 |
Family
ID=22668216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2001114511/04A RU2232048C2 (ru) | 1998-10-29 | 1999-10-26 | Катализатор и способ получения 1,3-пропандиола |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US5945570A (ru) |
| EP (1) | EP1131155B1 (ru) |
| JP (1) | JP2002528261A (ru) |
| KR (1) | KR100615774B1 (ru) |
| CN (1) | CN1145528C (ru) |
| AT (1) | ATE302060T1 (ru) |
| AU (1) | AU1377300A (ru) |
| BR (1) | BR9914879A (ru) |
| CA (1) | CA2348006C (ru) |
| DE (1) | DE69926781T2 (ru) |
| ID (1) | ID28540A (ru) |
| MY (1) | MY123258A (ru) |
| NO (1) | NO20012088L (ru) |
| PL (1) | PL347502A1 (ru) |
| RU (1) | RU2232048C2 (ru) |
| TR (1) | TR200101152T2 (ru) |
| WO (1) | WO2000025914A1 (ru) |
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| US5210318A (en) * | 1990-05-04 | 1993-05-11 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes |
| US5093537A (en) * | 1991-07-24 | 1992-03-03 | Hoechst Celanese Corporation | Method for the manufacture of 1,3-propanediol |
| DE4218282A1 (de) * | 1992-06-03 | 1993-12-09 | Degussa | Verfahren zur Herstellung von 1,3-Propandiol |
| US5332490A (en) * | 1992-09-28 | 1994-07-26 | Texaco Inc. | Catalytic process for dewaxing hydrocarbon feedstocks |
| US5304691A (en) * | 1993-07-13 | 1994-04-19 | Shell Oil Company | Process for making 1,3-propanediol and 3-hydroxypropanal |
| US5256827A (en) * | 1993-02-05 | 1993-10-26 | Shell Oil Company | Process for making 3-hydroxypropanal and 1,3-propanediol |
| US5344993A (en) * | 1993-10-01 | 1994-09-06 | Shell Oil Company | Process or making 3-hydroxyaldehydes |
| US5902767A (en) * | 1993-08-03 | 1999-05-11 | Mobil Oil Corporation | Catalyst having an acidic solid oxide component and a group IB metal or metal oxide component |
| US5463145A (en) * | 1994-09-30 | 1995-10-31 | Shell Oil Company | Process for preparing 1,3-propanediol |
| US5525211A (en) * | 1994-10-06 | 1996-06-11 | Texaco Inc. | Selective hydrodesulfurization of naphtha using selectively poisoned hydroprocessing catalyst |
| US6030915A (en) * | 1996-03-11 | 2000-02-29 | Akzo Nobel N.V. | Process for preparing a large pore hydroprocessing catalyst |
| US5786524A (en) * | 1996-05-30 | 1998-07-28 | Shell Oil Company | Process for preparation of 1,3-propanediol via hydrogenation of 3-hydroxypropanal |
| EP0848992B1 (fr) * | 1996-12-17 | 2002-03-27 | Institut Francais Du Petrole | Catalyseur contenant du bore et du silicium et son utilisation en hydrotraitement de charges hydrocarbonées |
-
1998
- 1998-10-29 US US09/182,380 patent/US5945570A/en not_active Expired - Fee Related
-
1999
- 1999-06-14 US US09/332,460 patent/US6342464B1/en not_active Expired - Fee Related
- 1999-10-26 AU AU13773/00A patent/AU1377300A/en not_active Abandoned
- 1999-10-26 EP EP99971350A patent/EP1131155B1/en not_active Expired - Lifetime
- 1999-10-26 CN CNB998138525A patent/CN1145528C/zh not_active Expired - Fee Related
- 1999-10-26 WO PCT/EP1999/008163 patent/WO2000025914A1/en active IP Right Grant
- 1999-10-26 BR BR9914879-0A patent/BR9914879A/pt active Search and Examination
- 1999-10-26 TR TR2001/01152T patent/TR200101152T2/xx unknown
- 1999-10-26 KR KR1020017005336A patent/KR100615774B1/ko not_active IP Right Cessation
- 1999-10-26 JP JP2000579345A patent/JP2002528261A/ja active Pending
- 1999-10-26 RU RU2001114511/04A patent/RU2232048C2/ru not_active IP Right Cessation
- 1999-10-26 ID IDW00200100932A patent/ID28540A/id unknown
- 1999-10-26 PL PL99347502A patent/PL347502A1/xx not_active Application Discontinuation
- 1999-10-26 AT AT99971350T patent/ATE302060T1/de not_active IP Right Cessation
- 1999-10-26 DE DE69926781T patent/DE69926781T2/de not_active Expired - Fee Related
- 1999-10-26 CA CA002348006A patent/CA2348006C/en not_active Expired - Fee Related
- 1999-10-27 MY MYPI99004637A patent/MY123258A/en unknown
-
2001
- 2001-04-27 NO NO20012088A patent/NO20012088L/no not_active Application Discontinuation
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